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Oxidation Resistance Of An Atomically Flat Cu(111) Surface: A First-Principles Study, Bipin Lamichhane

Theses and Dissertations

The first-principles calculation based on density functional theory (DFT) was used to study the oxidation resistance of atomically flat and atomic-step edges of Cu(111), diffusion of Cu atoms in different surfaces of alumina and interface properties of alumina and Cu(111), and magnetic properties of Mn-substituted strontium hexaferrite. The dissociation of oxygen molecules is the primary reason for the corrosion of metals, which deteriorates their application. Cu(111) flat surface, mono-atomic, and multi-atomic step edges were used to study oxygen diffusion. Penetration of oxygen on a Cu(111) flat surface requires high energy, indicating oxidation resistance. Our DFT result of oxygen diffusion into …

Origin And Structure Of The First Sharp Diffraction Peak Of Amorphous Solids, Devilal Dahal

Dissertations

Several explanations have been reported in the literature about the origin of extended-range oscillations (EROs) in the atomic pair-correlation function of amorphous materials. Although the radial ordering beyond the short-range order of about 5 Å has been extensively studied in amorphous materials, the exact nature of the radial ordering beyond a nanometer is still not resolved. This dissertation address this problem and explains the nature of the EROs by using high-quality models of amorphous silicon (a-Si) obtained from Monte Carlo and Molecular Dynamics simulations. The extended-range ordering in a-Si is examined through radial oscillations on the length …

Generalized Langer Correction And The Exactness Of Wkb For All Conventional Potentials, Asim Gangopadhyaya, Jonathan Bougie, Constantin Rasinariu

Physics: Faculty Publications and Other Works

In this paper we investigate the exactness of the WKB quantization condition for translationally shape invariant systems. In particular, using the formalism of supersymmetric quantum mechanics, we generalize the Langer correction and show that it generates the exact quantization condition for all conventional potentials. We also prove that this correction is related to the previously proven exactness of SWKB for these potentials.

Constraining The Sources Of Ultra-High-Energy Cosmic Rays Across And Above The Ankle With The Spectrum And Composition Data Measured At The Pierre Auger Observatory, A. Abdul Halim, P. Abreu, M. Aglietta, I. Allekotte, K. Almeida Cheminant, A. Almela, B. Fick, D. Nitz, Et Al.

Michigan Tech Publications, Part 1

In this work we present the interpretation of the energy spectrum and mass composition data as measured by the Pierre Auger Collaboration above 6 × 1017 eV. We use an astrophysical model with two extragalactic source populations to model the hardening of the cosmic-ray flux at around 5 × 1018 eV (the so-called "ankle" feature) as a transition between these two components. We find our data to be well reproduced if sources above the ankle emit a mixed composition with a hard spectrum and a low rigidity cutoff. The component below the ankle is required to have a very soft …

Exploring The Interaction Of Minor-Groove-Binder Netropsin With Dna Using Optical Tweezers, Irbazhusain Shaikh

Honors Program Theses and Projects

Netropsin is an antibiotic that binds in the minor grooves of DNA, which also exhibits anticancer properties. There have been many previous studies that explored the binding of this drug to DNA using traditional methods where an ensemble averaging is used. In this study we explore the interaction of Netropsin with DNA at a single molecule level using dual beam optical tweezers. We trapped and stretched a single DNA molecule using optical tweezers to measure the force experienced by the DNA as a function of extension in the absence and presence of various concentrations of Netropsin. Our results show the …

The Future Is Now In Twisted Coil Polymer Actuators (Tcpa), Ryan Ronquillo

Electronic Theses and Dissertations

This thesis aimed to fabricate and test twisted coiled polymer actuators (TCPA) to understand the mechanical and thermal aspects of this artificial muscle fiber. The purpose of this thesis was to find a linear relationship using the LVDT sensor, fabricating TCPA fibers, and interpreting the data. The project tested whether nylon/polymer could be used as a better artificial muscle fiber.

