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Articles 8041 - 8070 of 78769
Full-Text Articles in Entire DC Network
Fundamental Theory And Technological Innovation In Soil Carbon And Nitrogen Cycling: Promoting Sustainable Development Of Agriculture, Xu Zhao, Longlong Xia, Yongqiu Xia, Xiaoyuan Yan
Fundamental Theory And Technological Innovation In Soil Carbon And Nitrogen Cycling: Promoting Sustainable Development Of Agriculture, Xu Zhao, Longlong Xia, Yongqiu Xia, Xiaoyuan Yan
Bulletin of Chinese Academy of Sciences (Chinese Version)
The Changshu National Agro-Ecosystem Observation and Research Station (hereinafter referred to as Changshu Station) was officially established in 1987. Changshu Station is the only multidisciplinary comprehensive observation, research, and demonstration station within Chinese Academy of Sciences in the Yangtze River Delta region, focusing on researches about agricultural production, resources utilization, and environmental protection. Since its establishment, Changshu Station is the pioneer in conducting systematic observational research on soil nitrogen cycling, soil carbon sequestration, greenhouse gas (GHG) mitigation, and agricultural non-point source pollution. Over the past five years, Changshu Station has focused on three major scientific issues facing green and sustainable …
Infograz: A Data Base For Tropical Grazing Systems, K G. Rickert, J Carter, C K. Mcdonald
Infograz: A Data Base For Tropical Grazing Systems, K G. Rickert, J Carter, C K. Mcdonald
IGC Proceedings (1977-2023)
INFOGRAZ is a prototype of a comprehensive relational database that describes the management of, and stores information from, grazing experiments in northern Australia associated with the wool, beef, and dairy industries. It provides permanent storage and public access for detailed measurements on climate, soil, plants, and animals, which are a valuable resource for future pasture scientists and computer modellers of grazing systems. Thus it will prevent the detailed observations being lost with the passage of time. Verified data from each experiment are stored in tables which can be distributed on CD-ROM, along with procedures to access the data and use …
Corrigendum To “Evaluation Of Operational Performance Of Wusongkou Cruise Port Through Network Data Envelopment Analysis”
Journal of Marine Science and Technology–Taiwan
No abstract provided.
Memetic Memory As Vital Conduits Of Troublemakers In Digital Culture, Alexander O. Smith, Jordan Loewen-Colón
Memetic Memory As Vital Conduits Of Troublemakers In Digital Culture, Alexander O. Smith, Jordan Loewen-Colón
School of Information Studies - Post-doc and Student Scholarship
Recent fears of data capitalism and colonialism often argue using implicit assumptions about cybernetic technology’s ability to automate data about culture. As such, the level of data granularity made possible by cybernetic engineering can be used to dominate society and culture. Here we unpack these implicit assumptions about the datafication of culture through memes, which both act as cultural data and cultural memory. Using Alexander Galloway’s critical method of protocological analysis and descriptions of media tactics, we respond to fears of cybernetic domination. Protocols – the source by which cybernetic technologies enable automated datafication – enables us to respond to …
Implementing Interdisciplinary Sustainability Education With The Food-Energy-Water (Few) Nexus, Chelsie Romulo, Bhawani Venkataraman, Susan Caplow, Shamili Ajgaonkar, Craig R. Allen, Aavudai Anandhi, Steven W. Anderson, Caterina Belle Azzarello, Katja Brundiers, Eunice Blavascunas, Jenny M. Dauer, Daniel L. Druckenbrod, Ennea Fairchild, Lydia R. Horne, Kyungsun Lee, Marizvkuru Mwale, John Mischler, Emily Pappo, Nirav S. Patel, Nicole D. Sintov, Carla S. Ramsdell, Shirley G. Vincent
Implementing Interdisciplinary Sustainability Education With The Food-Energy-Water (Few) Nexus, Chelsie Romulo, Bhawani Venkataraman, Susan Caplow, Shamili Ajgaonkar, Craig R. Allen, Aavudai Anandhi, Steven W. Anderson, Caterina Belle Azzarello, Katja Brundiers, Eunice Blavascunas, Jenny M. Dauer, Daniel L. Druckenbrod, Ennea Fairchild, Lydia R. Horne, Kyungsun Lee, Marizvkuru Mwale, John Mischler, Emily Pappo, Nirav S. Patel, Nicole D. Sintov, Carla S. Ramsdell, Shirley G. Vincent
