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Peripherally Restricted Opioid Conjugates And Its Use As Pharmacological Probes And Potential Therapeutics, Md Tariqul Haque Tuhin

University of the Pacific Theses and Dissertations

Opioid-induced constipation (OIC) is one of the major adverse effects of opioid analgesics used by millions of patients each year. While progress has been made, there remains a significant unmet medical need in the treatment of OIC. Major gaps remain in our understanding of the role of the gastrointestinal tract and central nervous system (CNS) in precipitating OIC. For the last four decades, numerous investigations to study the sites of action of opioid analgesics have utilized peripherally acting mu-opioid receptor antagonists (PAMORAs), which have been incorrectly believed to have limited penetration across the blood-brain barrier (BBB). Several preclinical and clinical …

The Synapse 33

The Synapse: Intercollegiate science magazine

No abstract provided.

การประเมินความเสี่ยงจากสภาพภูมิอากาศสำหรับพื้นที่เพาะปลูกข้าวและความพร้อมในการจัดการของหน่วยงานภาครัฐ: กรณีศึกษาเกาะลมบก ประเทศอินโดนีเซีย, ดอสมายา แอนเดรียอานี

Chulalongkorn University Theses and Dissertations (Chula ETD)

การเปลี่ยนแปลงสภาพภูมิอากาศนับเป็นประเด็นสำคัญที่ถูกอภิปรายว่าเป็นปัจจัยขับเคลื่อนต่อการเกิดอุบัติการณ์ภัยธรรมชาติ โดยการเปลี่ยนแปลงสภาพภูมิอากาศส่งผลกระทบต่อทุกมิติของชีวิตมนุษย์ โดยเฉพาะอย่างยิ่งในด้านความมั่นคงด้านอาหาร ทั้งนี้ พื้นที่เพาะปลูกข้าวนับเป็นพื้นที่ที่ถูกคุกคามมากที่สุดเนื่องจากการเปลี่ยนแปลงของปริมาณน้ำฝนและอุณหภูมิอันเนื่องมาจากการเปลี่ยนแปลงสภาพภูมิอากาศ บทบาทของรัฐบาลจึงมีความสำคัญในการลดความสูญเสียที่เกิดจากภัยธรรมชาติ โดยเฉพาะการยกระดับความสามารถในการปรับตัวของชุมชนท้องถิ่นต่อภัยธรรมชาติ วัตถุประสงค์ของการศึกษานี้คือการประเมินผลกระทบของภัยพิบัติจากการเปลี่ยนแปลงสภาพภูมิอากาศในพื้นที่เพาะปลูกข้าว และประเมินความพร้อมของรัฐบาลระดับท้องถิ่นในการรับมือกับการเปลี่ยนแปลงสภาพภูมิอากาศและอันตรายต่างๆ ที่เกี่ยวข้อง โดยคัดเลือก เกาะลมบก ของประเทศอินโดนีเซีย ซึ่งเป็นพื้นที่เกาะเล็กๆ และมีความเสี่ยงต่อการเปลี่ยนแปลงสภาพภูมิอากาศ ระเบียบวิธิวิจัยของการศึกษาครั้งนี้ ได้แก่ การประยุกต์ใช้กระบวนการลำดับชั้นเชิงวิเคราะห์ (Analytical Hierarchy Process: AHP) ร่วมกับระบบข้อมูลทางภูมิศาสตร์ (GIS) ในการประเมินความเสี่ยงที่เกิดจากการเปลี่ยนแปลงสภาพภูมิอากาศในพื้นที่เพาะปลูกข้าวทั้งจากผลกระทบจากอุทกภัย ภัยแล้ง และดินถล่ม ขณะเดียวกัน การศึกษานี้อาศัยการสัมภาษณ์ผู้เชี่ยวชาญ (n=15) เพื่อประเมินความพร้อมของรัฐบาลท้องถิ่นในการจัดการกับการเปลี่ยนแปลงสภาพภูมิอากาศ อาศัยการสัมภาษณ์ในประเด็นที่เกี่ยวข้องกับสถานการณ์ด้านการเพาะปลูก การจัดการภัยพิบัติ และการจัดการน้ำ โดยผลการวิจัยพบว่าพื้นที่ส่วนใหญ่ประมาณร้อยละ 88.18 ของเกาะลมบกมีความเสี่ยงด้านสภาพภูมิอากาศระดับปานกลาง และ พื้นที่เพาะปลูกข้าวเกือบทั้งหมดร้อยละ 96.56 มีความเสี่ยงด้านสภาพภูมิอากาศระดับปานกลางเช่นกัน ผลการสัมภาษณ์พบว่า ความพร้อมของรัฐบาลท้องถิ่นในการจัดการกับภัยอันตรายที่เกิดจากการเปลี่ยนแปลงสภาพภูมิอากาศมีอย่างจำกัด โดยเฉพาะประเด็นด้านงบประมาณและทรัพยากรบุคคล โดยผลการศึกษานี้จะเป็นประโยชน์สำหรับหน่วยงานท้องถิ่นในการดำเนินกิจกรรมการปรับตัวต่อการเปลี่ยนแปลงสภาพภูมิอากาศต่างๆ และเป็นกลยุทธ์ในการคาดการณ์ผลกระทบของการเปลี่ยนแปลงสภาพภูมิอากาศในพื้นที่เพาะปลูกข้าวของเกาะลมบก ประเทศอินโดนีเซียต่อไป.

