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Micromirror Array Control Of A Phase-Locked Laser Diode Array, Carl J. Christensen Dec 1995

Micromirror Array Control Of A Phase-Locked Laser Diode Array, Carl J. Christensen

Theses and Dissertations

A ten element micromirror array has been designed, fabricated, and employed to control the far field irradiance pattern of a phase locked laser diode array. The laser array used in this experiment was a ten element, gain guided array lasing at a nominal wavelength of 828 nm and operating in the it out of phase supermode. The laser's near field irradiance was imaged onto a micromirror array, where the it phase differences between adjacent laser elements were corrected. This was accomplished by moving the micromirrors with individually applied voltages. The result was the desirable single lobed far field pattern, placing …


Study Of The Long-Term Desorption Of Trichloroethylene From Clay Soils Using Infrared Spectroscopy, Mary P. Stager Dec 1995

Study Of The Long-Term Desorption Of Trichloroethylene From Clay Soils Using Infrared Spectroscopy, Mary P. Stager

Theses and Dissertations

Slow desorption of contaminants from soil presents one of the greatest challenges to modeling contaminant fate and transport and implementing effective remediation technologies. The kinetics of long-term desorption of trichloroethylene (TCE) from powdered clay soils were studied to determine the desorption rates and mechanism. Infrared absorption spectroscopy was used to monitor the concentration of TCE desorbed from contaminated flint clay for 71 hours. Observed gas phase TCE concentrations as a function of time were compared to that predicted by a one-site Langmuir desorption mechanism. The Langmuir model, with a single type of bonding site, did not account for the release …


Characterization Of Atmospheric Turbulence Over Long Horizontal Paths Using Optical Slope Measurements, Eric E. Silbaugh Dec 1995

Characterization Of Atmospheric Turbulence Over Long Horizontal Paths Using Optical Slope Measurements, Eric E. Silbaugh

Theses and Dissertations

Atmospheric turbulence has long been recognized as one of the fundamental factors affecting optical systems operating through the atmosphere. Turbulence over vertical paths has been well characterized, both theoretically and experimentally. Much less is known about turbulence over long, horizontal paths. Perturbations of the wave front phase can be measured using a Hartmann wave front sensor (H-WFS). Theoretical expressions for the tilt removed structure function of the H-WFS slope measurements were derived and evaluated using quadrature. These slope structure functions are functions of the phase structure function. The Kolmogorov turbulence model was assumed. Simulated H-WFS slope measurements were generated using …


Computer-Aided Diagnosis Of Mammographic Masses, William E. Polakowski Dec 1995

Computer-Aided Diagnosis Of Mammographic Masses, William E. Polakowski

Theses and Dissertations

A new Model-Based Vision algorithm was developed to find possibly cancerous regions of interest (ROIs) in digitized mammograms and to correctly identify the malignant masses. This work has shown a sensitivity of 92 percent for locating malignant ROIs. The database contained 272 images (12 bit, 1OO microns) with 36 malignant and 53 benign mass images. Of the 53 biopsied benign cases, 74 percent were correctly classified. The Focus of Attention (segmentation) Module algorithm used a physiologically motivated Difference of Gaussians (DoG) filter to highlight mass-like regions in the mammogram. The Index Module labeled the regions by their hypothesized class: large …


Two-Wavelength Neodymium Based Lasers, Scott H. Mccracken Dec 1995

Two-Wavelength Neodymium Based Lasers, Scott H. Mccracken

Theses and Dissertations

A dual wavelength Q switched laser cavity has been successfully designed and assembled to evaluate the new neodymium (Nd) based materials. Initial characterization has been achieved for Nd:YAG and Nd:YLF. The results indicate that for a fixed pulse repetition frequency, the delay time can be used to adjust the relative energy between the 1.06 and 1.32 micrometer pulses. Any deficiency in the performance of one transition can be made up by performance in the other simply by changing the relative amount of time the population inversion is allowed to build up for each pulse. The best performance was obtained using …


Design, Fabrication And Characterization Of Micro Opto-Electro-Mechanical Systems, Darren E. Sene Dec 1995

Design, Fabrication And Characterization Of Micro Opto-Electro-Mechanical Systems, Darren E. Sene

