Digital Commons Network^™

Automation And Upgrading Of Custom Cold Wall Uhv-Cvd Reactor For Group Iv Material Development, Alexander Golden

Graduate Theses and Dissertations

Group IV alloys have shown promising results for infrared optoelectronic applications where III-V materials are currently dominant. The III-V material system has vacancies that Group IV materials can fill, most importantly complementary metal oxide semiconductor (CMOS) process compatibility making quality devices much cheaper and widely available compared to the current state of the art. Silicon, being an indirect band gap Group IV material, has poor performance in optoelectronic applications but is the dominant material for most of the electronic industry. However, when silicon is alloyed or substituted with other group IV materials, these optoelectronic properties can be enhanced and, in …

Evidence Of Backwater Morphodynamics In Stratigraphy On Earth And Mars: Implications For Ancient Mars, Cory Mitchell Hughes

Graduate Theses and Dissertations

Geologic evidence indicates that liquid water once flowed in abundance across the martian surface. For this reason, in the search for evidence of extraterrestrial life, Mars represents a prime target for scientific inquiry. River systems encode climatic and environmental signals in their deposits on Earth and Mars, often in fan-shaped landforms (e.g., alluvial fans, river deltas, etc.). Distal fan-shaped deposits (i.e., river deltas), in particular, act as a relatively high-fidelity record of dynamic geologic processes. As such, NASA frequently sends rovers to locations on Mars’ surface with hypothesized river deltas (e.g., Perseverance and Jezero crater). Problematically, there are many different …

Solar Powered Conservation: The Effects Of Solar Photovoltaic Facilities On Avian Community Composition, Michael Christopher Ferrara

Graduate Theses and Dissertations

The expansion of solar photovoltaic energy infrastructure is transforming landscapes worldwide. Increasingly, facilities are planted with native vegetation, yet how vegetation characteristics and landscape variables shape wildlife communities in solar facilities remains poorly understood. Because avian populations have been in decline and are sensitive to habitat changes, understanding how solar facilities influence avian communities is important. In Chapter 1, we used autonomous recording units, local vegetation measurements, and land use and land cover data to quantify how avian community occupancy is influenced by solar cover in solar facilities and comparable reference sites. We used a Bayesian multi-species occupancy model to …

Novel Radical Chemistry Of Electron-Rich Double Bonds, Claire Allyson Beard

Graduate Theses and Dissertations

This work delves into the reactivity of nucleophilic N-heterocyclic carbenes (NHCs) and their ability to form electron-rich alkene intermediates, which can undergo various chemical transformations depending on the nature of the electrophile. Initial reports by Hahn disclosed the NHC promoted radical nature of electron-rich N,N’-benzyltetraazafulvalenes, which led to 2,2’- biimidazoles. We found that N-aryl substituted pyridinium salts also underwent rapid a similar NHC promoted dimerization when exposed to a base, producing 2,2’-bipyridyls. This is likely due to the adept radical nature of the bipyridinylidene intermediate for C-Naryl bond scission. We have also uncovered an unprecedented C-N bond scission of Breslow-like …

Multiple Aspects Of Environmental Temperature Have Complex Interactions With Avian Parental Behavior To Influence Offspring Outcomes, William H. Kirkpatrick

Graduate Theses and Dissertations

Anthropogenic climate change is projected to shift not only average temperatures across the globe, but also the amount of thermal variation experienced in the natural environment. Exposure to shifts in averages and a wider range of thermal experiences will cause shifts in wildlife behavior. In avian species, behaviors exhibited during reproduction have implications for the well-being of their offspring. Here, I explore specific incubation behaviors in four species: Scaled Quail (Callipepla squamata), Northern Bobwhite Quail (Colinus virginianus), Tree Swallows (Tachycineta bicolor), and Eastern Bluebirds (Sialia sialis). I examined constancy, or the percentage of time on the nest, and off-bout duration, …

Ring-Opening And Monofunctionalization Study On Spiro Cyclic Aminals And N, O-Acetals System Via Nitrogen-Centered Radical Intermediates, Chujun Zhou

Graduate Theses and Dissertations

The nitrogen-centered radical has been drawing increasing attention among researchers. Radical polarity is one of the key factors in studying nitrogen-centered radicals’ reactivity, and the functional groups attached to the nitrogen atom are of vital importance. Among different types of nitrogen-centered radicals, aminium radical and metal aminium radical are electrophilic due to the positive charge on the intermediate. The sulfonamide radical, amidyl radical, and cyanide amine radical are also electrophilic since the nitrogen is adjacent to electron electron-withdrawing group. The neutral amino radical, iminyl radical, masked nitrogen radical are nucleophilic because of the electron-donating groups. After classifying the nitrogen-centered radical, …