Knowledge, Attitude And Practices On Potato Pest Management Of Ethnic Farmers In Southern Shan State, Myanmar, Pyae Pa Pa Aung

Chulalongkorn University Theses and Dissertations (Chula ETD)

Potato is cultivated as the main tuber crop which is essential for ethnic farmers’ household income in Southern Shan State, Myanmar. Most ethnic farmers use chemical pesticides widely to enhance crop yield and to control pests in the farm. The use of chemical pesticides could lead to a series of health impacts of the farmers and environmental issues. The main aim of the study is to explore farmers’ knowledge, attitude and current farm practices on pest management in potato production. The participants of 100 farmers were chosen from each village with a cluster and purposive sampling technique using structured questionnaires …

Lead Removal From Water By Modified Activated Carbon Produced From Banana Stem, Imelda Octa Tampubolon

Chulalongkorn University Theses and Dissertations (Chula ETD)

Banana stem-activated carbon (BSAC) and modified banana stem-activated carbon, containing sulfur, nitrogen, and oxygen-containing groups derived from banana stem, were prepared and studied for Pb(II) ion removal. The materials were characterized by scanning electron microscopy, X-Ray diffraction, surface area analysis, and Fourier transform infrared spectroscopy. SEM images showed that the materials are porous, and XRD confirmed that the structures are amorphous and resemble the graphitic hexagonal structure of carbon materials. Surface areas of these materials ranged from 517.67 m2/g for the bare banana stem activated carbon to 234.03, 453.74, 252.97, and 22.96 m2/g for sulfur, oxygen, sulfur and oxygen and …

Life Cycle Assessment Of Canned Fish Production In Thailand, Chanya Kraiwed

Chulalongkorn University Theses and Dissertations (Chula ETD)

The canned fish industry is one of the world's most popular exports in Thailand. Moreover, the canned seafood industry ranks fourth in terms of energy consumption, which compares to all industry group (Wiriyatangsakul, 2021). Commercial competitiveness, on the other hand, must be improved because of the competitive conditions in the global market. Thus, this study evaluates the environmental performance of a factory in Samut Sakhon, Thailand, using Life Cycle Assessment (LCA) with Gate-to-Gate approach and setting functional unit by 1 ton fresh fish entering to process. The study used the SimaPro LCA application with the CML 2 baseline 2000 method, …

Assessment Of Greenhouse Gases Emissions From Dairy Cattle Production In Thailand, Phoo Pwint Pwint Thu

Chulalongkorn University Theses and Dissertations (Chula ETD)

Thailand’s agriculture sector plays a vital role in driving economic growth. Globally, livestock production is estimated to contribute about 18% of greenhouse gas (GHG) emissions. Despite its importance, there is a relative lack of research on GHGs assessment in the livestock sector in Thailand. The aim of this research was to estimate GHGs emissions from dairy cattle production in Saraburi and Ratchaburi provinces of Thailand. The 2019 Refinement to the 2006 IPCC guidelines for national greenhouse gas inventories was applied in this research. Twenty dairy farms (n=20) including both small farms (n=10) and medium farms (n=10) were selected as the …

