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Utilizing Coal For Mesophase Pitch-Based Carbon Fiber Production: Precursors, Processes, And Progress, Christina M. Thompson

Theses and Dissertations--Chemistry

Graphitic materials possess unique properties due to the unique combination of layered crystalline structure and carbon’s low atomic weight. High performance carbon fiber is one such example, displaying exceptional strength-to-weight ratios, stiffness, and thermal and chemical resistance. These properties render high performance carbon fiber a critical structural reinforcement material in the manufacture of composites across various industries, such as for automotive and aerospace applications. However, balancing fiber performance with precursor and processing costs remains a challenge. As alternative carbonaceous feedstocks are explored, coal has gained interest for utilization in graphitic products as a relatively abundant and low-cost source of aromatic …

Elucidating The Impacts Of Non-Covalent Interactions In Organic Materials Through A Multiscale Computational Approach, Sashen A. Ruhunage

Theses and Dissertations--Chemistry

Noncovalent interactions (NCIs) in π-conjugated organic materials serve as tunable levers that influence molecular structure and intermolecular interactions in the condensed phase and, in turn, impact the electronic, optical, and mechanical properties of these materials. NCIs include attractive dispersion, electrostatic, and induction interactions, as well as repulsive exchange interactions. However, how to design materials with NCI considerations remains an open question across many fields. Here, we seek to provide an electronic and atomistic perspective on these interactions through multiscale simulations to aid materials design, processing, and performance optimization. In this study, we investigate NCIs and their effects across various systems …

Student Familiarity With The Periodic Table Of The Elements: Results From Cued-Recall And Eye-Tracking Assessments On Memory, Victor A. Okuo

Theses and Dissertations--Chemistry

Learning element symbol–name associations and the spatial organization of elements on the periodic table is a foundational step in learning chemistry, supporting later understanding of chemical formulas, equations, bonding, and stoichiometry. Although students often rely on memorization strategies to learn periodic table content, this task is challenging due to the large number of elements and the apparent ambiguity in matching some element symbols to their names.

This study explores students’ recall of element names when given element symbols as cues and their knowledge of element locations on the periodic table when given element names as cues. The study also examines …

Symbolic Logistic Regression For Interval-Valued Predictors: A Simulation Study And Application To Health Data, Soad Abdullah

Graduate Research Theses & Dissertations

This thesis investigates symbolic logistic regression for interval-valued predictors through simulation studies and a real health data application. Classical logistic regression assumes exact predictor values, whereas in many practical settings variables are available only in interval form due to coarsening or reporting uncertainty. Two simulation studies examine the impact of interval uncertainty under asymmetric intervals and measurement error. Symbolic models based on midpoint and midpoint-plus-width representations are compared with the classical approach. Results show that midpoint modeling captures the general relationship but introduces bias under asymmetry, while incorporating width reduces this distortion. Under measurement error, classical logistic regression exhibits attenuation …

Plant Practices And Community At The Heart Of Hopewell: Paleoethnobotany At The Overly Site And Beyond, Abigail Deewaard

Graduate Research Theses & Dissertations

Paleoethnobotanical analyses of Ohio Hopewell habitation sites in past decades have shed light on the subsistence practices, settlement patterns, and environmental management of Indigenous peoples engaged in what archaeologists describe as the Hopewell phenomenon. However, comparatively less attention has been paid to the social dimensions of plant use, particularly at habitation sites in the Scioto Hopewell region. Hopewell is an archaeological term that refers to the Middle Woodland (ca. 100 BCE–400 CE) network of interregional relationships across eastern North America characterized by long-distance exchange, monumental earthwork construction, and ceremonial practices including the honoring of ancestors. This thesis applies a social …

New Methods For Bright Electron Beam Generation At The Argonne Wakefield Accelerator Facility, Emily Frame

Graduate Research Theses & Dissertations

Bright electron beams generated via photoinjectors have enabled many recent developments in accelerator technology, including x-ray free electron lasers and ultrafast electron microscopy and diffraction systems. The conceptual design, scientific reach, and accessibility of these and next-generation accelerator applications can be significantly improved by increasing electron beam brightness. Therefore, the development of novel methods to further enhance beam brightness remains a critical priority in the field.

