Digital Commons Network^™

Mössbauer-Effect Studies Of The Phase Transitions In Antiferroelectric Pbzro₃ And Ferroelectric Pbti₀.₀₂Zr₀.₈O₃, James P. Canner, C. M. Yagnik, Robert Gerson, William Joseph James

Physics Faculty Research & Creative Works

The Mössbauer spectra were studied for the antiferroelectric compound PbZrO₃ and for the closely related ferroelectric PbTi_0.2Zr_0.8O₃. In both cases, a substitution of 5-mol% BiFeO₃ was made to permit the Mössbauer measurements. Little difference was found in the isomer shift in these compounds, whether they were in the ferroelectric, antiferroelectric, or cubic state, indicating that the bonding character is not affected by the transitions among the states. There was a pronounced and approximately equivalent dip in the recoil-free fraction at the Curie points of both the antiferroelectric and ferroelectric materials, associated with …

A Two-Layer Model Of The North Atlantic Thermocline, P. P. Niiler, Edward R. Simco, R. Larue

Faculty Articles

A two-layer model of mid-oceanic thermocline is developed, and a comparison of the depth and temperature of the thermocline in this model is made with a root-mean-square description of the hydrographic structure of the North Atlantic. It is shown that the Sverdrup balance is maintained within the rms errors, and the entire estimated heat flux from the atmosphere is used to produce the observed density changes along the path of persistent flow.

Ua77/1 Western Alumnus, Vol. 40, No. 2, Wku Alumni Relations

WKU Administration Documents

Quarterly magazine created for WKU alumni. Regular features are Hilltopics, Sports, Alumni Newsgrams and Notes and In Memoriam. This issue includes:

• Graduate School (College) is On Its Way
• Evening Class is Thataway
• The Hilltopper Hundred to the Rescue
• ETV - Keep Watching, It's All in Color
• Student Interns Learn How Government Works
• Significant Statements: The New Year Begins
• Good News for Fishermen: Reservoir Research
• There it Was! Your Homecoming - 1971
• Performing Arts Illuminate the Campus Scene
• Discovery 1 - Uncovering the Kentucky of Antiquity
• Discovery 2 - Reviving the Heritage of Kentucky
• Discovery 3 - The Intercultural Studies Program …

Measurement Of Currents In Lake Mead With The Deep Water Isotopic Current Analyzer (Dwica), J. J. Sartoris, D. A. Hoffman, Bureau Of Reclamation

Publications (WR)

In Nov 1967, a Deep Water Isotopic Current Analyzer (DWICA) was used to study current patterns in the Boulder Basin of Lake Mead to determine if low-quality water from Las Vegas Bay might enter the Southern Nevada Water Project intake on Saddle Island. Secondary objectives were to study the general current patterns in Boulder Basin and the effect of power discharges at Hoover Dam on these currents. Results of current measurements at 3 stations in Boulder Basin are given. Observations indicate a definite possibility that low-quality water from Las Vegas Bay might enter the water intake on Saddle Island. Current …

Gravity Investigations Over A Salt Structure Near Lübbecke, Northern Germany, Reinhard K. Frohlich

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

A detailed gravity survey was conducted parallel to the “Wiehengebirge” northwest of Minden in Northern Germany. The survey localized between Liibbecke and Levern a salt deposit, which is known as “Münder Mergel” salt of the Upper Jurassic. The salt deposit forms a cylindrical structure with an axis striking NWW. With a deep drill hole detailed interpretation was possible using the polygon method of TALWANI, WORZEL and LANDISMAN [1959], The section shapes of salt bodies under eight profiles show asymmetrical figures of two salt units. Both increase in thickness strongly to the northeast, where the salt is interrupted by a fault …

Geophysical And Geological Analysis Of A Fault-Like Linearity In The Lower Clackamas River Area, Clackamas County, Oregon, Ronald Jay Schmela

Dissertations and Theses

A fault-like linearity along the lower Clackamas River is evaluated by analysis of physiographic and structural alignments, geological relationships, and by gravity and magnetic data. The study has resulted in the verification of a structural feature extending along the Clackamas River and the eastern front of the Portland Hills.

