Digital Commons Network^™

Enantiomeric Resolution And Chiral Recognition Of Racemic Nicotine And Nicotine Analogues By Β-Cyclodextrin Complexation: Structure-Enantiomeric Resolution Relationships In Host-Guest Interactions, Jeffrey I. Seeman, Henry V. Secor, Daniel W. Armstrong, Karen D. Timmons, Timothy J. Ward

Chemistry Faculty Research & Creative Works

High-performance liquid chromatography using β-cyclodextrin bonded phases was examined for the enantiomeric separation of racemic nicotine and 19 racemic nicotine analogues. Ten pairs of enantiomers were separated by this technique. This represents the first reported facile and direct separation of these racemates. Effects of pH, mobile phase composition, and structural features of the substrates (i.e., position and size of substituents, presence of pyrrolidine ring or hydrogen bonding functionalities, basicity) on the enantioselectivity are examined. Various structural aspects of the compounds were related to retention to the cyclodextrln-modlfied support and to the enantiomeric separations observed. Implications of this work to host-guest …

Survival And Reproduction Of The Freshwater Grass Shrimp Palaemonetes Paludosus (Gibbes 1850) (Decapoda:Palaemonidae), In Saline Water, Brian Thomas Lowe

OES Theses and Dissertations

To determine the effects of salinity on adult and larval survival, egg deposition, egg hatching and metamorphosis, shrimp were held in the laboratory and exposed to treatment salinities ranging from O to 35 ppt. Tests on adult survival indicate a 96 hour LC-50 between 30 and 35 ppt. Longer term tests on adult survival showed high mortality in salinities greater than 15 ppt. Shrimp became ovigerous in salinities of O - 20 ppt with egg hatching and metamorphosis limited to O - 5 ppt. Starved- larvae hatched from field captured ovigerous females in O ppt were able to metamorphose in …

Recent Benthic Foraminifera Of Breton And Stake Islands Northern Gulf Of Mexico, Eric S. Collins

OES Theses and Dissertations

Fifty-three species of recent benthic foraminifera and thecamoebians have been documented and described from the Breton and Stake Island area, northern Gulf of Mexico, and from a core from Barataria Basin, Mississippi delta.

Cluster analysis of benthic assemblages using presence/absence and transformed abundance data reveals the presence of a marsh and shallow water marine biofacies. Based on the results of a presence/absence cluster analysis, the shallow water marine biofacies can be subdivided into a miliolid biofacies am an Ammonia beccarii/Elphidium species biofacies. Cluster analysis of transformed abundance data, however, shows that the shallow marine biofacies can be subdivided into four …

Distribution Of Suspended Particulate Matter, Patuxent River Estuary, Maryland, Christopher W. Frye

OES Theses and Dissertations

Physical processes which may affect estuarine circulation in a coastal plain estuary were monitored to determine their relative importance on temporal and spatial variability of the concentration, composition, and particle-size of suspended particulate matter (SPM) in Patuxent River estuary, MD, during 1985-86. Discharge rates from Patuxent River determined the character of fresh and estuarine water mixing, and magnitude of SPM concentration in the upper estuary. The mixing zone between fresh and estuarine water, defined as 0 - 1.5 °‰, and turbidity maximum were geographically separated during most of the study period. This suggests that two-layer circulation may be less important …

The Synthesis And Evaluation Of 5-Phenyloxazolidines As Potential Cardiovascular Drugs, Tammy C. Wang

Chemistry & Biochemistry Theses & Dissertations

Drugs such as adrenoceptor antagonists and certain centrally acting agents are known to lower blood pressure and thus serve as clinically useful antihypertensive agents. Norepinephrine 4, a natural ∝-adrenoceptor agonist, is the major agent associated with increased blood pressure in the periphery. Based on a careful structure-activity comparison, a series of substituted oxazolidines, 20, 21, 22 and 23, have been designed as possible antihypertensive candidates. Specifically, 22 and 23 have been synthesized to serve as potential norepinephrine antagonists.