One of the primary factors limiting beam brightness is the mean transverse energy (MTE) of photoemitted electrons. The MTE is an intrinsic property of the photocathode and is proportional to the square of the …

4d-Qens And Diffuse Scattering: Analysis Of Dynamics And Local Ordering In Superionic Conductors, Jared Coles

Graduate Research Theses & Dissertations

Ionic conductors are increasingly central to electrochemical energy technologies because they enable charge transfer through the motion of mobile ions. Among them, superionic conductors are crystalline solids that exhibit exceptionally high ionic conductivities, making them promising candidates for safer and more sustainable next‑generation energy storage and conversion devices. Despite their technological importance, key gaps remain in our ability to connect macroscopic transport to microscopic structural disorder and correlated dynamics that enable fast‑ion motion. Neutron scattering provides a powerful set of tools for establishing these connections.

In total scattering experiments, Bragg diffraction measures the average crystallographic structure, while diffuse scattering probes …

Longitudinal Dechirping Of Electron Beams Using Negative Identity Drifts In A Transverse Deflecting Cavity-Based Chirper, Alex Desimone

Graduate Research Theses & Dissertations

Electron beam chirping for bunch compression is commonly achieved through off-crest acceleration in radio-frequency accelerating cavities. While it is effective, this method reduces average beam energy and introduces nonlinearities in the beam's longitudinal phase space, which can degrade beam quality in applications such as X-ray free electron lasers. An alternative chirping scheme has been proposed, in which accelerating cavities operate on-crest while transverse deflecting cavities generate the required longitudinal chirp. However, the efficiency of this approach and its impact on beam quality have not been systematically investigated, and the previously proposed dechirping scheme for this system is experimentally impractical. This …

Application Of Paper Spray Mass Spectrometry For Screening Acetylcholinesterase Inhibitors, Diksha Gautam

Graduate Research Theses & Dissertations

Paper spray mass spectrometry (PS-MS) is a novel ambient ionization method that allows chemical and biological samples to be rapidly analyzed with little preparation being required. In this paper, PS-MS was set up and streamlined as an acetylcholinesterase (AChE)-monitoring platform in addition to screening an existing and newly produced AChE-inhibitors. The detection of the substrate, acetylcholine (m/z 146), and the AChE catalysis product, choline (m/z 104) was performed without applying chromatographic separation or derivatization to the dried paper substrates. Assay conditions were optimized in a systematic way, to develop a robust MS-compatible enzymatic workflow.

Calibration curves for both, acetylcholine and …

On Values Taken By Characters Of Finite Groups, Christopher William Herbig

Graduate Research Theses & Dissertations

The characters of finite groups are a fundamental tool for analyzing the structure of finite groups and are interesting in their own right. In particular, we are concerned with how certain assumptions on the values taken by characters impact the structure of finite groups and vice versa. After establishing notation and stating some fundamental results in Chapter 2, this work begins with a presentation of results in relation to a conjecture of N. N. Hung and P. H. Tiep on fields generated by character values. In particular, we have found a large family of counterexamples to the conjecture by taking …

Bayesian Inference For A 12-Level Galton Board Using Terminal Bin Counts, Ace Frieders

Graduate Research Theses & Dissertations

A Galton board is a physical device in which a ball passes through a triangular array of pegs and is deflected left or right before landing in one of several bins. Under an idealized model, deflections are independent with probability 0.5 of moving right, implying a binomial distribution for the terminal bin location. Physical boards may deviate from this ideal due to asymmetries and other sources of bias. This thesis develops a Bayesian model for a 12-level Galton board in which each peg has its own right-move probability. Independent Beta priors are assigned to peg probabilities, and terminal bin counts …

Hallucination Detection In Scientific Writing: Quantification, Trend Analysis And Benchmarking, Adiba Ibnat Hossain

Graduate Research Theses & Dissertations

The landscape of scientific communication has undergone a significant transformation with the emergence and widespread adoption of Large Language Models (LLMs). LLMs have enhanced productivity and creativity in scientific writing, raising serious questions about the faithfulness and reliability of the generated content. A common problem in LLMs is hallucination, which occurs when models generate fluent but inaccurate or inconsistent content. When hallucinations enter scientific writing, the intended meaning may be distorted, coherence disrupted, and the study’s overall integrity threatened.

