Digital Commons Network^™

Competing Supramolecular Forces: Boron Coordination Vs Π-Π Stacking, Sidhaesh A. Agarwal, Gonzalo Campillo-Alvarado, Nicholas Lutz, Jesus Daniel Loya, Eric W. Reinheimer

Student Research Symposium

This study explores the impact of fluorination levels in azopyridine Lewis bases on their ability to direct the formation of B←N coordination adducts or cocrystals with phenylboronic ester. We hypothesize that the degree of fluorination can be used as a tool to control the outcome of supramolecular bonding competition, thus influencing complex self-assembly.

A series of azopyridines with varying degrees of fluorination were synthesized and reacted with phenylboronic ester. Their structures were analyzed using Hartree-Fock calculations, Hirshfeld surface analyses, and single crystal X-ray diffraction to assess the impact of fluorination on supramolecular interactions.

The study reveals that azopyridines with up …

Community Responses To Us Regional Clean Hydrogen Hubs, Bethani Turley

Student Research Symposium

In 2023, the Bipartisan Infrastructure Law designated 7 billion dollars to fund regional hydrogen hubs across the US with the goal of kickstarting a utility scale hydrogen economy for the US electric grid. A promising technology in the renewable energy transition, hydrogen can be made from a multitude of energy sources, often designated by colors: green hydrogen is made from solar and wind, pink hydrogen from nuclear, and blue hydrogen from natural gas. This presentation examines this new hydrogen economy through the case study of the Appalachian Regional Clean Hydrogen Hub (ARCH2). ARCH2 is a blue hydrogen hub proposal by …

Photocathodes From Aerobic Oxidation Of Tellurorhodamines, Amelia Jellison

Student Research Symposium

Contemporary dye-sensitized solar cells are far less efficient than silicon solar panels, therefore this project seeks to develop an improved dye sensitized photocathode. Tellurorhodamine dyes, including mesityl derivatives and tellurium black, have been chosen to increase efficiency through increased light harvesting. The photophysical and electrochemical properties of tellurorhodamines with varying structures are analyzed to quantify its efficiency to serve as a dye sensitized photo cathode. Dyes undergo aerobic oxidation facilitated by light, the absorption profile is obtained before and after. Mesityl derivatives are known to experience significant red-shifting following aerobic oxidation. At its base oxidation state, tellurium black experiences an …

Exploring The Potential Of Α-Aryl Substitution Of Gddota To Address Challenges Associated With Mri Contrast Agents., Charlene I. Kupara

Student Research Symposium

Gadolinium chelates have found widespread application as contrast agents in Magnetic Resonance Imaging (MRI) a cornerstone in modern medical diagnostics. In recent years two significant challenges have emerged to the use of Gd³⁺ chelates in MRI:

• The safety of these Gd³⁺-based agents, specifically related to the possible in vivo release of Gd³⁺.
• The environmental impact of anthropogenic Gd³⁺ pollution of surface waters arising from using contrast agents.

The escalating reports of Gd³⁺ presence in environmental matrices, and its adverse effects on marine life and human health, necessitate urgent intervention to mitigate consequential environmental …

Fireflies At Rpa Natural Area Final Report, Olivia H. Bush, Sydney M. Shea, Sofia J. Gordon, Nick S. Wiebke

Final Reports in ENST 411: Environmental Community Projects

Our group worked alongside community partners Shaunna Barnhart and Jim Dunn during the Spring 2024 semester to assist with their annual event Fireflies at RPA Natural Area. RPA Natural Area is a local park in South Williamsport, Pennsylvania that was recently acquired by Southside Recreational Authority. Since taking over the park, the organization has begun hosting an event each July to educate the general public about firefly biology and conservation by showing a film and guiding attendees through a firefly tour through the park. Our goals for this project included creating physical educational materials to be used at the park …

