Digital Commons Network^™

An Investigation Of The Mindset Context And Its Downstream Effects On Marginalized Student Outcomes In College Stem Courses, Ronia Naim Kattoum

Theses and Dissertations

Multiple national calls centered on critical thinking and social justice have been made to improve and reform higher education in science, technology, engineering, and mathematics (STEM) courses to increase the representation of students from marginalized groups in the STEM workforce and equip all students for success. To help answer this call, our project has two overarching goals: 1) Identify pathways to increase student success in STEM courses at a moderately selective metropolitan institution with a diverse population that can be generalized to similar institutions, and 2) determine how instructional practices influence perceptions of the learning environment, especially for marginalized students. …

`The Very Beautiful Principles Of Natural Philosophy': Michael Faraday, Paper Marbling And The Physics Of Natural Forms, Robert Pepperell

LASER Journal

In 1854, Michael Faraday wrote to thank the author who had sent him a book on the art of paper marbling. In the letter, Faraday referred to `the very beautiful principles of natural philosophy' involved in the process of dropping ink on thickened water. What are the `beautiful principles' that Faraday referred to, and how are they involved in the art of paper marbling? Here I consider some of the physical processes that occur in paper marbling and how the patterns that emerge represent `dissipative structures' that are governed by fundamental principles of nature, in particular the tendency for physical …

The Dartmouth Land Ethic: Synthesizing Environmental Ethical Beliefs In Hanover And Beyond, Conor M. Roemer

Environmental Studies Senior Theses

In this thesis, I seek to explore the nature of an environmental ethical paradigm at Dartmouth. In order to do so, I have chosen to begin with an examination of Aldo Leopold’s Land Ethic. This watershed essay has inspired many environmental ethical inquiries in the last eighty years. Leopold’s Land Ethic urged human beings to view the environment beyond what might be extracted for anthropogenic use and to see the land as a summation of everything that lies within it: not just the plants and animals, but the mountains, rocks, rivers, and soil as well. In turn, scores of philosophers …

Conserving The Public Lands: Policy And Spatial Analysis Of A Bureau Of Land Management Conservation Leasing Mechanism, Isaiah M. Menning

Environmental Studies Senior Theses

The Bureau of Land Management (BLM) is the largest land administrator in the United States, managing about 10% of U.S. lands, primarily in the Western states. The BLM manages under a multiple-use framework, issuing commercial authorizations for grazing, mining, oil and gas, and wind and solar on public lands, while also managing for ecosystem health. In April 2024, the agency finalized a rule that would create a conservation leasing mechanism to allow private, state, and tribal parties to lease BLM lands for restoration and mitigation purposes, which I investigate here. First, I find that while the conservation leasing mechanism does …

Designing Of Human Serum Albumin Nanoparticles For Drug Delivery: A Potential Use Of Anticancer Treatment, Ali Al-Ani, Rasha Alsahlanee

Karbala International Journal of Modern Science

Human serum albumin (HSA) nanoparticles have been widely used as versatile drug delivery systems for improving the efficiency and pharmaceutical properties of drugs. The present study aimed to design HSA nanoparticle encapsulated with the hydrophobic anticancer pyridine derivative (2-((2-([1,1'-biphenyl]-4-yl)imidazo[1,2-a]pyrimidin-3-yl)methylene)hydrazine-1-carbothioamide (BIPHC)). The synthesis of HSA-BIPHC nanoparticles was achieved using a desolvation process. Atomic force microscopy (AFM) analysis showed the average size of HSA-BIPHC nanoparticles was 80.21 nm. The percentages of entrapment efficacy, loading capacity and production yield were 98.11%, 9.77% and 91.29%, respectively. An In vitro release study revealed that HSA-BIPHC nanoparticles displayed fast dissolution at pH 7.4 compared to pH …

Modified Toulmin's Argumentation Model Based On Prior Experiences, Ali Hadi Hasan, Mohamad Ab. Saleh, Ahmed T. Sadiq

Karbala International Journal of Modern Science

Our work focuses on the usefulness of previously stored correct extracted results, which form a sort of stored knowledge got from previous experiences, from enhancing Toulmin's argument model that deals with drug conflict problems in therapeutic diagnostics. New patients are entered using friendly user interface to store in files and then they are matched with the records of previous results, patients’ symptoms and histories datasets which also contain the correct best drugs extracted results. If the new entered record of a patient is matching with any previous record then the correct result of drug will be found immediately and displayed. …

Looking For The Oldest Diatoms, Karolina Brylka, Sylvain Richoz, Andrew J. Alverson, David J. Conley

