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Thermochemical Investigations Of The Methanol-Isopropanol System, Elmer Lee Taylor

Masters Theses

"Heats of solution and partial molar excess volumes at infinite dilution were determined for n-butanol, acetone, chloroform, and water in pure methanol, pure isopropanol, and several mixtures of the two at 25.0⁰C. The partial molar excess enthalpies of methanol and isopropanol were also determined and were combined to obtain integral heats of mixing. All heat data were obtained using a calorimeter of the heat-leak design, containing approximately 300 ml of solvent. Sample sizes ranged for 0.1 to 8 ml. Individual heat measurements were reproducible to 0.05 calories and reported values are considered to be accurate to 1% + 0.5 calorie …

A Study Of Factors Which May Influence Attitudes Of Lds Teen-Agers Toward Family Home Evening, Don Leroy Miller

Theses and Dissertations

The purpose of this study was to identify factors related to attitudes of teenagers toward the Family Home Evening Program of the Church of Jesus Christ of Latter-day Saints. Hypotheses involving the relationships of certain factors to attitudes toward home evening were tested.

A cluster sample of twenty-three ninth grade classes was selected and data were gathered through use of a questionnaire. Statistics used in analysis of data included the Pearsonian product moment correlation coefficient, and analysis of variance. Responses to open-end questions were content analyzed by three independent judges.

Findings suggest that perceived participation by teenagers in planning and …

A Study Of The Energy Loss Spectra Induced By Impact Of 23-125 Kev Protons On Helium Atoms, Franklin Dean Schowengerdt

Doctoral Dissertations

"Results of a study of the inelastic energy loss spectra induced by the impact of protons on gaseous helium at energies of 25 to 125 keV are reported. The spectra were obtained by sending an accelerated beam of protons through a chamber containing the helium target gas, mass-analyzing the forward-scattered beam, then decelerating the beam to a low, well-defined energy for energy analysis and detection. The accelerating potential was varied to produce the spectra. An energy resolution of 2 eV was obtained. Apparent differential cross sections and absolute total cross sections were obtained from the spectra. Total cross sections for …

Infrared Cooling Near Atmospheric Temperature Inversions And Absorber Concentration Variations, Joey Keith Tuttle

Masters Theses

"Cooling due to infrared radiation near temperature inversions is investigated. Temperature inversions tend to hold pollution below the inversion level. The pollution itself may contribute to the stability of the inversion by selectively cooling certain portions of the atmosphere. A method is developed for evaluating infrared cooling rates at discreet points in the atmosphere. Several sample calculations are given to demonstrate the effects of variations of absorber concentration and lapse rate"--Abstract, page i.

An Experimental Comparison Of Various Nuclei Counters, Joel William Mansell

Masters Theses

"A series of simultaneous nuclei concentration measurements, with four different nuclei counters, have been made. these counters were a Pollak and a Gardner counter supplied by Mr. Paul Allee of the Environmental Science Services Administration, Boulder, Colorado, and a Pollak and a G.E. counter supplied; by Mr. Norman White of the National Center for Air Pollution Control, Cincinnati, Ohio. In the absence of any knowledge of the absolute concentrations in the samples, the data for each of the individual counters have been compared to the averages computed from all four counters. The results of these comparisons indicate the following: (1) …

Vertical And Lateral Variations In A Welded Tuff, Ted Richard Dinkel

Masters Theses

"During the Tertiary period, nuée ardente type eruptions spread large deposits of welded tuffs over southwestern Utah and southeastern Nevada. The Wah Wah Springs Tuff is a member of one of the most extensive of these units, the Needles Range Formation of Oligocene age. Its known outcrop area is estimated at 13,000 square miles. Relief was slight in the area during the time of eruption to enable the flows to spread over so large an area. In an effort to analyze the lateral and vertical continuity of the member, a petrographic study was undertaken. The average composition of the Wah …

