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Magnetic Solid-Phase Extraction Technique Based On Fe3o4@Coppy-Pth Nanocomposite For Extraction Of Cobalt, Chromium, And Nickel Prior To Determination By Micro-Sample Injection System-Flame Atomic Absorption Spectrometry In Alcoholic And Nonalcoholic Beverages, Meli̇ke Küçüksakalli, Qamar Salamat, Buket Ti̇reli̇, Şükrü Gökhan Elçi̇ Aug 2024

Magnetic Solid-Phase Extraction Technique Based On Fe3o4@Coppy-Pth Nanocomposite For Extraction Of Cobalt, Chromium, And Nickel Prior To Determination By Micro-Sample Injection System-Flame Atomic Absorption Spectrometry In Alcoholic And Nonalcoholic Beverages, Meli̇ke Küçüksakalli, Qamar Salamat, Buket Ti̇reli̇, Şükrü Gökhan Elçi̇

Turkish Journal of Chemistry

A novel Fe3O4@coPPy-PTH nanocomposite-based sorbent was prepared via in-situ oxidative polymerization using Fe3O4 nanoparticles with spherical and flower-like morphologies of thiophene and pyrrole as the feedstocks. The synthesized nanocomposite utilized sensitive extraction and determination of the metal ions Co(II), Cr(III), and Ni(II) without a chelating agent, followed by a micro-sample injection system-flame atomic absorption spectrometer (MIS-FAAS). The composition and morphology of Fe3O4@coPPy-PTH nanocomposite were characterized by advanced spectroscopic and imaging techniques like SEM and FT-IR. SEM observations showed the size of Fe3O4 nanoparticles changed from 30 nm to 120 nm in diameter after the copolymer (PPy-PTH) coating. The Fe3O4@coPPy-PTH nanocomposite …


Β-Ketoenamine-Linked Covalent Organic Framework For Efficient Iodine Capture, Onur Büyükçakir Aug 2024

Β-Ketoenamine-Linked Covalent Organic Framework For Efficient Iodine Capture, Onur Büyükçakir

Turkish Journal of Chemistry

Exploring the materials that effectively capture radioactive iodine is crucial in managing nuclear waste produced from nuclear power plants. Herein, a β-ketoenamine-linked covalent organic framework (bCOF) was reported as an effective adsorbent to capture iodine from both vapor and solution. bCOF's high porosity and heteroatom-rich skeleton offer a notable iodine vapor uptake capacity of up to 2.51 g g-1 at 75 oC under ambient pressure. Furthermore, after five consecutive adsorption-desorption cycles, the bCOF demonstrates a high reusability performance with a significant iodine vapor capacity retention. The adsorption mechanism was also investigated using various ex-situ structural characterization techniques, and these mechanistic …


Synthesis And Photooxygenation Of 3-(P-Substituted Phenyl)-3a,8a-Dihydro-4h-Cyclohepta[D]Isoxazoles: Facial Selectivity, Mahi̇re Emel Olgun, Abdullah Menzek, Ertan Şahi̇n, Yasi̇n Çeti̇nkaya Aug 2024

Synthesis And Photooxygenation Of 3-(P-Substituted Phenyl)-3a,8a-Dihydro-4h-Cyclohepta[D]Isoxazoles: Facial Selectivity, Mahi̇re Emel Olgun, Abdullah Menzek, Ertan Şahi̇n, Yasi̇n Çeti̇nkaya

Turkish Journal of Chemistry

Two 3-(p-substituted phenyl)-3a,8a-dihydro-4H-cyclohepta[d]isoxazoles were synthesized by 1,3-dipolar cycloaddition of the corresponding nitrile oxides with cycloheptatriene. Two endoperoxides were synthesized as facially selective and single products in high yields (93-95%) from the reactions of isoxazole derivatives with singlet oxygen. The exact configurations of the endoperoxide with a methyl group in the phenyl ring and the diol synthesized from it were confirmed by X-ray analysis. To elucidate the mechanism, the formation energy of the endoperoxide was investigated by simulations using the software package Gaussian 09 and density functional theory calculations via the M06-2X/6-311+G(d,p) level method in dichloromethane. The results were consistent with …