Major Axes Of Variation In Tree Demography Across Global Forests, Melina De Souza Leite, Sean M. Mcmahon, Paulo Inácio Prado, Stuart J. Davies, Alexandre Adalardo De Oliveira, Hannes P. De Deurwaerder, Salomón Aguilar, Kristina J. Anderson-Teixeira, Nurfarah Aqilah, Norman A. Bourg, Warren Y. Brockelman, Nicolas Castaño, Chia-Hao Chang-Yang, Yu-Yun Chen, George Chuyong, Keith Clay, Álvaro Duque, Sisira Ediriweera, Corneille E. N. Ewango, Gregory Gilbert, I. A. U. N. Gunatilleke, C. V. S. Gunatilleke, Robert Howe, Walter Huaraca Huasco, Akira Itoh, Daniel J. Johnson, David Kenfack, Kamil Král, Yao Tze Leong, James A. Lutz, Jean-Remy Makana, Yadvinder Malhi, William J. Mcshea, Mohizah Mohamad, Musalmah Nasardin, Anuttara Nathalang, Geoffrey Parker, Renan Parmigiani, Rolando Pérez, Richard P. Phillips, Pavel Šamonil, I-Fang Sun, Sylvester Tan, Duncan Thomas, Jill Thompson, María Uriarte, Amy Wolf, Jess Zimmerman, Daniel Zuleta, Marco D. Visser, Lisa Hülsmann

Wildland Resources Faculty Publications

The future trajectory of global forests is closely intertwined with tree demography, and a major fundamental goal in ecology is to understand the key mechanisms governing spatio-temporal patterns in tree population dynamics. While previous research has made substantial progress in identifying the mechanisms individually, their relative importance among forests remains unclear mainly due to practical limitations. One approach to overcome these limitations is to group mechanisms according to their shared effects on the variability of tree vital rates and quantify patterns therein. We developed a conceptual and statistical framework (variance partitioning of Bayesian multilevel models) that attributes the variability in …

A Spatial Decision Support System For Rent Estimation Of Retail Spaces In Manhattan Using Geographically Weighted Regression And Spatial Regression, Andie M. Migden Miller

Theses and Dissertations

This report outlines an automated, three-phase Spatial Decision Support System that creates models to estimate rent of retail spaces across Manhattan. First, enrich data with predictors. Second, optimize spatially aware neighborhood-level models by combining GWR, spatial regression, and non-spatial regression. Finally, visualize results in an Esri-based WebApp.

Pre-Plinian Perplexity: Identifying And Constraining An Anomalous Pdc During The Initial Stages Of The May 18, 1980 Mt. St. Helens Eruption, Justin Crevier

Geosciences Undergraduate Theses

The Mount St. Helens (MSH) 18 May 1980 eruption was a formative event for a generation of volcanologists. With so much data available from detailed studies of the Blast and Plinian phases, MSH could aptly be called one of volcanology's greatest teachers—and the volcano may yet have more to teach us. The transition period, which occurred between the end of the Blast phase (0830) and the beginning of the Plinian phase (0920) on the morning of May 18, 1980, has not yet benefited from the same degree of comprehensive review as either of those phases. The conditions which caused the …

Magdm Model Using Single-Valued Neutrosophic Credibility Matrix Energy And Its Decision-Making Application, Jun Ye, Rui Yong, Wanlu Du

Neutrosophic Systems with Applications

This paper aims to develop a MAGDM model using single-valued neutrosophic credibility matrix (SVNCM) energy in a SVNCM scenario. To do it, first, SVNCM energy and its score function are presented as a conceptual extension of existing single-valued neutrosophic matrix (SVNM) energy. Then, a MAGDM model is developed in terms of SVNCM energy and its score function in a SVNCM scenario and also its decision algorithm is provided to solve MAGDM problems with SVNCMs. Finally, the developed MAGDM model is applied in the school site selection problem as an actual example, then the comparative investigation of the decision results in …

Grey Relational Analysis And Canonical Correlation Analysis Of Air Pollution In Three Kentucky Counties, Sarah Hartman

Masters Theses & Specialist Projects

Air pollution is a crucial factor that affects both the environment and public health. Various methods are available for assessing air quality and pollution levels, such as regression models, principal component analysis, and factor analysis tools. However, some of these methods present issues in multicollinearity and the nature of collected data. It is important to recognize that air pollution data is often uncertain, incomplete, and contains limited valid data points. Weather conditions and economic activities are also factors that can affect air pollution. With growing communities in Kentucky (KY), it is essential to address these factors as the state has …

Green At Eye Level: From Measurement Approaches To Simulated Models And Inequality Assessments In U.S. Major Cities, Jingjing Yan

Graduate Theses and Dissertations

This dissertation delves into the multifaceted dynamics of urban greenness, addressing critical aspects of sustainable urban development. Providing urban green spaces has been widely acknowledged to offer numerous benefits to individuals and communities. Recently, there has been a growing recognition of the importance of evaluating urban greenness from a human-centered perspective, partly due to the rapid development of eye-level greenness measurement. First, to provide a comprehensive overview of measurement approaches and topics related to eye-level urban greenness, a systematic review of 77 papers was conducted in this research. This review revealed that street view images are the primarily utilized data …