GGS Faculty Publications
Growth in the green jobs sector has increased demand for college graduates who are prepared to enter the workforce with interdisciplinary sustainability skills. Simultaneously, scholarly calls for interdisciplinary collaboration in the service of addressing the societal challenges of enhancing resilience and sustainability have also increased in recent years. However, developing, executing, and assessing interdisciplinary content and skills at the post-secondary level has been challenging. The objective of this paper is to offer the Food-Energy-Water (FEW) Nexus as a powerful way to achieve sustainability competencies and matriculate graduates who will be equipped to facilitate the transformation of the global society by …
Future Climate Doubles The Risk Of Hydraulic Failure In A Wet Tropical Forest, Zachary Robbins, Jeffrey Chambers, Rutuja Chitra-Tarak, Bradley O. Christoffersen, L. Turin Dickman, Rosie Fisher, Alex Jonko, Ryan Knox, Charles Koven, Lara Kueppers
Future Climate Doubles The Risk Of Hydraulic Failure In A Wet Tropical Forest, Zachary Robbins, Jeffrey Chambers, Rutuja Chitra-Tarak, Bradley O. Christoffersen, L. Turin Dickman, Rosie Fisher, Alex Jonko, Ryan Knox, Charles Koven, Lara Kueppers
School of Integrative Biological & Chemical Sciences Faculty Publications
Summary
- Future climate presents conflicting implications for forest biomass. We evaluate how plant hydraulic traits, elevated CO2 levels, warming, and changes in precipitation affect forest primary productivity, evapotranspiration, and the risk of hydraulic failure.
- We used a dynamic vegetation model with plant hydrodynamics (FATES-HYDRO) to simulate the stand-level responses to future climate changes in a wet tropical forest in Barro Colorado Island, Panama. We calibrated the model by selecting plant trait assemblages that performed well against observations. These assemblages were run with temperature and precipitation changes for two greenhouse gas emission scenarios (2086–2100: SSP2-45, SSP5-85) and two CO2 levels (contemporary, …
Gender-Specific Mental Health Outcomes In Central America: A Natural Experiment, Thea Nagasuru
Gender-Specific Mental Health Outcomes In Central America: A Natural Experiment, Thea Nagasuru
Computer Science Summer Fellows
While COVID lockdown measures have had varying effects on the mental health of different demographics, several bodies of research have noted their disparate effect on women. Why is women's mental health more negatively impacted by lockdown measures, and how much more are they impacted than men? How can we predict and mitigate these negative effects on women? This paper aims to contribute to answering those questions by comparing COVID stringency measures and their effect on the gap in depression rates between men and women in two neighboring countries: Nicaragua and Honduras.
Synthesis And Computational Studies Of Α- And Δ-Substituted Macrocyclic Europium And Ytterbium Complexes, Delainey Amara Winder
Synthesis And Computational Studies Of Α- And Δ-Substituted Macrocyclic Europium And Ytterbium Complexes, Delainey Amara Winder
Dissertations and Theses
The uses of macrocyclic lanthanide complexes are vast, with many targeted MRI contrast agents at the forefront of the field. Many of these are ParaCEST agents, which require exchangeable protons accessible on the macrocycle and the slow exchange of coordinated water molecules. The substitution at both the α- and δ-carbon on the amide pendant arm of these macrocyclic lanthanide complexes can lock bulky groups on the δ-carbon to a pseudo-axial position. When the α- and δ-carbons have the same chirality, the bulky group will be pseudo-equatorial, and when the chirality is opposed, the bulky group will be pseudo-axial. By performing …
Limit Theorems For Increments Of Branching Particle Systems With Linear Rates And Poisson Initial Condition, Alexander Kreinin, Vladimir V. Vinogradov
Limit Theorems For Increments Of Branching Particle Systems With Linear Rates And Poisson Initial Condition, Alexander Kreinin, Vladimir V. Vinogradov
Journal of Stochastic Analysis
No abstract provided.