Dolphins ‘Orient-Against-Current’: Foraging In Dredged Channels, Eliza M.M. Mills, Sarah Piwetz, Dara N. Orbach

Marine Science

Bottlenose dolphins (Tursiops sp.) are opportunistic foragers with global distributions that utilize diverse feeding tactics based on environmental factors, habitat features, prey behavior, group dynamics, and genetics. We describe a unique foraging tactic regularly observed in the confluence of dredged shipping channels with high anthropogenic disturbance, and explore potential abiotic (temporal, tidal, habitat) drivers of the behavior. A shore-based digital theodolite was used from 2021 to 2022 to observe common bottlenose dolphins (T. truncatus) foraging within a current in a technique we term Orient-Against-Current (OAC). During OAC, dolphins position themselves facing into the flow of a current, swimming at a …

Stochastic Functional Data-Driven Models For Real-Time Battery Health Forecasting Under Dynamic Operating Conditions, Joshua Owusu

Electronic Theses and Dissertations

This thesis provides an effective statistical model to predict the real-time state of lithium-ion batteries for reliable Battery Management Systems (BMS). It highlights battery data (voltage, current, temperature) as smooth functional curves. The principal method demonstrates diminishing trends to health outcomes like State of Health (SoH) and Remaining Useful Life (RUL) by employing Functional Principal Component Analysis (FPCA) and Bayesian Functional Linear Models (FLMs). The primary objective is to figure out how uncertain forecasts are. Simulations demonstrate that the highest accuracy (lowest MSE) is achieved through low noise levels along with large sample sizes. The final system provides a highly …

Soil Characterization With Proximal Geophysics, Sophia M. Becker

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

High quality soil data is crucial for addressing numerous threats to human well-being such as water scarcity, food insecurity, and intensified natural disasters. True soil property values are determined by analyzing soil samples in a laboratory, but soil sampling is often expensive and time-consuming. Some in-field point sensors and remote sensing products are available to measure soil properties, but they have inherent limitations in measurement extent and resolution. Geophysical methods can fill the measurement scale gap between point measurements and remote sensing products, but various research questions remain open. This dissertation aims to advance understanding of geophysics-derived soil property measurements …

An Integrated Modeling Framework To Evaluate Circularity Of The Corn–Water–Ethanol–Beef Nexus, Heydi Han

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

This dissertation examines the transition from conventional linear agricultural and food bioenergy systems toward more circular, resilient, and resource-efficient configurations. Prior research indicates that spatial and temporal variability in soil, weather, animal biological responses, and management decisions strongly influences productivity, nutrient-use efficiency, and profitability. Studies have also shown that a diversified circular system can buffer these sources of variability, improving stability and adaptive capacity. Building on these insights, the central focus of this work is to develop an integrated modeling framework to evaluate circularity within the Corn-Water-Ethanol-Beef (CWEB) nexus and explore how climate variability and management choices shape system-wide performance. …

Investigating Molecular Rotation And Vibration With Ultrafast Electron Diffraction, Haoran Zhao

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

Ultrafast electron diffraction (UED) has emerged since the late 20th century as a powerful technique for resolving molecular dynamics. With its high spatial and temporal resolution, UED can now measure rotational motion induced by linearly polarized, nonresonant, nonadiabatic laser pulses—one of the fundamental molecular degrees of freedom with broad applications. By combining laser-induced alignment with UED, new capabilities such as three-dimensional structural retrieval and isotope detection have been demonstrated, as discussed in Chapter 2.

In Chapter 3, three symmetry relations in the coefficients of rotational wave packets are identified and derived, reducing the computational cost of simulating asymmetric-top molecular alignment …

Electrical And Magnetic Properties Of Ferroic Oxide Thin Films And Free-Standing Membranes, Qiuchen Wu

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

This dissertation presents a comprehensive study of the electrical, magnetic, and transport properties of epitaxial ferroic oxide thin films and free-standing membranes, including ferroelectric PbZr_0.2Ti_0.8O₃ (PZT) and ferrimagnetic NiCo₂O₄ (NCO).