A Low Frequency Phase Shift Method, Ronnie Carroll Mcmillan

Masters Theses

"The phase shift method of measuring atomic lifetimes is particularly useful because it allows us to make measurements in the steady state mode instead of in the transient mode. High frequency phase shift techniques cause many problems. The equipment, which was designed and built to make low frequency phase shift techniques possible, is shown schematically and discussed. The new experimental techniques employed in our apparatus are a phase multiplier and a unique method of using a photomultiplier as a mixer. In the photomultiplier the final dynode is used as the grid of a triode. The next to the last dynode …

Stratigraphy And Economic Geology Of Uranium-Bearing Sediments In The Poison Spider District, Natrona County, Wyoming, Carlos Enrique Reijenstein D'Acierno

Masters Theses

"Geologic, stratigraphic, and mineralogic characteristics of the Eocene Wind River and Oligocene White River Formations were determined for the southern portion of the Poison Spider District, Natrona County, Wyoming. Sieve analysis and heavy mineral techniques were used to recognize stratigraphic units, determine their environment of deposition, obtain a better knowledge of the grain size distribution, and to identify a possible source area for the sediments. Particular emphasis was concentrated on the evaluation and interpretation of the available geophysical data (gamma ray and resistivity logs), and geological information which had led to the establishment of several relationships between the local geology …

Longitudinal Optical Phonon-Plasmon Coupling In Ionic Semiconductors, Thomas Joseph Mcmahon

Doctoral Dissertations

"The coupling of free carriers and lattice vibrational modes is studied in CdS and InSb by room temperature far infrared reflectance measurements. When the free carrier concentration is such that the plasma frequency is at or near the longitudinal optical mode frequency it is shown that while the transverse modes remain fixed, the longitudinal modes mix with the plasma mode and are shifted in a manner similar to that described by Varga in 1965. Using the dielectric function for the coupled system permits the determination of electron effective masses by reflectance measurements with lattice effects excluded. This method allows one …

A Five Parameter Study Of Spherical Transient Waves In A Generalized Voigt Model, Liang-Juan Tsay

Doctoral Dissertations

"Transient spherical waves in a generalized Voigt model were investigated in this study. Both Laplace and fourier transform solutions of the spherical wave equation for a generalized Voigt model were obtained by means of the correspondence principle. Laplace transform solutions were inverted numerically into the domain for the study of the characteristics of the wave forms, and Fourier transform solutions were utilized for the analysis of frequency dependency attenuation in the models. Generalized Voigt models A and B in which a dashpot is connected in series with spring and dashpot components were unable to represent a solid which would simulate …

A Theoretical Study On The Interpretation Of Resistivity Sounding Data Measured By The Wenner Electrode System, Siew Hung Chan

Doctoral Dissertations

"This thesis deals with a theoretical study on the interpretation of resistivity sounding data measured by the Wenner electrode system. The objectives of this investigation are twofold: (i) to derive from the apparent resistivity data some suitable functions from which the resistivity and thickness of each member of the sequence of layers composing the earth may be determined, and (ii) to devise suitable methods for analyzing the resulting functions. In this investigation it is shown that the solution of the boundary value problem associated with an n-layered earth model leads to an integral equation for the Wenner electrode system. This …

A.C. Hall Effect Measurements On Very High Resistivity Materials Exhibiting Electrode Polarization, James Dale Boyd

Doctoral Dissertations

"A variable frequency, a.c. Hall effect measurement technique has been designed for mobility studies in very high resistivity (>10⁹ ohm·cm) materials exhibiting electrode space charge polarization effects. It incorporates a neutralized input capacitance preamplifier detector which reduces the total input shunting capacitance, including the sample interelectrode capacitances, to a very low, definable value (<0.1 pf) and thereby provides very high and well defined a.c. detector input impedances (4 x 10⁹ and 7 x 10⁹ ohms at 600 and 200 Hz, respectively). Lumped parameter equivalent circuits have been defined to approximate the electrical behavior of sample materials in the measurement configuration. These equivalent circuits, together with independent measurements of the detector input and sample impedances, allow one to correct the detected Hall voltage and obtain the true value from which mobility data may be derived. The validity of these circuits has been established by independent a.c. and d.c. measurements on photoconductive CdS (dark resistivity >10¹⁰ ohm·cm) which exhibited maximum differences of less than 4%. The existing literature has been critically reviewed and the measurement criteria established by this study have been applied to resolve differences in reported data and to suggest improvements in the resolution of previously employed experimental …

