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Hammett Correlations In The 1H Nmr Spectra Of Some N-Arlydihalonicotinamides, Frank L. Setliff, Nikhil G. Soman, Jody Z. Caldwell, Debra L. Rogers

Journal of the Arkansas Academy of Science

Excellent linear correlations of amide proton chemical shifts (Snh) (in DMSO-d6 ) with Hammett substituent constants (5) for a series of 4-substituted anilides of four dihalonicotinic acid systems were observed. Dihalonicotinanilides with chlorine in the pyridine 2 - position exhibited a more positive slope in a Hammett plot of S^H vs - aR- where R is the substituent in the 4 position of the benzene ring. This observation is explained in terms of the inductive effect of chlorine which results in a slightly more acidic amide proton, which in turn causes an enhanced hydrogen bonding tendency to solvent. Four disubstituted …

Lake Trout Spawning In Lake Tahoe: Egg Incubation In Deepwater Macrophyte Beds, D. A. Beauchamp, B. C. Allen, R. C. Richards, Wayne A. Wurtsbaugh, C. R. Goldman

Watershed Sciences Faculty Publications

Although most populations of lake trout Salvelinus namaycush spawn over rocky shoals, use of these substrates by lake trout has not yet been found in Lake Tahoe. Large cobble substrate exists at depths less than 20 m, and steep, fractured, rocky substrate can be found in isolated areas from the surface down to at least 100 m, but no evidence of spawning activity in these areas has been found. Instead, at least a portion of the population spawns on deepwater mounds (40–60 m deep) over beds of the macrophyte Chara delicatula. This is the first known report of lake trout …

Current Research On Soil Nitrate Testing For Corn In Kentucky, John H. Grove

Soil Science News and Views

Concern has been expressed that growers do not have the "slte-specific" information they need for more efficient nitrogen (N) fertilizer management on a field-by-field basis. Soil testing has routinely been used to guide recommendations for phosphorus, potassium, and lime additions to individual fields, but effective soil N test procedures have long eluded soil scientists working in warm, humid regions with substantial winter rainfall. Now, recent research suggests that a new soil test procedure has some potential to guide fertilizer N applications for corn. The purpose of this report is to define the concept of soil nitrate testing; to describe how …

Factors Affecting Crop Response To Liming, Kenneth L. Wells, J. L. Sims

Soil Science News and Views

Soil acidity levels directly affect the rate, kinds, and degree of chemical reactions which take place in soil. Crops respond to varying degrees to these chemical reactions. For the most part, these reactions affect the solubility of mineral elements in soil and the activity of the soil's biological processes. As a result, the availability of many plant nutrient elements is regulated by soil acidity. The level of availability of plant required nutrients can be adequate, deficient, or toxic to the plant, depending on the nutrient, soil acidity, and the crop. That is why measurement of soil acidity is regarded by …

Butenolide Synthesis Via Cation-Initiated Ring Expansion/Elimination Of Β-Lactones, Jianhua Huang

Masters Theses

An area of recent research in the Black research group is an exploration of the potential of cation-initiated β-lactone ring expansions, accompanied by the elimination of a proton or other electrofuge, as a protocol for the synthesis of multisubstituted butenolides.

Γ-Bromo β-lactones were prepared via bromolactonization of the appropriate β,Γ-unsaturated acids under basic conditions. The nucleofugal bromine atom on the Γ-carbon was then employed to effect carbocation formation adjacent to the lactone ring oxygen atom; the most efficacious reagent combination was found to be silver nitrate in refluxing acetic acid. Generation of this cation initiated a migration of the β-lactone …

The Effects Of Beaver-Created Wetlands On Surface Water Quality Of Streams And Rivers In Dupage County, Illinois, Brian Conklin

Masters Theses

Dam construction by beavers creates wetlands which have the potential to improve water quality, especially in areas near urban centers. However, beaver dams may also cause flooding problems which can result in the removal of the beaver(s) and the destruction of their dam. A further understanding of how beaver-created wetlands affect water quality will provide additional data which can be utilized in beaver management decisions.