Framing Wildlife Conservation: Exploring Political Bias In States' Wildlife Action Plans, Ciara Nelson

Department of Environmental Studies: Undergraduate Student Theses

Climate change affects regions of the United States differently due to factors such as the country's diverse physical landscapes, political environments, and population distributions. This variation leads to varying impacts on humans, wildlife, and ecosystems, with anthropogenic climate change—acknowledging humans as a significant contributor—being a point of contention, especially among some prominent politicians. The relationship between political party affiliation and climate change acknowledgment is evident, with recent political discourse highlighting differing views on the severity of climate change. This political framing influences how environmental policies are perceived and accepted, with the choice of language and framing playing a crucial role …

Opportunities For Urban Resilience To Climate Change: Understanding Local Climate Perceptions, Motivations, And Barriers To Green Infrastructure Use, Emmilene Berski

Department of Geography: Dissertations, Theses, and Student Research

Global climate change poses a substantial threat to cities in the United States, particularly through increases in flooding and extreme heat. Cities must adapt to these threats to preserve their residents’ livelihoods and prevent economic loss. One adaptation strategy is the implementation of green infrastructure (GI). The opportunity for GI to foster urban resilience to climate change necessitates a deeper understanding of the extent to which cities utilize GI as a strategy for local climate change adaptation as well as perceptions and motivations surrounding the use of GI at a local level. I sought to address this need through a …

Predicting The Effects Of Precipitation On Groundwater Contamination Near Capped And Uncapped Coal Ash Storage Facilities In Louisville, Kentucky., Daryl Jialiang Chen

Electronic Theses and Dissertations

This study examines the impact of rainfall event characteristics and water table elevations on arsenic and boron contamination in groundwater near two coal ash ponds in Louisville, Kentucky. Utilizing data from 2011 to 2019, the research focuses on both capped and uncapped ponds at Mill Creek and Cane Run sites, employing Threshold Analysis, Regularized Discriminant Analysis (RDA) and Random Forest (RF) to assess contamination levels in groundwater. Analysis shows that capped ponds generally exhibit reduced arsenic levels, though variations exist depending on the contaminant and site. Key predictors such as maximum precipitation and river height were identified, highlighting their significant …

Educational Influences On Environmental Perception: A Semester Analysis Of The New Ecological Paradigm Scale In Undergraduates, Zoe Zingler

Department of Environmental Studies: Undergraduate Student Theses

This study evaluated the impact of a geography course, GEOG 181: Global Environmental Issues, at the University of Nebraska-Lincoln on students’ endorsement of the New Ecological Paradigm (NEP) using a pre-course and post-course NEP scale survey. Analyzing paired responses (n = 40) through t-tests and z-scores, only four of 15 statements had statistically significant shifts observed for the entire sample. However, a targeted analysis of students initially possessing lower endorsement of the NEP—early deniers—revealed significant paradigm shifts post-course. While women initially showed stronger NEP endorsement, men demonstrated notable changes following the course towards endorsement of the NEP. Academic majors, whether …

Aspirations Incubator: 2017–2023 Final Evaluation Report, Sarah Goan, Elora Way, Emma Schwartz, Becky Wurwarg

Publications

The Rural Futures Fund launched the Aspirations Incubator in 2017 as a six-year pilot initiative aimed at supporting youth development in rural Maine by increasing resiliency, fostering connections to communities, and expanding students’ awareness of opportunities beyond their everyday environments. The program partnered with select rural youth organizations to build capacity for mentoring-based programs serving students from seventh grade through high school graduation. Guided by the Trekkers Youth Programming Principles, the initiative focused on long-term mentorship, meaningful relationship-building, and community engagement. A comprehensive multi-year evaluation conducted by the Data Innovation Project at the University of Southern Maine examined the implementation …

Water Justice And Equity: The Disproportionate Effects Of Pollution On Black, Indigenous, And Other Communities Of Color, Rae Cade

Theses, Dissertations and Culminating Projects

Access to clean drinking water is a basic human right, regardless of an individual’s background. Yet, discriminatory practices in the United States have disproportionately burdened Black, Indigenous, and other people of color (BIPOC) with contaminated sources of water. Understanding how and why water is disproportionately contaminated in areas with increased diversity, and identifying and targeting areas of environmental injustice, are essential steps for ensuring future water equity. Here, I examine the drivers of inequitable access to clean drinking water within the northeastern United States. In chapter one, I look at the historical drivers of land inequity within the United States. …