This thesis investigates hallucinations in scientific writing from both an analytical and dataset-driven approach. First, it offers a comprehensive analysis of …

Simulation And Experiment Of Two-Bunch Wakefield Dynamics And Energy Recovery In Dielectric-Lined Thz Structures, Calcifer Phillips

Graduate Research Theses & Dissertations

Beam-driven structure wakefield acceleration (SWFA) is a proposed method of particle acceleration that produces higher acceleration gradients. This technique could lead to the development of smaller and more efficient particle accelerators. In SWFA, a charged "drive" bunch passing through a dielectric or metallic structure created an electromagnetic "wake" field which can then be used to accelerate a following "witness" bunch. This work studies the effects of structure geometry on wake excitation, presents simulation results of wakefield dynamics in various geometries, and explores how SWFA could be used to achieve higher energy gradients. The use of a circular cross-section structure was …

High-Throughput Strip Clustering On Fpgas For The Hl-Lhc, Hayden Shaddix

Graduate Research Theses & Dissertations

With the advent of the High-Luminosity Large Hadron Collider (HL-LHC), the demand for modern approaches to high-throughput data processing has increased substantially. The HL-LHC will deliver far higher collision rates (pile-up reaching ⟨μ⟩ ∼200), producing a dramatic rise in detector activity and placing significant pressure on real-time reconstruction algorithms. One strategy for meeting this challenge is to leverage commodity hardware such as field-programmable gate arrays (FPGAs) and graphics processing units (GPUs), which can accelerate bandwidth-intensive portions of the reconstruction chain. In particular, FPGAs programmed through high-level synthesis (HLS) offer a promising balance between flexibility and performance, allowing physicists to design …

Beam Dynamics Of Non-Relativistic Proton Bunch Compression In Extreme Space Charge: Setting The Stage For Next Generation Intensity-Frontier Machines, Benjamin Simons

Graduate Research Theses & Dissertations

Next-generation intensity-frontier particle accelerators, such as the proposed Muon Collider and Neutrino Factories, require proton drivers capable of delivering high-intensity, short-pulse bunches. Achieving the required peak currents demands aggressive longitudinal compression, a process fundamentally limited by the extreme repulsive space-charge forces inherent to high-intensity, tightly compressed bunches.

Through the development and use of the FAST/IOTA Bunch Rotation Experiment (FI- BRE) at Fermilab as a dedicated testbed, this dissertation establishes a comprehensive physical design and simulation framework to probe these fundamental intensity limits. By isolating the dynamics of a 2.5 MeV non-relativistic proton beam (β ≈ 0.073) circulating in the Integrable …

Development And Characterization Of Flat And Flexible Rebco Cables For High-Field Accelerator Magnets, Emily Romancew

Graduate Research Theses & Dissertations

High-Temperature Superconducting (HTS) materials are at the forefront of innovation for fundamental particle physics. The next generation of particle accelerators aims to explore higher mass particles and is dependent on the ability to achieve higher fields in the 20–30 T range to keep machine size within a practical footprint. Current magnet technology relies on low-temperature superconductors (LTS) such as NbTi and Nb₃Sn, which are limited to fields of approximately 8–16 T, while high-temperature superconductors (HTS), particularly Rare-Earth Barium Copper Oxide (REBCO), offer a promising pathway toward higher-field magnets due to their ability to carry large currents at elevated magnetic fields. …

A Transmission Electron Microscopy Study Of Structural Design And Modifications Of Li And Na – Ion Battery Cathodes For Performance Optimization, Maksim Andreyevich Sultanov

Graduate Research Theses & Dissertations

The importance of Li ion batteries as an energy storage device cannot be understated. The industry around energy storage has been steadily growing over the last few decades and continues to grow. However, the design of these devices has run into a bottleneck as both academics and industry specialists try to achieve even higher performance parameters, as well as trying to supplement critical materials such as Co, Li and Ni while maintaining cost and energy density. In particular, energy density, capacity retention, thermal and mechanical stability have become very important to improve. These critical parameters within the device are dominated …

Dynamic Aperture Maximization Methods, Kevin J. Hamilton

Graduate Research Theses & Dissertations

Particle accelerators consist of some of the most prolific machines for achieving a long-standing history of successful experiments that have progressed fields such as particle physics, nuclear physics, solid state physics, and medical physics. In recent years, multiple studies have been conducted on how further progress in these fields can be made and the beams physics community has concluded that developing new accelerators to minimize the loss of particles, induce high intensity beams, and remain stable under perturbations is essential to the continued success of physics research. Each of these qualities correspond to finding methods to increase the so-called dynamic …