This research accomplished three goals: (1) designing and fabricating a system capable of creating supercoiled muscle fibers consistently, (2) calibrating the Linear Variable Differential Transformer (LVDT) and Core, and (3) analyzing/interpreting the data of the Twisted Coiled Polymer Actuators (TCPA) …

Improvements To Isru For Rocket Fuel Generation, Justin Sharp

James Madison Undergraduate Research Journal (JMURJ)

The development of efficient in-situ resource utilization (ISRU) technologies is crucial for the establishment of an extraterrestrial, self-sustaining colony. The generation of rocket fuel at potential colony locations is necessary to provide the transportation of people and cargo to and from these locations.Three processes are discussed for the improvement of ISRU methods to generate rocket fuel: electrolysis and electrochemical improvements to the process of crude fuel production, physical and chemical methods for separation of gaseous H2 and O2, and materials and cryogenics engineering for storage and transportation of liquid hydrogen (LH2) and liquid oxygen (LOX). Storage and transportation of cryogenics …

Transit Photometry Of Multiple Exoplanet Watch Targets, Jonah Becken

Celebrating Scholarship and Creativity Day (2018-)

Since 1995 exoplanet research has increase dramatically, as a result it is more important than ever to precisely know the dates and times of future transits for repeated observations of a target. NASA’s Exoplanet Watch database and accompanying light curve producing code EXOTIC have the goal of allowing small observatories across the world help find future transits. Under these objective observations of known exoplanet transits where made, using the Saint John’s University observatory, to find the transit midpoint, the ratio of the planet radius and the solar radius, and the period. Using these values, the confirmation that a transit happened …

Search For B Mesogenesis At Babar, J. P. Lees, V. Poireau, E. Grauges, A. Palano, G. Eigen, D. N. Brown, Yu. G. Kolomensky, M. Fritsch, H. Koch, R. Cheaib, C. Hearty, T. S. Mattison, J. A. Mckenna, R. Y. So, V. E. Blinov, A. R. Buzykaev, V. P. Druzhinin, E. A. Kozyrev, Milind Purohit, Et. Al.

Faculty Publications

A new mechanism has been proposed to simultaneously explain the presence of dark matter and the matter-antimatter asymmetry in the Universe. This scenario predicts exotic B-meson decays into a baryon and a dark-sector antibaryon (ψD) with branching fractions accessible at B factories. We present a search for B→Λψ_D decays using data collected by the BABAR experiment at SLAC. This reaction is identified by fully reconstructing the accompanying B meson and requiring the presence of a single Λ baryon in the remaining particles. No significant signal is observed, and bounds on the B→Λψ …

Preparation, Characterization And Electron Yield Analysis On Highly Insulating Granular Particles, Heather Allen

Physics Capstone Projects

This study focuses on obtaining reliable electron yield measurements of highly insulating granular particles of various shape, size, and composition. Measurements of this kind have long been considered too difficult to collect on granular samples due to experimental complexities leading to a critical knowledge gap in the fundamental electrostatic behaviors of dust. A significant portion of this study was spent on preparing and characterizing granular samples before any type of measurement took place. Particles of varying sizes ranging from ~1 μm to ~100 μm, shapes including cubical, spherical, and angular, and composition including NaCl, MgO, Al₂O₃ and …

The Use Of Fluorescence Resonance Energy Transfer And Bent Dna To Study Dna And Ion Interactions, Kaitlin Bullard

Physics Undergraduate Honors Theses

Studying DNA interactions is advantageous to developments in the medical field since DNA and its interactions affect our health greatly. In addition, it is important to understand how the bendability of DNA depends on metal ions, which are essential for various fundamental processes in cells. In this work, we investigate the use of FRET and self-assembled bent DNA molecules to quantify DNA interactions with magnesium ions. We measured that the FRET efficiency increased at higher concentrations of magnesium ions. We also ran simulations to further understand the mechanisms. These observations show that magnesium ions increase the stability and flexibility of …

Fabrication Of Black Phosphorus Terahertz Photoconductive Antennas, Nathan Tanner Sawyers

Physics Undergraduate Honors Theses

Terahertz (THz) photoconductive antennas (PCAs) using 40nm thin-film flakes of black phosphorus (BP) and hexagonal boron nitride (hBN) have been shown computationally to be capable of THz emission comparable to those based on GaAs [2]. In this paper, I briefly describe the scientific and practical interest in THz emissions and explain what warrants research into black phosphorus as a photoconductive semiconductor in THz devices. Furthermore, I outline the basic principle of how these antennas work and mention alternative designs produced by other researchers in the past. Finally, I summarize the fabrication process of these antennas, as well as the measurements …

Automating The Determination Of Tight-Binding Representations For Two-Dimensional Ferroelectrics, Joseph Roll