A Global Analysis Of Carbon And Nitrogen Stocks In Natural And Anthropogenic Soils, Shih-Chieh Chien

Theses, Dissertations and Culminating Projects

In terrestrial biomes, soils possess the highest amount of carbon and nitrogen stocks that regulate biogeochemical processes and provide ecosystem services. The amount of carbon and nitrogen stored in soils, as a balance of nutrient influxes and outfluxes, is controlled by various environmental and soil factors, while at the same time soil carbon and nitrogen stocks can be subject to anthropogenic impacts, like nutrient storage in urban soils. To inform a better, general understanding of carbon and nitrogen distribution in urban soils, the present dissertation gathers four articles (from Chapters 2 to 5, respectively) addressing different aspects of the issue, …

Evaluation Of Heavy Metal Pollution, Water Quality, And The Effectiveness Of Remedial Sediment Dredging In The Lower Passaic River, New Jersey, Oluwafemi Soetan

Theses, Dissertations and Culminating Projects

Toxic metal pollution is a leading environmental concern for aquatic systems globally and remedial dredging has been widely employed to mitigate its harmful impacts. In terms of the short-term impacts of remedial dredging, mixed results are reported in several studies. Despite its immediate negative impacts including saturation of water with toxic metals, increased turbidity, and sediment resuspension, positive impacts can be recorded over a stabilization period of 6 – 24 months after dredging. Nevertheless, the sustainability of these recorded positive effects cannot be ascertained as some studies have reported long-term regression in remediated sites’ conditions. Evaluation of success determinants, site-measure …

Barrier Removal Prioritization To Increase Climate Resiliency And Aquatic Connectivity For Communities In The Upper Susquehanna Basin, Cassandra Mae Davis

Legacy Theses & Dissertations (2009 - 2024)

The streams and rivers of the Upper Susquehanna Basin have been heavily modified over centuries through deforestation of nearshore areas and creation of physical barriers, such as dams and culverts. Dams and undersized culverts negatively affect aquatic organisms by modifying habitat conditions and restricting movement of these organisms. In addition, improperly maintained dams and undersized culverts can intensify flooding impacts and negatively affect water quality. A standardized method is needed to determine which barriers should be prioritized for assessment and potential replacement or removal based on multiple ecosystem and societal factors. The goal of this analysis was to have a …

Evaluating And Enhancing The New York State Mesonet (Nysm) Snow Accumulation Estimation, Christopher Gilberti

ALL - Honors Theses

This research project aims to examine and enhance the performance of the New York State Mesonet (NYSM) Snow Accumulation Estimation. The NYSM is a state-of-the-art network of 126 standard weather stations located across the state of New York, collecting high-quality meteorological data to improve forecast accuracy, reduce uncertainty, and mitigate harm. All NYSM standard stations measure snow depth with Campbell Scientific’s SR50A ultrasonic distance sensor. This acoustic sensor measures the distance from the sensor to a rigid snowboard if there is no snow on the ground or the top of snow layer. A reference distance and a temperature correction are …

Spatiotemporal Negative Inventory Outlier Decomposition For Supply Chain Applications In Consumer-Packaged Goods (Cpg), Hayden Mcdonald

Data Science Undergraduate Honors Theses

Coca-Cola is a popular soft drink brand with sales occurring in every Walmart store across the world, which generates large quantities of data and requires a robust supply chain system. However, the company does not currently have a sophisticated, automated, and/or prescriptive system for detecting where, when, and why inventory outages occur and applying preventative measures to avoid loss of revenue from the absence of inventory on store shelves. This thesis proposes and applies a novel, prescriptive system for this purpose. An inventory outage can be seen as a ‘negative’ statistical outlier in a time series of inventory for an …

A Spatiotemporal Analysis Of Violent Crime In Little Rock, Arkansas From 1999-2022, Nicole Rogers

Data Science Undergraduate Honors Theses

Little Rock, Arkansas is not only the capital and largest city in Arkansas, but it has one of the highest crime rates amongst cities with over 100,000 people in the country. According to the US Census in 2020, Little Rock had a population of 202,591. In the same year, Little Rock Police Department recorded 3,567 cases of violent crime, leading to a violent crime rate of 1,805 violent crime occurrences per 100,000 people. For perspective, Chicago’s violent crime rate was approximately half of that of Little Rock during the same time period. Crime, like other social phenomena is unevenly distributed …

The Effect Of Agrivoltaics On Irrigation Water Consumption In Central California, London Camba

