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The Synthesis And Characterization Of Some Thermally Stable Polypyrazoles And Acetylene Terminated Aspartimides, John W. Connell

Theses and Dissertations

Reactions involving the nucleophilic addition cyclization to activated acetylenes have been employed as a novel route to moderate to high molecular weight polymers. Polypyrazoles (PI to P12) have been prepared from the Michael-type addition cyclization of various aromatic dihydrazines to aromatic dipropynones in m-cresol. The aromatic dihydrazines employed were 4, 4'-dihydrazinodiphenyl ether (4,4' -DHDPE), 4,4 '-dihydrazinodiphenylmethane (4, 4'-DHDPM), and 4, 4' -dihydrazinodiphenyl sulfone (4,4'-DHDPS). The dipropynone sutilized were 1,1’- (1,4-phenylene) bis (3-phenyl- 2-propyn-l-one), (l,4 -PPPO), 1,1’ - (1, 3-phenylene) bis (3 -phenyl- 2 -propyn-l-one), (1,3-PPPO), 1,1 '-(1,4 -phenylene) bis (2 -propyn- l-one), (1,4 -PPO), and 1,1’- (1,3 -phenylene) bis (2 …

Earth Observing System, Volume Iia: Data And Information System, Report Of The Eos Data Panel, Raymond Arvidson, Frederick Billingsley, Robert Chase, Pat Chavez Jr., Michael Devirian, Frederick Mosher, Et Al.

Publications

The purpose of this report is to provide NASA with a rationale and recommendations for planning, implementing, and operating an Earth Observing System data and information system that can evolve to meet the Earth Observing System's needs in the 1990s. The Earth Observing System (EOS), defined by the EOS Science and Mission Requirements Working Group, consists of a suite of instruments in low Earth orbit acquiring measurements of the Earth's atmosphere, surface, and interior; an information system to support scientific research; and a vigorous program of scientific research, stressing study of global-scale processes that shape and influence the Earth as …

A Geographer's Response To The 1982 Nuclear Waste Policy Act, Robert Bixby

Journal of the Minnesota Academy of Science

No abstract provided.

Ion Selective Electrodes Based On Aza- Substituted Crown Ethers, Lisa Ann Wellington

Retrospective Theses and Dissertations

A cation-responsive electrode system has been developed which incorporates aza-substituted crown ethers as ligands. In a novel application, uncomplexed crown ethers were used in the pelletized form for ionic transport. Electrodes have been produced which can be conditioned for a particular ion and following their use, be reconditioned and reused for other ions. Preparation method and lifetime studies are included.

The responses of two crown ethers with plasticizers were evaluated for thirteen representative cations. The concentration range covered in each evaluation was 1 x 10^-1 to 1 x 10^-7 M. For those ions exhibiting Nernstian or near-Nernstian response, …

Electrochemistry Of Dihalogenated Nicotonic Acids In Aqueous And Aprotic Media, Ali U. Shaikh, Tappi A. Dixon, Lourie A. Battles, Frank L. Setliff

Journal of the Arkansas Academy of Science

The electrochemical reduction of several 2,5- and 5,6- dihalonicotinic acids have been studied in dimethyl sulfoxide as well as in aqueous buffers of different pH. The polarographic half-wave potentials for the reduction of these compounds in both media are reported here. The compounds appear to reduce at the carboxyl group. The presence of halogen atoms on the pyridine ring facilitates reduction.

Summary Of Rhizobium Experiments., J. G. Howieson

Experimental Summaries - Plant Research

Rotation trials, 84ME32, 84ME24, 84N18, 84M18, 85KA58. Cross row trials, 85M28. One year trials, 86M41, 86M42. On-going trials, 86M58, 85KA64, 86V3, 86AL. 84WH24.

Electrochemical Investigation Of The Effects Of Temperature, Ph, And Electrolyte On The Electron Transfer Reactions Of Cytochrome C, Kent Brian Koller

Theses and Dissertations

Spectroelectrochemical and electrochemical methods have been used to investigate the characteristics of heterogeneous electron transfer between cytochrome c and indium oxide electrodes. Direct electron transfer between cytochrome c and solid electrodes is of interest due to the interfacial character of electron transfer between the protein and its membrane-bound physiological redox partners. The conformation of ferricytochrome c is affected more by changes in temperature or pH than is its reduced form, ferrocytochrome c. This difference in conformational stability is attributed to the +1 charge of the heme in ferricytochrome c that is largely embedded in the hydrophobic interior of the enzyme. …