Performance Of Black Soldier Fly Frass Fertiliser On Maize (Zea Mays L.) Growth, Yield, Nutritional Quality, And Economic Returns, C. M. Tanga, D. Beesigamukama, M. Kassie, P. J. Egonyu, Changeh J. Ghemoh, Kiatoko Nkoba, S. Subramanian, A. O. Anyega, S. Ekesi

All Peer-Reviewed Publications

Although the black soldier fly frass fertiliser (BSFFF) is globally recognised as a promising and potential high-quality organic fertiliser, there is inadequate information on its impact on the growth performance and nutritional status of maize. Furthermore, no information exist on their combination with mineral fertiliser (NPK) as well as economic impact on maize production. This study evaluated the comparative impact of BSFFF, NPK and commercial organic fertiliser (Evergrow®) on growth, nitrogen use efficiency, yield, nutritional quality, and profitability of maize under greenhouse conditions. The treatments included: (1) sole application of BSFFF, conventional compost of brewers’ spent grain (BSG), Evergrow, and …

Carnivore And Ungulate Responses To Cattle In A Grazed Forest Ecosystem, Rebecca Carniello

Cal Poly Humboldt theses and projects

Habitat disturbance, a leading threat to biological diversity, comes in many forms and can alter the behavior of wildlife and reduce the amount of suitable habitat. Livestock grazing, a form of habitat disturbance, is the most widespread influence on native ecosystems of western North America. Research on the impacts of introduced domestic herbivores on wild carnivores and ungulates varies, and the degree to which wildlife species are affected is often species-specific. I used remote trail cameras to compare the activity patterns of black bears (Ursus americanus), coyotes (Canis latrans), bobcats (Lynx rufus), mountain lions …

Safety, Regulatory And Environmental Issues Related To Breeding And International Trade Of Edible Insects In Africa, S. Niassy, E. R. Omuse, N. Roos, A. Halloran, J. Eilenberg, J. P. Egonyu, C. Tanga, F. Meutchieye, R. Mwangi, S. Subramanian, R. Musundire, P. O.Y. Nkunika, J. P. Anankware, J. Kinyuru, A. Yusuf, S. Ekesi

All Peer-Reviewed Publications

Insect breeding or farming for food and feed is an emerging enterprise that can address the ever-growing demand for protein and curb high unemployment rates in Africa and beyond. However, for the sector to prosper, its value chain needs to be regulated to ensure sustainability and safety for consumers and the environment. Although a few African countries, such as Kenya, Uganda and Rwanda, have promulgated standards on the use of insects as food and feed, greater efforts are needed in other countries, and relevant policies governing the sector need to be formulated. All over the globe, attention to the regulation …

Disentangling The Complex Evolutionary History Of Invasive Russian Thistle: Phylogenetic Relationships, The Role Of Hybridization, And Public Engagement, Deva Raj Khanal

Electronic Theses and Dissertations

Invasive species are forces of environmental, economic, and social change with detrimental impacts on ecosystems, commerce, agriculture, and human health. However, we still have a poor understanding of the processes that could be driving invasive potential. Hybridization may contribute to the establishment and spread of invasive lineages, as it may enhance genetic variation and facilitate rapid adaptation. Focusing on Russian thistle (Salsola tragus s.l., family Amaranthaceae) and closely related species, my thesis aims to clarify phylogenetic relationships and investigate how hybridization has shaped the invasion dynamics of these lineages. Known as one of the fastest plant invasions in the United …

A Post-Pneumonia Epizootic Evaluation Of The Rapid City, South Dakota Bighorn Sheep Herd, Amanda N. Ensrud

Electronic Theses and Dissertations

Pneumonia is a major factor affecting populations of free-ranging bighorn sheep (Ovis canadensis) across western North America. Pneumonia can occur in large-scale epizootics, during which greater than half of the population typically dies. After these epizootics, surviving ewes continue to conceive and bear lambs. However, lamb recruitment may remain low due to periodic or annual pneumonia outbreaks causing high lamb mortality rates, sometimes greater than 90%. Our study focused on the Rapid City, South Dakota bighorn sheep (BHS) herd that has recorded pneumonia-induced population decline since 2009. The first objective was to improve lamb health and survival by identifying and …