Physics Undergraduate Honors Theses

Two-dimensional (atomically thin) materials have been greatly explored in the last two decades since the exfoliation of graphene in 2004. Since then, many exotic material properties have been shown for these systems; these new properties often arise from certain crystal symmetries or lack thereof. One of interest is ferroelectricity in which a noncentrosymmetric crystal structure can lead to a switchable intrinsic electric dipole in our material. This can then lead to second-harmonic generation in which two photons enter a material at a given frequency and one photon exits the material at double the original frequency. The study presented here makes …

Exploring Numerical Simulations Of Localized Geomagnetic Disturbances, Elizabeth Vandegriff

Physics Dissertations - Archive

One of the prominent effects of space weather is the formation of rapid geomagnetic field variations on Earth’s surface driven by the magnetosphere-ionosphere system. These Geomagnetic Disturbances (GMDs) cause Geomagnetically Induced Currents (GICs) to run through ground-conducting systems. GMDs can often be high amplitude and small-scale (100-500 kilometers) and we classify these as Localized GMDs (LGMDs). LGMDs are both hazardous to the power grid and difficult to predict. Modeling LGMDs is therefore a critical step for risk mitigation but is complicated due to the dynamic and sometimes highly localized nature of the phenomena. At present, global magnetohydrodynamic (MHD) models of …

Super P-Sulfur Cathodes For Quasi-Solid-State Lithium-Sulfur-Batteries., Milinda Bharatha Kalutara Koralalage

Electronic Theses and Dissertations

Lithium-Sulfur (Li-S) batteries have become a promising candidate to meet the current energy storage demand, with its natural abundance of materials, high theoretical capacity of 1672 mAhg-1, high energy density of 2600 Whkg-1, low cost and lower environmental impact. Sulfide based solid state electrolytes (SSEs) have received greater attention due to their higher ionic conductivity, compatible interface with sulfur-based cathodes, and lower grain boundary resistance. However, the interface between SSEs and cathodes has become a challenge in all solid-state Li-S batteries due to the rigidity of the participating surfaces. A hybrid electrolyte containing SSE coupled with a small amount of …

First Principles Study Of 2d Polar Heterostructures., Safia Abdullah R Alharbi

Electronic Theses and Dissertations

Recently, two-dimensional (2D) heterostructures have attracted extensive attention in nanomaterials science. They have been successfully fabricated and applied to nanotechnology in many fields, such as nanoelectronics, solar cells, sensors, energy stores, quantum information, etc. The most common heterostructures are 2D-lateral heterostructure (LH) and 2D-vertical heterostructure (VH) where each of them exhibits unique features depending on the direction of assembly, i.e., along in-plane or out-of-plane direction. Beyond the van der Waals-VH which possess of van der Waals (vdW) interaction, there are other types of heterostructures made of 2D polar materials that possess different types of chemical bonding nature, e.g., chemical bonds …

Metasurfaces For Holography, Scott Howell

Physics Capstone Projects

Holography uses the interference of light waves to store information about an object, which can then be seen from different angles to create a partial 3D view. A simple experiment can be done using a laser diode, photographic plate, and a set of dice to create a holographic image. The holographic film is thin and can only hold a single image. Reflection holography can create a 3D diffraction pattern and allows more information to be packed into a single medium. Computer generated holograms can be designed to create holograms without a real object to be used in augmented reality. High …

Engineering Lab Building Telescope Manual, Aidan L. Tueller

Physics Capstone Projects

In partnership with Dr. Jan Sojka, head of the Physics Department, a plan was created to make the telescope on top of the Engineering Lab building operational again for either staff, students, classes, or labs to use. The telescope was purchased through funds by Utah NASA Space Grant Consortium. This paper will contain basic information about how to operate the telescope and use its equipment. There is an online manual from Meade that is much longer but goes into much more detail about individual pieces and specific parts of the telescope.

