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Reaction Of Tricarbonyl(Dienal)Iron Complexes With B-Allyldiisopinocampheylborane, Vadapalli Prahlad, Abdel-Aziz S. El-Ahl, William A. Donaldson

Chemistry Faculty Research and Publications

Addition of allyldiisopinocampheylborane to racemic (dienal)iron complexes, followed by oxidation, affords diastereomeric (1,4,6-trien-3-ol)iron complexes with moderate to low enantioselectivity. The high enantioselectivity typically observed for this allylborane reagent is attenuated by steric interaction between the Fe(CO)₃ group and the chiral isopinocampheyl groups. Further diminution of the enantioselectivity is observed for dienal complexes in which one rotomer predominates.

Reaction Of Caffeic Acid With Amino Acids, Yonggang Wang

Masters Theses

The reaction of caffeic acid with tryptophan was studied as a model for the reaction of caffeic acid with amino acids in the aquatic environment. Although the autoxidation reaction of caffeic acid in aqueous solution with subsequent dimerization had been previously studied, it was examined as well for comparison purposes. The present studies demonstrate that oxidized caffeic acid would react with tryptophan. The reaction, like the dimerization reaction, was catalyzed by the presence of iron(III) ions at low pH ( <4) and by hydroxide ions at high pH (10). The reaction of caffeic acid with itself yielded six products, four of which were identified by mass spectroscopy as dimers, with the other two being trimers. The reaction of caffeic acid with tryptophan yielded three product peaks. Two of the product peaks had similar retention times to the dimers from the self-reaction of caffeic acid; the third was a new product resulting from the reaction of caffeic acid with the tryptophan.

A mechanism for the reaction of caffeic acid with tryptophan has been proposed. This mechanism was based on the analysis …

42nd Rocky Mountain Conference On Analytical Chemistry

Rocky Mountain Conference on Magnetic Resonance

Abstracts from the 42nd annual meeting of the Rocky Mountain Conference on Analytical Chemistry, co-sponsored by the Colorado Section of the American Chemical Society and the Rocky Mountain Section of the Society for Applied Spectroscopy. Held in Broomfield, Colorado, July 30 - August 3, 2000.

Evaluation And Assessment Of Agrichemical Contaminants In The Creighton, Ne Area, Mark E. Burbach, Roy F. Spalding

School of Natural Resources: Faculty Publications

The Lewis and Clark Natural Resources District (LCNRD) has reported elevated nitrate- nitrogen (NO3-N) concentrations in ground water near Creighton, NE. The U.S. Environmental Protection Agency has set a maximum contaminant level (MCL) of 10 mg/L for NO3-N in public water supplies. NO3-N in the city of Creighton municipal drinking water wells and several rural domestic and irrigation wells have exceeded the MCL. The city of Creighton has constructed a reverse-osmosis water treatment system at a cost of $1.1 million to reduce the NO3-N concentration below the MCL in its water supply. In response to this NO3-N contamination problem the …

Pyridoxamine, An Inhibitor Of Advanced Glycation Reactions, Also Inhibits Advanced Lipoxidation Reactions: Mechanism Of Action Of Pyridoxamine, Joelle M. Onorato, Alicia J. Jenkins, Suzanne R. Thorpe, John W. Baynes

Faculty Publications

Maillard or browning reactions lead to formation of advanced glycation end products (AGEs) on protein and contribute to the increase in chemical modification of proteins during aging and in diabetes. AGE inhibitors such as aminoguanidine and pyridoxamine (PM) have proven effective in animal model and clinical studies as inhibitors of AGE formation and development of diabetic complications. We report here that PM also inhibits the chemical modification of proteins during lipid peroxidation (lipoxidation) reactions in vitro, and we show that it traps reactive intermediates formed during lipid peroxidation. In reactions of arachidonate with the model protein RNase, PM prevented modification …

Interaction Of Mitochondrial Elongation Factor Tu With Aminoacyl-Trna And Elongation Factor Ts, Ying Chun Cai, James M. Bullard, Nancy L. Thompson, Linda L. Spremulli

School of Integrative Biological & Chemical Sciences (Formerly Dept. of Chemistry)

Elongation factor (EF) Tu promotes the binding of aminoacyl-tRNA (aa-tRNA) to the acceptor site of the ribosome. This process requires the formation of a ternary complex (EF-Tu·GTP·aa-tRNA). EF-Tu is released from the ribosome as an EF-Tu·GDP complex. Exchange of GDP for GTP is carried out through the formation of a complex with EF-Ts (EF-Tu·Ts). Mammalian mitochondrial EF-Tu (EF-Tu_mt) differs from the corresponding prokaryotic factors in having a much lower affinity for guanine nucleotides. To further understand the EF-Tu_mt subcycle, the dissociation constants for the release of aa-tRNA from the ternary complex (K _tRNA) and for …

Santa Clara Magazine, Volume 42 Number 1, Summer 2000, Santa Clara University

Santa Clara Magazine

8 - ATTACK OF THE KILLER TOMATOES? By Miriam Schulman. Beyond the hype of the headlines, there are no simple answers to the ethical questions raised by genetically modified food.