Preliminary evaluation of these compounds indicated that they were not antihypertensive in nature. The more active compound, 23, …

Optimization Of The Tungstic Acid Denuder Technique For The Measurement Of Atmospheric Ammonia, Patricia Diane Roberts

Chemistry & Biochemistry Theses & Dissertations

Measurement of - atmospheric ammonia with the tungstic acid denuder technique is discussed. Characterization of denuder tubes for manual sampling in terms of, repeatability, reliability and the development of ammonia blank signals was determined. Field testing of the manual sampling apparatus was performed at ground test sites and in a biomass burn smoke plume. Ammonia emissions from biomass burning are discussed.

A Study Of Human Exposure To Benzo(A)Pyrene (Bap) Through Different Pathways. Part A ; Assessment Of Benzo(A)Pyrene (Bap) Exposure Through Urine Analysis With The Hydriodic Acid Reduction Reaction. Part B, Shao-Keng Liang

Theses

PART A: An investigation of total human exposure to an environmental pollutant is described. The study is being conducted in a community impacted by a foundry suspected to be a dominant local source of benzo(a)pyrene (BaP). The research aims to assess the relative contributions of indoor and outdoor sources and to measure BaP in media including indoor air, outdoor air, food and water.

PART B: A method for biological monitoring of exposure to benzo(a)pyrene, a representative polycyclic aromatic hydrocarbon (PAH), has been developed. The analytical procedure includes extraction of PAH and PAH metabolites from urine using commercial cartridges containing c …

Early Lake Ontogeny Following Neoglacial Ice Recession At Glacier Bay, Alaska, Daniel R. Engstrom, Sherilyn C. Fritz

Department of Earth and Atmospheric Sciences: Faculty Publications

This study explores the environmental forces controlling lake ontogeny at Glacier Bay as a model for early Holocene lake evolution in north temperate lakes worldwide. Long-term chemical and biological changes in lakes are investigated with two complementary research strategies: (1) limnological conditions are compared among 32 lakes of known age and in different stages of primary catchment succession and (2) sediment cores from these same lakes are analyzed stratigraphically for fossil diatoms to ascertain developmental trends in pH, alkalinity, algal composition, and trophic status at individual sites.

Trends in water chemistry inferred from the chronosequence approach include a progressive loss …

Singular-Value Decomposition And The Grassberger-Procaccia Algorithm, Alfonso M. Albano, J. Muench, C. Schwartz, A. I. Mees, P. E. Rapp

Physics Faculty Research and Scholarship

A singular-value decomposition leads to a set of statistically independent variables which are used in the Grassberger-Procaccia algorithm to calculate the correlation dimension of an attractor from a scalar time series. This combination alleviates some of the difficulties associated with each technique when used alone, and can significantly reduce the computational cost of estimating correlation dimensions from a time series.

The Prairie Naturalist Volume 20, No.3. September 1988

The Prairie Naturalist

Paul B. Kannowski, Editor

Nikki R. Seabloom, Assistant Editor

Douglas H. Johnson, Book Review Editor

TABLE OF CONTENTS

MOVEMENTS OF ADULT STRIPED BASS TRACKED IN WILSON RESERVOIR, KANSAS ▪ K. E. Hampton, T. L. Wenke, and B. A. Zamrzla

GROWTH, POPULATION STRUCTURE, AND MORTALITY OF CHANNEL CATFISH FROM THE POWDER RIVER AND CRAZY WOMAN CREEK, WYOMING ▪ J. B. Smith and W. A. Hubert

HABITAT USE BY WHITE-TAILED DEER IN PRAIRIE-AGRICULTURAL HABITAT IN MONTANA ▪ G. L. Dusek, A. K. Wood, and R. J. Mackie

BEAVER CROP DEPREDATION IN EASTERN SOUTH DAKOTA ▪ C. D. Dieter and T. R. McCabe …

State Of The Fisheries Report 1987, Fisheries Department Of Western Australia

Status Reports of the Fisheries and Aquatic Resources

Western Australia continues to be one of the leading fishing States in Australia. The total gross value of fish, crustaceans and molluscs for 1986/87 was $172 million (Table 1) to which may be added the value of the pearl culture industry resulting in a total value of approximately $213 million.