We evaluate the effects of electrostatic and mechanical boundary conditions on the ferroelectric properties of free-standing PZT membranes by transferring them on three types of base layers: the metallic Au, strongly correlated oxide La_0.67Sr_0.33MnO₃ (LSMO), and 2D semiconductor MoS₂. The coercive field and domain wall roughness depend sensitively on the metallicity and surface roughness of …

Evaluating Fall And Spring Planted Cover Crops For Integrated Management Of Herbicide Resistant Palmer Amaranth And Effect On Soil Health, Vipin Kumar

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

Herbicide-resistant Palmer amaranth (Amaranthus palmeri S. Watson) pose a severe threat to agronomic crop productivity in the United States, including corn and soybean production in Nebraska. Therefore, there is an urgent need for diversified and sustainable management approaches. Integrating cover crops (CCs) with herbicide programs represents a promising strategy to achieve Palmer amaranth suppression, sustain crop yields, and contribute to long-term soil health in irrigated corn–soybean production systems in Nebraska.

A meta-analysis of 41 studies and 595 paired observations demonstrated that CCs reduced Amaranthus spp. density and biomass by 37–59% depending on the growing season, with grasses and mixtures …

Synthesis And Study Of Stable Organic Radicals For Mri Contrast Agents And New Materials, Sabina Dhakal

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

The first part of this dissertation focuses on the design, synthesis, and characterization of a thermally robust S =1/2 phototetrazolinyl monoradical and the development of synthetic methodologies for a high-spin (S = 1) phototetrazolinyl diradical. Electrochemical studies of the phototetrazolium cation (precursor to the monoradical) revealed a remarkably narrow electrochemical band gap (Ecell ≈ 0.82 V), suggesting promising electrical conductivity. Thermal analysis of the monoradical demonstrated excellent stability, with the onset of decomposition at 232 °C. Building on the excellent thermal stability and promising properties for electrical conductivity of the monoradical, we developed two condensation-based synthetic routes that provide viable …

Rainfall-Runoff Modelling In An Indonesian Humid Tropical Area Using Satellite-Based Precipitation Products, Noordiah Helda

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

This dissertation explores three rainfall-runoff models in the humid tropical regions of Indonesia using satellite-based precipitation products (SBPPs) and develops integrated machine-learning modeling frameworks. Several ground-based observations from BMKG (Badan Meteorologi, Klimatologi, dan Geofisika (also known as the Indonesian Agency for Meteorology, Climatology, and Geophysics)) stations across Indonesia (133−165 stations) are compared and evaluated against satellite products, indicating that GPM performs well, with R-squared values ranging from 0.54 to 0.76 and correlation coefficients ranging from 0.45 to 0.69, respectively.

In the Martapura Watershed, South Kalimantan, due to a lack of observational discharge data, streamflow was generated using the FJ Mock …

Global, Continental, And Local Scale Paleoenvironmental Reconstruction Methods For Interpreting The History Of Miocene North America And The Great Plains, Willow Hue Nguy

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

The Miocene of North America is characterized by dynamic changes in herbivore communities, habitat composition, and global climate. Long-term cooling and drying trends influenced large changes in floral and faunal communities. The Great Plains, North America shifted from closed-canopy biomes to open-canopy biomes with C3-grasses to biomes with C4-grasses. This shift affected the herbivore communities as browsing-adapted ungulates were replaced by grazing-adapted ungulates. Much focus has centered on the Great Plains, so it is not well understood how the changes in biomes compare to other regions of North America. The models used for vegetation density indicate open-canopy biomes since at …

Residential Hvac Installation Faults: Field Prevalence, Drivers, And Energy Impacts, Seyed Ali Rooholghodos

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

Faults in residential comfort systems can have detrimental effects on the performance of the system, reducing the energy efficiency, affecting indoor comfort, and shortening equipment lifespan. Many of the faults occur at installation. However, there has not previously been a systematic and nationally representative study to indicate the prevalence of the faults, meaning the distribution of faults by fault type and fault intensity. Understanding true fault prevalence is essential to be able to identify derivers, and to assess the incremental electricity consumption of the new installation systems.