Biological Sciences Faculty Publications and Presentations

Paleontological observations of ancient flora and fauna provide powerful insights into past diversity and relationship dynamics between organisms and their environments. Diatoms are globally distributed protists that influence major biogeochemical cycles and sustain oceanic food webs. The fossil diatom record extends 120 million years back to the Early Cretaceous where rare deposits were discovered worldwide and are occasionally represented by diverse communities. However scarce, the taxonomic richness and geographical spread of these diatom communities suggest prior evolutionary events and therefore earlier deposits. To complement the existing fossil information and to discover diatom deposits predating 120 Ma, we examined 33 study …

Investigation Of Collision Cross Sections & Time-Resolved Structural Modification Of Biomolecules, Host-Guest Systems, & Small Molecules Using Ion Mobility & Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, Noah Mismash

Theses and Dissertations

This thesis explores the structures and structural changes of supramolecular host-guest systems, proteins, and other small molecules in the gas phase, utilizing a combination of computational modeling and experimental data. The primary instruments employed were a Fourier transform ion cyclotron resonance mass spectrometer (FTICR-MS) and an ion mobility mass spectrometer (IM-MS). In the IM-MS experiments, the focus was on investigating the binding behavior of cyclodextrin macrocycles—specifically α, β, and γ-cyclodextrin—with per-fluoroalkane substances (PFAS), which are pervasive environmental contaminants. This investigation involved measuring ion-neutral collision cross sections and using computational modeling to determine whether PFAS compounds bind inside or outside the …

Exploring The Dynamics Of September Fish Spawning On The West Florida Shelf Through The Dna Barcoding Of Fish Eggs, Keith G. Keel

USF Tampa Graduate Theses and Dissertations

Identifying spawning areas for economically and ecologically important fishes is critical for fisheries conservation and ecosystem-based management. Additionally, monitoring the spawning dynamics of fishes is increasingly important as temperatures and oceanic conditions change. I used genetic barcoding to identify fish eggs collected across the West Florida Shelf (WFS) during September of 2013, 2014, and 2019. Fish eggs were collected on National Oceanic and Atmospheric Administration (NOAA) Southeast Area Monitoring and Assessment Program (SEAMAP) ichthyoplankton cruises using a Continuous Underway Fish Egg Sampler (CUFES). Analysis of 4,400 fish eggs from the three years resulted in the identification of 83 unique species …

Wildfire Smoke Impacts Lake Ecosystems, Mary Jade Farruggia, Janice Brahney, Andrew J. Tanentzap, Jennifer A. Bentrup, Ludmila S. Brighenti, Sudeep Chandra, Alicia Cortés, Rocio L. Fernandez, Janet M. Fischer, Alexander L. Forrest, Yufang Jin, Kenneth Larrieu, Ian M. Mccullough, Isabella A. Oleksy, Rachel M. Pilla, James A. Rusak, Facundo Scordo, Adrianne P. Smits, Celia C. Symons, Minmeng Tang, Samuel G. Woodman, Steven Sadro

Watershed Sciences Faculty Publications

Wildfire activity is increasing globally. The resulting smoke plumes can travel hundreds to thousands of kilometers, reflecting or scattering sunlight and depositing particles within ecosystems. Several key physical, chemical, and biological processes in lakes are controlled by factors affected by smoke. The spatial and temporal scales of lake exposure to smoke are extensive and under-recognized. We introduce the concept of the lake smoke-day, or the number of days any given lake is exposed to smoke in any given fire season, and quantify the total lake smoke-day exposure in North America from 2019 to 2021. Because smoke can be transported at …

Oscillations In Neuronal Activity: A Neuron-Centered Spatiotemporal Model Of The Unfolded Protein Response In Prion Diseases, Elliot M. Miller, Tat Chung D. Chan, Carlos Montes-Matamoros, Omar Sharif, Laurent Pujo-Menjouet, Michael R. Lindstrom

School of Mathematical & Statistical Sciences Faculty Publications

Many neurodegenerative diseases (NDs) are characterized by the slow spatial spread of toxic protein species in the brain. The toxic proteins can induce neuronal stress, triggering the Unfolded Protein Response (UPR), which slows or stops protein translation and can indirectly reduce the toxic load. However, the UPR may also trigger processes leading to apoptotic cell death and the UPR is implicated in the progression of several NDs. In this paper, we develop a novel mathematical model to describe the spatiotemporal dynamics of the UPR mechanism for prion diseases. Our model is centered around a single neuron, with representative proteins P …