Development And Testing Of Small-Scale Flash Dryer For Maize Bran, Eden Ngowi Aug 2024

Development And Testing Of Small-Scale Flash Dryer For Maize Bran, Eden Ngowi

Tanzania Journal of Engineering and Technology (TJET)

Sun drying is the most common technique used to dry various food products due to its economic convenience. However, it is not effective owing to its unreliable nature leading to microbial deterioration and aflatoxin contamination of food. In Tanzania, about 1.3 million tonnes of maize bran are at risk of deterioration annually due to improper drying. The aim of this study was to design, fabricate and test an efficient small-scale flash dryer for maize bran. Using principles of material and energy balance, a small-scale flash dryer with a throughput of 500 kg of dry product per hour was designed resulting …


Exploring The Transformation Of Sustainable Collective Spaces: A Study From Mlalakuwa Informal Settlement, Jacob Lutta Aug 2024

Exploring The Transformation Of Sustainable Collective Spaces: A Study From Mlalakuwa Informal Settlement, Jacob Lutta

Tanzania Journal of Engineering and Technology (TJET)

A major challenge in collective space transformation is addressing the complexity of informal urbanisation in developing countries. Using a case study approach, this paper examines the concerns related to a particular informal settlement's sustainable collective space transformation. One of the key findings is that the absence of formal rules and regulations in the development of informal settlements in combination with land-grabbing leads to the absence of open spaces that could be used collectively. It is observed that sustainability in urban development is another body of critical thought that integrates several streams of current urban elements and embodies various conceptions of …


Investigations Of Cell Tower Antennas Parameters On Reduction Of Radio Frequency Radiation Levels From Radio Base Stations, Florence U. Rashidi Aug 2024

Investigations Of Cell Tower Antennas Parameters On Reduction Of Radio Frequency Radiation Levels From Radio Base Stations, Florence U. Rashidi

Tanzania Journal of Engineering and Technology (TJET)

The widespread deployment of mobile cellular base stations in populated areas has raised public health concerns due to increased exposure to radio frequency (RF) radiation emissions. Exposure to high levels of RF radiation can have potential thermal and non-thermal biological effects. Optimizing the configuration of cell tower antenna parameters is crucial for mitigating these radiation levels. This study therefore aims at systematically investigating the influence of different cell tower antenna parameters on reducing the RF radiation levels from mobile base stations. Field measurements were conducted at two cell sites shared by multiple mobile operators. Electric field strengths were measured at …


Evaluation Of Business-Driven Reference Architecture For Big Data Analytics Implementation By Public Sector Organizations In Resource-Constrained Setting: A Case Study Of Uganda, Matendo Didas Aug 2024

Evaluation Of Business-Driven Reference Architecture For Big Data Analytics Implementation By Public Sector Organizations In Resource-Constrained Setting: A Case Study Of Uganda, Matendo Didas

Tanzania Journal of Engineering and Technology (TJET)

Big Data Analytics (BDA) is a new area at the nexus of agenda, public sector organizations, and government business. It may satisfy the growing need for trustworthy, cost-effective services in the public sector for better, more informed decision-making processes. BDA has been proposed on the planning schedules of several public sector organizations and the government. Therefore, from the previous work, using Uganda as a case study, specifically the Uganda Bureau of Statistics (UBOS), Ministry of Health (MoH), and Ministry of Education and Sports (MoES), this study aims to evaluate a designed Business-Driven Reference Architecture for Big Data Analytics Implementation (BRABDAI) …


Investigation Of Heavy Metal Composition And Associated Health Risks From Selected Groundwater Wells In Temeke, Dar-Es-Salaam, Justin M. Jeremiah Aug 2024

Investigation Of Heavy Metal Composition And Associated Health Risks From Selected Groundwater Wells In Temeke, Dar-Es-Salaam, Justin M. Jeremiah

Tanzania Journal of Engineering and Technology (TJET)

Water quality continues to be the challenge to residents in Dar es Salaam due to various anthropogenic activities in the city. This study was conducted to assess groundwater quality by determining concentrations of heavy metals. Both probability and Nonprobability sampling techniques were used to collect samples from 40 groundwater wells in 24 wards of Temeke municipal and analysed using Microwave Plasma Atomic Emission Spectrometer (Agilent 4210 MP-AES) at the Geochemistry Laboratory of the University of Dar es Salaam. Results indicated varying heavy metal concentrations ranging from 0.71 ± 0.08 to 6.64 ± 0.21 mg/l for As, 0.02 ± 0.01 to …