This study presents on-site data from 341 new central cooling systems—air conditioners and …

Large-Scale Experimental Study On The Impact Of Air Cleaning & Ventilation On Indoor Air Quality And Student Illness-Related Absenteeism, Daud Nosham

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

This large-scale randomized experimental field study investigated the effect of portable air purifiers (PAPs) on classroom’s air quality and student’s illness related absenteeism. PAPs were installed in 317 classrooms from various school districts located in Eastern Nebraska. The classrooms were randomly assigned into four conditions: three treatment conditions (T1, T2 & T3) and one control condition (device without any filter). T1 was equipped with HEPA filters, T2 added Activated Carbon (AC) layer to HEPA, and T3 further integrated Germicidal Ultraviolet (GUV) alongside HEPA and AC filters. The measured variables were carbon dioxide (CO2), fine particles (PN2.5) and coarse particles (PNcoarse), …

Assessing Crop Rotation Productivity, Soil Health, And Fertility, And Economic Performance, To Enhance Semi-Arid High Plains Cropping Systems Sustainability, Ezequiel Maria Villamil

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

Sustainable crop production in the semi-arid High Plains of Nebraska faces challenges from limited precipitation, high interannual variability, and economic risk. This dissertation investigates the long-term productivity, water use, soil health, and economic sustainability of dryland crop rotations, with emphasis on the role of pulses as alternatives to fallow.

Chapter 1 analyzes nearly three decades (1995–2023) of on-farm data from the High Plains Agricultural Laboratory (Sidney, Nebraska) to compare seven crop rotations, including wheat, corn, millet, sunflower, and field peas. Results showed that wheat–corn–fallow (W–C–F) consistently outperformed traditional wheat–fallow (W–F) and more intensified four-year rotations, providing the highest grain yields, …

Detecting Prescribed Fire, Haying And Grazing Events Via Remote Sensing To Create Grassland Disturbance Landcovers For The Ring-Necked Pheasant (Phasianus Colchicus), Megan A. Baldissara

School of Natural Resources: Dissertations, Theses, and Student Research

This dissertation developed disturbance detection models to fulfill the need for remote sensing landcover products describing grassland structure. The use of landcover products derived from remote sensing is increasing over time in pheasant (Phasianus colchicus) research. Such landcover, however, does not provide relevant pheasant structural habitat information (Chapter 1). Pheasants require tall, high-density grassland for nesting, tall grassland with medium density for brood rearing, and tall grassland for wintering. Time since disturbance can serve as a proxy for structure, as it shapes vegetation by removing biomass and resetting succession. Disturbance is easier to detect than structure with current …

On Bayesian Empirical Likelihood-Based Method For Complex Survey Data With Application To Non-Probability Sampling, Md Hasibur Rahman

Department of Statistics: Dissertations, Theses, and Student Research

This thesis develops a Bayesian empirical likelihood (BEL) framework for inference under complex survey designs and extends it to non-probability sampling. Parametric likelihood based methods are difficult to apply to complex survey data because the likelihood is rarely available in closed form. EL provides a flexible alternative by replacing the parametric likelihood with an empirical likelihood constructed from moment conditions. The proposed method first integrates empirical likelihood constraints with survey design features then extends BEL to non-probability sampling through selection models and design consistent restrictions. Posterior inference is carried out using a Metropolis–Hastings MCMC algorithm. A real-data analysis further illustrates …

Modeling The Greenland-Iceland-Faroe Ridge Using Integrated Geophysical Analysis, Zachary Clowdus

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

The Greenland-Iceland-Faroe Ridge (GIFR) is an area of significant geologic interest with anomalously thick crust related to enhanced melt generation from the interaction between the Mid-Atlantic Ridge and the Iceland hotspot. To the northeast of Iceland lies the Jan Mayen Microcontinent (JMMC), which is a continental fragment separated from Greenland during the opening of the Northern Atlantic. The overall extent of the JMMC, especially its southern boundary, remains poorly constrained. The crust beneath the GIFR is believed to be primarily of oceanic affinity. However, a recent discovery of felsic lavas in Iceland led to an alternative hypothesis that implies the …

The Urban Heat Island And Its Role In Shaping Convective Environments: An Observational Study, Benjamin W. Moll

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

The continued spread of urbanization and its well-documented effects on regional weather and climate necessitate further research. Urban environments are often warmer and drier than their rural surroundings. This trade-off between a warmer but drier environment could have a complex impact on deep convection and its initiation. Previous studies have noted significant changes in precipitation patterns around cities as well as changes to ongoing deep convection. Given the well-documented theory and past research, it is hypothesized here that urban areas have a significant impact on the PBL thermodynamics of convective environments. The urban heat island (UHI) component of the Micro …

Dancing With Logic: The Impact Of Integrating Dance In Teaching Introductory Computer Science Concepts On Student Understanding And Engagement, April Monk