The Hydrological Impacts Of Woody Plant Encroachment On Coastal Tallgrass Prairie Of Texas, Zhiwei Guo
The Hydrological Impacts Of Woody Plant Encroachment On Coastal Tallgrass Prairie Of Texas, Zhiwei Guo
LSU Master's Theses
Globally, woody plant encroachment into grassland and savanna ecosystems impacts the hydrological functions of grasslands and associated wetlands. In the coastal tallgrass prairie of Texas, encroachment of woody plants has altered vegetation structure, but the hydrological impacts are poorly understood. In this study, I evaluated and quantified how woody plant encroachment affects hydrological processes on the pimple mounds and inter-mound freshwater marsh, including precipitation partitioning, infiltration in the vadose zone, groundwater recharge, and water volume in the inter-mound marsh. I randomly selected three pimple mounds with woody plants and three pimple mounds with tallgrass w to quantify hydrologic processes. The …
Investigation Of Solvation Structures And Dynamics Of Li-Ion Battery Electrolytes And Amides In Water: An Infrared Spectroscopy, Electrochemical And Computational Study, Ernest O. Nachaki
Investigation Of Solvation Structures And Dynamics Of Li-Ion Battery Electrolytes And Amides In Water: An Infrared Spectroscopy, Electrochemical And Computational Study, Ernest O. Nachaki
LSU Doctoral Dissertations
The investigation of solvation structures and dynamics in lithium-ion battery electrolytes and amides in water has significant implications for both fundamental science and practical applications. Understanding the solvation dynamics of lithium electrolytes can lead to the development of safer and more efficient LIBs. The study of hydrogen bond dynamics of N-alkyl substituted amides has important implications for the development of thermos-responsive polymers used in biomedical applications. By understanding how N-alkyl substitutions affect the hydration structure and dynamics of amides, this research can inform the design of polymers with tailored properties for drug delivery, tissue engineering, and other medical applications. This …
Advances In Stereoselective Glycosylation: Electron-Withdrawing Groups, Benzyne-Mediated Stereoinversion, And Visible-Light Photochemistry For 1,2-Cis O-Glycosylation, Erik Giovanni Alvarez Valenzuela
Advances In Stereoselective Glycosylation: Electron-Withdrawing Groups, Benzyne-Mediated Stereoinversion, And Visible-Light Photochemistry For 1,2-Cis O-Glycosylation, Erik Giovanni Alvarez Valenzuela
LSU Doctoral Dissertations
The symbiotic relationship between humans and their microbiota is essential for health, with imbalances in the complex microbiota ecosystem linked to a variety of disorders ranging from neurodegenerative to gastrointestinal diseases. Bacteria within the human microbiota, comprising over 1000 known species, are densely and diversely coated with oligosaccharides crucial for functions like cell recognition, communication, signaling, adhesion, proliferation, and pathogenic inhibition. However, studying the structure-activity relationships of these sugars which are also secreted by bacteria is challenging due to difficulties in obtaining homogenous samples from natural sources.
Chemical synthesis offers a solution by enabling the production of well-defined oligosaccharides in …
Epigenome-Wide Association Study Of Lung Cancer Among Never Smokers In Two Prospective Cohorts In Shanghai, China, Mohammad L Rahman, Charles E Breeze, Xiao-Ou Shu, Jason Y Y Wong, Batel Blechter, Andres Cardenas, Xuting Wang, Bu-Tian Ji, Wei Hu, Qiuyin Cai, H Dean Hosgood, Gong Yang, Jianxin Shi, Jirong Long, Yu-Tang Gao, Douglas A Bell, Wei Zheng, Nathaniel Rothman, Qing Lan
Epigenome-Wide Association Study Of Lung Cancer Among Never Smokers In Two Prospective Cohorts In Shanghai, China, Mohammad L Rahman, Charles E Breeze, Xiao-Ou Shu, Jason Y Y Wong, Batel Blechter, Andres Cardenas, Xuting Wang, Bu-Tian Ji, Wei Hu, Qiuyin Cai, H Dean Hosgood, Gong Yang, Jianxin Shi, Jirong Long, Yu-Tang Gao, Douglas A Bell, Wei Zheng, Nathaniel Rothman, Qing Lan
Faculty, Staff and Student Publications
BACKGROUND: The aetiology of lung cancer among individuals who never smoked remains elusive, despite 15% of lung cancer cases in men and 53% in women worldwide being unrelated to smoking. Epigenetic alterations, particularly DNA methylation (DNAm) changes, have emerged as potential drivers. Yet, few prospective epigenome-wide association studies (EWAS), primarily focusing on peripheral blood DNAm with limited representation of never smokers, have been conducted.