Post-Fledging Habitat Selection And Movements Of Juvenile Mallards In The Prairie Pothole Region, Cynthia E. Anchor

Electronic Theses and Dissertations

The Prairie Pothole Region (PPR) of North America provides critical habitat for waterfowl across life stages, but anthropogenic changes to the landscape have negatively impacted habitat quality for waterfowl. The mallard (Anas platyrhynchos) is abundant and socioeconomically valuable in the PPR, as it is a preferred target species of waterfowl hunters. Extensive research has evaluated breeding ecology of mallards in the PPR, but the period between juvenile mallards fledging and migrating has rarely been studied. The post-fledging ecology of juvenile mallards is a vital consideration for comprehensive waterfowl management. Further, juvenile mallards are a significant portion of hunter harvest at …

The Times, They Are A-Changin': Tracking Shifts In Mental Health Signals From Early Phase To Later Phase Of The Covid-19 Pandemic In Australia, Siqin Wang, Xiao Huang, Tao Hu, Mengxi Zhang, Zhenlong Li, Huan Ning, Jonathan Corcoran, Asaduzzaman Khan, Yan Liu, Jiajia Zhang, Xiaoming Li

Geosciences Faculty Publications and Presentations

Introduction Widespread problems of psychological distress have been observed in many countries following the outbreak of COVID-19, including Australia. What is lacking from current scholarship is a national-scale assessment that tracks the shifts in mental health during the pandemic timeline and across geographic contexts.

Methods Drawing on 244 406 geotagged tweets in Australia from 1 January 2020 to 31 May 2021, we employed machine learning and spatial mapping techniques to classify, measure and map changes in the Australian public’s mental health signals, and track their change across the different phases of the pandemic in eight Australian capital cities.

Results Australians’ …

First Determination Of Anticancer, Cytotoxic, And In Silico Adme Evaluation Of Secondarymetabolites Of Endemic Astragalus Leucothrix Freyn & Bornm, Ayşe Şahi̇n Yağlioğlu, Duygu Güneş Gürbüz, Melda Dölarslan, İbrahi̇m Demi̇rtaş

Turkish Journal of Chemistry

Isolation and characterization of anticancer activity guided secondary metabolites of endemic Astragalus leucothrix Freyn& Bornm were aimed. Aerial parts of the plant were extracted by maceration method in the solvent system methanol-chloroform (1 : 1) at room temperature. The obtained crude extract was dissolved in purified water. Then, the extract was partitioned with n-hexane, chloroform, ethyl acetate, and n-butanol, respectively. Anticancer activity tests of all the fractions were performed against HeLa and C6 cancer cells. The chloroform fraction that has highest anticancer activity was subjected to chromatographic methods such as column chromatography and thin layer chromatography. Pentyl tetratetracontanoate (1), alfalone …

Supramolecular Solvent-Based Microextraction For The Preconcentration Of Pb2+ Andcd2+ Prior To Spectrophotometric Detection, Huma Zafar, Faheem Shah, Rafaqat Ali Khan, Asad Muhammad Khan, Jan Nisar, Bushra Ismail

Turkish Journal of Chemistry

Supramolecular solvent-based dispersive liquid-liquid microextraction technique has been developed as a preconcentration tool for the determination of trace level of Pb2+ and Cd2+. Dodecanol dispersed in tetrahydrofuran has been utilized as a supramolecular-solvent system for the extraction of analytes prior to their quantitative determination with graphite furnace atomic absorption spectrophotometer. Both Pb2+ and Cd2+, which were efficiently extracted by supramolecular solvent system, were complexed with dithizone followed by the addition of supramolecular solvent. The experimental variables that could possibly influence the extraction efficiency, i.e. pH value, temperature, sample volume, centrifugation time, rate of centrifugation, ionic strength, etc. were subjected to …

Chromatographic Evaluation Of Tocols And Sterols Of Processed Canola Oil And Deodorizerdistillate, Hadia Shoaib, S. Tufail Sherazi, Saba Naz, Dr Sarfaraz Ahmed Mahesar, Abdul Rauf Khaskheli, Siraj Uddin, Ahmed Raza Sidhu, Hami̇de Fi̇li̇z Ayyildiz, Hüseyi̇n Kara, Mustafa Topkafa