Topological Regression As An Interpretable And Efficient Tool For Quantitative Structureactivity Relationship Modeling, Ruibo Zhang, Daniel Nolte, Cesar Sanchez-Villalobos, Souparno Ghosh, Ranadip Pal

Department of Statistics: Faculty Publications

Quantitative structure-activity relationship (QSAR)modeling is a powerful tool for drug discovery, yet the lack of interpretability of commonly used QSAR models hinders their application inmolecular design.We propose a similaritybased regression framework, topological regression (TR), that offers a statistically grounded, computationally fast, and interpretable technique to predict drug responses. We compare the predictive performance of TR on 530 ChEMBL human target activity datasets against the predictive performance of deep-learning-based QSAR models. Our results suggest that our sparse TR model can achieve equal, if not better, performance than the deep learningbased QSAR models and provide better intuitive interpretation by extracting an approximate …

Back To The Future: A Case For The Resurgence Of Approximation Theory For Enabling Data Driven “Intelligence”, Michael Dominic Ciocco

Theses and Dissertations

Artificial Intelligence (AI) has exploded into mainstream consciousness with commercial investments exceeding $90 billion in the last year alone. Inasmuch as consumer-facing applications such ChatGPT offer astounding access to algorithms that were hitherto restricted to academic research labs, public focus of attention on AI has created an avalanche of misinformation. The nexus of investor-driven hype, “surprising” inaccuracies in the answers provided by AI models – now anthropomorphically labeled as “hallucinations”, and impending legislation by well-meaning and concerned governments has resulted in a crisis of confidence in the science of AI. The primary driver for AI’s recent growth is the convergence …

Rock Glaciers In Utah, Scott Hotaling, Kendall Becker, Matthew Morriss

All Current Publications

Utah’s primary water supply––winter snowpack––is in decline due to climate warming coupled with more precipitation falling as rain instead of snow. As snowpack dwindles, other sources of cold stream water, such as rock glaciers, will become more important. Rock glaciers contain significant volumes of internal ice covered by debris. This internal ice provides cold meltwater to mountain streams, sustaining flows in summer and supporting biodiversity. Rock glaciers are common in Utah’s mountains and are projected to be more stable under climate change than Utah’s snowpack. Thus, rock glaciers are likely to persist in their current form even as snowpack volumes …

Sensitivity Of Ocean Circulation To Warming During The Early Eocene Greenhouse, Sandra Kirtland Turner, Andy Ridgwell, Allison L. Keller, Maximilian Vahlenkamp, Adam K. Aleksinski, Philip F. Sexton, Donald E. Penman, Pincelli M. Hull, Richard D. Norris

Geosciences Faculty Publications

Multiple abrupt warming events ("hyperthermals") punctuated the Early Eocene and were associated with deep-sea temperature increases of 2 to 4 °C, seafloor carbonate dissolution, and negative carbon isotope (δ¹³C) excursions. Whether hyperthermals were associated with changes in the global ocean overturning circulation is important for understanding their driving mechanisms and feedbacks and for gaining insight into the circulation's sensitivity to climatic warming. Here, we present high-resolution benthic foraminiferal stable isotope records (δ¹³C and δ¹⁸O) throughout the Early Eocene Climate Optimum (~53.26 to 49.14 Ma) from the deep equatorial and North Atlantic. Combined with existing …

06.03.2024 Orsp Connect, Liz Williamson

ORED Newsletter

Center for Population Studies, NSF Postdoc Berg, Quinn Appointed to HEPAP, Smitherman migraine research

Single-Molecule Orientation Imaging Reveals The Nano-Architecture Of Amyloid Fibrils Undergoing Growth And Decay, Brian Sun, Tianben Ding, Weiyan Zhou, Tara S. Porter, Matthew D. Lew

Electrical & Systems Engineering Publications and Presentations

Amyloid-beta (Aβ42) aggregates are characteristic Alzheimer’s disease signatures, but probing how their nanoscale architectures influence their growth and decay remains challenging using current technologies. Here, we apply time-lapse single-molecule orientation-localization microscopy (SMOLM) to measure the orientations and rotational “wobble” of Nile blue (NB) molecules transiently binding to Aβ42 fibrils. We correlate fibril architectures measured by SMOLM with their growth and decay over the course of 5 to 20 min visualized by single-molecule localization microscopy (SMLM). We discover that stable Aβ42 fibrils tend to be well-ordered and signified by well-aligned NB orientations and small wobble. SMOLM also shows that increasing order …

Dft Based Modeling Of The Heavy Atom Effect In Triplet Photosensitizers: From Fundamental Mechanics To Rational Design, Bret Andrew Steinkamp

Dissertations and Theses

Photochemistry is the study of how light interacts with molecules and includes both the absorption and release of light. This document focuses on triplet photosensitizers -- molecules that utilize the excited triplet state -- for a variety of applications including photodynamic therapy and photocatalysis. There are many factors that influence the design of triplet photosensitizers; in this work, we have developed and used a methodology for the rational design of triplet photosensitizers based on an approximation of the heavy atom effect (HAE) from density functional theory calculations and the experimentally measured singlet oxygen quantum yield (Ф_Δ).

