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Articles 8791 - 8820 of 293734
Full-Text Articles in Entire DC Network
A Simulation Study On A Dual-Borehole Dc Resistivity System For Advance Detection Under Varying Angles, Zhou Guanqun, Xu Shaotian, Zhang Weixin, Wang Yafei, Wu Xiaoping, Hu Xiongwu, Chen Xinghai, Cao Yu
A Simulation Study On A Dual-Borehole Dc Resistivity System For Advance Detection Under Varying Angles, Zhou Guanqun, Xu Shaotian, Zhang Weixin, Wang Yafei, Wu Xiaoping, Hu Xiongwu, Chen Xinghai, Cao Yu
Coal Geology & Exploration
Significance Mine direct current (DC) methods, an efficient geophysical exploration technique, can be used to identify and delineate underground electrical resistivity anomalies, serving as a critical means for the advance detection of water-bearing or hydraulically conductive structures ahead of the mining face. Methods By combining the water exploration and discharge boreholes commonly used in coal mining and making reference to the observation system of the ground-based cross-borehole DC resistivity CT method, this study devised a dual-borehole DC resistivity observation system for advance detection. Through numerical simulation using the COMSOL software, this study constructed a homogeneous full-space model, in which a …
Structural Evolution And Spontaneous Combustion And Activation Mechanisms Of Coals Treated Under Inert Atmospheres In A Coal Mine Goaf, Zhang Leilin, Li Wanting, Wen Chenchen
Structural Evolution And Spontaneous Combustion And Activation Mechanisms Of Coals Treated Under Inert Atmospheres In A Coal Mine Goaf, Zhang Leilin, Li Wanting, Wen Chenchen
Coal Geology & Exploration
Objective When used for the treatment of fire zones in deep coal mine goafs, low-oxygen and inertization techniques suffer from a scientifically blind spot, i.e., the fire prevention and control bottleneck caused by a high susceptibility to re-ignition of coals after being treated with high-temperature, low-oxygen (or inert) gas. To overcome this limitation, this study aims to systematically determine the mechanisms by which the evolution of the physical and chemical structures of coals after heat treatment under different atmospheres influences their spontaneous combustion and activation behavior. The purpose is to provide theoretical support for the treatment and safe opening of …
A Method For Interpretating Acoustic Reflection Imaging Logging Data Of Fractured-Vuggy Reservoirs Based On Their Theoretical Response Characteristics, Huang Ruokun, Jiang Kai, Wu Xingneng, Ma Kunyu, Su Yuanda, Wang Bing, Chen Xu
A Method For Interpretating Acoustic Reflection Imaging Logging Data Of Fractured-Vuggy Reservoirs Based On Their Theoretical Response Characteristics, Huang Ruokun, Jiang Kai, Wu Xingneng, Ma Kunyu, Su Yuanda, Wang Bing, Chen Xu
Coal Geology & Exploration
Objective During the exploration and development of fractured-vuggy carbonate reservoirs, acoustic reflection imaging logging technology enables the detection of fractured-vuggy bodies around wells. However, this technology suffers from unclear response characteristics and a strong multiplicity of solutions. Focusing on the Tarim Oilfield, this study aims to establish a tailored interpretation method by integrating geological and geophysical characteristics. The purpose is to enhance the identification accuracy and reliability of fractured-vuggy bodies in these reservoirs. Methods Based on the distribution characteristics of fractured-vuggy carbonate reservoirs in the Tarim Oilfield, this study established the numerical simulation models of three typical fractured-vuggy bodies: inter-breccia …
Numerical Simulations Of Dynamic Rock Damage Under Laser-Induced Shock Waves, Xu Yuelin, Qin Enwei, Li Wei, Wang Ying
Numerical Simulations Of Dynamic Rock Damage Under Laser-Induced Shock Waves, Xu Yuelin, Qin Enwei, Li Wei, Wang Ying
Coal Geology & Exploration