The Probe, Issue 85 - August/September 1988

The Probe: Newsletter of the National Animal Damage Control Association

THE PROBE
National Animal Damage Control Association
AUGUST/SEPTEMBER 1988
Trapping’s Future?
The Toxic Collar
APHIS Activity Report
Pet Food Institute Report
Cholecalciferol
The Repellent, Ro-pel.
Strychnine
House/Tree Sparrows
Letters to Ye Ed

Postfire Vegetation Change Detection Using Landsat Mss And Tm Data, Mark Edward Jakubauskas

All-Inclusive List of Electronic Theses and Dissertations

Three dates of Landsat digital data were classified and then analyzed using a geographic information system (GIS). The intent of this study was to determine if differences in burn severity relate to later vegetative cover within a northern pines forest. The May 5, 1980, Mack Lake Fire in the Huron National Forest, Michigan, was selected as the study site for this research. This wildfire burned over 9000 hectares of jack pine, red pine, and mixed deciduous forest within a six-hour period. Landsat MSS data from June 1973 and TM data from October 1982 were classified using an unsupervised approach to …

The Effect Of Preozonation On The Anaerobic Biodegradability Of Resistant Phenolic Compounds, Yi-Tin Wang, Pin-Chieh Pai, James L. Latchew

KWRRI Research Reports

Ozone pretreatment studies of four model phenolic compounds were conducted to evaluate the effects of ozonation on the anaerobic biodegradability and toxicity of these compounds. Two types of batch studies, the Biochemical Methane Potential (BMP) and the Anaerobic Toxicity Assay (ATA), were performed on samples ozonated upon phenol, o-cresol, 2,5-dichlorophenol, and 2,4-dinitrophenol.

Experimental results showed that toxic and refractory phenolic compounds were converted to methane gas by means of preozonation. In general, the biodegradable fraction of the oxidation products increased as the ozone dose was increased. However, ozonation to achieve at least 60% COD reduction was necessary to faciliate methane …

Water Current, Volume 20, August 1988

Water Current Newsletter

Pacific Northwest Destination of Annual Water Resources Fall Tour
Roger Gold to Direct UNL Water Center
We've Moved! Water Center on East Campus
EPA Releases Booklet on Grondwater Protection
Research Review: Recent Projects Completed by UNL Scientists
Water Quality Initiative Teams Gear Up for Nebraska Water Quality Priority Initiative
Conservation Called for on Annual Water Resources Tour

The Role Of Term Symmetry In E-Unification And E-Completion, Blayne E. Mayfield, Ralph W. Wilkerson

Computer Science Technical Reports

A major portion of the work and time involved in completing an incomplete set of reductions using an E-completion procedure such as the one described by Knuth and Bendix [070] or its extension to associative-commutative equational theories as described by Peterson and Stickel [PS81] is spent calculating critical pairs and subsequently testing them for coherence. A pruning technique which removes from consideration those critical pairs that represent redundant or superfluous information, either before, during, or after their calculation, can therefore make a marked difference in the run time and efficiency of an E-completion procedure to which it is applied.

The …

Miscellaneous Production 23/87 - Animal Production In The Spinifex And Shrubland Regions Of Western Australia, D. Burnside

Animal production and livestock published reports

The role of the Rangeland Management Branch is to promote the sustained economic use of the rangeland resource. It provides research and extension services to the pastoral industry, provides advice on the condition of the range resource to Government and provides technical information on rangelands to other rangeland managers. A principal objective to be met in fulfilling that role is the development and promotion of economically efficient place systems that conserve the rangeland resource. At the inaugural Pastoral Soil Conservation Districts Conference in Meekatharra in May 1987, pastoralist delegates emphasized the importance of achieving that objective within the various soil …

Foraminiferal Biostratigraphy And Paleoenvironmental Analysis Of The Anahuac Formation (Late Oligocene-Early Miocene) From A Deep Well In Vermilion Parish, Louisiana, Audrey Lynne Orndorff

OES Theses and Dissertations

In the subsurface of Vermilion Parish, Louisiana, sediments from the Anahuac Formation in the #1 J. W. Steen well are assigned an Upper Oligocene-Lower Miocene age based on planktonic foraminifera. Previous age determinations for sediments from this formation elsewhere range from Middle to Late Oligocene based on the presence of larger foraminifera contained within these strata. Planktonic foraminifera in Anahuac formation sediments in the #1 J. W. Steen well permit their assignment to an established worldwide zonation scheme and indicate that the age ranges from the Globorotalia kugleri Interval Zone (Upper Oligocene) to the Catapsydrax dissimilis Zone (Lower Miocene). Benthic …

Economic Considerations For Artificial Reef Development In Coastal Virginia, Dean Thomas Devereaux

OES Theses and Dissertations

The contingent valuation method, recommended by the U. S. Water Resources Council, was used to estimate the economic value of sport fishing and diving at the Chesapeake Light Tower Artificial Reef. The study is based on a random sample of 170 anglers and 33 divers who participated in telephone, personell and mail-in surveys in 1985 and 1986.