Suggestions For Establishing Nuclear Safety Barrier In Bohai Rim Region Of China, Longchuan Zhuang, Chuanyuan Wang, Song Qin Aug 2024

Suggestions For Establishing Nuclear Safety Barrier In Bohai Rim Region Of China, Longchuan Zhuang, Chuanyuan Wang, Song Qin

Bulletin of Chinese Academy of Sciences (Chinese Version)

Under the dual carbon strategy goal, the Bohai Rim, as the core region for nuclear power deployment in northern China, is pivotal in establishing a robust nuclear safety barrier, which aligns with the national maritime power development strategy and is essential for ensuring regional marine ecological safety and national energy security. Currently, the Bohai Rim region in China faces challenges such as inadequate nuclear radiation monitoring and early warning capabilities, insufficient data for health risk assessment, an underdeveloped scientific and technological support system, and limited public participation in both depth and breadth. Based on a scientific assessment of the potential …


Assessing The Importance Of Air-Decking Blasting In Controlling Bigv At An Open Pit Gold Mine In Tanzania Using Ann Model, Karim R. Baruti Aug 2024

Assessing The Importance Of Air-Decking Blasting In Controlling Bigv At An Open Pit Gold Mine In Tanzania Using Ann Model, Karim R. Baruti

Tanzania Journal of Engineering and Technology (TJET)

Air-decking blasting technique is used to control blast induced ground vibration (BIGV) in several mines including open-pit gold mines located in Tanzania. While the importance of air-deck to control BIGV is practically evident, theoretical models such as BIGV prediction models cannot be used to assess the importance of air-decking. The main objective of this study was to assess the importance of the air-decking blasting technique to control BIGV using the artificial neural network (ANN)Model. To achieve this objective, ANNs were modeled and trained to learn the pattern of data using Multilayer Perception with Back Propagation to predict BIGV. The main …


July 2024 Berkeley Pit Migratory Waterfowl Protection Monthly Report, Mark Thompson, Loren Burmeister Aug 2024

July 2024 Berkeley Pit Migratory Waterfowl Protection Monthly Report, Mark Thompson, Loren Burmeister

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.


Research And Implications Of The Us Clean Energy Strategy, Lanchun Li, Qing Liu, Wei Chen, Yun Tang, Jun Chen Aug 2024

Research And Implications Of The Us Clean Energy Strategy, Lanchun Li, Qing Liu, Wei Chen, Yun Tang, Jun Chen

Bulletin of Chinese Academy of Sciences (Chinese Version)

As the world enters a new period of carbon neutrality, the US government is actively building a clean energy innovation ecosystem through both internal and external measures. Systematically tracking and in-depth analysis of the intent, structure, approach, and other characteristics of the new phase of the US clean energy strategy is of practical significance to Chinese energy revolution. The US focuses on the strategic objectives of science and technology innovation, energy security, and infrastructure, and has constructed an innovation ecology characterized by technology lists, planning blueprints, full-chain research, and innovative subjects from the perspective of whole-government coordination, cross-institutional decision-making, deep …


Analysis Of Serum Exosome Metabolites Identifies Potential Biomarkers For Human Hepatocellular Carcinoma, Tingting Zhao, Yan Liang, Xiaolan Zhen, Hong Wang, Li Song, Didi Xing, Hui Li Aug 2024

Analysis Of Serum Exosome Metabolites Identifies Potential Biomarkers For Human Hepatocellular Carcinoma, Tingting Zhao, Yan Liang, Xiaolan Zhen, Hong Wang, Li Song, Didi Xing, Hui Li

Faculty, Staff and Student Publications

Currently, the clinical cure rate for primary liver cancer remains low. Effective screening and early diagnosis of hepatocellular carcinoma (HCC) remain clinical challenges. Exosomes are intimately associated with tumor development and their contents have the potential to serve as highly sensitive tumor-specific markers. A comprehensive untargeted metabolomics study was conducted using exosome samples extracted from the serum of 48 subjects (36 HCC patients and 12 healthy controls) via a commercial kit. An ultra-performance liquid chromatography-mass spectrometry (UPLC-MS) strategy was used to identify the metabolic compounds. A total of 18 differential metabolites were identified using the non-targeted metabolomics approach of UPLC-QTOF-MS/MS. …