14 - BRAVE NEW WORLD By Tamara Straus. Now the lawyers want inside your head as they struggle to answer, "Who owns an idea?" Just the mere question is changing the face of legal education.

18 - THE GREAT GRADE GIVEAWAY By Jeff Zorn. Today's grades don't mean jack. So says one Santa Clara professor in this memoir and commentary on the evils of modern day grade inflation.

22 - …

India’S Arid Region And The Current Drought, Pratap Narain, K. D. Sharma, A. S. Rao, D. V. Singh, B. K. Mathur, Usha Rani Ahuja

Drought Network News (1994–2001)

We recently surveyed some of the drought-affected areas (Figure 1) in the Indian arid region in a publication entitled “Strategy to Combat Drought and Famine in the Indian Arid Zone.” This article is a summary of the report.

The present drought in the arid and semiarid regions of India is due to the cumulative effect of inadequate rainfall during 1997–99. Twelve states in India are in the grip of severe drought, with Rajasthan, Gujarat, Andhra Pradesh, and Madhya Pradesh (Table 1) being the most affected. The Indian arid zone encompasses 32 million ha and is highly prone to droughts and …

Scwds Briefs: Volume 16, Number 2 (July 2000)

Southeastern Cooperative Wildlife Disease Study: Publications

• CWD and Human Health: “There currently is no evidence that Chronic Wasting Disease in Cervidae is transmitted to humans”…
• SCWDS recently completed the fieldwork of a research project to investigate the epidemiology of avian vacuolar myelinopathy (AVM), previously known as the Avian Brain Lesion Syndrome (ABLS).
• NIH Funds SCWDS Ehrlichiosis Study: Since 1985, three new tickborne zoonoses caused by bacteria in the genus Ehrlichia have been recognized in the United States. Human monocytotropic ehrlichiosis (HME) caused by E. chaffeensis occurs across a broad area of the eastern and south-central United States. HME is transmitted by lone star …

Canadian Cooperative Wildlife Health Centre Newsletter, Volume 7-1, Summer 2000

Canadian Cooperative Wildlife Health Centre: Newsletters and Publications

New Staff Member - Western/Northern Regional Centre Surveillance for West Nile Virus - Summer 2000 Dorsal-spined Larvae in Cervids Organophosphate Pesticide Poisoning of Seagulls - St. John's, Newfoundland Successful euthanasia of a juvenile fin whale Psittacosis in Wild Rock Doves Walleye myopathy The St-Lawrence beluga whale: summary of lesions detected in stranded individuals submitted for necropsy during 1999 An Epizootic of Iridovirus in Oregon Spotted Frog Tadpoles (Rana pretiosa) Epidemic Avian Cholera in Double-Crested Cormorants in Saskatchewan Winter Ticks in Stone's Sheep California Bighorn Sheep in British Columbia

An Overview Of Recreation And Parks Professional Preparation Programs In Higher Education, Jennifer Y. Mak

Management Faculty Research

The purpose of this paper is to give an overview of recreation and parks professional preparation programs in higher education. This paper will (a) help to understand the framework of recreation and parks professional preparation programs, (b) discuss the factors which influence the professional preparation outcomes, and (c) help to identify future research needs. The discussion is based on the framework for studying professional preparation programs by Stack, et al. (1986). The key element of the framework for studying recreation and parks professional preparation programs is the recreation and parks professional preparation environment which was the product of external, internal …

Benthic Biological Monitoring Program Of The Elizabeth River Watershed (1999), Daniel M. Dauer

Elizabeth River Reports

Executive Summary

A study of the macrobenthic communities of the Elizabeth River watershed was conducted in summer 1999. The three objectives of the Benthic Biological Monitoring Program of the Elizabeth River watershed are: (1) To characterize the health of regional areas of the tidal waters of the Elizabeth River watershed Chesapeake Bay as indicated by the structure of the benthic communities. These characterizations are based upon application of benthic restoration goals and the Benthic Index of Biotic Integrity (BIBI) developed for the Chesapeake Bay to five primary strata - the Mainstem of the river, the Lafayette River, the Southern Branch, …

The University Of Nebraska At Omaha Center For Space Data Use In Teaching And Learning, Neal Grandgenett, Uno Aviation Institute