Rntuple For Atlas Analysis Workflow, Fatima Ariana Rodriguez

Graduate Research Theses & Dissertations

RNTuple is the new data storage format set to replace TTree at the start of the High-Luminosity LHC. An investigation was conducted to evaluate how analysis workflows for ATLAS researchers will change with RNTuple, using reading speed, writing speed, disk space, and memory consumption as metrics. In this study, all metrics were measured using converted RNTuple inputs from ATLAS Open Data, compared to their TTree equivalents. Additionally, RNTuples produced with the LZ4 compression algorithm were generated and compared with those produced using ZSTD. Finally, two new versions of the Analysis Grand Challenge (AGC) using ATLAS Open Data were completed for …

The Effects Of Problem-Based Learning On Mathematical Creativity And Self-Efficacy Of High School Students, Margaret Remus

Graduate Research Theses & Dissertations

Mathematical creativity is recognized as an important component of mathematics education; however, there is limited understanding of how instructional approaches can effectively support this skill among high school students, particularly through problem-based learning (PBL). This study examined the effects of problem-based learning on mathematical creativity among high school students.

This study employed a mixed-methods approach using an alternating treatment design with two groups of participants. Group 1 received the PBL intervention followed by a control condition, while Group 2 received the control condition followed by the PBL intervention. Quantitative data were collected through a mathematical creativity test measuring flexibility, fluency, …

Evaluating Planting Methods For Native Seed Production And Exploring Granivory In The Northern Great Plains, Allison Dollen

Electronic Theses and Dissertations

Temperate grasslands have faced immense losses due to land use change in the last 150 years and less than half of the overall grasslands that once covered North America remain today. A portion of historic and remaining U.S. grasslands are located within the northern Great Plains (NGP) region which is home to over 1,600 species of native plants and provides many ecosystem services and economic benefits. Initiatives to restore grasslands and their ecosystem services are currently underway, but barriers such as limited native seed supply and granivory hinder restoration efforts. My first chapter addresses knowledge gaps in planting methods for …

Quantum Mechanics As A Framework For Data Assimilation And Its Application To Atmospheric Parameterization, David Freeman

Dartmouth College Ph.D Dissertations

Quantum mechanics, as a mathematical system, can be understood as a generalization of classical probability theory. Quantum Mechanical Data Assimilation (QMDA) is a method in which classical dynamical systems are embedded into a quantum mechanical setting, with an associated data assimilation scheme leveraging the operator algebraic setting. In this dissertation, the algebraic structure underlying the operator theoretic formulation of QMDA is discussed. A procedure for closure of dynamical systems based on QMDA, known as Quantum Mechanical Closure (QMCl), is then constructed, and the procedures for constructing the quantum embeddings and implementing QMCl in practice are laid out and implemented for …

Fifty Years Of Research In The Commonwealth Of The Bahamas: A Quantitative Thematic Analysis Of Scholarly Output, Amina Moss, Krista D. Sherman, Williamson Gustave, Kathleen Sullivan Sealey, Charlotte Dunn, Nicola Simone Smith, Lindy Knowles, Christy Gibson

Gulf and Caribbean Research

This study presents the first longitudinal bibliometric mapping of peer—reviewed research on The Bahamas, analyzing 12,113 Web of Science records (1975–2025) using CiteSpace v.6.4.R2. We identified 36 co—citation clusters (modularity Q = 0.7967; silhouette = 0.9231) and 28 keyword clusters (Q = 0.7523; silhouette = 0.8695), revealing 8 thematic trajectories over 5 decades. Early research (prior to 1990) focused on carbonate geology and sea—level dynamics across the northwestern Bahama Platform and Blake—Bahama Basin (Cluster#0, silhouette = 0.939). From the 1990s–mid—2000s, attention shifted to marine fisheries, Aliger gigas, coral reefs, and ecological resilience (Cluster #1, n = 203). In the …

Cybercrime, Vulnerability And Digital Guardianship: Opportunity Structures And Prevention In A Changing Online Landscape, Mike Toro-Alvarez, Amy Lim

International Journal of Cybersecurity Intelligence & Cybercrime

No abstract provided.

