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The Chemical Effects Of Gamma Radiation On Halogenated Methanes, Clifford G. Shultz

Chemistry and Chemical Biology ETDs

The fundamental processes of radiation chemistry and photochemistry are quite parallel, and any consideration of one must include the theory of the other as well. Probably the first work done in photochemistry was that of Stephen Hales on photosynthesis, between 1677 and 1721. This was followed by descriptions of the action of light on silver salts by Schultz, Beccarius, and Scheele. The latter also demonstrated that the action of light on silver chloride varied with the waveleneth of the light. Grotthus, in 1817, stated the first law of photochemistry: Only that light which is absorbed can give rise to a …

Internal Friction In Manganese Copper Alloys, William Paul Dixon

Masters Theses

"The study of the physical properties of the manganese-copper alloys is an intriguing one. These alloys show promise of usefulness in instances in which high internal friction is needed to reduce the noise and vibrational stresses at resonant frequencies of a part of a machine. The purpose of this study has been to learn more about the internal friction of manganese-copper alloys as a function of temperature, stress amplitude, frequency, time, and past history of the specimen. From this information the mechanism for absorption of vibrational energy is proposed, or at least some progress has been made toward its determination. …

The Phosphoria Formation Of The Northeastern Big Horn Basin, Wyoming, William A. Beatty

Masters Theses

"Purpose and Scope. — The Phosphoria formation of the northern Rocky Mountains of the United States has received considerable attention from geologists because of its important reserves of phosphate and petroleum. In the Big Horn Basin of Wyoming, however, still more work is needed to compile the information necessary for a complete understanding of the facies changes exhibited by this formation.

The purpose of this paper is two-fold: first to present a description of the lithology and the paleontology of the Phosphoria formation in the northeast part of the Big Horn Basin, and secondly to show the stratigraphic relationship of …

A Probe For Measuring Ultrasonic Pressures, Robert F. Rohrer

Masters Theses

"In the study of acoustics, the term ultrasonics is defined as those wave motions that have frequencies greater than about 20,000 cycles per second. The characteristics of a sound wave at any point in a medium can be regarded as completely defined when the amplitude, frequency, and phase of its Fourier components are known.

Sound measurements at their best are difficult. In the last few years sensitive linear microphones and electronic amplifiers have become available. Still, there are two difficulties of prime importance with their use in a sound field. First, there is the precise, absolute calibration of the equipment …

Thermal Reaction Of Hydrogen And Oxygen In Small Bore Tubes, Shib Charan Chattoraj

Theses and Dissertations

The thermal reaction of hydrogen and oxygen has been investigated from the standpoint of the important intermediate hydrogen peroxide in the region between 620-720 degrees centigrade in small bore Pyrex and steel tubes. The minimum explosion-temperatures with different flow rates and compositions of the mixture have been determined. They have been found to vary with the composition and flow rate of the mixture. The minimum explosion temperature is also found to vary with the condition of the reaction tube surface. The yield of hydrogen peroxide has been determined as a function of temperature, contact time, composition of feed stream, and …

A Geological Study Of The Irvine Ranch Area, Johnson And Campbell Counties, Wyoming, Gale E. Butterfield

Masters Theses

"The discovery of uranium in the Powder River Basin, Wyoming, by the U. S. Geological Survey in 1952 has lead to an extensive exploration program throughout the region by both private and governmental agencies. This report is a geological study of an area in the southwestern part of the basin.

Geological and radiometric mapping carried out as a part of this report indicated several areas of uranium occurrence. Some of these occurrences warrant tests by drilling.

Mineralogical and petrographic study has shown the principal uranium minerals to be carnotite and metatyuyamunite. The mineralization occurs in arkosic sandstones. Assays of the …

Transference Numbers Of Concentrated Manganous Chloride Solutions, Marshall L. Severson

Masters Theses

"Electrolytic conduction differs from metallic conduction only in the nature of the carrier of the current. In the case of metallic conduction the carrier is electrons. The passage of an electric current through an electrolyte occurs only by the movement of ions of opposite charge moving in opposite directions under an applied potential. The current carried by a particular ionic species is a direct function of the concentration, the charge on the ion, and the ionic mobility. A transference number is the fraction of the total current a given ion carries in a particular electrolyte undergoing electrolysis. The sum of …

Some Thermodynamic And Structural Properties Of A Linear Chain Of Atoms, And Extension Of The Model To Two- And Three-Dimensional Cases, Hari Gopal Mukerjee