08.19.2024 Orsp Connect, Liz Williamson Aug 2024

08.19.2024 Orsp Connect, Liz Williamson

ORED Newsletter

Lei Cao NSF award

FDP Meeting Summaries Available

August LINC Lunch

Collaboration Opportunities


Object Classification, Detection And Tracking In Challenging Underwater Environment, Md Modasshir Aug 2024

Object Classification, Detection And Tracking In Challenging Underwater Environment, Md Modasshir

Theses and Dissertations

The main contributions of this thesis is the applicability and architectural designs of deep learning algorithms in underwater imagery. In recent times, deep learning techniques for object classification and detection have achieved exceptional levels of accuracy that surpass human capabilities. However, the effectiveness of these techniques in underwater environments has not been thoroughly researched. This thesis delves into various research areas related to underwater environments, such as object classification, detection, semantic segmentation, pose regression, and semi-supervised retraining of detection models.

The first part of the thesis studies image classification and detection. Image classification is a fundamental process that involves assigning …


Role Of Vegfa In Intervertebral Disc Pathoanatomy And Low Back Pain, Ryan Potter Aug 2024

Role Of Vegfa In Intervertebral Disc Pathoanatomy And Low Back Pain, Ryan Potter

McKelvey School of Engineering Graduate Student Theses & Dissertations

Chronic low back pain (LBP) affects more than 80% of Americans and causes significant disability and staggering public health costs. Despite this astonishing prevalence, there are currently no disease modifying therapies. Intervertebral disc (IVD) degeneration accounts for a considerable proportion of LBP, but the precise mechanisms driving the painful pathoanatomy are not understood. The degenerating IVD exhibits a complex array of inflammatory and physiologic changes, and many are associated with the presentation of LBP. For example, the presence of nerves and blood vessels in degenerate IVDs have been identified in patients and animals presenting with LBP symptoms. However, no studies …


Sustainable Transportation: Transforming Utah Through Community Action, Isabella Erwin, Kendall Becker, Patrick A. Singleton, Scott Hotaling Aug 2024

Sustainable Transportation: Transforming Utah Through Community Action, Isabella Erwin, Kendall Becker, Patrick A. Singleton, Scott Hotaling

All Current Publications

Transportation in the United States accounts for 4% of global greenhouse gas emissions. Over half of these emissions come from on-road vehicles. Nationwide, Utah has the third highest rate of car ownership, and the resulting air pollution from on-road vehicles has significant implications for the climate and public health. This fact sheet provides information on how Utah’s government and other entities are working to expand modes of transport that minimize harm to communities and the environment.


Analysis Of The Effect Of Vaccination, Efficient Surveillance And Treatment On The Transmission Dynamics Of Cholera, Loyinmi Adedapo Chris, Ajala Adebisi Shukurat, Alani L. Ijaola Aug 2024

Analysis Of The Effect Of Vaccination, Efficient Surveillance And Treatment On The Transmission Dynamics Of Cholera, Loyinmi Adedapo Chris, Ajala Adebisi Shukurat, Alani L. Ijaola

Al-Bahir

In this study, we presented a modified SIR-SI model to investigate the dynamics and potential controls for cholera transmission, with an incident rate equipped with a saturation factor to investigate the combined impact of three vital measures which include effective surveillance, vaccination campaign and proper treatment in case severity. We established among other things, the qualitative analysis of the model to validate the results. Furthermore, the reproduction number (R0) was found to be less than unity (1), through the stability analysis. Additionally, finite different scheme was utilized in solving the differential equations of the model. MATLAB software was used for …


Interventional Radiology's Exploration Into Artificial Intelligence, Raymond Nguyen Aug 2024

Interventional Radiology's Exploration Into Artificial Intelligence, Raymond Nguyen

Master's Projects and Capstones

Background: Artificial intelligence (AI) has become more prominent in our daily lives in recent years. This includes various aspects of healthcare. Interventional radiology (IR) is one of these specialties that has taken strides in understanding how AI can be leveraged for patient care. This literature review aims to understand what areas will be most impacted by AI in IR and how it will influence both the patient and interventional radiologist.

