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Some Plant Leaves Have Orientation-Dependent Epr And Nmr Spectra, Douglas C. Mccain, Ted C. Selig, University Of Illinois At Urbana-Champaign, John L. Markey

Department of Chemistry: Faculty Publications

Proton nuclear magnetic resonance (¹H NMR) spectra of leaves from 50 plant species were obtained at a spectrometer frequency of 470 MHz. Water present in leaf samples gives rise to characteristic spectral patterns. Most species show only one broad ¹H NMR peak; however, the leaves of some plants display complex, orientation-dependent spectra in which a common three-line pattern is discerned. The pattern varies with the angle between the leaf surface and the external magnetic field. Proton relaxation measurements show the presence of at least two water compartments in the leaves. The compartments are responsible for different components …

Small Mammals In Prairie Wetlands: Habitat Use And The Effects Of Wetland Modifications, Grey W. Pendleton

Electronic Theses and Dissertations

Although well documented for other habitat types, small mammal habitat use patterns in prairie wetlands are poorly understood. The distribution of the mammal fauna of South Dakota is also not well known. Because of the lack of information in these areas, evaluation of the impacts of wetland modifications on the resident mammal community is not possible. The objectives of this study were (1) to document the species composition and abundance of small mammal communities inhabiting prairie wetland basins, (2) to determine the effects of small scale habitat modification on small mammals, (3) and to explain local species distribution patterns using …

Las Vegas Wash Advanced Water Quality Study: Final Report, Richard A. Roline, James J. Sartoris, U.S. Bureau Of Reclamation

Publications (WR)

The purpose of the Las Vegas Wash Advanced Water Quality Study is to determine the existence, extent, and mechanisms of nutrient and toxin stripping in Las Vegas Wash under present conditions and under future conditions, both with and without construction of the proposed salinity control unit as described by the Bureau of Reclamation (USBR, 1982b). This study was performed for the Lower Colorado Region Division of Planning by personnel of the Environmental Sciences Section of the Division of Research and Laboratory Services, E&R Center, Denver, Colorado. Work on the study began in February 1983. The general approach adopted for this …

Investigations And Research In Nevada By The Water Resources Division, U. S. Geological Survey, 1982-83, Terry Katzer, Otto Moosburner, William D. Nichols

Publications (WR)

The Water Resources Division, U.S. Geological Survey, is charged with (1) maintaining a hydrologic network in Nevada that provides information on the status of the State's water resources and (2) engaging in technical water-resources investigations that have a high degree of transferability. To meet these broad objections, 26 projects were active in Nevada during fiscal year 1982 in cooperation with 36 Federal, State, and local agencies. Total funds were $3,319,455, of which State and local cooperative funding amounted to $741,500 and Federal funding (comprised of Geological Survey Federal and cooperative programs plus funds from six other Federal agencies) amounted to …

Factors Affecting Reproductive Success Of Bonytail Chubs And Razorback Suckers In Lake Mohave, Michael A. Bozek, Larry J. Paulson, James E. Deacon, U.S. Department Of Interior, Fish And Wildlife Service

Publications (WR)

Razorback suckers (Xyrauchen texanus) and bonytail chubs (Gila elegans) were once widespread throughout the Colorado River system. The ranges and populations of these native species and others have declined in the past 50 years. Bonytail chubs appear to be extremely rare and possibly nearing extinction in the Upper Colorado River Basin. The razorback sucker is widely distributed in the upper river but is considered rare throughout most of that range and is also rare in the Grand Canyon. Razorback suckers are abundant only in a few habitats in the upper river. They congregate and spawn over …

Effect Of Temperature On The Association Constants Of Some Divalent Metal Ions With Chloride In Sea Water-Like Solutions, Jose Vinicio Macias Zamora

University of the Pacific Theses and Dissertations

Association constants for the formation of lead (II) chloride complexes were studies in aqueous solutions also containing copper (II) and cadmium (II) ions.

The ionic strength was adjusted with sodium perchlorate to resemble that of sea water. The temperature was set at fixed values between 5° and 35° C to determine the effect on the equilibria in these systems. The total metal concentration was less than 10^-8 M.

Differential pulse anodic striping voltammetry was used with a conventional three electrode system and a thin-film working electrode of Pt/Hg. Complex formation was followed as a function of the ligand concentration …

Sediment Oxygen Demand In Streams Receiving Sewage Effluent, John J. Schultz

Masters Theses

Sediment oxygen demand is an important factor in determining dissolved oxygen concentrations in streams and rivers subjected to sewage effluents and other sources of organic pollution. Resuspension of sediments during bottom-scouring after periods of heavy precipitation exerts an immediate and increased oxygen demand on the water and is expected to decrease sediment oxygen demand at the site.