Masters Theses

"An attempt has been made in the present work to derive some thermodynamic and structural properties of a linear chain of atoms (under somewhat idealized conditions) moving in the fields of nearest neighbours and assuming a parabolic well in the interaction of pairs within the range of relative movements. The equation of state and other formulas derived are applicable only to the linear model which could be considered as a simplified form of one-dimensional crystals in the form of chain-like molecules of rubber-like substances. An attempt has also been made to extend the model to two- and three-dimensional cases"--Introduction, page …

Detection Of Low Energy Positive Ions By Scintillation Methods, Graydon J. Hanson

Masters Theses

"This thesis deals with the feasibility of efficiently detecting low energy positive ions, those with energies of less than several hundred electron volts, using phosphors.

The scintillation technique, first used visually and greatly improved in the last ten years by the use of a photomultiplier tube, has greatly advanced detection in high energy fields. The photomultiplier is capable of delivering milliampere pulses of current of short duration and these can be registered directly by the many electronic devices currently in use.

Extensive work has been done with phosphors which scintillate under which energy bombardment, due in part to their wide …

The Synthesis Of 7-Methyl-3,4-Benzpyrene, 6,7-Dimethyl-3,4-Benzpyrene, 10-Methyl-3,4-Benzpyrene And 7,10-Dimethyl-3,4-Benzpyrene, Joseph Leonard Comp Jr.

Chemistry and Chemical Biology ETDs

Interest in carcinogenic compounds began to develop when a form of cancer was found occurring in chimney sweeps in 1775. Skin cancer was found among workers in tar industries in 1875, and in 1887 workers in cotton spinning industries were known to have cancer which was attributed to contact with lubricating oils. Girls who painted the luminous dials of watches contracted cancer from exposure to the radioactive paint, and men who worked with B-naphthylamine developed bladder cancer. Many other cases of occupational cancer were reported before a systematic study of carcinogenic substances was begun. Early attempts to produce cancer in …

A Comparison Of The Accuracy Of Finite Difference Methods And Variational Methods In The Numerical Solution Of Partial Differential Equations, Robert F. Brodsky

Mathematics & Statistics ETDs

The purpose of this thesis is to investigate some of the numerical methods available to solve partial differential equations intractable to analytic solutions with a view towards: 1. Indicating where particular methods appear most applicable, from the standpoints of accuracy, easy of solution, minimum expenditure of effort; and 2. Indicating the accuracy to be expected in the use of two of the more powerful methods investigated as applied to a problem of elasticity.

The Monadnock Volume 31, Number 1, December 1956, Clark University Geographical Society

The Monadnock (Clark Geographical Society)

Volume 31, Issue 1 of The Monadnock. The Monadnock was the alumni magazine of the Clark University Geographical Society (1927-1985) (2014-present).

Oxidation Of Molybdenite With The Aid Of Microorganisms, Ralph Anderson

Theses and Dissertations

This work represents a study on the biological oxidation of molybdenite, MoS2. The principal objective of this study was to investigate the possibility of the biological oxidation of molybdenite, to determine the physical and chemical conditions under which the oxidative process occurs, and to develop a strain of bacteria or alter the activity of the microorganisms by acclimatization to increase their activity on sulfide minerals, in particular molybdenite. Minerals used in this study were pyrite (FeS2), chalcopyrite (CuFeS2), molybdenite concentrate, and molybdenite ore. The microorganisms used in this investigation were autotrophic bacteria obtained from the leaching streams of Bingham Canyon, …

The Instability Constant Of The Cobaltous Citrate Complex Ion Using Cobalt-⁶⁰ As A Tracer, Lee T. Cox

Theses and Dissertations

The instability constant of a substance shows the tendency of a substance to dissociate into simple ions. The stability of the substance can be related to stabilities of other substances through the instability constant. Schubert gives a method for the determination of the instability constant which involves measurements of the adsorption of a radiotracer cation on a cation exchange resin. Two different types of resin were employed in this research. It was found that with a resin containing carboxylic acid exchange groups the adsorption of the cobaltous ion changed rapidly with pH but with a resin containing nuclear sulfonic acid …

A Correlation Of The Catalytic Activity Of Various Mixtures Of Rhenium And Molybdenum Sulfides In Liquid-Phase Hydrogenation Of Certain Reducible Organic Groups, Li-Chen Hsu