In this study, 41 chemical parameters were examined from water taken above and below beaver-created wetlands that existed in DuPage County, Illinois between May and September 1991. This study was designed to examine the effects …

Population Status And Characteristics Of Macrhybopsis Gelida, Platygobio Gracilis And Rhinichthys Cataractae In The Missouri River Basin, Selena J. Werdon

Electronic Theses and Dissertations

Few sturgeon chub (Macrhybopsis gelida: Cyprinidae) have been collected in the last decade, therefore their status, habitat selection and morphology were investigated at 172 previous collection sites. Data on two ecologically similar species, Platygobio gracilis and Rhinichthys cataractae, were also collected. Macrhvbopsis gelida were collected at 28 sites on the Powder River (n = 158) in Wyoming and Montana, and at one site on the Yellowstone River (n = 1) in Montana. Age-I, Age-II and Age-III M. gelida were collected. Specimens were 37 to 95 mm in total length. Macrhvbopsis gelida were ripe in mid-June, at water temperatures of 18.3-22. …

A Proposal For United States/Polish Collaboration On Energy And The Environment, Carole B. Szpunar

Chemistry: Faculty Publications and Other Works

Argonne National Laboratory, a U.S. Department of Energy facility that is operated by the University of Chicago and located southwest of Chicago, Illinois, has proposed a collaborative effort by the United States and Poland to conduct applied research on energy and environmental topics of common interest. Through this collaboration, evaluative studies on energy and environmental assessment issues could be developed and implemented by Argonne and one or more sister institutions in Poland, which could lead to active research, development, and demonstration joint activities. The objective of this initiative is to produce strategies and options for review by Poland's decision makers …

Denitrification In The Elk Valley Aquifer, Northeastern North Dakota, Gale G. Mayer

Theses and Dissertations

Biological denitrification controls nitrate distribution in the Elk Valley aquifer, which underlies approximately 725 square kilometres of northeastern North Dakota and provides drinking water for farms and rural communities in the area. Increased irrigation has raised concerns over potential contamination from agricultural practices. The purpose of this study was to establish the role of biological denitrification in minimizing concentration and distribution of nitrate and to determine the effect irrigation practices have on groundwater flow and nitrate distribution in the saturated zone.

The aquifer is unconfined and consists of up to 20 metres of glacial outwash and deltaic shale-rich sand deposits. …

Winter 1992, Nsu Oceanographic Center

Currents

No abstract provided.

Impingement Of Organic-Rich, Contaminated Sediments On Manatee Pocket, Florida, John H. Trefry, Nai-Chi Chen, Robert P. Trocine, Simone Metz

Ocean Engineering and Marine Sciences Faculty Publications

Fine-grained, organic-rich sediments are adversely impacting portions of the coastal zone in Florida. One extreme example is found in Manatee Pocket, on the southeastern coast of Florida, where sediments with >4% organic carbon have an average thickness of about 1 m and a total volume of 340,000 m3 . These deposits formed as soil and organic matter were carried into Manatee Pocket and trapped during the past 100 years of regional development. Vertical profiles for Cd, Cu, Hg, Pb, and Zn show that contamination, at 5-10 times above natural levels, is restricted to the top 15-30% of the organic-rich layers …

The Origin Of Metalliferous Argillites In The Shoal Arm Formation Of North-Central Newfoundland, Volker Brüchert

Geology Theses and Dissertations

The Middle Ordovician Shoal Arm Formation, which is located in the central volcanic belt of north-central Newfoundland, is a tripartite assemblage of hematitic argillites, grey cherts, and black shales directly underlying a flysch sequence. The hematitic argillites are enriched in Fe, Mn, Ni, Pb, and Co. Factor analysis and principal component analysis indicate the presence of a hydrothermal component, presumably derived from hydrothermal activity in the coeval Lawrence Head volcanics. Unusual, (?) calcareous Mn-Fe-oxide nodules are present in the top parts of turbidites in the hematitic argillites. Electron microprobe analysis of a color transition from a red to a green …

Science On The Great Plains: The History Of Physics And Astronomy At The University Of Nebraska-Lincoln, M. Eugene Rudd

M. Eugene Rudd Publications

The year 1988 marked the 100th anniversary of the founding of the Department of Physics at the University of Nebraska. While the year passed without fanfare in the department, DuaneJaecks, one of the members of the faculty, suggested to the author that it would be a good time to write a history of what is now the Department of Physics and Astronomy. He not only provided the initial impetus for the project, but has also given it his continual help and encouragement. While the initial plan was to write only a brief, informal departmental history, the project, like Topsy, grew. …