Objective Traditional laser thermal rock breaking technologies suffer from high energy consumption and a limited damage depth. To overcome these challenges, this study proposed a novel mechanical rock breaking method based on high-pressure plasma shock waves induced by short pulsed lasers, aiming to transform a thermodynamics-dominated rock breaking mechanism into a dynamics-dominated mechanism. Methods and Results Under the Abaqus/Explicit explicit dynamics framework, this study constructed a finite element model to simulate the interactions between nanosecond laser-induced shock waves and rocks. The accurate loading of shock wave pressure in the spatial and temporal domains was achieved using the VDLOAD user subroutine. …
A Novel Model For Calculating In Situ Stress Within Deep Coal Seams Considering Microstructural Characteristics And Its Application, Zhao Haifeng, Shi Hongwei, Xie Fei, Wang Chengwang, Wang Zongfei, Chen Gaojie
A Novel Model For Calculating In Situ Stress Within Deep Coal Seams Considering Microstructural Characteristics And Its Application, Zhao Haifeng, Shi Hongwei, Xie Fei, Wang Chengwang, Wang Zongfei, Chen Gaojie
Coal Geology & Exploration
Objective Research on in situ stress serves as a bridge between geological and engineering analyses. Accurate insights into in situ stress regimes are crucial for ensuring engineering efficiency and development benefits. However, microstructures are well developed in deep coal seams, for which no effective model is currently available for calculating in situ stress. Methods and Results By classifying structures into macrostructures and microstructures, this study established a novel model for calculating in situ stress in deep coal seams while considering microstructural characteristics. In the novel model, the horizontal in situ stress was decomposed into three components: the horizontal components induced …
Technique For Water-Preserved Coal Mining Based On Zonal Height Limits Along Mining Face And Mechanisms Behind Overburden Failure, Sun Xueyang, Cao Hongyi, Li Peng, Han Dehao, Luo Qiyao, Liu Kuan, Li Jihong, Yin Xu
Technique For Water-Preserved Coal Mining Based On Zonal Height Limits Along Mining Face And Mechanisms Behind Overburden Failure, Sun Xueyang, Cao Hongyi, Li Peng, Han Dehao, Luo Qiyao, Liu Kuan, Li Jihong, Yin Xu
Coal Geology & Exploration
Objective The exploitation of shallow coal seams under water bodies faces a contradiction between water resource preservation and overburden disturbance. In this case, achieving safe mining while preventing water-conducting fracture zones from affecting key aquifers and exploring techniques that place equal emphasis on water preservation and efficient resource recovery have emerged as popular research topics. Methods An integrated aquifer-overburden-coal seam model was constructed using 3D geological visualization technology. This model, combined with the principles for the setting up of waterproof coal pillars, enabled accurate delineation of zones with water inrush risks. Accordingly, a technical scheme for mining based on zonal …
Simulation Of Groundwater Flow Field Evolution And Water Inrush Risks Under The Deep-Well Reinjection Of High-Tds Mine Water, Liu Qi, Sun Yajun, Fan Jianguo, Tan Xianfeng, Xiao Shengxin, Yang Chuanwei, Chen Weiyang, Chen Ge
Simulation Of Groundwater Flow Field Evolution And Water Inrush Risks Under The Deep-Well Reinjection Of High-Tds Mine Water, Liu Qi, Sun Yajun, Fan Jianguo, Tan Xianfeng, Xiao Shengxin, Yang Chuanwei, Chen Weiyang, Chen Ge
Coal Geology & Exploration
Objective The deep-well reinjection of mine water results in a regional groundwater level rise to varying degrees, possibly inducing hydrogeological hazards such as floor water inrushes or water inrushes along faults. In this context, determining the evolutionary pattern of the groundwater flow field under long-term mine water reinjection and conducting reinjection safety assessments play a critical role in ensuring both the safety of mine water reinjection and water conservation-based coal mining.Methods This study examined the reinjection of mine water in a coal mine within the Juye coalfield, North China. Based on the geological conditions for mine water reinjection in …