Theses and Dissertations

The promoter action of mixtures of catalysts has been reported in literature to be valuable in industries. Whether mixtures of rhenium and molybdenum sulfides would have promoter actions in the hydrogenations of certain reducible organic groups was the main object of this research. Mixtures of rhenium and molybdenum sulfides of various compositions were prepared by three different methods, i.e., (a) by saturating perrhenate and molybdate with hydrogen sulfide in hydrochloric acid solutions, (b) in ammonium hydroxide solutions followed by acidification, and (c) by treating perrhenate and molybdate with thiosulfate in dilute sulfuric acids followed by extraction with toluene to remove …

Photo-Oxidations Sensitized By Physiologically Important Substances, Ernel D. Ihnen

Theses and Dissertations

A study of the photo-oxidation of the 2,6-dichlorophenol indophenol-ascorbic couple was undertaken with a view to investigating the postulated mechanism of oxidation by a component of the oxygen evolving sequence operative in photosynthesis. A spectrophotometric method for the measurement of the progress of photo-oxidation was developed. Temperature and pH dependence were determined and the effect of various common inhibitors and physiological substances tested. None of the common Hill reaction inhibitors were effective in the ascorbic acid photo-oxidation in the system used. KCN and catalase as well as a few other high molecular weight proteins were able to inhibit dark auto-oxidation …

The Vertical Gradients Of Ozone Concentration And Its Relation To The Eddy Coefficient Of Diffusion, Joseph Levine

Physics & Astronomy ETDs

The purpose of this thesis is to apply this method to a tentative evaluation of the eddy coefficient of diffusion. Actually the investigation was more specifically an attempt to relate the difference in ozone concentration between the two stations to the average wind shear and to the vertical thermal stability.

Geology And Ground-Water Resources Of The Portales Valley Area, Roosevelt And Curry Counties, New Mexico, Sherman E. Galloway

Earth and Planetary Sciences ETDs

Since 1910, and particularly since the closing years of World War II, considerable development of the ground water occurring in the valley fill has been made for irrigation purposes. This increase in development has resulted in a progressive decline of the water levels in this area. The results of this study indicate that the water occurring in the valley fill is the only water of good chemical quality occurring in the Portales Valley that can be obtained in quantities that are sufficient for normal irrigation, municipal, industrial, stock, and domestic uses, and that if the present rate of ground water …

A Study Of Isotopic Exchange Between Potassium Iodide And Benzyl Iodide. Solvent Effects, Joseph A. Leary

Chemistry and Chemical Biology ETDs

The kinetics of nucleophilic aliphatic substitution reactions has been studied by numerous investigators during the past fifteen years. Included in this type of reaction are well-known general reactions such us (1) the Finkelstein reaction, (2) the Menschutkin reaction, (3) the alcoholysis of alkyl halides, and (4) various isotopic exchange reactions.

Geology Of The Rinconada Canyon Area, Valencia County, New Mexico., John Mohar Jr.

Earth and Planetary Sciences ETDs

Within this area are found two small domes superimposed upon the McCarty syncline. North dome, the larger of the two, is located at the head of Rinconada Canyon. South dome is located in the southern part of the area near the mouth of the canyon. Thus far the mineral resources of the area have been of little economic value. There are, however, large deposits of commercial uranium deposit at depth which cannot be disregarded.

Beta And Gamma Distributions, Calvin Rogers

Mathematics & Statistics ETDs

The purpose of this paper is to exhibit the main properties of Gamma and Beta distributions and show their relation to certain well known distributions.

In chapter II the Gamma and Beta distributions are defined in terms of Gamma and Beta functions. The moments of these distributions are calculated, and the moment generating function and cumulant generating function for the Gamma distribution are obtained. The curves are classified with respect to parameter values and the curves are graphically illustrated in Figures 1, 2, and 3. The exponential distribution, as a special case of interest, is shown to be a Gamma …

Geology Of The Central Front Of The Fra Cristobal Mountains, Sierra County, New Mexico, Richard C. Jacobs

Earth and Planetary Sciences ETDs

This report includes about seven square miles of the central front of the Fra Cristobal Mountains. The area contains rocks from Precambrian, Cambrian, Pennsylvanian, and Quaternary Age. Fragmentary exposures of the Permian sedimentary rocks are also present.