Analyzing Modern Scam Typologies: From Pig-Butchering And Nigerian Advance-Fee Fraud To Crypto Airdrop Schemes, Katalin Parti, Sinyong Choi, Thomas Dearden

International Journal of Cybersecurity Intelligence & Cybercrime

Rapid advancements in digital infrastructure and decentralized networks have fundamentally altered the nature of contemporary cybercrime, making comprehensive empirical and technical analysis more crucial than ever. To address these challenges, this editorial summarizes the research contributions featured in this issue of the International Jour nal of Cybersecurity Intelligence and Cybercrime. The included papers examine the structural on-chain dynamics of sanctioned pig-butchering operations, the representational production and AI-driven evolution of the “Nigerian scam” label, the critical transaction-authorization factors driving losses in crypto airdrop schemes, and the optimization of sentence-transformer models for automated Host Intrusion Detection System (HIDS) alert enrichment. Together, these …

Three-Tier On-Chain Transaction Architecture In A Sanctions-Linked Pig-Butchering Network: A Blockchain-Forensics Case Study, Matthew Stern, Kyung-Shick Choi

International Journal of Cybersecurity Intelligence & Cybercrime

n October 2025, the U.S. Department of the Treasury’s Office of Foreign Assets Control (OFAC) sanctioned 29 Bitcoin addresses asso ciated with the Prince Group and Chen Zhi, providing an opportunity to examine the internal on-chain structure of a sanctions-linked pig-butchering network. This blockchain-forensics case study analyzes the group of 29 addresses using blockchain tracing, cross-plat form attribution checks across multiple commercial analytics platforms, exposure screening, and thematic analysis of transaction be havior. Because the case rests on OFAC designations and DOJ allegations, the traced flows are interpreted as patterns consistent with suspected laundering rather than adjudicated crimes; no fiat …

Attribution Post ‘Aura’ Loss: A Qualitative Discourse Analysis Of The Nigerian Scam Label And Fraud Attribution, Emaediong Akpan

International Journal of Cybersecurity Intelligence & Cybercrime

In this essay, I employ qualitative discourse analysis of eleven purposively selected literature to examine how “Nigerian scam” became an established yet detached signifier of advance-fee fraud in global discourse. I do not treat this association as a reflection of offender identity or national inclination. Instead, the analysis traces how attribution is produced through representational repetition, institu tional uptake, and the circulation of familiar narrative cues. Using qualitative discourse analysis and an interpretive approach, this paper distinguishes among the socio-technical conditions that enable fraud, the institutional processes that stabilize attribution, and the semiotic dynamics through which national categories acquire durability. …

Improving The Quality Of Physics Practice, Wyatt W. Thompson

All Graduate Theses, Dissertations, and Other Capstone Projects

This case study started with personal observations and experiences. As a lab teaching assistant, I observed on many occasions that students do not like their current homework platforms, often venting to me about their frustrations during lab time. As a student, I shared similar sentiments with them. To develop a possible solution to these observations, a theory of reasoning was chosen as the foundation. The heuristic-analytic theory of reasoning (HATR) suggests that people present an epistemic model (beliefs and ideas about a phenomenon) through a heuristic process (generation from memory) and engage in an analytic process to validate the epistemic …

An Analysis Of Slms For Machine Translation Of Healthcare Documents, Wyatt Clausen

All Graduate Theses, Dissertations, and Other Capstone Projects

The language barrier creates significant healthcare challenges for patients who struggle with English. While large language models (LLMs) have advanced machine translation, their high computational costs, environmental impact, and risk of data breaches have raised concerns. Small language models (SLMs) can address these concerns and be further adapted to specific tasks through parameter-efficient fine-tuning (PEFT) methods, including Quantized Low-Rank Adaptation (QLoRA). This study compares the Spanish-to-English translation quality of two 7-billion-parameter SLMs, Mistral and Llama 2 7B, in the medical domain, using BLEU, chrF, and COMET as evaluation metrics. It further investigates whether QLoRA fine-tuning and Retrieval-Augmented Generation (RAG) on …

A Comparative Analysis Of The Ecophysiology Between The Invasive Macroalgae Starry Stonewort And The Native Macroalgae Chara To Predict Invasion Potential, Thomas J. Zellmer

All Graduate Theses, Dissertations, and Other Capstone Projects

Starry stonewort (Nitellopsis obtusa) is an invasive macroalga from Eurasia. Currently, starry stonewort’s invasive range consists of the upper Midwest and Great Lakes region, including the Mississippi River. Starry stonewort poses recreational and ecological problems by forming dense canopies that extend through the water column. Starry stonewort occupies a late-season niche space with dense biomass occurring in late July and persisting well into autumn. There is a lack of information on the ecophysiology of starry stonewort. In this study, two populations of starry stonewort, Minnesota and New York, were analyzed to compare regional differences in ecophysiology, along with chara (native …