An Experimental Study On The Deterioration Characteristics Of Sandstone Masses With Rock Bridges Under Cyclic Freezing And Thawing, Zhang Huimei, Li Zengle, Chen Shiguan, Yuan Chao, Zheng Shihang
An Experimental Study On The Deterioration Characteristics Of Sandstone Masses With Rock Bridges Under Cyclic Freezing And Thawing, Zhang Huimei, Li Zengle, Chen Shiguan, Yuan Chao, Zheng Shihang
Coal Geology & Exploration
Objective To determine the deformation and failure mechanisms of fractured rock masses with rock bridges in alpine regions, this study conducted mechanical property tests on rock samples with varying lengths of rock bridges subjected to cyclic freezing and thawing. Methods Through experiments, this study summarized the characteristics of the static strength deterioration of rock masses under the combined effects of different numbers of freezing and thawing cycles and varying rock bridge lengths. By combining acoustic emission signal monitoring and scanning electron microscopy, this study thoroughly explored both the evolutionary characteristics of fractures and rock rupture modes. Accordingly, it revealed the …
Table Of Contents, The Editors
Reservoir Responses To Reactions In Co2 Mineral Trapping And Geologic Carbon Sequestration Prospects For Basalts In Western Guizhou Province, China, Han Sijie, Ai Zhixi, Liu Jijie, Zhou Xiaozhi, Gao Wei, Liu Zhu
Reservoir Responses To Reactions In Co2 Mineral Trapping And Geologic Carbon Sequestration Prospects For Basalts In Western Guizhou Province, China, Han Sijie, Ai Zhixi, Liu Jijie, Zhou Xiaozhi, Gao Wei, Liu Zhu
Coal Geology & Exploration
Background Geologic CO2 sequestration in basalts has attracted wide attention in recent years owing to its safe, stable, and efficient CO2 trapping mechanisms.Methods Focusing on basalts in the Longtan Formation within western Guizhou Province, China, this study simulated the CO2-water-basalt geochemical reactions under varying temperatures, pressures, and times. Through tests and comparison of mineralogy, geochemistry, and reservoir physical properties before and after the reactions, this study investigated the factors influencing the reactions and elucidated the post-reaction co-evolution mechanism between minerals and pores. Furthermore, the mechanisms behind CO2 trapping in basalts were summarized, and the …
Spatial Distribution And Source-Sink Matching Of Stationary Co2 Emissions In Zhejiang Province, Zhu Qianlin, Chen Dongbao, Liu Hanxiao, Lu Shijian, Chen Fu
Spatial Distribution And Source-Sink Matching Of Stationary Co2 Emissions In Zhejiang Province, Zhu Qianlin, Chen Dongbao, Liu Hanxiao, Lu Shijian, Chen Fu
Coal Geology & Exploration
Objective Carbon capture, utilization, and storage (CCUS) is supposed to become an essential technology for the consumption of fossil fuels under the background of achieving carbon neutrality. Delving into the spatial distribution of regional CO2 stationary sources and the source-sink matching characteristics will contribute to more rational decision-making in CCUS deployment and promote the development of carbon sequestration technology. Methods This study investigated the spatial distribution of CO2 stationary sources in Zhejiang Province and, using the carbon emission factor method, assessed their CO2 emissions based on their scales. Furthermore, it analyzed the geological features of both onshore …
Supersaturation Effect And Its Characterization In Gas-Rich Intervals Of Deep Coal Seams, Zhou Lihong, Li Yong, Ding Rong, Li Yun, Li Yongzhou, Kong Jintao
Supersaturation Effect And Its Characterization In Gas-Rich Intervals Of Deep Coal Seams, Zhou Lihong, Li Yong, Ding Rong, Li Yun, Li Yongzhou, Kong Jintao
Coal Geology & Exploration
Objective and Method High free gas content serves as a key factor controlling the enrichment and high productivity of deep coalbed methane (CBM). However, its direct determination is challenging, making the accurate identification of free gas-rich coal seam intervals a core scientific issue for efficient exploration and recovery of CBM. This study investigated the Daning-Jixian block (also referred to as the Daji Block) within the Ordos Basin. Based on analyses and tests of the gas content, coal macrolithotype, physical properties, and log responses of cores collected from representative wells through pressure-retained coring, this study systematically assessed the vertical heterogeneity of …