METHODS: We conducted a nested case-control study of 80 never-smoking incident lung cancer cases and 83 never-smoking controls within the Shanghai Women's Health Study and Shanghai Men's Health Study. DNAm was measured in prediagnostic oral rinse …
Soft Matter Physics Of The Ground Beneath Our Feet, Anne Voigtländer, Morgane Houssais, Karol A. Bacik, Ian C. Bourg, Justin C. Burton, Karen E. Daniels, Sujit S. Datta, Emanuela Del Gado, Nakul S. Deshpande, Olivier Devauchelle, Behrooz Ferdowsi, Rachel Glade, Lucas Goehring, Ian J. Hewitt, Douglas Jerolmack, Ruben Juanes, Arshad Kudrolli, Ching Yao Lai, Wei Li, Claire Masteller, Kavinda Nissanka, Allan M. Rubin, Howard A. Stone, Jenny Suckale, Nathalie M. Vriend, John S. Wettlaufer, Judy Q. Yang
Soft Matter Physics Of The Ground Beneath Our Feet, Anne Voigtländer, Morgane Houssais, Karol A. Bacik, Ian C. Bourg, Justin C. Burton, Karen E. Daniels, Sujit S. Datta, Emanuela Del Gado, Nakul S. Deshpande, Olivier Devauchelle, Behrooz Ferdowsi, Rachel Glade, Lucas Goehring, Ian J. Hewitt, Douglas Jerolmack, Ruben Juanes, Arshad Kudrolli, Ching Yao Lai, Wei Li, Claire Masteller, Kavinda Nissanka, Allan M. Rubin, Howard A. Stone, Jenny Suckale, Nathalie M. Vriend, John S. Wettlaufer, Judy Q. Yang
Physics
The soft part of the Earth's surface - the ground beneath our feet - constitutes the basis for life and natural resources, yet a general physical understanding of the ground is still lacking. In this critical time of climate change, cross-pollination of scientific approaches is urgently needed to better understand the behavior of our planet's surface. The major topics in current research in this area cross different disciplines, spanning geosciences, and various aspects of engineering, material sciences, physics, chemistry, and biology. Among these, soft matter physics has emerged as a fundamental nexus connecting and underpinning many research questions. This perspective …
Topics In Photonic Quantum Technology: Polarization Entanglement Dynamics In Optical Fibers And Low-Light Imaging., Pratik J. Barge
Topics In Photonic Quantum Technology: Polarization Entanglement Dynamics In Optical Fibers And Low-Light Imaging., Pratik J. Barge
LSU Doctoral Dissertations
Recent advances in quantum photonics promise transformative impacts on computing, communication, sensing, and imaging. This thesis explores two areas in photonic quantum technology: polarization entanglement dynamics in optical fibers and low-light imaging. Optical fibers are the most suitable medium for photonic qubits and long-distance entanglement distribution is a critical requirement to realize quantum technologies. We study the decay of polarization-entanglement of the Bell state photons propagating through imperfect optical fibers with spatially fluctuating refractive index. Furthermore, to extend the distribution distance, we propose the use of dynamical decoupling in the optical fiber using half waveplates and show that significant improvement …
Riesz Particle Markov Chain Monte Carlo Methods, Xiongming Dai
Riesz Particle Markov Chain Monte Carlo Methods, Xiongming Dai
LSU Doctoral Dissertations
Markov chain Monte Carlo (MCMC) methods are simulations that explore complex statistical distributions, while bypassing the cumbersome requirement of a specific analytical expression for the target. This stochastic exploration of an uncertain parameter space comes at the expense of a large number of ``burn-in'' samples, and the computational complexity leads to the curse of dimensionality. Although at the exploration level, some methods have been proposed to accelerate the convergence of the algorithm, such as tempering, Hamiltonian Monte Carlo, Rao-redwellization, and scalable methods for better performance, they cannot avoid the stochastic nature of this exploration. We develop algorithms for the energy …
Analysis Of The Potential For Enhancing The Efficiency Of A Floating Photovoltaic (Fpv) System, How-Ping Wu, Ching-Yi Tseng, Chuan-Chung Jen, Yuan-Ching Chiang, Sih-Li Chen
Analysis Of The Potential For Enhancing The Efficiency Of A Floating Photovoltaic (Fpv) System, How-Ping Wu, Ching-Yi Tseng, Chuan-Chung Jen, Yuan-Ching Chiang, Sih-Li Chen
Journal of Marine Science and Technology–Taiwan