Methods: Twenty-six publications from 2019-2024 were selected from PubMed and Scopus. Publications were sourced through a combination of keywords, subject headings (MeSH terms), and citation searching.

Results: This literature review …


Re: Comment Letter For The Butte Priority Soils Operable Unit (Bpsou) Diggings East 60% Remedial Design Package Submittal (Dated April 23, 2024), Emma Rott Aug 2024

Re: Comment Letter For The Butte Priority Soils Operable Unit (Bpsou) Diggings East 60% Remedial Design Package Submittal (Dated April 23, 2024), Emma Rott

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.


Detection And Analysis Of Solid-Phase Nutrients In Complex Benthic Cyanobacterium Communities, Cassidy Ann Crandell Aug 2024

Detection And Analysis Of Solid-Phase Nutrients In Complex Benthic Cyanobacterium Communities, Cassidy Ann Crandell

Theses and Dissertations

Eutrophication is one of the most serious water quality issues affecting aquatic systems in the United States. Densely populated urban areas as well as mining and agriculture are major sources of anthropogenic nutrient loading into lakes and rivers. Excess loading of nutrients like phosphorus (P) into these ecosystems can cause native algal species to be outcompeted by harmful algal bloom (HAB) species. Increases in these HAB events are a growing public health concern as contact with excreted toxins can be harmful for human, aquatic, and land species. Remediation techniques like total maximum daily loads (TMDLs) have been implemented to reduce …


Erlang-Distributed Seir Epidemic Models With Cross-Diffusion, Victoria Chebotaeva Aug 2024

Erlang-Distributed Seir Epidemic Models With Cross-Diffusion, Victoria Chebotaeva

Theses and Dissertations

We examine the effects of cross-diffusion dynamics in epidemiological models. Using reaction-diffusion dynamics to model the spread of infectious diseases, we focus on situations in which the movement of individuals is affected by the concentration of individuals of other categories. In particular, we present a model where susceptible individuals move away from large concentrations of infected and infectious individuals.

Our results show that accounting for this cross-diffusion dynamics leads to a noticeable effect on epidemic dynamics. It is noteworthy that this leads to a delay in the onset of epidemics and an increase in the total number of people infected. …


Simulation Study On Count Data Based On Double Poisson Distribution, Chao Ma Aug 2024

Simulation Study On Count Data Based On Double Poisson Distribution, Chao Ma

Theses and Dissertations

This thesis delves into the double Poisson distribution. Regression based on the double Poisson distribution, as proposed by Efron in 1986, offers an alternative approach that allows for more accurate regression models when dealing with discrete data that exhibit either over- or under-dispersion compared to the Poisson distribution. In this thesis, two methods of calculating the exact double Poisson density are compared: one utilizes the exact probability with the normalizing constant c(mu, theta) by definition or the “finite sum” method, while the other employs an approximation of the normalizing constant c(mu, theta). Furthermore, a simulation was …


The Control And Operation Of Optical Sensors For Environmental Monitoring With Microcontrollers As Data Acquisition And Processing Systems, Zechariah Kitzhaber Aug 2024

The Control And Operation Of Optical Sensors For Environmental Monitoring With Microcontrollers As Data Acquisition And Processing Systems, Zechariah Kitzhaber

Theses and Dissertations

Phytoplankton are microscopic unicellular organisms, and they are ubiquitous in marine and freshwater environments across the globe. They play a critical role in primary production, carbon fixation, and O2 production through photosynthesis. Phytoplankton comprise an abundant variety of genera and species, and the taxonomic makeup of a community can be an important indicator of environmental health. Phytoplankton are spatially and taxonomically diverse; they change in size and cellular content throughout their lifetime, and they can also alter their pigmentation in response to environmental factors, so it is important to understand the variability in size and pigmentation between individuals of the …


Assessing Multi-Annual Phytoplankton Community Compositions And Biomass Across Tidal Creek And Open Water Estuarine Habitats In South Carolina, Shannon Elizabeth Powers Aug 2024