Physical Simulation Experiments On 4d Visualization Of Dynamic Methane Diffusion And Adsorption In Low-Porosity And Low-Permeability Coals, Liu Tong, Jiao Baizhuo, Lin Baiquan, Sang Shuxun, Yang Wei, Liu Shiqi, Liu Ting, Li He, Yang Mingxing
Physical Simulation Experiments On 4d Visualization Of Dynamic Methane Diffusion And Adsorption In Low-Porosity And Low-Permeability Coals, Liu Tong, Jiao Baizhuo, Lin Baiquan, Sang Shuxun, Yang Wei, Liu Shiqi, Liu Ting, Li He, Yang Mingxing
Coal Geology & Exploration
Objective and Method The diffusivity of methane (CH4) in coal seams significantly influences the surface extraction of coalbed methane (CBM) and underground gas drainage. However, the visualized characterization of the diffusion and migration processes of CH4 in coals remains challenging. To address this issue, this study systematically demonstrated the similarity between krypton (Kr) and CH4 in their adsorption and diffusion behavior in coals. Utilizing Kr—a gas with high X-ray attenuation—as a tracer substitute for CH4, this study achieved the transparent observation of the dynamic gas migration process in low-porosity, low-permeability, and heterogeneous coals using …
Organically-Bound Forms Of Alkali And Alkaline Earth Metals In High-Alkali Coals And Their Geological Indications, Wang Xiaoling, Wang Shaoqing, Zhao Yungang, Mu Ruifeng, Shao Yan
Organically-Bound Forms Of Alkali And Alkaline Earth Metals In High-Alkali Coals And Their Geological Indications, Wang Xiaoling, Wang Shaoqing, Zhao Yungang, Mu Ruifeng, Shao Yan
Coal Geology & Exploration
Objective and Method Alkali and alkaline earth metals (AAEMs) in coals adversely affect coal processing and utilization. Among the AAEMs, water-soluble and mineral-hosted metals can be largely removed through water washing, flotation, and heavy liquid separation, while organically-bound AAEMs are difficult to eliminate. In this study, high-alkali coal samples with varying vitrinite/inertinite ratios (V/Is) collected from the Zhundong coalfield in Xinjiang were selected to investigate the organically-bound forms of AAEMs. Through sequential chemical extraction, combined with experimental techniques such as 23Na cross-polarization magic-angle spinning nuclear magnetic resonance (23Na CP/MAS NMR) and transmission electron microscopy-energy dispersive …
Mechanisms Behind Soil Water Evaporation And Infiltration During Long-Term Microbial Reclamation In Coal Mining-Induced Subsidence Areas In Northern Shaanxi Province, China, Ke Zengming, Bi Yinli, Yang Wei
Mechanisms Behind Soil Water Evaporation And Infiltration During Long-Term Microbial Reclamation In Coal Mining-Induced Subsidence Areas In Northern Shaanxi Province, China, Ke Zengming, Bi Yinli, Yang Wei
Coal Geology & Exploration
Background Water scarcity is identified as an important factor restricting ecological restoration in arid and semi-arid mining areas. The application of microbial reclamation technologies, especially inoculation with Arbuscular mycorrhizal fungi (AMF), has achieved encouraging ecological effects in mining areas. In this case, investigating soil water movement and its controlling factors in mining areas undergoing long-term microbial reclamation is a key scientific issue for understanding the long-term ecological restoration mechanisms of AMF. Methods This study investigated the microbial reclamation base in the coal mining-induced subsidence area of the Daliuta coal mine of northern Shaanxi Province, located in the middle reaches of …
An Experimental Study On The Selection Of Slow-Release Carbon Source Materials For Sulfate-Reducing Bacteria-Based Remediation Of High-Sulfate Mine Water In Coal Mines, Xiahou Ming’An, Zhang Li, Xu Zhimin, Guo Juan, Chen Ge, Xiong Xiaofeng, Sun Yajun