This study examined the power generation capabilities of FPV systems and the advantages of employing active cooling on floating solar panels. Floating solar panels exhibit improved efficiency due to operating at lower temperatures facilitated by the cooling effect of water evaporation. Additionally, the high availability of water renders the application of the active cooling technique economically viable. This study developed a comprehensive simulation of a floating solar system, integrating a mathematical model to validate experimental findings and a temperature model derived from an energy equation specific to floating solar panels. This model calculates the heat transfer among the three different …
Effects Of Two Grazing Conditions On The Reproductive Achievement Of Male Alpaca In The Northern Peru Grasslands, C Pinares, E Malpartida, S Cortez
Effects Of Two Grazing Conditions On The Reproductive Achievement Of Male Alpaca In The Northern Peru Grasslands, C Pinares, E Malpartida, S Cortez
IGC Proceedings (1977-2023)
Alpaca have recently been introduced to the northern Peru grasslands (Jalca). Effects of two systems of grazing management, co-grazing (with sheep) under fair grassland condition (CGFC) versus exclusive grazing under good grassland condition (EGGC), upon the reproductive achievement was examined from the 6th to the 16th month of age. Each system involved 20 Huacaya animals, managed by individual herders. Availability of herbage preferred by alpaca (HMA) and animal measurements (herbage intake, liveweight, testicle size, penis release from preputial attachments, plasma testosterone) were monitored monthly. Puberty, judged by the penis release from the preputial attachments, was achieved by 7 …
Experiences Of Eight Ohio Beef And Sheep Producers With Year Round Grazing, H M. Bartholomew, S L. Boyles, B Carter, E Vollborn, D Miller, R M. Sulc
Experiences Of Eight Ohio Beef And Sheep Producers With Year Round Grazing, H M. Bartholomew, S L. Boyles, B Carter, E Vollborn, D Miller, R M. Sulc
IGC Proceedings (1977-2023)
Livestock producers participated in a demonstration project to extend the grazing season and evaluate dormant forage quality and yield. Differences were not detected in yields among forage species but yield differences existed among sites. Yield estimates did not change over time across all forage species but some sites were only able to participate for two months. Producers utilizing fescue beyond November had reductions in herbage mass. Crude protein, available crude protein, acid detergent fiber, and neutral detergent fiber content differed among forage species and sites. Energy and lignin content were similar for all forage species and sites. Sodium and copper …
Forage Production Of Irrigated Lecerne- Grass Mixtures Grazed By Sheep, M L. Enrique, D P. Minon
Forage Production Of Irrigated Lecerne- Grass Mixtures Grazed By Sheep, M L. Enrique, D P. Minon
IGC Proceedings (1977-2023)
The forage production and botanical changes of lucerne cultivars in pure stands and in grass mixtures were studied in a split-plot experiment with irrigation and sheep grazing. The non dormant lucerne cultivars (Medicago sativa) CUF 101, Monarca SPINTA, P 30 and common were the main plots, and tall fescue (Festuca arundinacea), canarygrass (Phalaris aquatica), cocksfoot (Dactylis glomerata), tall wheatgrass (Thynopirum ponticum) and prairie grass (Bromus catharticus) were the subplots. The experiment was grazed 3, 6 and 4 times during 3 years. Total yield was similar for all lucerne …
Oat Grazing: Forage Composition And Supplementation Response, A J. Freddi, M J. Arzadun, A A. Pissani, P Sastre
Oat Grazing: Forage Composition And Supplementation Response, A J. Freddi, M J. Arzadun, A A. Pissani, P Sastre
IGC Proceedings (1977-2023)
Oat forage (Avena sativa), which has low soluble carbohydrates (SC) and high soluble protein (SP) content, can reduce liveweight gain of grazing animals; supplementation with grain and low degradability protein may serve to counteract the effect. A grazing trial was carried out on two soils with different nitrogen (NO3 -) availability, from 16 April 1994 to 6 September 1994. Steers were randomly allocated to 3 treatments: low nitrogen (LN), high nitrogen (HN) and high nitrogen with supplementation (HNS). Forage of LN showed lower SP (p<0.05) during the first month of grazing, and higher SC (p<0.05), than HN during the first two months of the trial. Animal liveweight gain was: 892, 909 and 775 g/an/day for LN, HNS and HN, respectively, with animals in HN of significantly lower liveweight gain (p<0.05). Under the conditions of this trial, animals grazing on oat forage with lower SC and higher SP had lower liveweight gain and responded to supplementation.