A Implementation Plan For The Rainwater Basin Joint Venture, Richard A. Gersib, Kenneth F. Dinan, Jon D. Kauffeld, Michael D. Onnen, P. Joe Gabig, John E. Cornely, Gerald E. Jasmer, Joseph M. Hyland, Kenneth J. Strom

Nebraska Game and Parks Commission: White Papers, Conference Presentations, and Manuscripts

Nebraska's Rainwater Basin (RWB) wetland area is identified by the North American Waterfowl Management Plan (NAWMP) as a waterfowl habitat area of major concern in North America. The Rainwater Basin area is recognized as the focal point of a spring migration corridor used by millions of ducks and geese annually (Figure 1). This migration corridor is shaped like an hourglass, with the Rainwater Basin and Central Platte River located at the constriction.

Seasonal Phytoplankton Development Within Three Rivers In The Lower Chesapeake Bay Region, Harold G. Marshall, Lewis F. Affronti

Biological Sciences Faculty Publications

The seasonal and inter-annual concentrations of phytoplankton were studied over a 50 month period in the lower James, York and Rappahannock Rivers (USA). Differences in the onset, duration and magnitude of major seasonal growth periods varied from year to year. There was a tendency for spring, summer and fall maxima, with a winter period of reduced abundance. An additional study of picoplankton over a 12 month period indicated greatest abundance during summer and fall, with least development in winter.

Structure Of (22S)-3Β-Acetoxy-20-(3-Isopropylisoxazolin-5-Yl)-4,4,14 Α-Trimethylpregn-8(9)-Ene, Sergey V. Lindeman, Mikael S. Alexanyan, Yuri T. Struchkov, Rajesh Kumar Thaper, Irina G. Reshetova, Alexey V. Kamernitzky

Chemistry Faculty Research and Publications

C₃₂H₅₁NO₃, M_r = 497·7, orthorhombic, P2₁2₁2₁, a = 7·577 (2), b = 10·510 (2), c = 35·399 (7) Å, V = 2819 (1) ų, Z = 4, D_x = 1·173 g cm^-3, λ (Mo Kα) = 0·71073 Å, μ = 0·69 cm^-1, F(000) = 1096, T = 153 K, R = 0·0497 for 2235 observed reflections. The compound investigated is found to be a (22S)-epimer.

Nebraska Summary: S126 Massey Ferguson 3690, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data. EXPLANATION OF THE TEST PROCEDURES Purpose The purpose of …

Nebraska Summary: S165 Ford 8340 16x16, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data. EXPLANATION OF THE TEST PROCEDURES Purpose The purpose of …

Nebraska Summary: S164 Ford 8240 16x16, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data. EXPLANATION OF THE TEST PROCEDURES Purpose The purpose of …

Nebraska Summary: S161 Ford 6640 12x12, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data. EXPLANATION OF THE TEST PROCEDURES Purpose The purpose of …

Studies Of Ecological Factors That Affect The Population And Distribution Of The Western Gray Squirrel In Northcentral Oregon, Susan Ann Foster

Dissertations and Theses

The western gray squirrel (Sciurus griseus griseus Ord) occur only in the Pacific states and in a small corner of extreme western Nevada. Field studies of aspects of the ecology of the most widely distributed subspecies of western gray squirrel (S. griseus) were conducted at three sites in the ponderosa pine-Oregon white oak zone on the eastern slopes of Mt. Hood, Wasco County, Oregon, between 1981 and 1989. From 1981 through 1987, a Hunter Cooperation Program provided remains of squirrels shot during the annual late summer-early autumn hunting season. Other data were gathered through capture and release studies, radiotelemetry, and …

Adsorption Of Halogenated Phenolate Ions To Egg-Phosphatidylcholine Vesicles, Andreas Blochel

Dissertations and Theses

In this study, parameters for the adsorption of several halogenated phenolate ions to egg-phosphatidylcholine vesicles have been determined by microelectrophoresis.