Biological Effects Of Heavy Ions From The Standpoint Of Target Theory, Robert Katz

Robert Katz Publications

The biological effect of heavy ions is best described through the action cross section, as a function of the end-point of interest and the charge and speed of the ion. In track theory this is called the “ion-kill" cross section, for it is the effect produced by a single heavy ion and its delta rays. As with nuclear emulsions the biological track structure passes from the grain count regime to the track width regime to the thindown region with an increase in LET. With biological cells, as with any detector capable of storing sub-lethal damage, with low LET irradiation the …

Characterization Of The Capsular Polysaccharides On Cell Membranes Of Rhizobium Trifolii And Three Of Its Nod- Mutants, Jesse Ardosa

Masters Theses

The ever-present specter of the inavailability of food production to increase in direct proportion to population growth haunts practically every nation of the world. As more and more tracts of land are incorporated to accommodate expanding cities, they become less available for food production. Emphasis, therefore, is placed on obtaining a higher yield per acreage planted. Since fertilization is not reliable in the long term due to an eventual depletion of raw materials for fertilizers, the ability of plants like legumes to assimilate free soil nitrogen on their own has become increasingly important [1,11,14,17]. However, the mechanisms involved are still …

Isolation And Partial Analysis Of Proteins And Polysaccharides Of Rhizobium Trifolii, Manuelito M. Ordonez

Masters Theses

The outer membrane and periplasmic proteins of Rhizobium trifolii ANU 843 and its mutants ANU 851 and ANU 845(pRt150) were isolated and analyzed by polyacrylamide gel electrophoresis (PAGE). ANU 843 is the wild type strain which possesses all the characteristics necessary for nitrogen fixation. ANU 851 has a transposon (Tn5) inserted into the nodD gene of the root hair curling region of the symbiotic plasmid. It has lost its ability to cause root hair curling and therefore can not form nodules and can not fix nitrogen. ANU 845(pRt150) harbors only the 5.5 kb root hair curling region of the …

Analysis Of The Charleston, Illinois Water Supply For The Presence Of Organic Mutagens Utilizing The Ames Salmonella/Microsome Assay, Steven Lee Washburn

Masters Theses

Water samples from the Charleston, Illinois water supply and selected agricultural run-off areas were tested for the presence of organic mutagenic chemicals. The Ames Salmonella/microsome mutagenicity assay utilizing strains TA98 and TA100 was used to analyze concentrated water samples. A special set of samples was exposed to the S9 activation system coupled with the TA98 strain to simulate the mammalian metabolic system.

No mutagens were detected in any of the samples tested. Several positive and negative control systems were included in the testing system. Negative control systems were used to determine the average spontaneous reversion rates for each strain for …

Water Quality Management Studies For Water Resources Development In The Bear River Basin, Darwin L. Sorensen, Craig Caupp, William J. Grenney, Steve Eberl, Jay J. Messer, Phillip Ludvigsen, Charles W. Ariss

Reports

Summary: The quality of water that develops in the proposed reservoirs of the Upper Bear River Storage Project will determine the possible uses of the water. Previous studies of water quality in the Bear River and its tributaries have reported water quality problems relating to nitrate ion, sanitary indicator bacteria, suspended solids, and phosphorus concentrations. Most point sources of water pollution inthe basin have been eliminated or improved in quality, but nonpoint sources of pollution continue to degrade the quality of the Bear River. Concentrations of phosphours have been sufficiently high to encourage dense algal growth and create eutrophic conditions …

Utah Water Research Laboratory, Utah Center For Water Resources Research, A Program Overview, L. Douglas James, Donna H. Falkenborg

Reports

Organization of Prepared Material: This overview presents the water resources research program administered through the Utah Water Research Laboratory and the Utah Center for Water Resources Reserach. The document is prepared for an internal review by a faculty team organized by the Administration of Utah State university and an external review by a team organized by the U.S. Geological Survey as part of a national effort to evaluate the water research centers in every state over a 2-year period. These materials are prepared to stimulate discussion and spark innocative ideas for building an even stronger program. The UWRL/UCWRR administration sees …

Appendices: Water Quality Management In Utah Mountain Watersheds, Keith R. Kimball, E. Joe Middlebrooks

Reports

No abstract provided.