Sediment samples were collected monthly from April through November, 1983 from three small streams subjected to sources of organic pollution. The samples collected were arbitrarily categorized into wet and dry period samples based on the total precipitation between collection dates. Sediment oxygen demand …

The Synthesis Of Various Substituted 3-Amino-7-Hydroxy-2,2-Dimethyltetralins And Their Opioid-Related Activities, David Alan Lippman

University of the Pacific Theses and Dissertations

A series of aminotetralones and aminotetralins were synthesized from the common intermediate F, 3-amino-2,2-dimethyl-7-methoxy- 1-tetralone. The final compounds derived from F were simple substituted and/or reduced analogues. The products would allow a progressive structure activity relationship to be drawn based on pharmacological testing.

The common intermediate F was synthesized utilizing a six step procedure starting with p-methoxyphenylacetic acid. The overall yield from the precursor to the F:HC1 was 25%. Compound F was either O-demethylated to form 3-amino-2,2-dimethyl-7-hydroxy-l-tetralone (I) or was dimethylated on the amine and subsequently O-demethylated to yield the 3-dimethylamino-7-hydroxy-2,2-dimethyl-l-tetralone (J). The last major modification was the reduction of …

Setchenov Parameters For Naphthalene, Gerardo Gold Bouchot

University of the Pacific Theses and Dissertations

It is the purpose of this work to study the solubility of naphthalene, the simplest polycyclic aromatic hydrocarbon as a function of the salt content and the temperature, in ranges that span those likely to be found in natural ecosystems. Another goal is to set up a high-pressure generator, to study the effect of pressure on the solubility of hydrocarbons.

Studies On The Biochemical And Antibiotic Patterns Of The Genus Citrobacter, Craig Richard Tanner

University of the Pacific Theses and Dissertations

Today three species are recognized in the genus: C. freundii, C. amalonaticus, and C, diversus. C. freundii is known to occur as three varieties: C. freundii H₂S +, IND -, C. freundii H₂S +, IND +, and C. freundii H₂S -, IND -.

The role of Citrobacter in disease has not been investigated thoroughly. The organism is a normal inhabitant of the human intestine, being as common as Escherichia coli in infants. With age, the child's intestine begins to show a greater ratio of E. coli to Citrobacter (Nahhas, personal communication). Citrobacter has been …

Applications Of Aerial Imagery In Identification Of Natural Areas, Kendall Duane Wessel

Dissertations and Theses @ UNI

There is current interest in utilizing aerial imagery to obtain information on natural vegetation. The purpose of this study is to utilize and evaluate commonly available aerial imagery to identify potential natural areas suitable for preservation and to initiate development of a procedure for imagery interpretation to meet this goal.

Clayton County, located in the northeastern quarter of the state of Iowa, was selected for study because it is dissected by steep, narrow stream valleys that are unsuitable for cultivation and may still possess native vegetation of a quality suitable for preservation.

Baseline or control communities were selected from known …

Totally Empirical Wavefunctions From X-Ray Diffraction Data, Martin Jeffry Goldberg

Dissertations, Theses, and Capstone Projects

The interpretation of coherent x-ray diffraction experiments by a quantum model is described. Adjusting the coefficients of an LCAO expansion to best fit measured Bragg intensities results in a totally empirical quantum wavefunction. The quantum model is compared to a multipole expansion. The constraints imposed by quantum mechanics are examined, and several methods of satisfying these constraints while best fitting a wavefunction to measured Bragg intensities are detailed. Application is made to beryllium metal, with a resultant fit R(,1) = .00249. Similar applications to graphite and diamond are outlined. The formalism is extended to explicitly include solid-state effects, and this …

Mechanism Of Translational Control By Partial Phosphorylation Of The Α Subunit Of Eukaryotic Initiation Factor 2, John Siekierka, Veeraswamy Manne, Severo Ochoa

Department of Chemistry and Biochemistry Faculty Scholarship and Creative Works

Catalysis of ternary complex formation by the GDP exchange factor (GEF), in the presence of Mg2+, is blocked by phosphorylation of the α subunit of the eukaryotic initiation factor 2 (eIF-2). We proposed earlier that this phosphorylation interferes with the interaction between eIF-2 and GEF (then termed ESP). If so, inhibition should be related to the extent of phosphorylation. However, work in other laboratories indicated that in fully inhibited, heme-deficient lysates only 20-40% of the EIF-2 is phosphorylated. To understand the nature of the molecular lesion in eIF-2-α phosphorylation we used a system of pure components in which the rate …

Thermodynamics Of Aqueous Solutions Of 1-Naphthyl Methylcarbamate, Miguel Angel Huerta Diaz

University of the Pacific Theses and Dissertations

Accurate solubility measurements for the pesticide l-naphthyl-N-methylcarbamate (carbaryl) in water, natural and artificial seawater, NaCl, Na₂SO₄, CaCl₂ and (CH₃)₄NBr, at different temperatures covering the range 5-45 °C, were obtained using a combination of the generator column method and absorption spectroscopy techniques. As a rule, it was found that the solubility of carbaryl in water and in the electrolyte solution increased with an increase in temperature.