Undergraduate Theses

An agricultural system where solar energy generation and agricultural systems are used together for mutual benefit, agrivoltaics reduces loss of water due to evaporation, particularly in drylands. Central California has faced extreme droughts, and water has become a scarce resource. However, the wide-scale use of agrivoltaics has been limited due to lack of knowledge about agrivoltaics and also the lack of funding for start-up agrivoltaics projects. Therefore, this research investigated the potential for agrivoltaics in Central California to reduce irrigation water consumption using a review of multiple crop studies using agrivoltaics to determine an optimal crop for agrivoltaics and a …

A Compilation, Analysis, And Categorization Of 403 Atmospheric And Climate Science Misconceptions, Haeli Leighty

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

The National Association of Geoscience Teachers (NAGT) has listed the inaccessibility of research related to misconceptions in atmospheric and climate science as a Geoscience Education Research Grand Challenge (Cervato et al. 2018). This project was a direct response to this call for research and consisted of three distinct steps: 1) data gathering, which included reviewing the literature for relevant misconception data, 2) a qualitative analysis, which included compiling, organizing, and categorizing the data collected, and 3) a quantitative analysis, which included determining the prevalence of each misconception across topic categories, demographic categories, and over time. A total of 403 misconceptions …

Microwave Emission Model Parameter Tuning For Surface Soil Moisture Retrieval Using Uav-Mounted Dual Polarization L-Band Radiometer, Santiago Hoyos Echeverri

Open Access Theses & Dissertations

Surface soil moisture retrieval from L-band brightness temperature has been developed for the past decades due to multiple beneficial characteristics of 1-2 GHz frequency bands for remote sensing of the environment. Numerous microwave emission models have been proposed for tower and satellite-based operations with successful retrieval of surface soil moisture and vegetation water content. As a result of the development of cost-effective and low-mass microwave L-band radiometers such as the Portable L-band Radiometer (PoLRa), surface soil moisture surveying traditionally developed by satellite missions SMOS and SMAP can now be developed at local scales, bringing these operations to commercial small unmanned …

Magdm Model Using Single-Valued Neutrosophic Credibility Matrix Energy And Its Decision-Making Application, Jun Ye, Rui Yong, Wanlu Du

Neutrosophic Systems with Applications

This paper aims to develop a MAGDM model using single-valued neutrosophic credibility matrix (SVNCM) energy in a SVNCM scenario. To do it, first, SVNCM energy and its score function are presented as a conceptual extension of existing single-valued neutrosophic matrix (SVNM) energy. Then, a MAGDM model is developed in terms of SVNCM energy and its score function in a SVNCM scenario and also its decision algorithm is provided to solve MAGDM problems with SVNCMs. Finally, the developed MAGDM model is applied in the school site selection problem as an actual example, then the comparative investigation of the decision results in …

The Effects Of Using Machine Translators On The Performance Of Second Language Learners, Kasey Myer

University Honors College

With the rise of technology has also come the development of various online language translators and artificial intelligence that are often utilized by individuals learning a second language. However, there is a wide range of quality between the different machine translation tools, and many people tend to be under the impression that it is inferior to the quality of interpretations provided by human translators. This paper considers the positives and negatives of machine translation as a tool for second language learning. Variations between the input and output languages on a grammatical and cultural level are analyzed. Machine translation is compared …

College Of Natural Sciences Newsletter, Spring 2024, College Of Natural Sciences

College of Natural Sciences Newsletters and Reports

Page 1 Dean's Message
Page 2 New Faculty and New Club on Campus
Page 3 2024 URSCAD Awards
Page 4 Day of Scholars 2024
Page 5 SDSU's First Representation at the Association for Anatomy's 2024
Annual Conference
Page 6-7 2024 Honor's College Convocation
Page 8 Other Student Activities
Page 9 Faculty Awards
Page 10-11 Other News
Page 12 2024 Drone Day and American Association of Geographers Convention - Hawaii
Page 13 55th Annual Geography Convention
Page 14 2024 Stethoscope Ceremony
Page 15 Open PRAIRIE Data

Agricultural Groundcover Update March 2024, Justin Laycock

Natural resources published reports

• In March, over 10% (1,577,000 ha) of the arable farmland in the south-west of Western Australia had less than 50% vegetative groundcover, which is inadequate to prevent wind erosion.

• The northern grainbelt had the highest risk of wind erosion and over 20% of this farmland had inadequate groundcover.

• About 1.3% (191,000 ha) of arable land had a high to very high risk of wind erosion because groundcover was less than 30%.