The average user value (consumer surplus) was $21.13, $110,75, and $13.30 for head boat anglers, private boat anglers and sport divers, respectively, who claimed to have used the reef in 1985. Variation in consumer surplus was statistically affected by trip expense, distance from …

Oxidative Degradation Of Glucose Adducts To Protein: Formation Of 3-(NE-Lysino)-Lactic Acid From Model Compounds And Glycated Proteins, Mahtab U. Ahmed, John A. Dunn, Michael D. Walla, Suzanne R. Thorpe, John W. Baynes

Faculty Publications

The chemistry of Maillard or browning reactions of glycated proteins is being studied in model systems in vitro in order to characterize potential reaction pathways and products in biological systems. In previous work with the Amadori rearrangement product N alpha-formyl-N epsilon-fructoselysine (fFL), an analog of glycated lysine residues in proteins, we showed that fFL was oxidatively cleaved between C-2 and C-3 of the carbohydrate chain to yield N epsilon-carboxymethyllysine (CML) and D-erythronic acid. We then detected CML in proteins glycated in vitro, as well as in human lens proteins and collagen in vivo (Ahmed, M. U., Thorpe, S. R., and …

Wildlife Management: State And Tribal Jurisdiction At Umatilla, Douglas Nash

Natural Resource Development in Indian Country (Summer Conference, June 8-10)

11 pages.

Fisheries Management In The Regional And International Contexts: Columbia River Basin, Howard G. Arnett

Natural Resource Development in Indian Country (Summer Conference, June 8-10)

7 pages.

Contains references.

Bay/Delta Standards Memorandum And Exhibits, Thomas J. Graff

Water Quality Control: Integrating Beneficial Use and Environmental Protection (Summer Conference, June 1-3)

47 pages.

The 1987 Nonpoint Source Pollution Amendments And State Progress Under The New Program, John H. Davidson

Water Quality Control: Integrating Beneficial Use and Environmental Protection (Summer Conference, June 1-3)

143 pages.

Contains 4 pages of references.

The San Joaquin–Sacramento Delta, David R. Beringer

Water Quality Control: Integrating Beneficial Use and Environmental Protection (Summer Conference, June 1-3)

20 pages.

Contains 2 pages of references.

Public Land Livestock Grazing, Water Quality And Riparian Ecosystems: The Evolving Legal And Technical Context, Richard H. Braun

Water Quality Control: Integrating Beneficial Use and Environmental Protection (Summer Conference, June 1-3)

8 pages.

Contains 1 page of references.

Legal Issues: San Francisco Bay, Sacramento-San Joaquin River Delta And Estuary, Stuart L. Somach

Water Quality Control: Integrating Beneficial Use and Environmental Protection (Summer Conference, June 1-3)

48 pages.

Contains footnotes.

Pretreatment Issues, Sue Ellen Harrison

Water Quality Control: Integrating Beneficial Use and Environmental Protection (Summer Conference, June 1-3)

28 pages.

Contains references.

The Effluent Charge Approach To Water Quality Control, Ralph W. Johnson

Water Quality Control: Integrating Beneficial Use and Environmental Protection (Summer Conference, June 1-3)

10 pages.

Contains references.

Qualitative And Quantitative Aquatic Algal Data Compilation To Determine Macrotrends - Iv, Richard L. Meyer

Arkansas Water Resources Center Technical Reports

A data base of the algae of Arkansas ecoregions has been estabblished by the use of a relational data base management system (dBase III plus). The system was chosen to be readily available for a variety of microcomputers using MS- and PC-DOS. The data base contains taxonomic fields from division through variety, synonymy, authors, initial description, date, and definitive descriptive source. The data are cross-referenced by ecoregion, Round's community and subcommunity designations. The data base contains greater than 1,500 taxonomic records in all divisions and classes of freshwater algae. The data are sortable by any of the included parameters. The …