New Reaction Conditions For The Synthesis Of Wieland-Miescher Ketone, Jonathan J. Bates

Presidential Scholars Theses (1990 – 2006)

Natural products chemistry is a very important field of chemistry to chemists, biochemists, and biologists. The ability to synthesize a naturally occurring chemical in the laboratory is necessary for some experiments. Often it is difficult to isolate a large quantity of a compound from its natural source when needed for certain experiments. Established procedures for artificial synthesis of this compound can produce higher yields. Sometimes, the function of a natural product is tested by observing the behavior of analogues in the same biological system. The differences in behavior can be related to differences in structure . Since such analogues are …

Desorption Hysteresis In Five Ion Exchanged Montmorillonites, Jerry Paul Fairley

UNLV Theses, Dissertations, Professional Papers, and Capstones

It is generally believed that the formation of recalcitrant (slowly desorbing) fractions of volatile organic compounds (VOCs) in soils is due to diffusion of compounds to sorption sites inaccessible to bulk fluid. The exact nature of these sites, however, is not well understood. In clay minerals, researchers favor two probable areas for the storage of persistent contamination; sites between the clay lamella, or sites with clay particle aggregates.

To test the hypothesis that recalcitrant fractions are formed in interlamellar spaces, a Na/Ca Montmorillonite (Smectite) was ion exchanged with five different cations (K⁺, Na⁺, Ca⁺, …

Zooplankton Community Abundance And Diversity In Dardanelle Reservoir, Arkansas, 1981-1990, John D. Rickett, Robert L. Watson

Journal of the Arkansas Academy of Science

Zooplankton samples were collected quarterly from five stations representing the discharge bay and four "control" or "dispersing impact" stations. Rotifers dominated all samples numerically and by the number of taxa. All major groups (Rotifera, Cladocera, Copepoda, and Protozoa) exhibited greatest abundances during the summer. Quarterly variations in abundance and number of taxa were documented. Except for an increase in taxonomic analysis detail between 1981 and 1984 resulting in several more taxa added to the list, no long-term increases, declines or repeating cycles were apparent. Margalef's Richness Index reflected this change and showed a long-term increase with evidence of a 5- …

Development Of A Variable Wavelength Flame Infrared Emission Gas Chromatography Detector, Weiqun Zhang, M. Keith Hudson, Mokhtar Mofidi

Journal of the Arkansas Academy of Science

No abstract provided.

River Channel Stability And The Implications For Fish Habitat, John T. Beebe

Theses and Dissertations (Comprehensive)

The purpose of this project was to investigate various aspects of river channel stability as they relate to fish habitat. Two headwater creeks of the Credit River system, Black and Silver Creeks, and their confluent stream, the West Credit River in Southern Ontario were used in the study. Thirty-five cross-sections were established and revisited during four flow regimes, summer base flow, fall secondary peak flow, spring melt-high flow and post-spring high flow. Measurements of width, depth and temperature were taken at these times. Water samples were taken for determination of suspended sediment concentration. Channel stability was investigated in relation to …

How Stubble Affects Organic Matter, Plants And Animals In The Soil, Judy Tisdall

Journal of the Department of Agriculture, Western Australia, Series 4

Cereal yields have not increased greatly in Australia over the past 30 years and they are still only about half the potential determined by rainfall. One of the reasons for these low yields is our fragile soils, worsened by traditional systems of tillage and the burning of stubble. These systems reduce the levels of organic matter and biological activity in soil

Using Physical, Chemical And Biological Indicators To Assess Water Quality On The Ouachita National Forest Utilizing Basin Area Stream Survey Methods, J. Alan Clingenpeel, Betty G. Cochran

Journal of the Arkansas Academy of Science

The Ouachita National Forest (ONF) has developed a series of Best Management Practices (BMP's) designed to protect water quality and associated beneficial uses (fisheries, municipal water supplies, etc.). A monitoring program is necessary to document the effectiveness of that protection. The Basin Area Stream Survey (BASS) methodology provides a monitoring link from BMP's to the aquatic ecosystems. The goal of BASS is to identify the physical, chemical and biological characteristics of a stream in a format that will allow comparisons with other streams, and indicate when a stream is being impacted. Six index streams within two ecoregions were selected and …

A Study Of The Summer Steelhead, Oncorhynchus Mykiss In Several Intermittent Tributaries Of The Satus Creek Basin, Washington, Joel Denney Hubble

All Master's Theses

The summer steelhead, Oncorhynchus mykiss population was studied in three intermittent tributaries in the Satus Creek Basin. There was a strong tendency for post emergent fry, resulting from redds located in intermittent reaches to move downstream. However, survival to perennial flow conditions was very low. Steelhead production in Dry Creek appears to be lower than in Logy Creek, because of elevated water temperatures and minimal spring and summer stream flow.