Theses and Dissertations

Several micro-opto-electro-mechanical structures were designed using the Multi-User MEMS Process (MUMPS). Specific design techniques were investigated for improving the capabilities of elevating flip up structures. The integration of several flip up microoptical structures into a microoptical system was explored with emphasis on the development of a microinterferometer. The thermal effects on the Modulus of Elasticity were determined by detecting the resonant frequency for a square Flexure Beam Micromirror Device. The resonance of the device was found to match theory to within 0.1 % and the Modulus of Elasticity was found to decrease by 0.041 GPa/K from 290 to 450 K. …


Observation Of Beam-Induced Changes In The Polarization Of Balmer-Α Radiation Emitted Following Beam--Tilted-Foil Transmission, Wang Qi, David D. Allred, Larry V. Knight, Douglas L. Harper, Royal G. Albridge, Norman H. Tolk Dec 1995

Observation Of Beam-Induced Changes In The Polarization Of Balmer-Α Radiation Emitted Following Beam--Tilted-Foil Transmission, Wang Qi, David D. Allred, Larry V. Knight, Douglas L. Harper, Royal G. Albridge, Norman H. Tolk

Faculty Publications

Measurements of the circular polarization of Balmer-α radiation emitted by excited hydrogen atoms, following the transmission of (20-50)-keV protons through thin, tilted amorphous carbon foils, exhibit markedly unexpected behavior as a function of exposure of the foil to the proton beam. Specifically, the circular polarization changes from an initially well understood tilt-angle dependence to a behavior which, for low tilt angles, gives the opposite handedness of circular polarization from that predicted. In addition, the degree of alignment, indicated by the linear Stokes parameter M/I, is enhanced also as a function of dose. These changes in the tilt-angle dependence of the …


Simple Description Of Pion-Pion Scattering To 1 Gev, Joseph Schechter, Masayasu Harada, Francesco Sannino Nov 1995

Simple Description Of Pion-Pion Scattering To 1 Gev, Joseph Schechter, Masayasu Harada, Francesco Sannino

Physics - All Scholarship

Motivated by the 1/Nc expansion, we present a simple model of pion-pion scattering as a sum of a `current-algebra' contact term and resonant pole exchanges. The model preserves crossing symmetry as well as unitarity up to 1.2 GeV. Key features include chiral dynamics, vector meson dominance, a broad low energy scalar (sigma) meson and a `Ramsauer-Townsend' mechanism for the understanding of the 980 MeV region. We discuss in detail the `regularization' (corresponding to rescattering effects) necessary to make all these nice features work.


Image Restoration Of Dispersion-Degraded Images From A Liquid-Crystal Beam Steerer, Ronald J. Broessel, Vince Dominic, Russell C. Hardie Nov 1995

Image Restoration Of Dispersion-Degraded Images From A Liquid-Crystal Beam Steerer, Ronald J. Broessel, Vince Dominic, Russell C. Hardie

Electrical and Computer Engineering Faculty Publications

Liquid-crystal arrays represents one of the first practical technologies capable of steering light by electronic control only. We use such a device to steer the field of view of a broadband imaging sensor. Unfortunately, dispersion degrades the image quality by smearing out details in the image and by introducing multiple diffraction orders (echoes) at the detector plane. We present a method to compensate for these unwanted effects and thus restore the broadband images obtained with the beam steerer. We use the beam-propagation method to find the wavelength-dependent impulse response, from which we determine the appropriate Wiener filter. When training data …


Fast Relaxation Mode In A Thermotropic Uniaxial Nematic Liquid Crystal, Sanjay Tripathi, Hua Zhong, Rolfe G. Petschek, Charles Rosenblatt Nov 1995

Fast Relaxation Mode In A Thermotropic Uniaxial Nematic Liquid Crystal, Sanjay Tripathi, Hua Zhong, Rolfe G. Petschek, Charles Rosenblatt

Faculty Scholarship

Results are reported from a light scattering measurement in the uniaxial nematic phase in the thermotropic liquid crystal octylcyanobiphenyl, a material which does not exhibit a biaxial phase. In addition to a slow Goldstone mode associated with twist fluctuations, a fast mode whose relaxation time is independent of both wave vector and temperature has been observed. The possible origins of this relaxation are discussed.


