Digital Commons Network^™

The Psychological Needs Of Hospital Dietary Supportive Personnel, Ralph Morales Jr.

Loma Linda University Electronic Theses, Dissertations & Projects

Achieving objectives in hospital food service systems is made more critical by the increasing rate of labor turnover. One of the major emphases that seems to offer promise for solving certain current manpower problems is a better understanding of the factors which may contribute to turnover. A quantitative approach to the identification of human needs in the work environment should provide information relevant to more effective planning and utilization of human resources.

The purpose of this research was to determine if by examining the psychological needs of hospital dietary supportive personnel, information could be derived for more objective management of …

A Quantum Mechanical Investigation Of The Heh3+ Energy Surface, Merle J. Benson

Chemistry and Chemical Biology ETDs

An all-electron ab-initio calculation of the energy surface for the reaction He+ H⁺₃ → HeH⁺ + H₂ was performed using a 9slp gaussian basis set for helium and a 4slp gaussian basis for hydrogen. Reaction paths calculated were of C_2V, C_S, and C_3V symmetry. The lowest energy configuration was found with the molecule in C_2V symmetry with the three hydrogen atoms in an equilateral triangle of side length 1.64 a.u. with the helium atom 3.85283 a.u. from an apex of the triangle. The molecule was found to remain in C …

Effect Of The Pedernal Axis On Permian And Triassic Sedimentation, Philip F. Hock

Earth and Planetary Sciences ETDs

The area surrounding the Pedernal Hills has been of scientific and economic interest for a number of years. The effect of the Pedernal axis on sedimentation and stratigraphy of late Paleozoic rocks is of major importance. The principal purposes of this study were to determine whether the Precambrian terrane was an active source of sediment and what effect it had on thickness of strata during Permian and Triassic time. the area was also mapped in as much detail as the scale (1:125,000) permitted.

The 1963-64 Lake Mead Survey, J. M. Lara, J. I. Sanders, Bureau Of Reclamation

Publications (WR)

The 1963-64 Lake Mead survey was run to compute the reservoir capacity. Results of the geodetic and hydrographic surveys and sediment sampling equipment are described. The geodetic survey showed Hoover Dam subsided an average of 118 mm since 1935. Sonic sounding, photogrammetry, and crosssectional profiling methods were used to run the hydrographic survey. Reservoir area and capacity tables were generated using an electronic computer. The present lake capacity is 29,755,000 acre-ft and the reservoir surface area is 162,700 acres at elevation 1229 ft. 2,720,000 acre-ft of sediments accumulated in the lake since 1935. A unit weight of 60 Ib/cu ft …

The Effects Of Various Treatments On Thiamin Diphosphate And Total Thiamin Levels Of Rat Tissues, Dong Hwa Park

Theses and Dissertations

Tissue thiamin diphosphate was assayed enzymatically utilizing purified brewer's yeast apotransketolase. With this assay ten uumoles of thiamin diphosphate could be detected. Total thiamin was fluorometrically measured. For one to three days rats were placed under conditions of stress, consisting of loud noise treatment, emotional stress, deprivation of paradoxical sleep, and swimming to exhaustion, respectively. The body weight was markedly decreased at the end of the respective experimental periods except with the loud noise treated group, compared with the corresponding controls. Following two to three such consecutive treatments, the adrenal weight also showed a significant increase. Thiamin diphosphate and total …

The Chemistry Of Dehydronaphthalene, Richard Harold Hales

Theses and Dissertations

The reaction of monohalonaphthalenes with potassium t-butoxide in a t-butyl alcohol-dimethyl sulfoxide (DMSO) mixture has been studied. The 1-bromonaphthalene reaction was extensively studied. Fifteen identifiable products were observed and conditions were found where the desired products, 1- and 2-t-butyl naphthyl ethers (V and VI) were formed in maximum yield, and their decomposition products, 1- and 2-naphthol (XIV and XV), were formed in minimum yield. The mole percent ratio of 1-substituted products (V and XIV) to 2-substituted products (VI and XV) was found under standardized conditions to be 0.35 ± 0.03 in every case when the halogen was I, Br and …

Labor Time Analysis By Work Function Activity In Production Of Vegetarian Entrees, Maynard W. Lebrun

Loma Linda University Electronic Theses, Dissertations & Projects

The specific objectives of this research were to (1) develop a method for determining labor time and labor cost of cooks by work functions in the production of selected vegetarian entrees, and (2) determine the percentage relationship of cooks' labor to food cost in selected classifications of entrees.