Physiographic alignments were examined in twelve 15 minute and two 7-1/2 minute quadrangle maps. A significant northeasterly morphologic trend, N. 20⁰ W. and N. 40° W., and other secondary trends, namely, the N-S, E-W, and N. 50-60° E., has developed in the Portland area. The consistent northwest trend is observed throughout …

A Preliminary Ecological Study Of Areas To Be Impounded In The Salt River Basin Of Kentucky, Louis A. Krumholz

KWRRI Research Reports

This report covers work that is an extension of Project No. A-019-KY. A series of 25 sampling stations was established in the mainstream and tributaries of the Salt River that extend from the source of the stream in Boyle County to a few miles below the site of Taylorsville Darn in Spencer County. Sampling for water chemistry and biota was carried out semimonthly. Data on temperature, oxygen, depth, and discharge, along with analyses for cations (Ca, Mg, Fe, Mn) and anions (PO₄, NO₃, NO₂, CO₃, HCO₃) have been accumulated and …

Evidence For The Existence Of Two Stable Sites For Cobalt Impurity Atoms In Aluminum, Arun Venkatachar

Dissertations and Theses

Using Fe⁵⁷Mössbauer spectroscopy, two alternative sites occupied by cobalt (10^-4 at. % ) impurity atoms in aluminum have been isolated. The substitutional site A is the stable position after annealing the sample above 840 K, followed by a rapid quench. The impurity atoms in site A are characterized by a single line Mössbauer spectrum (indicative of a cubic environment), a room-temperature f = 0.502 (r. m. s. displ. 0.071 A) and an I. S. (reI. to Fe) = -0.421 mm/sec. For anneals below 770 K the cobalt atoms migrate to site B, which is characterized by a …

The Thermal Decomposition Of 2,2'-Azoisobutane, Mervin Dewain Atwood

Theses and Dissertations

Nitrogen, isobutane, isobutylene and 2,2,3,3-tetramethylbutane are the only products found in the thermal decomposition of 2,2'-azoisobutane. They are the results of the direct free radical dimerization and disproportionation. Ratio of the rate constants of disproportionation to dimerization was found to be 1.9 at 268°C and 4.5% azobutane in helium. This compared with Blackham and Eatough's value of 1.4 at 243°C and 3.6 at 290°C with 4% azobutane in helium. The ratio of the disproportionation to dimerization increased with an increase in temperature. A change in contact time affected the ratio at lower reaction temperatures but had little effect on it …

An Investigation Of Some Free Radicals.|Ni.|Pdecomposition Of Nitrosyl Disulfonate Ion In Polar Non-Aqueous Solvents.|Nii.|Preaction Between 2,2-Diphenyl -1- Picryl Hydrazyl And Nitrosyl Disulfonate Ion Free Radicals, Janan Mary Hayes

Theses and Dissertations

Part I reports the stud y of the decomposition of nitrosyl disulfonate ion in DMSO, acetonitrile, and dichloromethane. A multi-step mechanism involving sulfite ion, sulfite ion radical, and nitrosyl monosulfonate radical as intermediates is proposed. The products of the decomposition are nitrosonium ion, hydroxylamine disulfonate ion, and hydroxylamine trisulfonate ion. A competitive chain reaction was observed when the decomposition occurred in DMSO. The chain reaction was insignificant in carefully dried acetonitrile and dichloromethane. Part II reports the study of the reaction between 2,2-diphenyl-1-picryl hydrazyl (DPPH) and nitrosyl disulfonate ion. Product analysis and kinetic data obtained from stopped-flow procedures suggest that …

A Comparative Investigation Of The Effects Of Frequent Testing Upon Achievement In Secondary Advanced Algebra, John Thomas Fullerton

All Master's Theses

Relatively speaking, few studies have concerned themselves with the problem of frequent testing, and as Keys pointed out, empirical evidence, uncomplicated by differences in the amount of testing material employed, on the effects of frequent testing is, at best, scarce (14:427). Also many studies used tests and test results for direct instruction, thus introducing additional variables. Furthermore, the choice of subjects and disciplines has been limited, the better part being taken from college psychology and sociology classes or high school science classes. This investigation was not an attempt to modify previous experiments, nor was it an attempt to identify which …

A Kinetic Analysis Of The Iodination Of Pyruvic Acid And Pyruvate Esters, Mohamed M. Fahmi Hegazi