Native And Introduced Forage Systems For Cow-Calf Production, S W. Coleman, W A. Phillips, J D. Volesky
Native And Introduced Forage Systems For Cow-Calf Production, S W. Coleman, W A. Phillips, J D. Volesky
IGC Proceedings (1977-2023)
The objectives of this study was to compare a highly productive introduced warm-season perennial grass to native range for cowcalf production over two years. Three systems, 1) native range with pelleted soybean or cottonseed meal as winter protein supplement (NC); 2) native range with wheat pasture (NW); and 3) Plains Bluestem with wheat pasture (PB) were compared. Protein supplements were given twice weekly and cows grazing wheat pasture were allowed 6 hrs to graze. Cows on NW were heavier with higher condition at breeding in the spring of 1994 than those on NC and cows on PB were heavier and …
Rotational Stocking And Soil Nutrient Distribution On Hawaiian Grasslands, B W. Mathews, J P. Tritschler, L E. Sollenberger
Rotational Stocking And Soil Nutrient Distribution On Hawaiian Grasslands, B W. Mathews, J P. Tritschler, L E. Sollenberger
IGC Proceedings (1977-2023)
A naturalized kikuyu (Pennisetum clandestinum Hochst. ex Chiov.) grassland was grazed by heifers (Bos taurus) for 2 years to determine the effects of two rotational stocking methods (short vs. long grazing periods) on soil N, P, K, Ca, Mg, and S distribution in paddocks with natural shade. Additionally, kikuyugrass-greenleaf desmodium (Desmodium intortum Urb.) paddocks were used to evaluate soil nutrient distribution in rotationally stocked paddocks (long grazing periods) without shade. In the study with shade, soil N, P, and K distribution did not differ between stocking methods. These nutrients accumulated within 15 m of shade, but did not …
Relationship Between Height And Sward Quality In Rotational Dairy Systems, M R. Mosquera-Losada, A Gonzalez-Rodriguez
Relationship Between Height And Sward Quality In Rotational Dairy Systems, M R. Mosquera-Losada, A Gonzalez-Rodriguez
IGC Proceedings (1977-2023)
Height is a good guide for management in dairy systems.Intake by dairy cows depends on amount offered and quality of pasture and for this reason a relationship between that offered and pasture quality with height should be studied. The experiment was conducted in NW of Spain with three different stocking rates in dairy systems. A lower quality sward was found in the taller offered pasture as indicated by its higher ADF and lower CP percentages. Total sward ADF (kg x ha-a) was higher in taller offered pasture, which indicated a lower pasture quality, however the total CP was positively related …
Non-Destructive Methods For The Estimation Of Sward Production, M R. Mosquera-Losada, A Gonzalez-Rodriguez
Non-Destructive Methods For The Estimation Of Sward Production, M R. Mosquera-Losada, A Gonzalez-Rodriguez
IGC Proceedings (1977-2023)
Two non- destructive methods of grass production were compared: grassmeter and sward stick, in order to find an equation for transforming one into the other in dairy rotational systems. Linear, logarithmic and quadratic equations were fitted to the data. Linear equation was preferred by simplicity. General equations which included all the year periods showed no differences between sward stick and grassmeter. A detailed study of the different phenology states showed lower heights with grassmeter than with the sward stick method, which should take into account grazing management height recommendations.