Application of the continuous time study methodology as developed in this research was restricted to the observation of entree cooks in a 408 bed non-profit university hospital. Observation of work function activities during the first week of a four week cycle menu for three consecutive cycles was classified under three major categories: …

Effects Of Hydrocarbon Chain Length On The Thermodynamics Of Formation Of Bis(N-Alkylamino)-Silver (I) Complex Ions, Don J. Temer

Chemistry and Chemical Biology ETDs

As part of a comprehensive study of the thermodynamics of conformational changes of n-alkyl groups in aqueous solution, the equilibrium constants, enthalpy changes, and entropy changes have been measured for the stepwise formation of bis(n-alkylamino)silver(I) complex ions at 25° in dilute aqueous solution. The attachment of the charged Ag⁺ to the end of the amine molecule is thought to cause changes in the conformation of the n-alkyl chain. The effects of these conformational changes on the formation constants, enthalpy changes, and entropy changes of the Ag⁺ complexes are discussed and compared with the effects on the formation constants, …

Electron Optical Study Of A Secondary Electron Multiplier, Chang Min Shen

Dissertations and Theses

Electron orbital theory was applied to the design of the geometrical structure of an electron multiplier for an image intensifier. A special structure satisfying production requirements was studied. Electron optical calculations consisted of determining the potential distribution and tracing the electron trajectories. Liebmann's procedure was used to solve Laplace's equation with constant potentials on the multiplier electrodes as boundary conditions. The trajectories were determined by solving the equation of motion in an electrostatic field using a Runge-Kutta procedure. The initial conditions for the trajectories were the initial energies, initial positions, and the initial directions of the secondary electrons. The plotted …

A New Method In The Wkb Approximation, Raymond Pierce Engelke

Physics & Astronomy ETDs

A new WKB-like quantization rule is developed by means of a transformation method. This method makes use of a combination of a Liouville-like substitution and the Prüfer transformation. The only quality required of the potential is that it be twice differentiable on the real axis. The new quantization rule is an exact rule. However, some terms in the rule must be approximated before it can be evaluated for any particular potential function. An interesting feature of the derivation is that no asymptotic expansions are used -- unlike the usual development of the 1st order WKB quantization rule (FWKBQR). The terms …

Molecular Orbital Calculations To Determine Stable Conformations Of The Nucleotide Deoxycytidine-3'-Monophosphate., Marvin Lawrence Chatkoff

Physics & Astronomy ETDs

Extended Huckel, semi-empirical, molecular orbital analyses were performed for deoxycytidine-31 -monophosphate and cytidine-3'-monoohosphate corresponding to single nucleotides of double helical DNA and RNA to determine whether the experimentally derived models correspond to theoretically stable configurations. The A, B, and C models of DNA, and linearly interpolated intermediate con­figurations were investigated. For RNA, the experimental A configuration, a pseudo RNA nucleotide formed from the B configuration of DNA, and intermediate conformations were used.

From the B model of DNA the base was displaced and angles adjusted until close coordinate fits were obtained at the A and C configurations. Intermediate points were …

A Spectroscopic Investigation Of Electron Transfer Transitions In Osmium (Ii) Complexes, Brian J. Pankuch

Chemistry and Chemical Biology ETDs

Osmium (II) complexes containing organic coordinating ligands 2.2'-bipyridine, 1.10-phenanthroline, 2.2' .2"­terpyridine were studied spectroscopically. Syntheses were carried out by published methods, and each complex was checked by chemical analysis and thin layer chromatography. The complexes were shown to be d6 strong field systems by magnetic susceptibility measurements performed at room temperature in air.

Room temperature absorption spectra in the visible and near-ultraviolet were measured in solvents of different polarities (H₂O, MeOH, CH₃CN, DMF, CHCl₃) and solvent shifts of the band maxima of 0.3 to 3 kK were found. Low temperature (approximately 82-90°K) absorption spectra …

Preparation Of New Amino-, Thio-, And Sulfonyladamantane Derivatives, Joseph Craig Argyle