Turkish Journal of Chemistry

Tocopherols and tocotrienols in the combined form are known as tocols. Changes of total and individual tocols and sterols concentration of canola oil and deodorizer distillate (DD) during different processing stages were evaluated with the application of gas chromatography (GC) and high-performance liquid chromatography (HPLC). For sterols analysis, GC coupled with flame ionization detector (FID) was used while tocols in canola oil samples and DD, normal phase (NP) HPLC was applied. The results of the present study indicated that levels of total and individual tocols and sterols content were decreased during processing (neutralization to deodorization). Deodorization was found to be …

A Simple And Rapid Rp-Hplc Method For The Assessment Of Cobalamin (Vitamin B12) Intilapia And Snoek Fishes, Labaran Ibrahim, Aminu Usman

Turkish Journal of Chemistry

This study developed a rapid reversed-phase high-performance liquid chromatography (RP-HPLC) method equipped with a UV-Vis detector. The aquaponics system?s tilapia and marine snoek fishes were extracted using an autoclaving process and enzymatic treatment. The technique enabled the separation and quantification of cobalamin present in these fishes extracts. Phenomenex Luna® 5 μm C18 (2) 100 A LC-column (150 × 4.6 mm) was used as a stationary phase, while the mobile phase consisted of methanol and phosphoric acid in a ratio of 35:65 (v/v), respectively. The developed method was revealed to be rapid (a retention time of less than 5.0 min), linear …

Synthesis Of Some New Isoxazole Compounds And Their Biological Tyrosinase And Antioxidant Activities, Seda Fandakli

Turkish Journal of Chemistry

In this study, 7 new isoxazole compounds (8-14) were synthesized from the cyclization of chalcone compounds (1-7) containing different functional groups with hydroxylamine hydrochloride in alkaline medium. Tyrosinase and antioxidant properties of 8-14 were investigated. IC50 values for the tyrosinase enzyme inhibition of compounds 8, 11, 12, and 13 were varied between 61.47 ± 3.46 and 188.52 ± 5.85, while compounds 9, 10 and 14 did not show any inhibition effect. The antioxidant properties of 8-14 were investigated by DPPH and CUPRAC methods. Compound 12 showed the best DPPH radical scavenging activity (SC50: 40.21 ± 2.71), while 12 and 13 …

Induction Of Lutein Production In Scenedesmus Obliquusunder Different Culture Conditions Prior To Its Semipreparative Isolation, Ayşegül Erdoğan, Ayça Büşra Karataş, Zeli̇ha Demi̇rel, Meltem Dalay

Turkish Journal of Chemistry

Microalgae with their improved growth rates and accumulation of high-value-added products make their commercial production attractive. Among them, lutein, which is a carotenoid, plays a very important role due to its various applications in the food and pharmaceutical industry. Induction of its biosynthesis can be triggered by various stress conditions like light. In this study, three different light intensities (50,150 and 300 μmol photons/m2s) and aeration rates (1, 3, and 5 L/min) were utilized to induce the lutein biosynthesis and biomass productivity in Scenedesmus obliquus. Lutein was isolated by preparative chromatography using a semiprep C30 column (10 × 250 mm, …

Peg4000 Modified Liposomes Enhance The Solubility Of Quercetin And Improve The Liposome Functionality: In Vitro Characterization And The Cellular Efficacy, Gülen Meli̇ke Demi̇rbolat, Ömer Erdoğan, Gökni̇l Peli̇n Coşkun, Özge Çevi̇k

Turkish Journal of Chemistry

Quercetin, a multifunctional therapeutic agent, is used in various types of cancer. However, its therapeutic effect is limited by virtue of poorly aqueous solubility and instability in the physiological medium. To overcome these limitations, we aimed (i) to design quercetin loaded liposomes with unlinked-PEG4000 with regard to not only surface modification but also solubility enhancement, and (ii) to investigate the antineoplastic effects on HeLa cells. PEG4000 increased the quercetin solubility 2.2 fold. PEG4000 modified liposomes displayed small particle size (254 ± 69 nm), low polydispersity index (0.236 ± 0.018), favorable zeta potential (-35.4 ± 0.6 mV), high quercetin encapsulation efficiency …

Fabrication Of Electrospun Cellulose-Derived Nanofiber Membranes With Enhanced Stability Properties Of Arginase, Ceyhun Işik, Mustafa Teke