Characterizing Topologies By Continuous Selfmaps, Derald David Rothmann

Doctoral Dissertations

"Various topological spaces are examined in an effort to describe topological spaces from a knowledge of their class of continuous selfmaps or their class of autohomeomorphisms. Relationships between topologies and their continuous selfmaps are considered. Several examples of topological spaces are given and their corresponding classes of continuous selfmaps are described completely. The problem, given a set X and a topology U when does there exist a topology V either weaker or stronger than U such that the class of continuous selfmaps of (X,V) contains the class of continuous selfmaps of (X,U), is considered. M* and S** spaces are defined …

Low-Lying Levels In Some Spherical And Rotational Nuclides By Coulomb Excitation And Radiative Capture Of Thermal Neutrons, Donald Allan Mcclure

Doctoral Dissertations

"The work presented in this dissertation was performed in order to obtain additional information on the level schemes and decay properties of several nuclei in an attempt to explain the observations in terms of an applicable nuclear model. Various nuclear models are discussed in Section II. A general review from the classical point of view of the Coulomb excitation reaction is discussed in Section III and the thermal-neutron-capture reaction is outlined in Section IV. The experimental equipment and procedure is discussed in Section V in which the ramper method of energy determination is outlined. This method allows the measurement of …

MöSsbauer Effect Studies Of Ferroelectric Phase Transitions In The Pbzro₃ - Pbtio₃ - Bifeo₃ Ternary System, James P. Canner

Doctoral Dissertations

"The Mössbauer Effect was used to measure the phase transitions in the following ferroelectric compounds: 95% PbZ4₀.₈Ti₀.₂ - 5% BiFeO₃ [and] 95% PbZ4₀.₇Ti₀.₃ - 5% BiFeO₃ and in the antiferroelectric compound: 95% PbZrO₃ - 5% BiFeO₃. The parameters obtained were the area under the resonance peak, the isomer shift, and the electric quadrupole splitting, all as a function of temperature. The ionicity, electric field gradient, and Debye temperature were determined for room temperature. The data are discussed in terms of the lattice vibration model of ferroelectrics and antiferroelectrics, and the structural phase transitions as recently defined for these compounds. The …

Noble Gases: A Record Of The Early Solar System, E. C. Alexander

Doctoral Dissertations

"Analyses of the noble gases in samples of iron meteorites are presented which indicate the following: 1. The inclusions of iron meteorites contain noble gases with a wide range of isotopic compositions. 2. The noble gas concentration and isotopic anomalies arc often grossly inhomogeneously distributed within a given inclusion and vary from inclusion to inclusion in a meteorite. 3. Silicate inclusions appear to be the most promising samples for I-Xe and Pu-Xe dating. 4. Graphite and troilite in addition to the silicate inclusion contain significant radiogenic ¹²⁹Xe anomalies. 5. The total I-Xe (and in the case of Toluca silicates total …

Statistical Inferences For Location And Scale Parameter Distributions, Robert Henry Dumonceaux

Doctoral Dissertations

"The problem of discriminating between two location and scale parameter distributions is investigated. A general test based on a ratio of likelihoods is presented. A test based on a Pearson Goodness of Fit statistic is also considered. Tables are given for discriminating between the normal and exponential, the normal and double exponential, the normal and extreme value, and also between the normal and logistic. For location and scale parameter distributions, two-sided tolerance limits are shown to always be obtainable by Monte Carlo simulation. A method for obtaining confidence intervals on the reliability at a fixed time t is also given. …

Statistical Inferences For The Cauchy Distribution Based On Maximum Likelihood Estimators, Gerald Nicholas Haas

Doctoral Dissertations

"Various estimators of the location and scale parameters in the Cauchy distribution are investigated, and the superiority of the maximum likelihood estimators is established. Tables based on maximum likelihood estimators are presented for use in making statistical inferences for the Cauchy distribution. Those areas considered include confidence intervals, tests of hypothesis, power of the tests, and tolerance intervals. Both one- and two-sample problems are considered. Tables for testing the hypothesis of whether a sample came from a normal distribution or a Cauchy distribution are presented. The problems encountered in finding maximum likelihood estimators for the Cauchy parameters are discussed, and …