Theses and Dissertations

Various synthetic schemes were used to prepare a number of new amino-thio- and sulfonyladamantane compounds. By a nucleophilic substitution on 1-bromoadamantane, 1-(p-nitrophenylthio)adamantane was prepared from p-nitrothiophenol; the amino- and sulfonyl- derivatives of this compound were also prepared. Silver tosylate was used to generate the 1-adamantyl carbonium ion from 1-bromoadamantane in a synthetically useful procedure for preparing 1-adamantylamides from nitriles. Three 1-(1-adamantylcarbinyl)-2,5-dialkylpyrroles were prepared by Knorr-Paal reactions and reduced to the corresponding pyrrolidines. Thio- and aminomethyl 1-adamantyl ketones were prepared from methyl and bromomethyl 1-adamantyl ketones, respectively. Aliphatic and aromatic oxiranes were reacted with 1-aminoadamantane in a bomb at elevated temperatures …

The Reactivity And Selectivity Of The Reaction Of Sulfur Trioxide And Bromobenzene, Sullivan E. Blau

Theses and Dissertations

The sulfonation of bromobenzene with sulfur trioxide in liquid sulfur dioxide at -12 to -13° C. was studied to determine its relative reactivity. The relative rate constant ratio, kbenzene/kbromobenzene, was found to be 28.6 in a competitive reaction between benzene and bromobenzene. The isomer distribution was found to be 0.15 ± 0.02% for the meta, 0.91 ± 0.04% for the ortho and 98.93 ± 0.14% for the para isomers. The partial rate factors were calculated to be pf= 0.208, of= 0.0096 and mf = 0.00018. The relative rate data exhibited a distinctive behaviour previously noted in related systems, possibly due …

High Pressure Spectral Chemistry Of Selected Organic Compounds, Frank William Linsley

Theses and Dissertations

The series of compounds indicated by the formular C_6H_5-(CH=CH)n-C_6H_5 change in color from white (colorless) to yellow to orange to red to deep red as n increases from 1 to 12. Stilbene is the first compound of this series (n=1). Under pressure, exerted by a diamond anvil press, stilbene can be seen to change color from white to yellow to red as increasing pressure is applied. Similar color changes are observed for the compounds where n=2,3, and 4 when subjected to similar pressure. This study records and reports the spectra versus pressure for these compounds.

The Enzymatic Oxidation Of Aldehydes By Xanthine Oxidase, Duane Beal Gregory

All Master's Theses

As early as sixty years ago, the existence of an enzyme from mammalian tissues which catalyzed the oxidation of xanthine and hypoxanthine was recognized. The name given the enzyme was derived from its earliest recognized action, hence xanthine oxidase. Although little is known about the biological functions of the enzyme, the high affinity shown for xanthine and hypoxanthine may indicate that these are the most significant substrates biologically.

The Synthesis And Properties Of New Potentially Chemotheraputic [Sic] Pteridine Derivatives, Walter Wesley Parish

Theses and Dissertations

A new general synthetic method for the preparation of 6-thiopteridines has been developed. The method involves the addition of thiols to intermediate pyrimidine nitrones formed in situ by the reaction of 4-amino-5-nitrosopyrimidines with pyridinium-activated acetonitriles, acetates, acetophenones, and other methylketones. Ca. forty new pteridines were prepared by this method. The preparation of six new 6-pteridinyl ketones, two new 6- pteridinyl ketone thiosemicarbazones, and two new 6-sulfonylpteridines and their 4-acetamido derivatives is also reported. 4-Acetamido-2- amino-7-phenylpteridine 5-oxide was prepared by the reaction of 2- amino-4,6-diacetamido-5-nitrosopyrimidine with either phenylsulfonyl-acetophenone or phenacylpyridinium bromide. Evidence relating to the structure of the acylated 4-amino-5- nitrosopyrimidines …

An In Vivo Perfusion Apparatus For Studies On Gingival Disease In The Albino Rat : Assessment By A Perfusion Of The Enzymes Collagenase And Hyaluronidase, James A. Smith

Loma Linda University Electronic Theses, Dissertations & Projects

This thesis describes an in vivo perfusion apparatus which can continuously deliver controlled quantities of solutions to localized, contralateral intraoral areas in albino rats. Three animals were per fused on the experimental area (the mesial sulcular area of the maxillary first molar) on one side with tap water and Trypan blue. Localization of the solution delivered and minimal histological changes due to the presence of the apparatus was demonstrated on these animals. Solutions of .5%, 1%, and 2% hyaluronidase and collagenase were perfused on the experimental areas of nine animals. When both enzymes were used, hyaluronidase always preceded collagenase in …