All Master's Theses

In the present work the relative rates of iodination of pyruvic acid and ethyl and methyl pyruvate have been compared at 25.0° C. These studies allow the determination of the respective free energies of activation for these processes. Measurements have also been carried out at various temperatures to determine the enthalpies and entropies of activation for the spontaneous and base catalysed iodinations of these pyruvate systems. The present thesis also includes a comparison of the solvent deuterium isotope effects associated with the spontaneous rate of iodination of pyruvic acid and the alkyl pyruvates. Also, the catalytic rate coefficients associated with …

Orthogonality In Normed Spaces, Martin R. Mccarthy

All Master's Theses

This paper presents three definitions of orthogonality in normed spaces. Each definition is shown equivalent to the inner product being zero when restricted to an inner product space. The definitions arise from such properties in two space as the diagonals of a rectangle being equal and the Pythagorean Theorem. The third definition shows that the idea of an inner product can be generalized under certain conditions.

Synthesis And Characterization Of Some Dioxane Complexes, James Donald Satterlee

All Master's Theses

The boron trifluoride, tin (IV) fluoride and titanium (IV) fluoride complexes with 1,4-dioxane have been prepared and studied using infrared techniques. The compositions of the complexes have been determined and correspond to the 1:1 adducts in the case of the tin and titanium compounds. The boron trifluoride adduct is a 2:1 (acid:base) adduct. Infrared spectra in the region 1300 cm.-1 to 550 cm.-1 are given and the effects of coordination upon the ligand vibrations are described.

Studies Of Pig Brain Thiamin Pyrophosphokinase, James Weldon Peterson

Theses and Dissertations

Pig brain thiamin pyrophosphokinase (TPK) (ATP: thiamin pyrophosphotransferase, EC 2.7.6.2) was purified 260-fold over extracts of brain acetone powder. The purification was followed using a direct, radiometric assay. As determined in an analytical ultracentrifuge and by disc-gel electrophoresis, the most highly purified enzyme preparations were not homogeneous. The purified enzyme has a broad pH optimum extending from 8.3 to 9.3 in phosphate-glycylglycine buffer. It has an isoelectric point at about pH 4.2. For optimal enzymatic activity, the ratio of magnesium to ATP must be 0.6. Any deviation from this ratio causes a rapid drop in enzymatic activity. A study of …

An Extension Of The Cochran Q Test, Soo-Young Cho

Loma Linda University Electronic Theses, Dissertations & Projects

The familiar x ² test is ordinarily used to compare percentage distributions of categorical data for two or more independent samples. A more accurate com parison of the percentages is sometimes obtained if the samples consist of matched individuals. The NcNemar test is generally used when comparing only two related samples. Where there are three or more samples the Cochran Q test is used. Both of these tests apply only to the case of dichotomized responses. This thesis extends the Cochran Q test to the case where the responses are multinomial. A generalized statistic corresponding to Cochran's result is obtained. …

Analytical Aspects Of Laser-Induced Degradation Of Organic And Inorganic Compounds, William T. Ristau

Chemistry and Chemical Biology ETDs

The rapid deposition of energy by means of a pulsed ruby laser to degrade organic and inorganic materials is investigated as an analytical tool. Advantages and disadvantages of using a laser are discussed and compared to current conventional pyrolysis methods. The interaction of laser radiation with matter is briefly discussed. A number of different organic compounds including saturated and aromatic hydrocarbons, heterocyclic compounds, and polymers have been studied. The degradation products were separated and identified by use of a gas chromatograph. Degradation studies have also been done on a series of inorganic salts including nitrates, sulfates, thiosulfates, and oxalates. The …

Crystal Structure Determination Of Β-Lactoglobulin From Electron Micrographs, Richard Roeter

Dissertations and Theses

Often electron micrographs exhibit a repeating structure. Sometimes this repeating structure satisfies the definition of a crystal in that it has a three dimensional repeating structure. If the unit cell structure of this repeating structure can be determined it can be used to help categorize different sections of a particular sample. In some cases, the use of optical diffraction analysis of electron micrographs with repeating structure is a method of determining the unit cell structure.