The Quantum Computational Utility Of Symmetry-Protected Topological Order: From Near-Term Advantages To Universal Measurement-Based Quantum Computing, Austin Kevin Daniel

Physics & Astronomy ETDs

Quantum computers offer new avenues to approach difficult problems by taking advantage of the strange and often nonintuitive phenomena present in quantum physics. Though many quantum algorithms are believed or known to outperform the best known classical algorithms, the fundamental mechanism granting them their power remains elusive. In measurement-based quantum computation (MBQC), two key resources have been show to enable universal and provably nonclassical quantum computations, respectively. These are symmetry-protected topological order (SPTO), a notion describing a class of quantum magnets with hidden long-range correlations in their entanglement structure, and quantum contextuality, the fact that a quantum measurement outcome inherently …

Effect On Focusing Fields By Ferromagnetic Cell Cores In Linear Induction Accelerators, Cooper Guillaume

Senior Honors Theses

In the Los Alamos National Laboratories DARHT facility, there are two perpendicular linear induction accelerators, LIAs. The LIAs’ solenoids produce magnetic fields which focus the electron beam. Simultaneously, the accelerating pulse creates a magnetic field. These two field intensities act upon a ferromagnetic material in the cells to enhance magnetic flux density. Due to the nonlinearity of the material, this flux density will reach a saturation point. In turn, the magnetic field intensity of the axial solenoidal magnetic field will be affected and slightly altered. The width of the electron beam will increase, causing a decrease in effectiveness. Through simulation, …

Investigation Of Optical And Electrical Properties Of Noble Metal And Superconducting Thin Films And Design And Fabrication Of Metamaterial Solar Absorbers, Vivek Khichar

Physics Dissertations - Archive

An extensive study of light-matter interactions leading to the generation of photon drag voltage under surface plasmon resonance conditions in noble metal thin films was undertaken by performing a series of experimental measurements and numerical simulations. The drag voltage originates from a force that arises because of the transfer of momentum from incident light to electrons. This transfer of photon momentum leads to an electric current, which in turn results in the generation of drag voltage. The effect is particularly enhanced under surface plasmon resonance conditions and thereby reinforces the interaction between light and collective oscillations of the surface charges. …

Exploring Ferroelectric Phenomena In Batio3, Linbo3, And Liznsb: From Extended Oxygen Vacancies To Tri-Stable Polarization And Giant Hyperferroelectricity, Shaohui Qiu

Graduate Theses and Dissertations

This dissertation presents three projects that investigate the complex phenomena of ferroelectricity under different conditions in BaTiO3, LiNbO3, and LiZnSb using first-principles density functional calculations. Extended defects in ferroelectric solids play a crucial role in reducing the lifetime and performance of ferroelectric devices by causing fatigue, domain pinning, and aging. Thus, understanding their impact is of critical importance for the development of reliable and high-performance ferroelectric devices. In addition, hyperferroelectricity is an intriguing phenomenon that has attracted much attention in recent years. Despite the existence of depolarization field, spontaneous polarization persists under an open-circuit boundary condition (OCBC), making hyperferroelectric materials …

Applying Instrumental Neutron Activation Analysis To Assess Air Pollution With Spanish Moss As A Bioindicator In The Low Country Of The Savannah River Basin, Christina Jiang

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Savanah River Basin is an area of 9,850 square miles that stretches from the border between South Carolina and Georgia, which empties into the Atlantic Ocean near Savannah, Ga. This area is home to surrounding cities, industrial sites, and the Savanah River Site. It is well documented that traffic, industrial operations, and agriculture contribute to worsening air pollution that needs to be monitored. While Tillandsia usneoides (Spanish moss) has been used in previous studies that prove it to be an effective biomonitor for air pollution and an accumulator of heavy metals, there have been no biomonitoring studies in the …

Joint Constraints On Kepler-36 From Kepler And New Keck-Hires Data, Nicholas Juliano

UNLV Theses, Dissertations, Professional Papers, and Capstones

I analyze new HIRES Radial Velocity (RV) data in conjunction with transit mid-times and uncertainties from the full 17 quarters of Kepler data to reassess the orbital parameters of the Kepler-36 system. Six additional RV measurements were taken by the Keck-HIRES spectrograph from September 21, 2021 to October 11, 2021. I carry out a differential evolution Markov Chain Monte Carlo-based (DEMCMC) analysis to infer improved orbital elements for the two known planets in the system. Leveraging additional information provided by the new RV measurements, I extend this DEMCMC analysis to a possible three-planet configuration. I explore the likelihood of a …

Stoichiometric Determination Of Hydride Materials At Extreme Conditions, Gregory Alexander Smith