Record In Rock: A Handbook Of The Invertebrate Fossils Of Nebraska, Roger K. Pabian

Conservation and Survey Division: Faculty and Staff Publications

Table of Contents:

Introduction
What Are Fossils? How Do They Form?
Fossilization
How Are Fossiliferous Rocks Formed?
What is Paleontology?
What Can Fossils Tell Us?
Fossils and Geologic Time
Fossils as Environmental Indicators
Fossils and Conservation
How Are Fossils Named?
Where Are Fossils Found?
Collecting Courtesy
Tools for Collecting Fossils
Tips on Collecting Fossils
Safety Rules
Quarry Safety
Safety Don'ts to Remember
Preparation of Specimens
A Bit of Advice
General Characteristics of Nebraska's Important Fossils
Phylum Protozoa (Single-Celled Animals)
The Living Protozoan
Fossil Protozoans from Nebraska
Phylum Porifera (Pore Bearers or Sponges)
The Living Sponge
Fossil Sponges from Nebraska
Phylum …

Molecular Luminescence From Turhenium, Osmium, And Terbium Chelates: 2°K To 300°K, Raymond William Harrigan

Chemistry and Chemical Biology ETDs

Two experimental spectroscopic investigations spanning the temperature range 300°K to 2°K were carried out on molecular complexes. The nature of charge-transfer phenomena in transition-metal chelates was studied extensively, and the thermal quenching of the luminescence of terbium (III) chelates was briefly investigated. The experimental methods employed were absorption and luminescence spectroscopy including photoflash excitation for studying transient luminescence decays. Measurements were performed on three osmium and three ruthenium complexes, all containing bidentate or tridentate heterocyclic aromatics as ligands. The compounds were studied in rigid solvent glasses, in poly(methyl methacrylate) (PMM), in an isomorphic host of tris(2, 2'-bipyridine)zinc(II) sulfate, and in …

Surface Energies In The Caso4-H2o System And The Effect Of Supersaturation On The Crystallization Of Gypsum, Sandra C. Feldman

Earth and Planetary Sciences ETDs

The surface energy of gypsum has been experimentally determined to be 70. 2 erg/cm² at 30˚ C. The value for anhydrite is calculated as 112 erg/cm². At various extrapolated supersaturations, the number of particles or ions necessary to form nuclei of gypsum and anhydrite is:

Supersaturation

No. part. or ions/nucleus

Gypsum

Anhydrite

10

60.5

1000

51

8

2

99

20

4

Crystal size measurements and crystal shapes were noted for gypsum within the range of supersaturations studied (45.6 to 131). The maximum crystal size is attained at a slightly lower supersaturation than the critical supersaturation. The shape …

Transitive Subgraphs Of Undirected And Directed Graphs., Charles C. Harner

Mathematics & Statistics ETDs

A graph G is transitive if it is transitive when considered as a relation; i.e., if the edges ab and be are in G, so is ac. In this paper, several natural questions concerning transitivity and related concepts are investigated.

Because the terminology and notation of graph theory is not standard, a brief section of definitions and notation is included in Section II. Section III is a study of the transitive cut number of a graph, the minimum number of edges which must be removed from the graph so that the remaining subgraph is transitive. Undirected graphs on n points …

Distribution Of The Sum Of Independent Unity-Truncated Logarithmic Series Variables, Russell James Wayland

Dissertations and Theses

Let X₁, X₂, ..., X_n be n independent and identically distributed random variables having the unity-truncated logarithmic series distribution with probability function given by f(x;θ) = αθ^X/x x ε T where α = [-log(1-θ) - θ]^-1, 0 < θ < 1, and T = {2,3,...,∞}. Define their sum as Z = X₁ + X₂ + ... + X_n.

We derive here the distribution of Z, denoted by p(z;n,θ), using the inversion formula for characteristic functions, in an explicit form in terms of a linear combination of Stirling numbers of the first kind. A recurrence relation for the probability function p(z;n,θ) is obtained …

Crystal Structures Of Potassium Ferric Sulfate Minerals., Edward J. Graeber

Earth and Planetary Sciences ETDs

The potassium ferric sulfate minerals, yavapaiite [KFe(so ) J and goldichite [KFe(so4) •4H2oJ were studied 42 2 using x-ray diffraction methods, and the results correlated with the mineral krausite [KFe(so4)2 ·H20J .