An Experimental Study On The Selection Of Slow-Release Carbon Source Materials For Sulfate-Reducing Bacteria-Based Remediation Of High-Sulfate Mine Water In Coal Mines, Xiahou Ming’An, Zhang Li, Xu Zhimin, Guo Juan, Chen Ge, Xiong Xiaofeng, Sun Yajun
Coal Geology & Exploration
Background High-sulfate mine water poses a major aquatic environmental challenge in coal mining areas across China. Accordingly, the cost-effective and efficient treatment of such water has become an urgent need for the sustainable development of the mining industry. Despite its considerable promise, microbial remediation based on sulfate-reducing bacteria (SRB) shows limited efficiency due to the scarcity of dissolved organic carbon (DOC) in mine water.Methods The application of external slow-release carbon source (SRC) materials for SRB faces a range of challenges, such as the potentially excessive release of organic carbon in the initial stage, the unclear release mechanisms of dissolved …
Failure Mechanisms And Energy Dissipation Characteristics Of Anchorage Bodies Under Dynamic Loading, Wang Changcheng, Yang Ke, Liu Wenjie, Zhang Zhainan, Zheng Shizhang, Xu Rijie, Guo Penghui
Failure Mechanisms And Energy Dissipation Characteristics Of Anchorage Bodies Under Dynamic Loading, Wang Changcheng, Yang Ke, Liu Wenjie, Zhang Zhainan, Zheng Shizhang, Xu Rijie, Guo Penghui
Coal Geology & Exploration
Objective Under intense mining in deep parts of coal mines, the roadway support systems are significantly affected by both far- and near-field dynamic loads, accompanied by the strong deformations of the surrounding rocks. Therefore, investigating the failure mechanisms of anchorage bodies under dynamic loading becomes particularly important. Methods Using the split Hopkinson pressure bar (SHPB) test system and digital image correlation (DIC) technology, the study investigated the mechanical response characteristics of the anchorage bodies under different impact air pressures. Accordingly, it determined dynamic stress-strain relationships, energy dissipation characteristics, cracks’ evolutionary patterns, and failure modes of anchorage bodies. Results and Conclusions …
Advances In Research And Future Prospects Of Borehole Geophysical Prospecting Technology For Coal Mines, Li Ping, Wei Rong, Fan Tao, Zhao Rui, Jiang Bici, Tian Xiaochao, Wang Bingchun
Advances In Research And Future Prospects Of Borehole Geophysical Prospecting Technology For Coal Mines, Li Ping, Wei Rong, Fan Tao, Zhao Rui, Jiang Bici, Tian Xiaochao, Wang Bingchun
Coal Geology & Exploration
Background Borehole geophysical prospecting technology for coal mines integrates the advantages of both drilling and geophysical prospecting. Accordingly, multiple critical advances have been achieved in its applications to the technologies and equipment for intelligent coal mining in recent years, enabling long-distance, relatively high-precision geological exploration. This technology plays an increasingly important role in a range of fields, including deep mineral resource exploration and the reconnaissance surveys of hidden disaster-causing factors, providing robust support for safe and efficient coal mining. Advances This study systematically reviews the development history of borehole geophysical prospecting technology, elaborating advances in research on the methodology, theories, …
2025 December 25 - Tennessee Weekly Drought Summary, Tennessee Climate Office, East Tennessee State University
2025 December 25 - Tennessee Weekly Drought Summary, Tennessee Climate Office, East Tennessee State University
Tennessee Climate Office Weekly Drought Summaries
No abstract provided.
Novel Spectrophotometric Method For The Determination Of Paclitaxel Through Complex Formation With Osmium, Basima A.A.Saleem, Salim A. Mohammed, Amer Th. Al-Taee
Novel Spectrophotometric Method For The Determination Of Paclitaxel Through Complex Formation With Osmium, Basima A.A.Saleem, Salim A. Mohammed, Amer Th. Al-Taee
Turkish Journal of Chemistry