UNLV Theses, Dissertations, Professional Papers, and Capstones

Hydrogen was predicted to be a high-temperature superconductor at near-megabar conditions in 1968,[1] but only recently was been experimentally observed.[2] This is due to the extraneous metrological constraint of requiring 5 megabars of pressure to stabilize. A more practical approach for synthesis of high-temperature superconductors has been pro-posed through the use of hydride compounds. Recently, a surge of rare earth hydrides have achieved critical superconducting transition temperatures (T_C ) close to room temperature.[3, 4, 5, 6] However, due to limitations of the necessary instrumentation to achieve megabar pressures, many techniques traditionally used to measure stoichiometry are unavailable.Three works presented in …

Tdcosmo - Xii. Improved Hubble Constant Measurement From Lensing Time Delays Using Spatially Resolved Stellar Kinematics Of The Lens Galaxy, Anowar J. Shajib, Pritom Mozumdar, Geoff C.-F. Chen, Tommaso Treu, Michele Cappellari, Shawn Knabel, Sherry H. Suyu, Vardha N. Bennert, Joshua A. Frieman, Dominique Sluse, Simon Birrer, Frederic Courbin, Christopher D. Fassnacht, Lizvette Villafaña, Peter R. Williams

Physics

Strong-lensing time delays enable the measurement of the Hubble constant (H₀) independently of other traditional methods. The main limitation to the precision of time-delay cosmography is mass-sheet degeneracy (MSD). Some of the previous TDCOSMO analyses broke the MSD by making standard assumptions about the mass density profile of the lens galaxy, reaching 2% precision from seven lenses. However, this approach could potentially bias the H₀ measurement or underestimate the errors. For this work, we broke the MSD for the first time using spatially resolved kinematics of the lens galaxy in RXJ1131−1231 obtained from the Keck Cosmic …

Extending The Lifetime Of Optically Stimulated Dosimeters For Use In Output Checks At Iroc- Houston, Hayden Scott

Dissertations and Theses (Open Access)

Purpose: Optically Stimulated Luminescent Dosimeters (OSLDs) are a prominent form of in-vivo dosimeter used both in clinics as well as for the audits of radiological
equipment at the Imaging and Radiation Oncology Core (IROC)-Houston. These
dosimeters have a recommended dose limit of 10 Gy due to a change in signal response with dose. To assist with the OSLD operation at IROC-Houston, evaluating the signal response of these dosimeters with IROC’s methodologies offers the potential to extend the dose limit past 10 Gy, improve the efficiency of handling OSLDs, and reduce the cost and time spent on commissioning OSLDs.
Methods: The …

Magnetic Properties Of Polycrystalline Spinel Oxides From Solid State Reaction, Camden Olds

Honors Program: Senior Projects (Public)

Spinel crystal materials of nickel, cobalt, and iron oxides have seen abundant research for their strong conductivity, ferromagnetic and ferroelectric properties, and their catalytic uses. These can be synthesized by a number of means. This project explores the use of the solid state synthesis method, which benefits from simplicity, of this family of materials, looking for interesting phase shift lines in the triangle between of varying compositions of these three metals.

Nickel cobaltite and other related spinels were synthesized from two different solid state approaches and characterized using XRD and SQUID magnetometry. The range 0.5-0.6 of molar ratios of nickel …

Spectra Of Atmospheric And Astronomical Molecules, W. D. Cameron

Physics Theses & Dissertations

Spectroscopy techniques are focused on spectra of molecules of interest to the Earth’s atmosphere and/or astronomy and astrophysics. Laboratory spectroscopy as well as remote satellite sensing are applied. Using the Fourier transform spectrometer aboard the Atmospheric Chemistry Experiment (ACE) satellite to measure the absorption spectra of the Earth’s atmosphere through solar occultation limb observation demonstrates that volcanic eruption plumes can be located and tracked through their SO₂ content. The presence of those plumes is corroborated by overlaying infrared atmospheric aerosol extinction observed by the 1 μm imager on the same satellite. Tracking atmospheric aerosol movement with the ACE …

Nb3Sn Coating Of Twin Axis Cavity And Other Complex Srf Cavity Structures, Jayendrika Kumari Tiskumara

Physics Theses & Dissertations

In the field of Accelerator Science, for the low cost and increased quality factor, thin films coated niobium cavities are used in the modern SRF research. Within the potential substances, Nb₃Sn has shown higher critical temperature than niobium. Here the tin vapor diffusion method is used as the preferred technique to coat niobium cavities. So far, only elliptical cavities have been coated with Nb₃Sn and this technique has not yet been applied to cavities with complex geometries, which are also helpful in the accelerator science field. The Half-wave resonator could provide us data across frequencies of …