The thermodynamic parameter ΔG°, ΔH°, ΔS°, and ΔC°_p at 298.15 K, for the dissolution process carbaryl(s) to carbaryl(aq) and carbaryl(s) to carbaryl(aq. elect.), were calculated …

Parvec Workshop On Very Large Least Squares Problems And Supercomputers, John R. Rice

Department of Computer Science Technical Reports

No abstract provided.

A Decade Of Usda-Ars Predator Research, 1972-1982, Jeffrey S. Green

Great Plains Wildlife Damage Control Workshop Proceedings

Federal government restrictions in 1972 on several widely-used forms of predator control stimulated research on alternative methods of reducing depredation on livestock. In the same year, the U.S. Department of Agriculture began predator research through the Agricultural Research Service (ARS) and designed the U.S. Sheep Experiment Station CUSSES, near Dubois in southeastern Idaho as the principle location for the investigations. At the outset, the objective of ARS research was to examine non-lethal methods for reducing depredation, primarily by coyotes (Cants), on sheep. During the first several years, while predator research facilities were constructed at the USSES, ARS funds were primarily …

Great Plains Wildlife Damage Control Award Recipients

Great Plains Wildlife Damage Control Workshop Proceedings

Award Recipients

An Evaluation Of Burrow Destruction As A Ground Squirrel Control Method, Dennis C. Stroud

Great Plains Wildlife Damage Control Workshop Proceedings

Several researchers have suggested that the presence of burrows is a limiting factor for ground squirrel populations and that the destruction of these burrow systems can reduce the rate of reinvasion following control. However, no one has yet tested the potential value of burrow destruction as a control method.

Keynote Address, Robert J. Pool

Great Plains Wildlife Damage Control Workshop Proceedings

Most modern environmentalists during their formative years have had little actual contact with wildlife under natural conditions. Their wildlife philosophies have been developed via the mass media and from experiences with animals as pets or confined in zoos. In general, modern environmentalists are sincere, dedicated, idealistic and enthusiastic, but they often lack realism and are blessed with the innocence of naivete. The majority of people in the United States now exhibit strong affection for wild animals and are deeply concerned over any actions perceived as causing pain to individual animals. These attitudes towards wild animals will impact on future wildlife …

Behavioral Ecology Of Coyotes: Implications For Reducing Predator-Livestock Conflicts, William F. Andelt

Great Plains Wildlife Damage Control Workshop Proceedings

During the past 2 decades, numerous research projects have been conducted to gain a better understanding of coyote (Canis latrans) behavior and ecology which could be used to reduce livestock losses to predators. This paper synthesizes some of these investigations to provide some insight into methods of reducing livestock losses to coyotes.

Some International Approaches To Rat Control, Walter E. Howard

Great Plains Wildlife Damage Control Workshop Proceedings

There are many basic requirements concerning the political structure, financial support needed, proper organization, staff training, public education, laws and regulations, and the keeping of good records, which must be adequately considered before a rat control program can become successful. Likewise, there are also a number of basic principles concerning rodent control that must be understood and adhered to. Some villages in Korea and the country of Kuwait will be used as examples of new rat control approaches.

Workshop-Discussion Session, Joesph M. Schaefer

Great Plains Wildlife Damage Control Workshop Proceedings

The purpose of the workshop-discussion session was to establish a list of ideas that would provide the best focus and direction to improve wildlife damage control programs. During this session the Nominal Group Technique (NGT) (Delbecq et al. 1975) was used to: 1) identify and rank obstacles that limit the effectiveness of wildlife damage control efforts, and 2) generate possible solutions to the most important obstacles. This format allowed equal and full participation and was successful in generating many original ideas.

13C Nmr Investigation Of Nonenzymatic Glucosylation Of Protein, Carolyn I. Neglia, Helga J. Cohen, Albert R. Garber, Paul D. Ellis, Suzanne R. Thorpe, John W. Baynes

Faculty Publications

Nonenzymatic glucosylation of protein is initiated by the reversible condensation of glucose in its open chain form with the amino groups on the protein. The initial product is an aldimine (Schiff base) which cyclizes to the glycosylamine derivative. The aldimine can undergo a slow Amadori rearrangement to yield the relatively stable ketoamine adduct which is structurally analogous to fructose. 13C NMR has been used to characterize these early products of nonenzymatic glucosylation, using RNase A as a model protein. C-1 of the beta-pyranose anomer of the glycosylamine was identified at 88.8 ppm in the spectrum of RNase glucosylated approximately 1:1 …