Paclitaxel (Pac) is an important anticancer bioactive compound, and the availability of an accurate and robust analytical method for its quantification is of utmost importance. In this investigation, a novel, direct, and reliable spectrophotometric method has been proposed for the estimation of Pac via a complex formation reaction with osmium (Os). The method was based on the reaction of Pac with Os tetroxide, which produced a yellowish-brown complex. The resulting complex is soluble in water and displays a maximum absorption peak at 482 nm. The reaction conditions, including reactant concentration, pH, temperature, and reaction time, were optimized to obtain the …
Enhancing Analytical Performance Of Tyrosinase-Based Sensors With Nanoparticles For Detection Of Isoproterenol, Aysel Oktay, Sevi̇nç Kurbanoğlu, Gülsüm Gündoğdu, Cem Bülent Üstündağ, Frieder W. Scheller, Aysu Yarman
Enhancing Analytical Performance Of Tyrosinase-Based Sensors With Nanoparticles For Detection Of Isoproterenol, Aysel Oktay, Sevi̇nç Kurbanoğlu, Gülsüm Gündoğdu, Cem Bülent Üstündağ, Frieder W. Scheller, Aysu Yarman
Turkish Journal of Chemistry
In this work, electrochemical biosensors utilizing tyrosinase (Tyr) for the detection of the nonselective beta-adrenergic agonist isoproterenol (ISO) are presented. Three different configurations for immobilizing Tyr on a graphite electrode (GE) are compared: (1) GE modified with poly(diallyldimethylammonium chloride) (PDADMAC), PDADMAC/Tyr/GE; (2) PDADMAC combined with iridium nanoparticles (IrNPs) in a stepwise preparation, resulting in PDADMAC/IrNPs/Tyr/GE; and (3) a composite of PDADMAC and IrNPs mixed with Tyr at a 1:1 (v:v), forming PDADMAC/(IrNPs-Tyr)/GE. Surface morphology was characterized using scanning electron microscopy (SEM). Cyclic voltammetry (CV) and amperometry were applied to characterize the biosensor’s performance. Within the linear range of 5 μM …
Synthesis, Characterization, Antimicrobial, Antioxidant, And Antiinflammatory Evaluation And Molecular Docking Studies Of N-((2-Hydroxy-3-(2-(Substitutedbenzylidene)Hydrazine-1-Carbonyl)Naphthalen-1-Yl)(3-Nitrophenyl/3,4-Dimethoxyphenyl)Methyl)Acetamide Derivatives, Shikha Kamboj, Alka Yadav, Samridhi Thakral, Rekha Tanwar, Sunil Kumar, Vikramjeet Singh
Synthesis, Characterization, Antimicrobial, Antioxidant, And Antiinflammatory Evaluation And Molecular Docking Studies Of N-((2-Hydroxy-3-(2-(Substitutedbenzylidene)Hydrazine-1-Carbonyl)Naphthalen-1-Yl)(3-Nitrophenyl/3,4-Dimethoxyphenyl)Methyl)Acetamide Derivatives, Shikha Kamboj, Alka Yadav, Samridhi Thakral, Rekha Tanwar, Sunil Kumar, Vikramjeet Singh
Turkish Journal of Chemistry
Hydrazone chemistry has become important and plays a key role in the development of organic compounds. Hydrazones can be useful pharmacophores for creating novel derivatives, owing to their broad range of activities. In this study, a series of N-((2-hydroxy-3-(2-(substitutedbenzylidene)hydrazine-1-carbonyl)naphthalen-1-yl)(3-nitro-phenyl/3,4-dimethoxyphenyl)methyl)acetamide derivatives were prepared, characterized by FTIR, 1H-NMR, 13C-NMR, and mass spectroscopy, and evaluated for their antimicrobial, antiinflammatory, and antioxidant activities along with in silico studies. The substituted derivatives were synthesized by the reaction of acetonitrile, chlorosulphonic acid, and substituted benzaldehyde with the hydrazones. The antimicrobial evaluation showed that compound 3i had more antimicrobial potential than the other tested molecules. Compound 3j …
Structural Categorization And Identification Of Electrostatic Interactions In Two Proposed Human Serum Albumin Dimerization Patterns And Dipyridamole Interaction, Haluk Çeti̇nok, Veyi̇s Karakoç, Erol Erçağ, Yusuf Meli̇h Şekerer, Hasan Demi̇rci̇
Structural Categorization And Identification Of Electrostatic Interactions In Two Proposed Human Serum Albumin Dimerization Patterns And Dipyridamole Interaction, Haluk Çeti̇nok, Veyi̇s Karakoç, Erol Erçağ, Yusuf Meli̇h Şekerer, Hasan Demi̇rci̇
Turkish Journal of Chemistry