Turkish Journal of Chemistry

In this study, cellulose acetate (CA)/polyvinylpyrrolidone (PVP) and CA/PVP/Mn2+ nanofibers were produced by the electrospinning method, and these cellulose-derived membranes were used as carriers for arginase immobilization for the first time. The structural and morphological analysis of these cellulose-derived nanofibers were determined by attenuated total reflection-Fourier to transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), X-ray diffraction (XRD), and scanning electron microscopy (SEM). After the immobilization process, it was observed that the thermal properties of the cellulose-derived nanofibers especially improved. The optimum temperature value for free arginase was found to be 35 °C, and this value was found to be 40 …

Comprehensive Evaluation Of Reseda Lutea L. (Wild Mignonette) And 7 Isolated Flavonol Glycosides: Determination Of Antioxidant Activity, Anti-Alzheimer, Antidiabetic And Cytotoxic Effects With In Vitro And In Silico Methods, Hati̇ce Kiziltaş

Turkish Journal of Chemistry

In this study, anticholinergic, antidiabetic, antioxidant and cytotoxic activities of Reseda lutea L. (R. lutea) were determined. Ethanol extracts of R. lutea (EERL) and water extract of R. lutea (WERL) were prepared for biochemical analysis. The antioxidant capacities of EERL and WERL were evaluated with 6 different methods. In addition, acetylcholinesterase (AChE), α-amylase and α-glycosidase enzyme inhibition by EERL were measured. According to the results, EERL exhibited high inhibition effects against α-amylase, α-glycosidase and AChE enzymes. The IC50 values of EERL against AChE (2.21 μg/mL), α-glycosidase (1.38 μg/mL), and α-amylase (0.11 μg/mL) were determined. Also, high cytotoxic effect of EERL …

A Simple Quantitative Method Using Tlc-Image Analysis To Determine Fructooligosaccharides (Fos) In Food Samples, Diana Beatriz Muñiz Márquez, Marco Antonio Mártinez Cervantes, Alain Martinez, Cristobal Aguilar, Pedro Agui̇lar Zarate, Jorge Enrique Wong Paz

Turkish Journal of Chemistry

The thin-layer chromatography technique (TLC) is a simple and inexpensive analysis commonly used to identify qualitatively the presence of carbohydrates in food samples such as mono- di and oligosaccharides particularly. TLC assay could be improved using image processing software for the semiquantitative determination of this type of compound. In the present work, TLC-image analysis with Silica Gel 60 TLC plates was used for the semiquantitative determination of 6 standards of carbohydrates (glucose, fructose, sucrose, 1-kestose, nystose, and fructofuranosylnystose). Subsequently, the areas of the spots of each compound were determined by digitizing in a conventional office scanner. Then, the segmentation of …

Determination Of Triacylglycerol And Fatty Acid Compositions Of Impatiens Seed Oils Using Reverse Phase High Performance Liquid Chromatography, Anh Van Nguyen, Anh Thi Ngoc Vu, Victor Ivanovic Deineka, Huy-Trung-Kien Nguyen

Turkish Journal of Chemistry

In the present work, triacylglycerol and fatty acid compositions of Impatiens balsamina L. and Impatiens walleriana Hook.f. seed oils were determined using reverse phase high performance liquid chromatography with both refractive index and spectrophotometric detections. The presence of conjugated octadecatetraenoic moieties was confirmed by UV and IR spectroscopy. Triacylglycerol (TAG) compositions were performed using an incremental approach and confirmed by the results of MS and electronic spectra. The quantitative analysis of TAG was achieved by careful calibration, introducing correction factors for the sensitivity of each compound. The results showed that both Impatiens seed oils contain the same 23 TAGs. The …

Photocatalytic Degradation Of Aquatic Organic Pollutants With Zn- And Zr-Based Metalorganic Frameworks: Zif-8 And Uio-66, Fatma Defne Çalik, Bi̇lgesu Erdoğan, Esra Yilmaz, Gi̇zem Saygi, Seher Fehi̇me Çakicioğlu Özkan