Evaluation Of Volatilization Of Hazardous Constituents At Hazardous Waste Land Treatment Sites, R. Ryan Dupont, J. A. Reineman

Reports

The magnitude and extent of volatile organic emissions from hazardous waste land treatment systems were evaluated in laboratory and field studies using complex petroleum refining hazardous wastes. Laboratory experiments were conducted using two soils and a intert construction sand to investigate the emission flux rates of seven volatile constituents, i.e., benzene, toluene, ethylbenzene, p-, m-, o-xylene, and naphthalene, from API Separatory Sludge and Slop Oil Emulsion Solids wastes in column and flask laboratory units as a function of waste application rate, application method (surface versus subsurface), soil type and soil physical characteristics. Field experiemtns were conducted at an active petroleum …

Race, Sex And Occlusive Cerebrovascular Disease: A Review, L. R. Caplan, P. B. Gorelick, D. B. Hier

Chemistry Faculty Research & Creative Works

No abstract provided.

Amphiphilic Association Structures And Some Aspects Of Foam Stability, Jia-Hwa Fang

Doctoral Dissertations

"This investigation was performed in order to study two interesting and important problems in foams.

Foam separation was studied in the model system of water - sodium octylsulfonate - decanol. The efficiency of foam separation as a function of surfactant concentration and decanol content were measured. The results were related to the association structures of amphiphiles in aqueous systems.

Foam polymerization was conducted in the amphiphilic system containing water, polymerizable surfactant and oleyl alcohol. Liquid foams were produced in one three - phase region. The location and optical pattern of liquid crystals on the foam surface were observed by photomicroscope …

A Study Of Electron-Ion And Ion-Ion Recombination In Atmospheric Gas Discharges, Michael Corbin Cornell

Doctoral Dissertations

"In separate experiments, the electron-ion recombination rate, Y_ei, has been measured in CO₂ and in mixtures of He, CO₂, and N₂; and the ion-ion recombination rate, Y_ii, has been measured in SF6 and in mixtures of SF₆ and CH₄. The rate constant was determined by analyzing the rising edge of the discharge current pulse. Measurements were made as functions of reduced electric field strength, gas pressure, and gas composition.

In the electron-ion recombination study, Y_ei in CO₂ and in mixtures containing N₂ and CO_{2 …}

1986-1987 Nova College The Center For Undergraduate Studies Catalog, Nova Southeastern University

Undergraduate Programs Course Catalogs

No abstract provided.

The Effects Of Fly Ash And Flue-Gas Desulfurization Wastes On Groundwater Quality In A Reclaimed Lignite Strip Mine Disposal Site, Frank W. Beaver

Theses and Dissertations

Coal conversion wastes were generated at a lignite-coal-fired, steam-electric power station near Center, North Dakota, and were buried in unsaturated and saturated settings within the nearby stripmine, typical of settings used by the industry. The study ran for 8 years beginning in 1978. Approximately 240 piezometers were used for collecting groundwater level and groundwater chemistry data in the saturated zone. Pressure-vacuum lysimeters were installed to sample the unsaturated zone. Interstitial water was extracted from Shelby tube and auger samples at otherwise uninstrumented points.

More than 15,000 water-level recordings allowed precise definition of groundwater flow and occurrence at the study site. …

Tutorials For Software : A Comparison Of The Appleworks Software Tutorial With Pre-Entered Data And An Experimental Tutorial With User Entered Data, Toni L. Steil

University of the Pacific Theses and Dissertations

The attention directed toward computer software research has been sparse which is quite evident in particular facets such as learning methods, specifically towards tutorials. Some authors have identified various important issues which include cognitive factors, reduction of presentation of superfluous information, and the importance of interaction with software and hardware. The present . study examined two tutorials which were similar except in their level of required user behaviors. Tutorial A required only user manipulation of disk stored data. Tutorial B required the user to enter the data into the computer, design the screen format, and then to manipulate it. It …

Structural And Topological Contributions To The Electronic Properties Of Inhomogeneous Media (Fractal, Electrode, Impedance), Michael Kramer

Dissertations, Theses, and Capstone Projects

Recent theoretical developments in the theory of inhomogeneous media have enabled Physicists to explore various properties of random composites. We demonstrate how these techniques can be applied to the treatment of electrochemical systems, specifically porous structures. A Random Network Model is introduced to represent the porous electrode immersed in electrolyte, and using numerical simulation the a.c. impedance behavior of the system is explored. We explore how various compositional and structural parameters contribute to the electrical properties of the system. The topology of our model is analyzed, and the effect of fractal structures on impedance behavior is considered. To examine the …

Total Refraction At Oblique Incidence By A Transparent Bilayer Coating On A High-Index Transparent Or Absorbing Substrate, R. M.A. Azzam, Karim Javily