Human serum albumin (HSA) is a ubiquitous, multifunctional protein responsible for the systemic distribution of both endogenous metabolites and exogenous pharmaceuticals. Its inherent properties, particularly its ability to seep into tissues and its multiple ligand-binding sites, have rendered HSA an attractive vehicle for nanoparticle-based drug delivery systems, particularly for cancer targeting. In this study, we present high-resolution crystallographic data revealing two distinct dimerization patterns of HSA (Protein Data Bank [PDB] ID: 9V61) obtained under high-concentration crystallization conditions, along with results from dipyridamole docking. Both dimer types demonstrate extensive interface areas and a significant number of electrostatic interactions. Comparative analysis with …
Α-Glycosidase Activity Of Novel Coumarin–Triazole–Coumarin Dyads, Ersi̇n Şi̇ri̇n, Esra Sevi̇mli̇, Gökçe Seyhan, Burak Barut, Yunus Kaya, Baybars Köksoy
Α-Glycosidase Activity Of Novel Coumarin–Triazole–Coumarin Dyads, Ersi̇n Şi̇ri̇n, Esra Sevi̇mli̇, Gökçe Seyhan, Burak Barut, Yunus Kaya, Baybars Köksoy
Turkish Journal of Chemistry
Novel coumarin–triazole–coumarin dyads were synthesized and characterized, and their α-glycosidase inhibitory activities were evaluated spectrophotometrically. Compound 4e exhibited the most pronounced inhibitory effect, with an IC50 value of 38.98 ± 0.77 μM. The IC50 values for 4d and 4a were 93.55 ± 1.70 μM and 95.04 ± 3.55 μM, respectively. The Lineweaver–Burk plot showed that 4e inhibited α-glycosidase in a mixed type. In addition, the Ki value obtained from the Dixon plot was 19.95 ± 0.15 μM for α-glycosidase.
Bioorganometallic Tagging Of N-Acetylhistamine With An Fe(Co)₃ Unit: Synthesis, X-Ray Structure, And Protonation Behavior, Salah Merniz, Louiza Himed, Rofia Djerri, Belkis Akachat
Bioorganometallic Tagging Of N-Acetylhistamine With An Fe(Co)₃ Unit: Synthesis, X-Ray Structure, And Protonation Behavior, Salah Merniz, Louiza Himed, Rofia Djerri, Belkis Akachat
Turkish Journal of Chemistry
This study highlights the potential of organometallic carbonyl complexes as selective markers for biomolecules, enabling sensitive infrared (IR) detection. The regio- and stereoselective coupling of N-acetylhistamine, a histidine analogue, with the precursor complex 1 [Fe(CO)₃(1,4-η⁵-N-pyridiniocyclohexa-1,3-diene)] BF₄ affords the labeled complex 3 [Fe(CO)₃(1,4-η⁵-N-acetylhistaminocyclohexa-1,3-diene)]. X-ray diffraction (XRD) confirms the exo stereochemistry and reveals a rigid, well-defined architecture. IR and 1H nuclear magnetic resonance spectroscopic studies combined with IR-monitored acid–base titration demonstrate the complex’s stability in aqueous media between pH 5 and 8, alongside a modest increase in basicity relative to the free ligand. These findings establish the Fe(CO)₃ moiety as a robust …
Utilization Of Dual Catalysts For High-Yield Boron Nitride Nanotube Synthesis Via Chemical Vapor Deposition, Şaban Kalay
Utilization Of Dual Catalysts For High-Yield Boron Nitride Nanotube Synthesis Via Chemical Vapor Deposition, Şaban Kalay
Turkish Journal of Chemistry
The direct synthesis of boron nitride nanotubes (BNNTs) via chemical vapor deposition (CVD) in high-temperature furnaces remains highly challenging due to difficulties in optimizing key experimental parameters such as synthesis temperature and catalyst composition. These challenges often result in uncontrolled growth behavior, adversely affecting the quality and yield of the BNNTs. In this study, colemanite was effectively utilized as a boron source for the high-yield synthesis of directionally aligned BNNTs. The synthesis was carried out using a CVD method that used a dual-catalyst system comprising Fe2O3 and MgO in conjunction with a silicon carbide template under high-temperature conditions. The resulting …
New Bis-Piperazine Derivatives: Synthesis, Characterization (Ir, Nmr), Gamma-Ray Absorption, Antimicrobial Activity, Molecular Docking And Dynamics Study, Yasemi̇n Ünver, Arzu Coşkun, Fati̇h Çeli̇k, Hali̇l İbrahi̇m Güler, Kadri̇ye İnan Bektaş