Yavapaiite crystallizes in space group C2/m with two formula weights in a unit cell of dimensions a= 8 .152A, b = 5, 153A, c = 7,877A and S = 911.70°. Goldichite , in space group P2 /c, contains four formula weights in a unit cell with a= 10 . 387A, b = 10.486A, c = 9.086A and 6 = 101.67°.

The structures were solved by three-dimensional Patterson syntheses …

The Chemistry Of Trifluorothiolacetic Acid, Patricia Diane Weeks

Dissertations and Theses

Addition reactions of perfluorothiolacetic acid (TFTAA) with organic and inorganic substrates were studied and six new compounds containing the trifluoroacetyl group have been prepared. Two types of reactions were observed, free radical and nucleophilic addition. Under the influence of ultraviolet light, TFTAA (CF₃COSH) adds to olefins to form 1:1 adducts. The CF₃COS• radical appears to be the adding species. Three new olefin adducts were prepared: CF₃COSCFHCF₂H, CF₃COSCH₂CF₂H, and CF₃COSCH₂CFH₂. In addition, this was found to be a new way to prepare CF₃COSCH₂CH₃, which had been previously prepared by another route. Physical constants, analytical data, infrared, ultraviolet, nmr and mass spectra …

The Historic End Of Closed Seas, James Edward Grise

Marine Affairs Theses and Major Papers

The purpose of this paper is to consider the rather vague claims to closed seas by the Soviet Union and to determine what direction these claims are taking. The first part of the paper deals with the history and development of the closed seas concept and expands it into the present day claims in this area. It attempts to show how some of the past claims have remained over the years and how some of the others have progressed to claims of historic waters. In the final section an attempt is made to show some method for resolving some of …

Propagation Of Ultrasound In Plastic Crystals, Carl E. Scheie

Physics & Astronomy ETDs

The study of the organic solid state, and in particular of plastic crystals, is a relatively new branch of physics (1,2). Timmermans first surmised the existence of these solids from the anomalous values of the entropies of fusion. The solids possess many of the characteristics of liquids. They are easily deformed by pressure and they show dielectric properties that can be described on the basis of rotation of the molecules in their lattice positions. Still they have a definite crystal structure. Thus, even though the molecules are not symmetric, they appear to be to some degree because of the rotation. …

Trace-Element Geochemistry Of Southwestern Turquoise, Anne Marguerite Colberg Sigleo

Earth and Planetary Sciences ETDs

Southwestern turquoise (CuAl₆(PO₄)₄ OH₈ · 4H₂O) is associated with Laramide intrusions along the eastern and southern margins of the Colorado Plateau in Colorado, New Mexico, and Arizona, and with a zone of Late Devonian­Mississippian tectonic activity in Nevada. A review, of the previous work on the origin of turquoise is presented. Of these, the supergene hypothesis proposed by Sidney Paige in 1912 generally remains undisputed in the literature. Much of the data presented in this study, however, suggest a hydrothermal mode of formation. The concentrations of Co in particular are most similar …

Donor Properties Of Dimethylsulfoniumcyclopentadienylide And Tetramethylenesulfoniumcyclopentadienylide In Metal Complexes ; Part Ii. The Attempted Preparation Of Boron Tricyanide, Gary Scott Barney

Theses and Dissertations

Part I.--Complexes of dimethylsulfoniumcyclopentadientylide and tetramethylenesulfoniumcyclopentadienylide with metal ions were studied in order to determine the coordination site on the ylids. Infrared spectra indicate that the ylids are coordinated through the cyclopentadienyl ring in all complexes except for the Hg(CN)2 complexes. Coordination-of the HgI2, CdI2, ZnCl2, and AgNO3 complexes is through the number one position on the ring as suggested by NMR data. Infrared and NMR data strongly indicate that the ylids in the Hg(CN)2 complexes are coordinated through sulfur. Part II.--The only method given in the chemical literature for the preparation of boron tricyanide could not be duplicated in …

Studies In Computational Linguistics No. 1, The Recognition Of Alphabets, Edward F. Storm

Electrical Engineering and Computer Science - Technical Reports

Formal parsing rules for programming languages often have machinery for recognizing identifiers, numerical constants, and other substrings whose internal structure is only marginally relevant to the language structure as a whole. In this note alphabets are introduced in which identifiers, constants, etc. are regarded as single symbols. An alphabet is thus constructed out of a finite set of characters, is identified as a regular language and a simple recognition algorithm is described, giving the language designer considerable latitude in his choice of alphabet.