Master's Theses

The purpose of this study was to investigate the effectiveness of dance-integrated pedagogical methods in enhancing the learning experiences of students in an introductory computer science course. In particular, the research aimed to measure the impact of creative movement on student comprehension, engagement, and perceptions of computer science. To guide this investigation, the study explored three research questions: Does integrating dance into lessons impact students’ comprehension of fundamental computer science concepts? How does dance integration affect student perceptions of both dance and computer science? And what elements of dance contribute to differences in comprehension between dance-integrated and traditional lessons? A …

N-Aryl Phenoxazines As Polymer Supported Photocatalysts, Mary Kathryn Hall

Master's Theses

In photosynthesis, the energy of sunlight is perfectly harnessed to facilitate the production of small molecules that are essential for plant life on earth. Inspired by this model of energy efficiency and simplicity, this work seeks to mimic that ability to use the energy in visible light to perform new and more efficient chemistries. Just like in photosynthesis, photocatalysts can act as chromophores absorbing light to excite electrons opening new pathways for previously untapped reactivity. Recent research has provided a wide range of small molecule reactions that are made possible or easier by the use of a photocatalyst. However, these …

A Learning‑Augmented Dynamic Programming Approach For Orienteering Problem With Time Windows, Guansheng Peng, Lining Xing, Fuyan Song Ma, Aldy Gunawan, Aldy Gunawan

Research Collection School Of Computing and Information Systems

Recent years have witnessed a surge of interest in solving combinatorial optimization problems (COPs) using machine learning techniques. Motivated by this trend, we propose a learning-augmented exact approach for tackling an NP-hard COP, the Orienteering Problem with Time Windows, which aims to maximize the total score collected by visiting a subset of vertices in a graph within their time windows. Traditional exact algorithms rely heavily on domain expertise and meticulous design, making it hard to achieve further improvements. By leveraging deep learning models to learn effective relaxations of problem restrictions from data, our approach enables significant performance gains in an …

Semi‑Supervised Graph Anomaly Detection Via Robust Homophily Learning, Guoguo Ai, Hezhe Qiao, Hui Yan, Guansong Pang

Research Collection School Of Computing and Information Systems

Current semi-supervised graph anomaly detection (GAD) methods utilizes a small set of labeled normal nodes to identify abnormal nodes from a large set of unlabeled nodes in a graph. These methods posit that 1) normal nodes share a similar level of homophily and 2) the labeled normal nodes can well represent the homophily patterns in the entire normal class. However, this assumption often does not hold well since normal nodes in a graph can exhibit diverse homophily in real-world GAD datasets. In this paper, we propose RHO, namely Robust Homophily Learning, to adaptively learn such homophily patterns. RHO consists of …

Implications Of The Attenuated Allee Effect On Population Dynamics, Dana Strong

All Graduate Theses and Dissertations, Fall 2023 to Present

The Allee effect is an ecological phenomenon characterized by a per capita growth rate that increases as the population size increases in the context of low population density. The Allee effect can lead to rapid extinction events. Consequently, ecologists can attempt to control the strength of the Allee effect to help increase the population (in the case of endangered species) or decrease the population (in the case of parasites or pests).

This research aimed to study not the strength of the Allee effect, but the intensity of the Allee effect, or how rapidly cooperation between individuals causes the per capita …

(R2137) Smarandache Curved Ruled Surfaces And Their Characterizations According To Modified Orthogonal Frame In E^3, Gülnur Şaffak Atalay

Applications and Applied Mathematics: An International Journal (AAM)

In this study, the ruled surfaces generated by Smarandache curves are expressed according to the modified orthogonal frame defined according to both curvature and torsion of the given unit speed curve in 3-dimensional Euclidean space; some special characterizations of these surfaces such as developability, striction curves, distribution parameters are given. In addition, some examples of these surfaces are given in graphical form. We use Maple to draw the graphs of the examples.

(R2130) Cusum-Test For Unconditional Variance Change Detection In Bilinear Garch Models, Edoh Katchekpele, Abdou Kâ Diongue, Ben Célestin Kouassi

Applications and Applied Mathematics: An International Journal (AAM)

We examine CUSUM-type test for detecting changes in unconditional variance within Bilinear GARCH models. We derive the asymptotic distribution of the test statistic under both null and alternative hypotheses and assess test effectiveness in identifying single structural breaks. Simulation studies support our theoretical results and demonstrate the practical utility of the test.