New Bis-Piperazine Derivatives: Synthesis, Characterization (Ir, Nmr), Gamma-Ray Absorption, Antimicrobial Activity, Molecular Docking And Dynamics Study, Yasemi̇n Ünver, Arzu Coşkun, Fati̇h Çeli̇k, Hali̇l İbrahi̇m Güler, Kadri̇ye İnan Bektaş
Turkish Journal of Chemistry
A series of novel bis-piperazine derivatives (2a–2f) were synthesized and structurally characterized via Fourier transform-infrared and nuclear magnetic resonance spectroscopic techniques. Their gamma-ray shielding efficiencies were investigated through simulations on the Monte Carlo-based Geant4-GATE platform, and the results were benchmarked against data obtained from the XCOM and Phy-X software. A simulation model incorporating an NaI scintillation detector and a point gamma source was developed. Key shielding parameters, including mass attenuation coefficient, linear attenuation coefficient, half-value layer, and mean free path (MFP), were evaluated at gamma energies of 80, 120, 662, 1173, and 1332 keV. Additionally, the energy absorption buildup factor …
Efficient Recovery Of Y3+ From Aqueous Media Using Mdlm Technique:Transport Behavior And Kinetic Modeling, Volkan Demi̇rel, Ramazan Donat, Hacer Şensöz
Efficient Recovery Of Y3+ From Aqueous Media Using Mdlm Technique:Transport Behavior And Kinetic Modeling, Volkan Demi̇rel, Ramazan Donat, Hacer Şensöz
Turkish Journal of Chemistry
This study investigates the extraction behavior of Y³⁺ ions using a Multi-Dropped Liquid Membrane (MDLM) system that employs di(2-ethylhexyl) phosphoric acid (D₂EHPA) as the carrier ligand. The focus is on the system’s ability to transport ions between aqueous phases selectively. The extracted complex was analyzed spectrophotometrically via ultraviolet–visible (UV–Vis) measurements after complexation with 0.05% Arsenazo III. The aim of this study was to determine the influence of the optimum D₂EHPA carrier concentration, together with the pH and temperature conditions of the donor and acceptor phases, on the system’s extraction performance. Accordingly, a series of extraction experiments was performed at different …
Shaking Table Test And Numerical Simulation Of Seismic Response Characteristics Of Rock Slope With Muddy Interlayer, Duan Chenggang, Fang Yanlin, Tian Yeqing, Zhou Zhijun
Shaking Table Test And Numerical Simulation Of Seismic Response Characteristics Of Rock Slope With Muddy Interlayer, Duan Chenggang, Fang Yanlin, Tian Yeqing, Zhou Zhijun
Journal of China & Foreign Highway
In order to study the seismic macroscopic failure process and dynamic response characteristics of rock slope with muddy interlayer and reveal the influence of muddy interlayer on slope stability,a similar slope model with concave and convex slope types was designed,and shaking table test was carried out;finite element analysis was used for numerical modeling analysis,and the results obtained by the two models were compared.The results show that:① The macroscopic deformation and failure process of the model slope is divided into three stages.Muddy interlayer dislocates,and cracks occur;mud interlayer slips,and cracks expand;slope collapses;② The seismic load has a decisive influence on the stability …
Effect Of Lithium Slag Dosage On Strength And Dry Shrinkage Properties Of Cement Stabilized Recycled Macadam, Zhao Ziyu, Gan Xianyong
Effect Of Lithium Slag Dosage On Strength And Dry Shrinkage Properties Of Cement Stabilized Recycled Macadam, Zhao Ziyu, Gan Xianyong
Journal of China & Foreign Highway
To improve the mechanical properties and dry shrinkage properties of cement stabilized bases formed by cold in-place recycling of cement concrete pavements,lithium slag was mixed into the recycled mixture in mass ratios of 0%,6%,9%,and 12%.The effects of lithium slag dosage on the mechanical,dry shrinkage,and water stability properties of the recycled base were analyzed through the unconfined compressive strength,splitting,dry shrinkage,and water stability tests,and the mechanism underlying the improving effect of lithium slag on the cement stabilized base formed by cold in-place recycling of the cement concrete pavement was analyzed by X-ray diffraction (XRD ) and scanning electron microscopy (SEM ).The results …