Magnetic And Magneto-Optical Properties Of MnXCubi ( X =0.75 - 3.5 ) Films, Jian Chen, K. Wierman, Roger D. Kirby, David J. Sellmyer Nov 1995

Magnetic And Magneto-Optical Properties Of MnXCubi ( X =0.75 - 3.5 ) Films, Jian Chen, K. Wierman, Roger D. Kirby, David J. Sellmyer

Department of Physics and Astronomy: Faculty Publications

Magnetic and magneto-optical properties of MnxCuBi ( x = 0.75 - 3.5) thin films are presented. With increasing Mn concentration x, the perpendicular anisotropy constant (Ku the remanence squareness (S = Mr/Ms) and the coercivity (Hc)the perpendicular hysteresis loop increase. Remanence squareness as high as 0.95 has been obtained. Kerr rotation (θk) and ellipticity (ηk) spectra from all samples measured from substrate side are similar, with θk exhibiting a broad peak in the blue wavelength region with maximum Kerr rotation up to 0.7 degrees.


Magnetic And Magneto-Optical Properties Of MnXCubi ( X =0.75 - 3.5 ) Films†, Jian Chen, K. Wierman, Roger D. Kirby, David J. Sellmyer Nov 1995

Magnetic And Magneto-Optical Properties Of MnXCubi ( X =0.75 - 3.5 ) Films†, Jian Chen, K. Wierman, Roger D. Kirby, David J. Sellmyer

Department of Physics and Astronomy: Faculty Publications

Abstract - Magnetic and magneto-optical properties of MnxCuBi ( x = 0.75 - 3.5) thin films are presented. With increasing Mn concentration x, the perpendicular anisotropy constant (Ku), the remanence squareness (S = Mr/Ms) and the coercivity (Hc ), of the perpendicular hysteresis loop increase. Remanence squareness as high as 0.95 has been obtained. Kerr rotation (Өk) and ellipticity (ηk) spectra from all samples measured from substrate side are similar, with Өk exhibiting a broad peak in the blue wavelength region with maximum Kerr rotation up …


Spin Polarization Of The Conduction Bands Of Gd(0001)*, Dongqi Li, J. Pearson, S.D. Bader, D. N. Mcilroy, C. Waldfried, Peter A. Dowben Nov 1995

Spin Polarization Of The Conduction Bands Of Gd(0001)*, Dongqi Li, J. Pearson, S.D. Bader, D. N. Mcilroy, C. Waldfried, Peter A. Dowben

Peter Dowben Publications

Angle- and spin-resolved photoemission was utilized to investigate the 5d bulk bands and the surface state of Gd(0001) in the temperature range of 130 - 350 K. The bulk bands at 1-2 eV below the Fermi energy EF show Stoner-like behavior, while the temperature dependence of the surface state near EF indicates spin-mixing behavior due to fluctuating local 5d moments. The secondary electron spectra of the Gd surfaces both before and after initial oxygen adsorption show a polarization dip at low kinetic energies due to the extra scattering channel for minority electrons via the unoccupied 4ƒ level. The …


Steady-State Kinetics Of Br(2P1/2) Yields Co2(101) Electronic-To-Vibrational Energy Transfer Laser System, Stephen J. Karis Nov 1995

Steady-State Kinetics Of Br(2P1/2) Yields Co2(101) Electronic-To-Vibrational Energy Transfer Laser System, Stephen J. Karis

Theses and Dissertations

Steady state photolysis experiments were conducted to gain information relevant to the construction of a continuous wave electronic to vibrational pumped infrared laser. An Ar+ laser =488 µm) was used to produce the electronically excited state Br(2P1/2) (Br*) via photolysis of molecular bromine. Energy was then transferred to the near resonant vibrational state CO2(101) (CO2) via the collisional quenching of Br* by CO2. The dependence of the 2.71 µm Br* and 4.3 µm CO2 emissions on CO2 pressure was measured, as well as …


Light-Heavy Symmetry: Geometric Mass Hierarchy For Three Families, Aharon Davidson, Tomer Schwartz, Kameshwar C. Wali Oct 1995

Light-Heavy Symmetry: Geometric Mass Hierarchy For Three Families, Aharon Davidson, Tomer Schwartz, Kameshwar C. Wali

Physics - All Scholarship

The Universal Seesaw pattern coupled with a Light

↔ Heavy symmetry principle leads to the Diophantine equation N =NXi =1ni, where ni ≥ 0 and distinct. Its unique non-trivial solution (3 = 0+1+2) gives rise to the geometric mass hierarchy mW, mWǫ, mWǫ2 for N = 3 fermion families. This is realized in a model where the hybrid (yet Up ↔ Down symmetric) quark mass relations m dmt ≈ m2 c ↔ mumb ≈ m2 s play a crucial role in expressing the CKM mixings in terms of simple mass ratios, notably sin θC ≈ m c m b . …


Lattice Quantum Gravity: Review And Recent Developments, Simon Catterall Oct 1995

Lattice Quantum Gravity: Review And Recent Developments, Simon Catterall

Physics - All Scholarship

We review the status of different approaches to lattice quantum gravity indicating the successes and problems of each. Recent developments within the dynamical triangulation formulation are then described. Plenary talk at LATTICE 95 July 11-15, Melbourne, Australia.