As excited …

Assigning The Ch Stretch Overtone Spectrum Of Benzene And Naphthalene With Extension To Anthracene And Tetracene Using 2- And 3-Quanta Anharmonic Quantum Chemical Computations, Vincent J. Esposito, Ryan C. Fortenberry, Christiaan Boersma, Louis J. Allamandola

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

The CH stretch overtone region (5750–6300 cm⁻¹) of benzene and naphthalene is assigned herein using anharmonic quantum chemical computations, and the trend of how this extends to larger polycyclic aromatic hydrocarbons (PAHs) is established. The assignment of all experimental bands to specific vibrational states is performed for the first time. Resonance polyads and the inclusion of 3-quanta vibrational states are both needed to compute accurate vibrational frequencies with the proper density-of-states to match the experimental band shape. Hundreds of 3-quanta states produce the observed band structure in naphthalene, anthracene, and tetracene, and this number is expected to increase …

Nanoparticles As Antioxidant Agents: A Comprehensive Review, Sulyman Olalekan Ibrahim, Halimat Yusuf Lukman, Fatimat Ronke Abdulkadir, Monsurat Yemisi Bello, Yusuf Oloruntoyin Ayipo, Halimah Funmilayo Babamale, Marili Funmilayo Zubair, Olubunmi Atolani

Al-Bahir

This study seeks to provide a comprehensive overview of the latest progress in the antioxidant properties of nanoparticles. Nanoparticles (NPs) have emerged as a promising tool in several domains of science and industry, including their application as antioxidant agents. The main knowledge gaps seem to be in correctly identifying the make-up of the naturally occurring phytochemicals that give these nano-antioxidants their extraordinary pharmacology and drug-like properties. In many instances, that characterization is done using spectroscopy instrumentation such as fourier-transform Infrared (FT-IR), scanning electron microscope (SEM), and X-ray diffraction analysis (XRD). From literature appraisals, it was discovered that a lot of …

Tracking Mining Company Electric Vehicles For Sustainable Development Optimization Using Distributed Ledger Technologies, Teodora Hristova

Journal of Sustainable Mining

It is established that based on the industrial revolutions towards Industry 5.0, the population of the Earth and its well-being are increasing. To preserve and improve living conditions the development in all spheres of life is by the paradigm of sustainable development. Through the prism of the mining industry, one step could be the introduction of circular economy measures for digitized tracking of materials, repairs, consumed electricity, safety, and finances. Implementing of electric cars is an option to achieve this goal through automation, manageability, and data traceability via Industry 4.0 technologies. Such are blockchain technologies, IoT, V2V, and others. For …

Creative Connections: Building Empathy To Foster Ecoliteracy Through Art Education, Jocelyn Salim

Masters Theses

This thesis investigates the potential positive impact of fostering empathy and understanding for the natural world through art education. Through action research, this study examines various teaching approaches, such as incorporating scientific knowledge, employing literature to discuss ecological themes, and engaging in participatory storytelling activities to cultivate empathy among elementary school children. The objective of this thesis is to explore empathy as a potential pathway to encourage children to foster connections with the natural world and develop compassionate traits, attitudes, and behaviors towards nature as they grow. The findings of this study reveal that children exhibit high levels of enthusiasm …

Differential Methylation Region Detection Via An Array-Adaptive Normalized Kernelweighted Model, Daniel Alhassan, Gayla R. Olbricht, Akim Adekpedjou

Mathematics and Statistics Faculty Research & Creative Works

A differentially methylated region (DMR) is a genomic region that has significantly different methylation patterns between biological conditions. Identifying DMRs between different biological conditions is critical for developing disease biomarkers. Although methods for detecting DMRs in microarray data have been introduced, developing methods with high precision, recall, and accuracy in determining the true length of DMRs remains a challenge. In this study, we propose a normalized kernel-weighted model to account for similar methylation profiles using the relative probe distance from "nearby" CpG sites. We also extend this model by proposing an array-adaptive version in attempt to account for the differences …

(R2075) Truncated Saddlepoint Approximation For Testing Means Of Right-Skewed Populations, Kalanka P. Jayalath