Faculty Books and Monographs

UNOAI Report 2000-4

Within the context of innovative coursework and other educational activities, we are proposing the establishment of a University of Nebraska at Omaha Center for the Use of Space Data in Teaching and Learning. This Center will provide an exciting and motivating process for educators at all levels to become involved in professional development and training which engages real life applications of mathematics, science, and technology. The Center will facilitate innovative courses (including online and distance education formats), systematic degree programs, classroom research initiatives, new instructional methods and tools, engaging curriculum materials, and various symposiums. It will involve …

Investigations On The Use Of Ion Mobility Spectrometry For Clinical Chemistry Applications, Henri Parson Patten

Theses and Dissertations in Biomedical Sciences

The major objective of this research is to examine ion mobility spectrometry as a rapid screening tool for specific application to clinical chemistry research and laboratory use. Methodology was developed for target analytes representing several classes of physiologically active substances, including anesthetics, illicit drugs, and their metabolites. The IMS characteristics of animal tissues and other compounds such as amino acids and proteins were determined. Quality assurance and control procedures were developed for specific quality data objectives. Criteria were established relating to use of IMS for assessing the precision and accuracy of data, qualitative screening, and semi-quantitative analyses.

It was found …

Degradation In The Brockman River And Ellen Brook Catchments, Western Australia, Brian Lloyd

Natural resources published reports

An eight day survey of degradation in the Ellen Brook and Brockman River catchments revealed several areas of concern. Key concerns are:

Erosion and sedimentation

Various forms of erosion were observed during the survey that would cumulatively have an effect on the quality of both the Ellen Brook and the Brockman Rivers, and ultimately the Swan River. Erosion resulted from many situations including landholder management, subdivision design and infrastructure maintenance. Raising awareness as to consequences of erosion and sedimentation, along with remedial techniques and best management practices is recommended for the various levels of stakeholders.

Eutrophication

Eutrophication has been established …

Bulletin 4418 - Nebru Focus Catchment Report, Agriculture Western Australia

Bulletins 4000 -

Nehru Focus Catchment is located in the upper reaches of the Arrowsmith Catchment. It is roughly bounded by Sunset Road in the north, the north-south Kadathinni Hills to the east, the Three Springs - Eneabba Road to the south and Reed Road in the west. It changes in elevation from 372 metres Australian Height Datum (AHD) at roughly the intersection of Nehru Rd the Kadathinni Hills to the east and 220 metres AHD near the outlet of the catchment into the Arrowsmith River.

The total area of the catchment is just over 7,400 hectares.

One of the prime areas of …

Conservation Conundrum, Robert L. Brownell Jr., Barbara E. Curry, Peter Daszak, Andrew A. Cunningham, Alex D. Hyatt

United States Department of Commerce: Staff Publications

P. Daszak, A. A. Cunningham, and A. D. Hyatt present a convincing argument in their Review "Emerging infectious diseases of wildlife-threats to biodiversity and human health" (Science's Compass, 21 Jan., p. 443) that emerging infectious diseases (EIDs) pose a risk to wildlife, and they suggest that EIDs most often result from a change in the ecology of the pathogen or the host (or both). A situation they did not mention is that in some cases, the protection of threatened species can increase the risk of an EID outbreak by allowing a close association between wildlife and domestic animals where one …

Digestibility, Nitrogen Excretion, And Mean Retention Time By North American Porcupines (Erethizon Dorsatum) Consuming Natural Forages, Laura A. Felicetti, Lisa A. Shipley, Gary W. Witmer, Charles T. Robbins

United States Department of Agriculture Wildlife Services: Staff Publications

North American porcupines (Erethizon dorsatum) subsist predominantly on low-protein, high-fiber, high-tannin diets. Therefore, we measured the porcupine's ability to digest dry matter, fiber, and protein by conducting digestion trials on eight natural forages and one pelleted ration varying in concentration of fiber, nitrogen, and tannins. On these diets, dry matter intake ranged from 5 to 234 g/kg ^0.75/d and dry matter digestibility ranged from 62% to 96%. Porcupines digested highly lignified fiber better than many large hindgut fermenters and ruminants. The porcupine's ability to digest fiber may be explained, in part, by their lengthy mean retention time …

The Complexity Of Planning With Partially-Observable Markov Decision Processes, Martin Mundhenk

Computer Science Technical Reports

This work surveys results on the complexity of planning under uncertainty. The planning model considered is the partially-observable Markov decision process. The general planning problems are, given such a process, (a) to calculate its performance under a given control policy, (b) to find an optimal or approximate optimal control policy, and (c) to decide whether a good policy exists. The complexity of this and related problems depend on a variety of factors, including the observability of the process state, the compactness of the process representation, the type of policy, or even the number of actions relative to the number of …