Turkish Journal of Chemistry

Water treatment has been an essential issue with the increasing population over 40 years. Researchers center on the major organic pollutants, such as dyes, pesticides, and pharmaceutical products. Photocatalytic degradation is one of the promising methods for aquatic organic pollutant treatment. Over the years, scientists have been working on developments for photocatalysts to enhance their pollutant degradation performances. From the reviewed studies, it is seen that properties like surface area, chemical, mechanical, and thermal stability, and uniform distribution of active sites are crucial, and an increase in these properties provides better degradation efficiency. In this sense, metal-organic frameworks as photocatalysts …

Synthesis And Antioxidant Activities Of Benzylic Bromophenols Inclusive Of Natural Products, Çeti̇n Bayrak, Eda Mehtap Üç, Mohsen Rezaei, İlhami̇ Gülçi̇n, Abdullah Menzek

Turkish Journal of Chemistry

The synthesis of natural products 2-(2,3-dibromo-4,5-dihydroxyphenyl)acetic acid (1) and 2-(2,6-dibromo-3,5-dihydroxyphenyl)acetic acid (2) and as well as their derivatives 25 and 26 were carried out by substitution, hydrolysis and demethylation reactions of the corresponding four benzyl bromides. The antioxidant potentials of benzylic acid-derived bromophenols were, for the first time, appraised by several outstanding bioanalytical methods. Besides these, we estimated the antioxidant effects which were studied using the methods of DPPH·, ABTS^·+ scavenging activities, ferric (Fe³⁺) and cupric (Cu²⁺) ions and Fe³⁺-TPTZ reducing capacities. Benzylic acid-derived bromophenols were found as effective DPPH^·, and …

Chromatographic Profile Of Major Whey Proteins In Some Dairy Beverages Based On Milk Serum, Doina Prodan, Miuta Filip, Mihaela Vlassa, Marioara Moldovan, Rahela Carpa

Turkish Journal of Chemistry

The aim of this study was the determination of chromatographic profiles of major whey proteins (WP): α-lactalbumin (α-La), β-lactoglobulin A and B, (β-Lg A and B), bovine serum albumin (BSA) in dairy beverages based on Zonar milk serum. The studied WP were separated by high-performance liquid chromatography (HPLC) on Aeris XB-C18 column using gradient elution with 0.1% trifluoroacetic acid (TFA) in water and 0.1% TFA in 80% acetonitrile, at 214 nm detection. The HPLC method was validated for system suitability, selectivity/specificity, linearity (R² ≥ 0.996), precision (RSD% ≤ 2.01), trueness (recovery 96.29%-102.08%), sensitivity (limits of quantification (LOQ) 1.35-10.08 μg/mL), …

Biofilm Harvesters In Coastal Settings Of The Early Palaeozoic, Nora Noffke, M. Gabriela Mángano, Luis A. Buatois

OES Faculty Publications

The ichnogenera Syringomorpha and Daedalus are here interpreted as products of infaunal biofilm harvesters. This study investigated: (1) Syringomorpha nilssoni and Syringomorpha isp. from the Cambrian Series 2‐Miaolingian Campanario Formation, northwest Argentina; and (2) Daedalus halli from the Floian Grès et Schistes de la Cluse de l’Orb Formation, Montagne Noire, France. Syringomorpha nilssoni occurs in sandy to mixed intertidal to lower shoreface deposits, whereas Syringomorpha isp. in the lower intertidal zone. Daedalus halli occurs in a lagoon and intertidal to lower shoreface sands of a barrier island. Syringomorpha and Daedalus comprise a vertical J‐shaped causative burrow and deep spreite. These …

Bio-Go-Ship: The Time Is Right To Establish Global Repeat Sections Of Ocean Biology, Sophie Clayton, Harriet Alexander, Jason R. Graff, Nicole J. Poulton, Luke R. Thompson, Heather Benway, Emmanuel Boss, Adam Martiny

OES Faculty Publications

In this article, we present Bio-GO-SHIP, a new ocean observing program that will incorporate sustained and consistent global biological ocean observations into the Global Ocean Ship-based Hydrographic Investigations Program (GO-SHIP). The goal of Bio-GO-SHIP is to produce systematic and consistent biological observations during global ocean repeat hydrographic surveys, with a particular focus on the planktonic ecosystem. Ocean plankton are an essential component of the earth climate system, form the base of the oceanic food web and thereby play an important role in influencing food security and contributing to the Blue Economy. Despite its importance, ocean biology is largely under-sampled in …