Statistical Inferences For The Generalized Gamma Distribution, Harold Walter Hager

Doctoral Dissertations

"Procedures for handling statistical problems with nuisance parameters are considered with special reference to problems in the three parameter generalized gamma distribution. Maximum likelihood estimation of the parameters of this density has been investigated. Properties of these estimates are established which make it possible to make inferences about the parameters. Discrimination between various models for life testing problems is discussed and the robustness of the Weibull model is advanced. The question of the existence of the maximum likelihood estimates of the parameters for all samples is raised. Empiric evidence is presented indicating that they may not exist for all small …

The Statistics Of Finite, One Dimensional Lattice Fluids, John Roger Glaese

Doctoral Dissertations

"A one dimensional lattice fluid in which particles are allowed to assume only discrete positions is proposed. Particles are free to move from one lattice site to another interacting through a variety of potentials, including the Lennard-Jones type. The model allows the partition function to be evaluated as a discrete sum over the allowable configurations. Both the canonical ensemble and grand ensemble are treated by computer and a third, the pressure ensemble, is considered and shown to be useful in the theoretical treatment of lattice systems. The thermodynamic behavior of various systems is investigated in both the canonical and grand …

Stratigraphy And Correlation Of Precambrian Volcanic Rocks, Eminence, Missouri, Henry Hugh Fisher

Masters Theses

"A portion of the Precambrian rocks located in the vicinity of Eminence, Missouri are studied and describes. These rocks are exposed as rhyolitic knobs protruding through hills of Ordovician sediments. The Precambrian rocks under study consist principally of rhyolite, with smaller amounts of tuff and creccis. The rhyolite is a potash rhyolite porphyry, both flow banded and unbanded, with phenocrysts of kaolinized orthoclase in a matrix of quartz and orthoclase. The tuffs contain devitrified glass shards and occasional ash balls such as those exhibited at Cott Mountain. A stratigraphic sequence was determined with the oldest rocks to the south at …

The Incorporation Of Oxygen-18 Into Oxindole Acid By Cells Of Hygrophorous Conicus, William Green Allen

Masters Theses

"To understand the mechanism of a biological oxidation in which oxygen is incorporated into a substrate, it is necessary to determine the origin of the incorporated oxygen. The objective of this investigation was to determine the origin of the oxygen atom incorporated into indoleacetic acid (IAA) by the IAA oxidase of Hygrophorous conicus through the use of oxygen-18. To determine the source of the oxygen atom incorporated into IAA it is necessary to incubate H. conicus cells with tryptamine or IAA in the presence of ¹⁸O₂ and H₂¹⁶O in one case and ¹⁶O₂ and H₂¹⁸O in another. An examination of …

The Background Concentrations Of Copper, Lead, And Zinc In Streams Of The "New Lead Belt", Missouri, Nicholas Howard Tibbs

Masters Theses

"This study was initiated to determine the background concentrations of copper, lead, and zinc in the streams of the Viburnum Trend or New Lead Belt of southeast Missouri. Analytical methods were developed for atomic adsorption spectroscopy. These methods initially consisted of coextraction of cooper, lead, and zinc using the APDC/MIBK system, and finally of extraction of copper by APDC/MIBK and direct analysis of lead and zinc using the newly developed "Sampling Boat" technique. The data obtained from these analyses were arranged in histograms and critically analyzed. The background concentrations were established to be 4-6 ppb for all three elements. Methods …

Michael Reactions Part Iv Syntheses With Carboalkoxycarbenes, Frederick Ralph Carman