Applications and Applied Mathematics: An International Journal (AAM)

In the examination of the mean parameter of the skewed distributions, testing methods often rely on the central limit theorem and data transformation. Notably, Johnson’s and Chen’s modified ttests offer reliable alternatives by incorporating additional sample moments. This work directs its attention towards the truncated saddlepoint (TS) approximation method, which effectively estimates the right-tail probability of right-skewed continuous distributions using a limited number of sample moments. The TS approximation is employed to derive the p-value in one-sample mean testing. To evaluate its performance, a Monte Carlo simulation study is conducted, comparing the TS approximation at four distinct truncation levels with …

Investigating H2s Occurrence In Bakken Oil-Producing Wells Using Sulfur Isotopes In Gas, Water, And Rock Samples, Alexander V. Chakhmakhchev, Marc D. Kurz, T. Austin Mcrae, Xue Yu, Arash Abarghani, Darren D. Schmidt, Nicholas A. Azzolina, Bethany A. Kurz, James A. Sorensen

EERC Publications, Papers, & Presentations

This work investigated multiple mechanisms that can potentially lead to H₂S in the oil production stream of Bakken wells, including TSR, BSR, source rock generation, migration from deeper or shallower formations that contain H₂S, and geomechanical mechanisms related to reservoir stimulation work.

Herbicides, Department Of Primary Industries And Regional Development, Western Australia

Grains and other field crops factsheets

Herbicides play a vital role in integrated weed management programs. Knowledge of the mechanisms and activity of herbicides will improve the impact and sustainability of herbicides as a weed management tactic. This fact sheet is a guide to the types of herbicides available and when and how they should be used.

Hydrothermal Synthesis Of (C5h14n2)[Cocl4]⸳0.5h2o: Crystal Structure, Spectroscopic Characterization, Thermal Behavior, Magnetic Properties And Biological Evaluation, Sandra Walha, Noureddine Mhadhbi, Basem F. Ali, Abdellah Kaiba, Ahlem Guesmi, Wesam Abd El-Fattah, Naoufel Ben Hamadi, Mark M. Turnbull, Ferdinando Costantino, Houcine Naïli

Chemistry

The organic-inorganic compound (C₅H₁₄N₂)[CoCl₄]⸳0.5H₂O, I, was characterized by various physicochemical techniques. The X-ray diffraction analysis revealed that the compound crystallizes in the centrosymmetric space group C2/c of the monoclinic system. The atomic arrangement the Co(II) complex is built from isolated [CoCl₄]^2– anions, 1-methylpiperazine-1,4-diium [C₅H₁₄N₂]²⁺ cations and free water molecules. The crystal structure study showed that the cohesion of I is assured through N–H···Cl and N–H···O hydrogen bonds giving birth to a 3-D architecture. Hirshfeld surface analysis revealed that Cl···H/H···Cl and …

Effects Of Differing Radiation Methods On Charge Transport In Polymers, Zachary J. Gibson, Jr Dennison, Virginie Griseri

Conference Proceedings

Spacecraft charging issues are understood and mitigated through an understanding of material properties. Material properties are dynamic in the harsh environment of space. Approximations must be made to simulate the space environment in the laboratory. This paper reports on the investigation of the approximation that energy deposition causes the same aging effects in the materials regardless of the radiation source. Samples of polytetrafluoroethylene (PTFE) and polyether-etherketone (PEEK) were irradiated with x-rays, γ-rays, or electrons at total ionizing dose (TID) of either 2 x 10⁴, 2 x 10⁵, or 2 x 10⁶ rad. Charge was then …

Architectural Elements Contributing To Interpretability Of Deep Neural Networks (Dnns), Emily Barnes, James Hutson

Faculty Scholarship

The interpretability of Deep Neural Networks (DNNs) has become a critical focus in artificial intelligence and machine learning, particularly as DNNs are increasingly used in high-stakes applications like healthcare, finance, and autonomous driving. Interpretability refers to the extent to which humans can understand the reasons behind a model's decisions, which is essential for trust, accountability, and transparency. However, the complexity and depth of DNN architectures often compromise interpretability as these models function as "black boxes." This article reviews key architectural elements of DNNs that affect their interpretability, aiming to guide the design of more transparent and trustworthy models. The primary …

Herbicide Application, Department Of Primary Industries And Regional Development, Western Australia

Grains and other field crops factsheets

Herbicides can be applied by a variety of means, including boom sprayers, aerial spraying, misters, blanket wipers, rope wick applicators, weed seekers and back-pack sprayers. This fact sheet reviews the different methods, including nozzles and calibration of equipment, used to apply herbicides.