A Real-Space Renormalization Group For Random Surfaces, Simon Catterall, G. Thorleifsson Oct 1995

A Real-Space Renormalization Group For Random Surfaces, Simon Catterall, G. Thorleifsson

Physics - All Scholarship

We propose a new real-space renormalization group transformation for dynamical triangulations. It is shown to preserve geometrical exponents such as the string susceptibility and Hausdorff dimension. We furthermore show evidence for a fixed point structure both in pure gravity and gravity coupled to a critical Ising system. In the latter case we are able to extract estimates for the gravitationally dressed exponents which agree to within 2-3% of the KPZ formula.


Height Measurements Of Oi (557.7 Nm) Gravity Wave Structure Over The Hawaiian Islands During Aloha-93, Michael J. Taylor, G. R. Swenson, V. Taylor Oct 1995

Height Measurements Of Oi (557.7 Nm) Gravity Wave Structure Over The Hawaiian Islands During Aloha-93, Michael J. Taylor, G. R. Swenson, V. Taylor

All Physics Faculty Publications

During the ALOHA‐93 campaign simultaneous observations of gravity wave structure in the OI(557.7 nm) nightglow emission were made using two all‐sky CCD imagers; one located near the summit of Haleakala Crater, Maui and the other at Mauna Loa Observatory, Hawaii. On 19 October a set of bright, planar, monochromatic waves was imaged by both systems as it progressed rapidly over the Hawaiian Islands. Triangulation on these wave forms indicates a mean altitude of 95±2 km in good agreement with previous rocket soundings at mid‐latitudes. Two methods of triangulation were employed, both achieving similar results.


Aloha-93 Measurements Of Intrinsic Agw Characteristics Using The Airborne Airglow Imager And Groundbased Na Wind/Temperature Lidar, G. R. Swenson, Michael J. Taylor, P. Espy, C. S. Gardner, X. Tao Oct 1995

Aloha-93 Measurements Of Intrinsic Agw Characteristics Using The Airborne Airglow Imager And Groundbased Na Wind/Temperature Lidar, G. R. Swenson, Michael J. Taylor, P. Espy, C. S. Gardner, X. Tao

All Physics Faculty Publications

Monochromatic Acoustic Gravity Waves (AGWs) with periods < 1 hour are a prevalent feature in the mesospheric airglow layers. These waves are important dynamically and energetically to the region where their temporal and spatial morphology are not well established. The purpose of this study is establish the intrinsic AGW characteristics over an extended region (as flown by the NCAR Electra aircraft) and to present the data in terms of the predicted spectral domain defined by the Brunt‐Vaisala frequency and the diffusive filtering limit proposed by Gardner [1994]. On October 21, 1993, observations were made from the NCAR Electra aircraft during a 6 hour flight in a large triangle N and W of Maui, for a integral distance of ∼3000 km. The entire area observed [∼1 M km²] had a monochromatic AGW propagating toward the NW and the western half had a SW propagating wave superimposed. These waves were also observed with the Michelson interferometer on the aircraft and an airglow imager at the Haleakala location during this time. Intrinsic phase velocities were computed where the Na Wind/Temperature (W/T) lidar at Haleakala provided a measure of the mean wind to compensate phase velocities observed with the imager. The data were tabulated and plotted in an AGW spectral reference frame and compared to cutoff conditions predicted by diffusive filtering theory.


Strong X-Ray Emission From High-Temperature Plasmas Produced By Intense Irradiation Of Clusters, T. Ditmire, Thomas D. Donnelly, R. W. Falcone, M. D. Perry Oct 1995

Strong X-Ray Emission From High-Temperature Plasmas Produced By Intense Irradiation Of Clusters, T. Ditmire, Thomas D. Donnelly, R. W. Falcone, M. D. Perry

All HMC Faculty Publications and Research

The interaction of an intense laser pulse with large (∼100Å) clusters present in pulsed gas jets is shown to produce novel plasmas with electron temperatures far in excess of that predicted by above-threshold ionization theory. The enhanced absorption of the laser light by the dense clusters results in the production of high ion charge states via collisional ionization resulting in strong x-ray emission from the hot plasma.