Final Technical Report For Grant De-Fg01-96ew56093 Nevada Risk Assessment/Management Program (Nramp), Donald H. Baepler, Anthony Hechanova

Nevada Risk Assessment/Management Program

The Nevada Risk Assessment/Management Program (NRAMP) was part of a national effort by the U.S. Department of Energy (DOE) to develop new sources of information and approaches to risk assessment, risk management, risk communication and public outreach as these objectives relate to the ecological and human health effects of radioactive and hazardous material management and site remediation activities. This final report presents a synopsis of the NRAMP effort that occurred from 1995 to 2000. Included in this report is a brief history of NRAMP including a description of the DOE Notice of Program Interest (NOPI) goals and how the NRAMP …

Groundwater And Growth Management In The New West: Evolving Law And Practice, A. Dan Tarlock

Water and Growth in the West (Summer Conference, June 7-9)

13 pages.

Metropolitan Water Supply Investigation Final Report: Report To The Colorado Water Conservation Board, January 1999, Hydrosphere Resource Consultants, Inc. Et Al.

Water and Growth in the West (Summer Conference, June 7-9)

207 pages (includes color illustrations and maps).

Contains 5 pages of references.

The Effects Of Development On Indian Water Rights: Obstacles And Disincentives To Development Of Indian Water Rights, Jerilyn Decoteau

Water and Growth in the West (Summer Conference, June 7-9)

17 pages.

Contains references.

Regionalized Water Management: An Evolving Hydrocommons?, Gary D. Weatherford

Water and Growth in the West (Summer Conference, June 7-9)

26 pages.

Contains footnotes and 8 pages of references.

The Social Costs Of Moving Water In Northern New Mexico, David Benavides

Water and Growth in the West (Summer Conference, June 7-9)

15 pages.

Growth Pressures And Tmdls, David G. Davis, Jamal M. Kadri, Teresa J. Norfleet

Water and Growth in the West (Summer Conference, June 7-9)

18 pages.

Pulse And Canola Frost Identification:The Back Pocket Guide, Craig White

Bulletins 4000 -

This field guide will help you identify the common symptoms of frost damage in pulse and canola crops. It also contains pictures of other plant symptoms often confused with frost damage in these crops.

Frost damage reduces crop yield and grain quality. Early identification of symptoms allows timely crop salvage decisions to be made.

Inspect pulse and canola crops between bud formation and during pod growth if right air temperature (recorded 1.2 m above ground) falls below 2 degrees celsius and there was a frost.

Check low lying, light coloured soil types and known frost prone areas first. Then check …

The John Muir Newsletter, Summer 2000, The John Muir Center For Regional Studies

Muir Center Newsletters (1981-2015)

u Volume 10, Number 3 oi. Summer 21)01) NEWSLETTER Reconstruction of John Muir's First Public Lecture, Sacramento, 1876 by Steve Pauly, Pleasant Hill, California WEditor's Note: This is Part IV of Steve Pauly's article recreating John Muir's first public talk; the earlier parts appeared in 1999 issues.) OSEMITE CREEK GLACIER The broad, many-fountained glacier to which the basin of Yosemite Creek belonged, was about fourteen miles in BSngth by four in width, and in many places was not less than a ^thousand feet in depth. Its principal tributaries issued from lofty .iphitheatres laid well back among the northern spurs of …

Review Of: Daniel M. Kammen & David M. Hassenzahl, Should We Risk It: Exploring Environmental, Health, And Technological Problem Solving, Christopher Verni

RISK: Health, Safety & Environment (1990-2002)

A review of the book Should We Risk It: Exploring Environmental, Health, and Technological Problem Solving by Daniel M. Kammen & David M. Hassenzahl, (Princeton University Press 1999). Preface, acknowledgments, introduction, appendix, index. ISBN: 0-691-00426-9 [404 pp. $39.50. Cloth, 41 William Street, Princeton, NJ 08540].

Commercial Irrigation And Nutrition Practices For Strawberries In Western Australia, D. Phillips, D. Gatter, T. Calder, D. Pitman

Horticulture research reports

Irrigation practices employed by five commercial strawberry growers on sandy soils of the Swan Coastal Plain near Perth Western Australia were monitored for two consecutive seasons, 1995 and 1996 during the Spring production period.

Nutritional practices for the same grower group plus one Albany grower were monitored by plant, soil and sap analysis at 14 day intervals throughout the 1996 season.

Irrigation records showed that market quality strawberries could be produced at this time of year (August to December in Perth) on soils with very poor water retention properties with an average crop factor(E Pan) for the season of 0.7 …