Geology Of The White Rock Mountain Area, Gunnison County, Colorado, David L. Gaskill

Earth and Planetary Sciences ETDs

The White Rock Mountain area in central-western Colorado is included in the northwest corner of the Crested Butte quadrangle and the extreme southwest corner of the Aspen quadrangle. Mineral deposits were recognized in the early seventies, and in the literature the area is referred to as the Elk Mountain District.

An Indicator Of Position With Respect To The Earth's Magnetic Field, Lloyd C. Nielsen

Physics & Astronomy ETDs

A large amount of experimental research in the field of atmospheric physics involves carrying apparatus aloft by means of balloons. Data from balloon-borne instruments may be obtained either by recovery of the apparatus or by radio telemetering during the flight. Of these two methods, the latter is of course the more convenient and reliable, since recovery of the apparatus is time-consuming and often impossible.

The Motion Of A Charged Particle In Homogenous Time-Varying Magnetic Field, Thomas R. Bates

Physics & Astronomy ETDs

This paper will discuss the motion of a non-relativistic, non-radiating charged particle in an infinite homogeneous magnetic field which varies linearly with time. We shall assume the motion to be confined to a plane perpendicular to the magnetic field.

The Use Of Kamke's Transformation In Approximating The Zeros Of Orthogonal Polynomials, Robert L. Daniels

Mathematics & Statistics ETDs

The importance of the classical orthogonal polynomials has long been acknowledged. It has not been possible, however, to represent them in such a way that all of their important properties are immediately evident. In particular, the location of the zeros of these polynomials is of considerable interest.

This thesis is primarily concerned with a different technique in which Kamke's transformation is applied to the differential equations frequently used to define these polynomials. The resulting trigonometric differential equations cannot be explicitly solved either, but certain characteristics of these solutions facilitate the derivation of approximations to the zeroes of the solutions.

Geology Of The Canjilon Cauldron Sink Near Bernalillo, Sandoval County, New Mexico, Felix E. Mutschler

Earth and Planetary Sciences ETDs

Canjilon Hill is located on the west side of the Rio Grande, about 2 3/4 miles north-northwest of Bernalillo. Exposed on the hill is a local unit of breccia, conglomerate, and sandstone, which forms an elongate saucer-shaped body 4100 feet long, 2200 feet wide and 280 to 500+ feet thick. Unlike the underlying Santa Fe formation these strata contain an abundance of large angular basalt pebbles, cobbles, and boulders. In this paper these strata are termed the Canjilon formation of the Santa Fe group. Structural and sedimentological evidence suggest that the Canjilon formation was deposited in a subsidence depression initiated …

Paleozoic Stratigraphy Of The Mud Springs Mountains, Sierra County, New Mexico, John Davis Hill

Earth and Planetary Sciences ETDs

This thesis gives a history of the terminology of each of the formations found in the Mud Springs Mountains as well as a discussion of the characteristics of each. The Mud Springs Mountains Section of Paleozoic rocks is 3660 feet thick. Parts of all the Paleozoic systems are represented except the Silurian and Mississippian. The Bliss sandstone is 145 feet thick, the lower 65 feet being late Cambrian and the upper 80 feet being early Ordovician. The El Paso limestone of early Ordovician age is 460 feet thick.

Calorimetric Heats Of Mixing Of Some Nonelectrolytic Binary And Ternary Solutions, James Bevan Ott

Theses and Dissertations

The heat of mixing of nonelectrolytic liquids is important in predicting the type of molecular interactions which exist in solutions of nonelectrolyted. The problem was to construct a calorimeter in which these heats of mixing could be measured accurately. Once constructed, the calorimeter was used to measure the heats of mixing of some binary and a ternary solutions. The systems chosen for study were the three liquid pairs formed between benzane, carbon tetrachloride, and cyclohexane, and the ternary mixture of the three. The results of the experimentation are summarized by the following equations. (1) H_12^M = X_1x_2 [103.2 + 13.1(x_1 …

The Instability Of Folded Structures, Robert Del Mar

Earth and Planetary Sciences ETDs

Folded structures are not necessarily stable through geologic time. "Unfolding" is defined as the changes in attitude through with folded structures go subsequent to their creation by tectonic means, other than by faulting alone. The principal types of unfolding, together with their causes, are: (1) the effect of gravity on isolated structures, and the effects of loading and unloading insofar as the gravitational force is concerned; (2) basining action and its effect on unloading; (3) the action of vertical forces on folded structures; (4) migrating or "wave" folds in relation to unfolding.