Coherent Excitation Of The Singlet-Triplet Mixed 1s4f State Of Helium, Jingbo Wang, J. F. Williams, Andris T. Stelbovics, John E. Furst, Don H. Madison Oct 1995

Coherent Excitation Of The Singlet-Triplet Mixed 1s4f State Of Helium, Jingbo Wang, J. F. Williams, Andris T. Stelbovics, John E. Furst, Don H. Madison

Physics Faculty Research & Creative Works

In this paper, we present a detailed theoretical description for the coherent electron-impact excitation, the subsequent time evolution, and the cascading decay process of the singlet-triplet mixed 1s4f state of helium. The excitation amplitude and phase of each sublevel of this state are related to measurable coincidence intensities and polarizations of the emitted photons. It is found that the intensity and polarization of the emitted photons are time modulated due to the singlet and triplet mixing in the 1s4f state.


Heavy-Ion Interaction Models For Radiation Transport, Rajendra R. Dubey Oct 1995

Heavy-Ion Interaction Models For Radiation Transport, Rajendra R. Dubey

Physics Theses & Dissertations

This dissertation is concerned with finding the values for the nuclear cross sections used in the Boltzmann equation for space radiation transport and dose estimates. An extraordinary number of cross sections are required because of the large number of ion types and their extensive energy range, The Lippmann-Schwinger equation is numerically solved in momentum space for a first order optical potential (free space case) and calculations are made for the total and absorption cross sections for nudeus-nucleus scattering. Absorption cross sections are also calculated using a medium modified firstorder optical potential in the Lippmann-Schwinger equation and are compared with experimental …


Doubled Co2 Experiments With The Global Change Research Center Two-Dimensional Statistical Dynamical Climate Model, R. M. Mackay, M. A. K. Khalil Oct 1995

Doubled Co2 Experiments With The Global Change Research Center Two-Dimensional Statistical Dynamical Climate Model, R. M. Mackay, M. A. K. Khalil

Physics Faculty Publications and Presentations

The zonally averaged response of the Global Change Research Center two-dimensional statistical dynamical climate model (GCRC 2-D SDCM) to a doubling of atmospheric carbon dioxide (350 parts per million by volume (ppmv) to 700 ppmv) is reported. The model solves the two-dimensional primitive equations in finite difference form (mass continuity, Newton's second law, and the first law of thermodynamics) for the prognostic variables: zonal mean density, zonal mean zonal velocity, zonal mean meridional velocity, and zonal mean temperature on a grid that has 18 nodes in latitude and 9 vertical nodes (plus the surface). The equation of state, p=rhoRT, and …


A Relativistic Model For Heavy Mesons, Jialin Zeng Oct 1995

A Relativistic Model For Heavy Mesons, Jialin Zeng

Physics Theses & Dissertations

Motivated by the present interest in the heavy quark effective theory, we construct a model for heavy mesons based on a relativistic bound state wave equation, the Gross equation. The kernel we use is based on scalar confining and vector Coulomb potentials. Wave functions are treated to leading order and energies to order 1/MQ in the heavy-light systems, and to order 1/M2Q in heavy-heavy systems. Our results are in good agreement with experimental measurements. This model may be used to study weak decay properties in the framework of the heavy quark effective theory and ultimately to …


The Phase Diagram Of Crystalline Surfaces, Simon Catterall, Konstantinos N. Anagnostopoulos, Mark Bowick, Marco Falcioni, G. Thorleifsson Sep 1995

The Phase Diagram Of Crystalline Surfaces, Simon Catterall, Konstantinos N. Anagnostopoulos, Mark Bowick, Marco Falcioni, G. Thorleifsson

Physics - All Scholarship

We report the status of a high-statistics Monte Carlo simulation of non-self-avoiding crystalline surfaces with extrinsic curvature on lattices of size up to 128^2 nodes. We impose free boundary conditions. The free energy is a gaussian spring tethering potential together with a normal-normal bending energy. Particular emphasis is given to the behavior of the model in the cold phase where we measure the decay of the normal-normal correlation function.