Plasma Polymerization Of Tetramethyldisiloxane By A Magnetron Glow Discharge, Ashok K. Sharma, H. Yasuda

Chemistry Faculty Research & Creative Works

Plasma polymerization of tetramethyldisiloxane by a magnetron glow discharge was studied. The glow discharge was created between parallel electrodes with a 10 kHz electric power source with a superimposed magnetic field using permanent bar magnets. Polymers were deposited onto moving substrates placed on the surface of a rotating disc located in between the electrodes. The deposition rates were determined with a quartz crystal thickness monitor placed on the plane of the rotating disc and just outside the edge of the disc. The current-voltage relationship observed for plasma polymerization of the monomer depends on the monomer feed rate and the conditioning …

A Microsystem Sediment-Water Simulation Study For The Proposed Jordanelle Reservoir, Heber City, Utah, United States Department Of The Interior, Bureau Of Reclamation

Water

The technique of microsystem sediment-water simulation was used to predict water quality data for the proposed Jordanelle Reservoir, Heber City, Utah. Simulation microsystems were prepared for four sites located in the north arm of the reservoir basin including two sites located in an abandoned acid mine tailings pond. Data obtained from the tailings pond microsystems indicated that low pH water and high trace metal concentrations will exist in the north arm of the reservoir. These data suggested that some kind of membrane or compacted earth lining will be necessary to seal and contain the mine spoilage. Other sites in the …

Disposal Of Household Wastewater In Soils Of High Stone Content (1981-1983), E. M. Rutledge, C. R. Mote, D. T. Mitchell, M. S. Hirsch, M. D. Harper, H. D. Scott, C. L. Griffis

Arkansas Water Resources Center Technical Reports

Four experimental filter fields were constructed with built-in monitoring equipment in Nixa soils. These soils contain many chert fragments and a fragipan about 60 cm below the soil surface. The fragipan restricts downward movement of water and is the designlimitingfeature. The four filter fields were: 1. A "standard" filter field, 76 cm deep. The bottom of the trench was in the fragipan. 2. A "modified standard" filter field, 30 cm deep. The bottom of the trench was above the fragipan. 3. A "modified pressure" filter field, 40 cm deep. The bottom of the trench was above the fragipan. In addition, …

The Prairie Naturalist Volume 15, No. 4. December 1983

The Prairie Naturalist

Paul B. Kannowski, Editor

Nikki R. Seabloom, Assistant Editor

Douglas H. Johnson, Book Review Editor

TABLE OF CONTENTS

ASPECTS OF THE NESTING ECOLOGY OF LEAST TERNS AND PIPING PLOVERS IN CENTRAL NEBRASKA ▪ C. A. Faanes

LEAD SHOT INCIDENCE IN SANDHILL CRANES COLLECTED FROM ALASKA, CANADA, AND TEXAS ▪ B. M. Wallace, R. J. Warren and G. D. Gaines

LEAD SHOT INCIDENCE IN WATERFOWL COLLECTED FROM THE TEXAS HIGH PLAINS ▪ B. M. Wallace, R. J. Warren and R. J. Whyte

SMALL MAMMALS OF WINTER WHEAT AND GRAIN SORGHUM CROPLANDS IN WEST-CENTRAL KANSAS ▪ K. W. Navo and E. D. …

The Probe, Issue 38 - December 1983

The Probe: Newsletter of the National Animal Damage Control Association

The Probe National Animal Damage Control Association
No. 38 December, 1983
USFWS trying to close ADC
Ye Ed Comments
MIS Reports
Letters to Ye Ed
Meetings
Wolves

Cationic And Anionic Micellar Catalyzed Hydrolysis Of Hydroxamic Acids, Douglas Eugene Conran

Masters Theses

The hydrolysis of octanohydroxamic and N-methyloctanohydroxamic acids in the presence of cationic and anionic micelles was investigated. Rate constants were determined for the hydrolyses in cetyltrimethylammonium bromide (ctab), the cationic surfactant, with 0.1111 N NaOH and in sodium 1-dodecanesulfonate, the anionic surfactant, with 0.09270 N HC1 at 50.01 + 0.11°C. The acid hydrolysis and the base hydrolysis of N-methyloctanobydroxamic acid followed the standard model for micellar catalysis.

Rhode Island's Barrier Beaches: As Assessment Of Their Future, David J. Hampshire

Marine Affairs Theses and Major Papers

The lands and waters of the coastal zone have either been mismanaged or not managed at all since the early settling of the United States. Nowhere is this more evident, perhaps than along the nation's barrier beaches. Rhode Island, while not suffering nearly from the degree of development on its barrier beaches as other states, is no exception. Economic pressures brought to bear have forced federal, state, and local governments to grapple extensively with this issue. The need for the preservation of barrier beaches in their natural state cannot be overstated and is recognized by all levels of government. This …