Electrical Engineering Faculty Publications

Transparent bilayer coatings that produce total refraction (TR) of obliquely incident monochromatic light into an underlying substrate are considered. When the substrate is transparent, it is shown that TR takes place without any accompanying change of polarization. Totally refracting bilayers are realizable in the IR where high-refractive-index substrates are available. This is illustrated by a BaF₂–ZnSe bilayer on a Ge substrate at a 10.6-μm (CO₂-laser) wavelength and 45° angle of incidence. Limited changes of the angle of incidence, wavelength, and refractive indices and thicknesses of the two films of the bilayer are introduced, and their effects …

A Brief Chronology Of Some Events Related To Cancellation/Suspension Of The Predacides (Compound 1080, Strychnine, Sodium Cyanide) By The Environmental Protection Agency In 1972 And Ensuing Actions By Federal And State Agencies., Dale A. Wade

Great Plains Wildlife Damage Control Workshop Proceedings

Covers 1964-1986

Reported Beaver Damage And Control Methods Used In Texas, Jan E. Loven

Great Plains Wildlife Damage Control Workshop Proceedings

Beaver have greatly increased their range in Texas due to restocking and construction of man-made water impoundments. Damages can generally be categorized into dike and impoundment damage, tree damage, and flooding or other damages. These total $9,326,541 for the fiscal years 1983, 1984, and 1985. Methods used to remove beaver include: conibear traps, leg-hold traps, snares, spotlighting, and technical consultation. Live traps are seldom used. Total number of beaver taken for fiscal years 1983, 1984 and 1985 is 5,158.

Furbearer Management And The Steel Foothold Trap, Samuel B. Linhart

Great Plains Wildlife Damage Control Workshop Proceedings

The trapping of furbearers, particularly with steel foothold traps, has become more and more controversial. The controversy is significant because the steel trap is considered the most versatile of the various methods available for capturing furbearers (Payne 1980). Whether traps are used to reduce livestock losses by predators or to harvest furs, the controversy has gained the attention and interest of various social factions, each with differing beliefs, attitudes, and philosophies.

Appendix I, Dale A. Wade

Great Plains Wildlife Damage Control Workshop Proceedings

A brief chronology of some events related to cancellation/suspension of the predacides (Compound 1080, strychnine, sodium cyanide) by the Environmental Protection Agency in 1972 and ensuing actions by federal and state agencies.

Furbearer Management And The Steel Foothold Trap, Samuel B. Linhart

Great Plains Wildlife Damage Control Workshop Proceedings

The trapping of furbearers, particularly with steel foothold traps, has become more and more controversial. The controversy is significant because the steel trap is considered the most versatile of the various methods available for capturing furbearers (Payne 1980). Whether traps are used to reduce livestock losses by predators or to harvest furs, the controversy has gained the attention and interest of various social factions, each with differing beliefs, attitudes, and philosophies.

Investigation Of Electronic Holography Using Spice Computer Simulation Experiments, Monish Ranjan Chatterjee

Electrical and Computer Engineering Faculty Publications

Using SPICE experiments, it has been possible to verify most of the important aspects of electronic holography. The generation and properties of dynamic echoes under different types of nonlinearities have been extensively tested, and some new information has been garnered in the process. The case of pulse and generalized memory echoes has also been tested, and the results have been fairly satisfactory. Most of all, the simplicity with which the intriguing concept of memory echoes has translated into the circuit implementation on SPICE, and the closeness of the results to predicted behavior have been somewhat of a pleasant surprise.

Since …

Redox Reaction Kinetics Between Cobalt(Ii)-4,4',4",4'"-Tetrasulfophthalocyanine & Iodine In Various Solvents, Byung-Soo Yu

Masters Theses & Specialist Projects

Analyses of the kinetic data obtained on the redox reaction between cobalt(II)-4,4',4",4"-tetrasulfophthalocyanine [Co(II)TSPC4^-] and iodine in the presence of air show three reactions in dimethylsulfoxide(DMS0), N,N-dimethylacetamide(DMA), and diethylene glycol(DEG) while there are two reactions in methanol(Me0H). Two of the three reactions in DMSO, DMA, and DEG are biphasic with one reaction in all of the solvents being too fast to be accurately measured on the Cary Model 14 spectrophotometer. When the reactant solutions are purged with argon for 40 minutes under identical conditions, the same biphasic reactions are observed in DMSO and DEG while only one of the …