Temperature Fluctuations In Photoionized Nebulae, J. B. Kingdon, Gary J. Ferland Sep 1995

Temperature Fluctuations In Photoionized Nebulae, J. B. Kingdon, Gary J. Ferland

Physics and Astronomy Faculty Publications

Recombination lines in gaseous nebulae frequently yield parent-ion abundances that are several times larger than abundances derived from forbidden lines. One possible explanation for this discrepancy is the presence of temperature fluctuations. We examine temperature fluctuations in model nebulae by utilizing Peimbert's t2 parameter. We have run large grids of models, varying the stellar temperature and the total hydrogen density. We consider two abundance sets: The first uses "typical" planetary nebulae abundances, while the second examines the effect of increasing the metals and grains by a factor of 3. We also consider both a constant density distribution and one …


Floquet Description Of Multiphoton Processes In Li, D. I. Duncan, J. Greg Story, Thomas F. Gallagher Sep 1995

Floquet Description Of Multiphoton Processes In Li, D. I. Duncan, J. Greg Story, Thomas F. Gallagher

Physics Faculty Research & Creative Works

We have made several different types of measurements of the three-photon ionization of Li produced by 3-ps laser pulses and describe the results using a Floquet picture. Over the photon frequency range 15 000 to 15 800 cm-1, Li represents a strongly coupled three-state system with the 2s ground state coupled to the 2p and 3d states by one and two photons, respectively. Energy analysis of the photoelectrons allows the measurement of the intensity dependent shift of the 2s Floquet state during the laser pulse. The shift shows a strong frequency dependence that is not predicted by first-order …


Collisional Dynamics Of The Rubidium 52P Levels, Matthew D. Rotondaro Sep 1995

Collisional Dynamics Of The Rubidium 52P Levels, Matthew D. Rotondaro

Theses and Dissertations

The collisional dynamics of the 52P levels in rubidium has been examined using steady-state laser absorption and spectrally-resolved laser induced fluorescence techniques. State-to-state cross-sections for energy transfer between Zeeman split levels ranged from 16-248 °A2 for collisions with nitrogen and rare gases. These energy transfer cross-sections exhibit a significant dependence on (J,mj) state and certain symmetry relationships are demonstrated. A sub-Doppler spectrum of the Zeeman split levels indicating the isotopic shift in the D1 line of 106 ± 35 was obtained using laser saturation spectroscopy.


Comparison Of Branching Ratio And Sum-Rule Analyses Of Magnetic Circular Dichroism In X-Ray-Absorption Spectroscopy, James G. Tobin, George Daniel Waddill, Alan F. Jankowski, Philip A. Sterne, David P. Pappas Sep 1995

Comparison Of Branching Ratio And Sum-Rule Analyses Of Magnetic Circular Dichroism In X-Ray-Absorption Spectroscopy, James G. Tobin, George Daniel Waddill, Alan F. Jankowski, Philip A. Sterne, David P. Pappas

Physics Faculty Research & Creative Works

Two localized picture methods of analyzing the magnetic circular dichroism in x-ray absorption will be applied to experimental results: the branching ratio (BR) and sum rule (SR) approaches. A derivation of the BR formulas and detailed comparison to the SR expressions will be made, including error estimations. The BR approach will be seen to be a limiting case form of the SR spin-moment expression and provide a simple picture of the underlying physics in magnetic x-ray circular dichroism absorption in 3d magnetic materials.


Optical Characterization Of Indium Arsenide Antimonide Semiconductors Grown By Molecular Beam Epitaxy, Michael A. Marciniak Sep 1995

Optical Characterization Of Indium Arsenide Antimonide Semiconductors Grown By Molecular Beam Epitaxy, Michael A. Marciniak

Theses and Dissertations

The material parameters and crystalline quality of undoped, MBE-grown InAs1-xSbx nearly lattice-matched to (100) GaSb (-0.617% ≤ Δ a-a ≤ +0.708%) similar to material used for mid-infrared semiconductor lasers were determined by optical characterization. Absorption measurements at temperatures between 6-295 K determined the energy gap and wavelength-dependent absorption coefficient for each sample. The compositional dependence of the energy gap was anomalous when compared to previously reported data, suggesting phase separation existed in the material. The samples were also studied by temperature- and excitation-dependent photoluminescence (PL), which, for the majority of cases, showed only a single band-edge peak, …