Assessing Multi-Annual Phytoplankton Community Compositions And Biomass Across Tidal Creek And Open Water Estuarine Habitats In South Carolina, Shannon Elizabeth Powers

Theses and Dissertations

The urbanization of coastal environments in recent decades has caused an accelerating increase in nutrient-rich runoff from the landscape. The presence of these excess nutrients in the aquatic environment can result in degradation of water quality and harmful algal blooms. In South Carolina (SC), coastal development continues to threaten the resiliency of salt marsh estuaries, especially in combination with other stressors like climate change and sea level rise. Estuaries are important nurseries and habitats for fisheries and ecotourism. The South Carolina Estuarine and Coastal Assessment Program (SCECAP) is an ongoing monitoring program that assesses the habitat condition along the coast …


Impaired Waters: New Treatments And Improved Methods For Pfas And Algae Toxins, Alexandria Forster Aug 2024

Impaired Waters: New Treatments And Improved Methods For Pfas And Algae Toxins, Alexandria Forster

Theses and Dissertations

Per- and polyfluoroalkyl substances (PFAS) are high-profile environmental contaminants, many having long persistence in the environment and widespread presence in humans and wildlife. Following phase-out of perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA) in North America and restrictions in Europe, PFAS replacements are now widely found in the environment. While liquid chromatography (LC)-mass spectrometry (MS) is typically used for measurement, much of the PFAS is missed. To more comprehensively capture organic fluorine, we developed sensitive and robust methods using activated carbon adsorption, solid phase extraction, and combustion ion chromatography (CIC) to measure total organic fluorine (TOF) in industrial wastewaters, river …


Human-Human Vs Human-Ai Therapy: An Empirical Study, Mohammad Amin Kuhail, Nazik Alturki, Justin Thomas, Amal K. Alkhalifa, Amal Alshardan Aug 2024

Human-Human Vs Human-Ai Therapy: An Empirical Study, Mohammad Amin Kuhail, Nazik Alturki, Justin Thomas, Amal K. Alkhalifa, Amal Alshardan

All Works

In many nations, demand for mental health services currently outstrips supply, especially in the area of talk-based psychological interventions. Within this context, chatbots (software applications designed to simulate conversations with human users) are increasingly explored as potential adjuncts to traditional mental healthcare service delivery with a view to improving accessibility and reducing waiting times. However, the effectiveness and acceptability of such chatbots remains under-researched. This study evaluates mental health professionals’ perceptions of Pi, a relational Artificial Intelligence (AI) chatbot, in the early stages of the psychotherapeutic process (problem exploration). We asked 63 therapists to assess therapy transcripts between a human …


Re: Comment Letter For The Butte Priority Soils Operable Unit (Bpsou) Draft Final Annual Operations And Maintenance Report Butte Treatment Lagoon System – 2023 (Dated May 28, 2024), Emma Rott Aug 2024

Re: Comment Letter For The Butte Priority Soils Operable Unit (Bpsou) Draft Final Annual Operations And Maintenance Report Butte Treatment Lagoon System – 2023 (Dated May 28, 2024), Emma Rott

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.


Butte Mine Flooding Site Cd, Cv 02-35 Bu-Rfc, 2024 Second Quarter Report, Mark Thompson, Dave Griffis Aug 2024

Butte Mine Flooding Site Cd, Cv 02-35 Bu-Rfc, 2024 Second Quarter Report, Mark Thompson, Dave Griffis

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.


The Basic Dualism In The World: Object-Oriented Ontology And Systems Theory, Martin Zwick Aug 2024

The Basic Dualism In The World: Object-Oriented Ontology And Systems Theory, Martin Zwick

Complex Systems Faculty Publications and Presentations

Graham Harman writes that the “basic dualism in the world lies…between things in their intimate reality and things as confronted by other things.” However, dualism implies irreconcilable difference; what Harman points to is better expressed as a dyad, where the two components imply one another and interact. This article shows that systems theory has long asserted the fundamental character of Harman’s dyad, expressing it as the union of internal structure and external function, which correspond exactly to what Levi Bryant, characterizing Harman’s views, refers to as the intra-ontic and the inter-ontic, respectively. After interpreting Harman’s dyad in terms of the …