Masters Theses

"A preliminary investigation has been made involving syntheses with dicarboalkoxycarbenes for the purpose of developing new heterocyclic and alicyclic synthese employing functionalized carbenes. The ultimate goals were the development of a stereospecific synthesis of trans fused and angularly substituted ring systems suitable for conversion to natural products and the development of useful synthetic paths to the azabullvalene system. Although these ultimate goals were not realized, new and improved syntheses of alkyl substituted anisoles and diazomalonic esters, including the first reported synthesis of di-tert-butyl-diazomalonate were accomplished. The addition of dicarboalkoxycarbenes to di-, tri- and tetra- substituted ethylenes, tropilidene and 7-aza-tropilidenes by …

A Geochemical Study Of The Maquoketa Formation In Pike County, Missouri, John Siegfried Trapp

Masters Theses

"Statistical interpretation of geochemical data was used to determine the environment of deposition of the Maquoketa Formation in Pike County, Missouri. A cyclic sequence was noted which can be best explained by cyclic climatic changes. During the study it was found that elemental relationships which would be expected in a freshly deposited sediment can be found in core samples. In samples from outcrops and quarry faces these relationships have been destroyed. As these elemental relationships reflect mineralogical relationships, serious doubts have arisen as to the validity of petrographic studies of samples taken from outcrops. This study indicates weathering may be …

Consistency And Cluster Size In The Effective Field Theories Of Ferromagnetism, J. G. Chervenak, Harry A. Brown

Physics Faculty Research & Creative Works

No abstract provided.

Mixed Magnetic Systems: A Model With Application To (1-X)Cdcr2s4 · Xcdcr2se4, Harry A. Brown

Physics Faculty Research & Creative Works

The Curie temperatures and asymptotic Curie temperatures are calculated for mixed magnetic systems by a semi-classical Bethe-Peierls-Weiss cluster approach. The systems are typified by (1-x) CdCr2Se4 · xCdCr2Se4 in which the substitution changes the anions but not the magnetic cations. It is found that next-nearest-neighbor interactions are needed to match the data but that, with them, excellent agreement can be obtained for a reasonably unique choice of the exchange integrals. © 1969.

Semiempirical Determination Of The Hydrogen Bond Energy For Water Clusters In The Vapor Phase. I. General Theory And Application To The Dimer, Richard W. Bolandee, James L. Kassner, Joseph T. Zung

Physics Faculty Research & Creative Works

A simple semiempirical method is given for determining the hydrogen bond energy for water clusters in the vapor phase. This method is based on a general statistical-mechanical theory of clustering. The partition function for a system of clusters is used to determine the equilibrium distribution of clusters. In conjunction with available thermodynamic and spectroscopic data, the cluster equilibrium constants can be used to calculate the cluster potential energy and the hydrogen bond energy. Results for the water dimer agree quite well with other reported values obtained either by quantum-mechanical calculations or approximate thermodynamic estimates. A correct temperature dependence of the …

A Comparison Of The Late Wisconsinan Molluscan Fauna Of The Missouri Coteau District (North Dakota) With A Modern Alaskan Analogue, Samuel J. Tuthill

Theses and Dissertations

Study of forty fossiliferous sites in late Wisconsinan sediments from the Missouri Coteau district in central North Dakota has defined the molluscan fauna of the period of geologic time between 12,000 and 9,000 C14 years before the present. The fauna includes twenty-eight taxa of nonmarine gastropods and bivalves and is dominated by branchiates. The modern molluscan fauna of the Missouri Coteau district in North Dakota lacks four species which were resident in the late Wisconsinan and contains no unionids, one additional aquatic species, and is strongly dominated by pulmonate gastropods.

The geology of the Missouri Coteau has been interpreted as …

A Fluorescent Tracer Study At A Tidal Inlet (Rudee Inlet, Virginia), James W. Bunch

OES Theses and Dissertations

Patterns and approximate rates of littoral transport south of Rudee Inlet. Virginia were investigated with fluorescent tracers. Sand movement was traced under a variety of longshore current and wave conditions. Patterns of tracer dispersal reflected the importance of wave height, breaker angle, and longshore current velocity on modes of littoral transport. A direct relationship between angle of breaker incidence. generated longshore current. and direction of tracer sand movement was found. Onshore offshore paths were taken by tracer material during periods of weak longshore currents and small breaker angles while alongshore paths were followed by tracer material during strong longshore currents …