Theoretical And Spectroscopic Insights Into Molybdenum- And Tungsten-Sulfur Bonding, Jesse Lepluart
Theoretical And Spectroscopic Insights Into Molybdenum- And Tungsten-Sulfur Bonding, Jesse Lepluart
Chemistry and Chemical Biology ETDs
Molybdenum and tungsten chemistry in biology is dominated by bonding interactions with sulfur and the other chalcogens. The highly-conserved structures of these enzymes’ active sites suggest an early evolution in the history of life, with molybdenum and/or tungsten enzymes likely expressed by the last universal common ancestor. Despite their active site similarities, molybdenum and tungsten enzymes catalyze a diverse array of reactions via equally diverse mechanisms. A deep understanding of the electronic structures of these enzyme active sites and their catalytic intermediates is key to understanding this remarkable chemistry.
The work presented here aims to deepen the understanding of molybdenum …
Kinetic Characterization And Identification Of Key Active Site Residues Of The L-Aspartate N-Hydroxylase, Cree, Sydney B. Johnson, Hannah Valentino, Pablo Sobrado
Kinetic Characterization And Identification Of Key Active Site Residues Of The L-Aspartate N-Hydroxylase, Cree, Sydney B. Johnson, Hannah Valentino, Pablo Sobrado
Chemistry Faculty Research & Creative Works
CreE is a flavin-dependent monooxygenase (FMO) that catalyzes three sequential nitrogen oxidation reactions of L-aspartate to produce nitrosuccinate, contributing to the biosynthesis of the antimicrobial and antiproliferative nautral product, cremeomycin. This compound contains a highly reactive diazo functional group for which the reaction of CreE is essential to its formation. Nitro and diazo functional groups can serve as potent electrophiles, important in some challenging nucleophilic addition reactions. Formation of these reactive groups positions CreE as a promising candidate for biomedical and synthetic applications. Here, we present the catalytic mechanism of CreE and the identification of active site residues critical to …
Kinetic Characterization And Identification Of Key Active Site Residues Of The L-Aspartate N-Hydroxylase, Cree, Sydney B. Johnson, Hannah Valentino, Pablo Sobrado
Kinetic Characterization And Identification Of Key Active Site Residues Of The L-Aspartate N-Hydroxylase, Cree, Sydney B. Johnson, Hannah Valentino, Pablo Sobrado
Chemistry Faculty Research & Creative Works
CreE is a flavin-dependent monooxygenase (FMO) that catalyzes three sequential nitrogen oxidation reactions of L-aspartate to produce nitrosuccinate, contributing to the biosynthesis of the antimicrobial and antiproliferative natural product, cremeomycin. This compound contains a highly reactive diazo functional group for which the reaction of CreE is essential to its formation. Nitro and diazo functional groups can serve as potent electrophiles, important in some challenging nucleophilic addition reactions. Formation of these reactive groups positions CreE as a promising candidate for biomedical and synthetic applications. Here, we present the catalytic mechanism of CreE and the identification of active site residues critical to …
An Investigation Of The Sub-Lethal Impacts To Pollinators From Pesticides, Emily Beahm
An Investigation Of The Sub-Lethal Impacts To Pollinators From Pesticides, Emily Beahm
Theses
In order to feed a growing global population, agricultural practices must utilize pesticides to maintain high yields. Responsible use of pesticides should be based on literature confirming their efficacy and safety. When pesticides are not adequately investigated prior to their release, there can be severe consequences. Many highly effective pesticides, such as the class neonicotinoids, were allowed to be used commercially prior to thorough assessment of their environmental risks, resulting in consequences that largely have fallen to the exposed pollinator populations. To avoid similar outcomes, I tested the popular biopesticide Botanigard which contains Beauveria bassiana, an entomopathogenic fungus previously exposed …
The Effect Of Lighting In Color In The Interior Space Of The Residential Unit, Abd Elbary Eldininy Abd Elbary Eldininy
The Effect Of Lighting In Color In The Interior Space Of The Residential Unit, Abd Elbary Eldininy Abd Elbary Eldininy
Journal of Engineering Research
ABSTRACT: Humanity is spending more and more time indoors, both at work and at home - with studies showing that we now spend 87% of our lives indoors. Residential environ ments both positively affect the mood and well-being of its occupants, just as places with poor and uncomfortable lighting and colors can make life miserable. This is why we are interested in this issue. The importance of knowing the issues of lighting and colors in order to obtain a well thought-out interior design. The interior designer has the ability to control in the quality of lighting of various types, artificial …