Samples of β-Lactoglobulin were prepared for viewing in the electron microscope using both the crystalline material and carbon replicas of the crystal surface. Because the …

Measurement Of The Average Solar Neutron Flux And Its Correlation With Solar Activity, Pyung Syk Ro

Physics & Astronomy ETDs

Data from the University of New Mexico High Energy Neutron Detector flown on NASA satellite OSO-VI arc analyzed with the aim of detecting neutrons from the sun. The detector is a proton recoil telescope capable of directional discrimination and responsive to neutrons of energies between 20 and 200 MeV with an effective average efficiency for this analysis of 10^-4 and an effective area of 80cm². The detector was located in a wheel compartment of OSO-VI and scanned the sun once per revolution of the wheel at a rate of 30 rpm. The satellite was launched on August …

Some Applications Of Decompositions Of The Identity To Ordered Vector Spaces., John Annulis

Mathematics & Statistics ETDs

We study decompositions of the identity (for definition see Vulikh [13]) in Dedekind a-complete vector lattices. In Chapter 1, we define and develop a notion of continuous elements with respect to a decomposition of the identity. We shall also develop a spectral theory for these elements. In Chapter 2, two Stieltjes-type type integrals are defined with respect to decompositions of the identity. The relationship of these integrals to the continuous elements is then explored. In Chapter 3, we prove two results in ordered vector spaces. The first result is that every infinite dimensional Dedekind complete vector lattice has a base …

Geology Of The Rammel Mountain Area, Teton County, Wyoming, David W. Love

Earth and Planetary Sciences ETDs

The Rammel Mountain area, on the west side of the Teton Range, Wyoming, includes Precambrian metamorphic and igneous rocks; Paleozoic sandstone, shale, dolomite and limestone; and Cenozoic conglomerate, agglomerate and breccia, ash-flow tuffs and glacial deposits.

The Precambrian layered gneiss, granitic gneiss and migmatite have undergone at least two episodes of deformation and metamorphism in the sillimanite-cordierite-muscovite-almandine subfacies of the Abukuma-type facies series prior to the emplacement of quartz monzonite. Dia-base dikes, quartz-epidote and epidote veins transect these earlier rocks.

The Cambrian-Mississippian shelf-facies rocks were folded, faulted and eroded to a plain in Late Cretaceous time and were buried by …

Structure And Stratigraphy Of The Florida Mountains, Luna County, New Mexico., Lonnie Leroy Corbitt

Earth and Planetary Sciences ETDs

Precambrian rocks in the Florida Mountains have a long and complex history of orogeny and epeirogeny. The oldest recorded event is regional metamorphism (amphibolite facies) of sedimentary and igneous rocks which are intruded by granite. Following a long period of erosion, diamictite was deposited on a deeply weathered surface of igneous and metamorphic rocks.

At least 3,000 feet of Paleozoic strata is preserved above the Precambrian rock1s. The Paleozoic strata are mostly shelf carbonates; the Bliss Formation and the Devonian Percha Shale are the only major Paleozoic elastic units present. From Cambrian through Mississippian time the Florida Mountains area was …

A Maximum Principle For An Optimal Control Problem With Integral Constraints., Vernon Bakke

Mathematics & Statistics ETDs

In this problem necessary conditions are obtained for an optimal control problem ·whose state variables are given in terms of integral equations. The conditions are obtained separately for Volterra equations and Fredholm equations. The main result for each case is the maximum principle and multiplier rule. For the Volterra equations, transversality conditions are obtained.

Relationships Between Reversible And Connected Automata, Robert Michael Johnson

All Master's Theses

The present investigation explores some of the relationships among special classes of automata defined by Bavel and Muller (1:231-240), Trauth (6:170-175), and Cutlip (2).

High-Pressure Equation Of State For Nacl, Kcl, And Cscl, Daniel L. Decker

Faculty Publications

A calculation of the equation of state for NaCl from a Mie-Grüneisen equation was repeated using more accurate values of the zero-pressure compressibility. It was also extended to KCl and CsCl. An analysis of this approach to pressure calibration indicates that it will yield pressures with about the same accuracy as can be presently achieved by experimental measurements above 25 kbar, and thus furnishes a temporary practical pressure scale.

Structure, Stratigraphy, And Ore Deposits Of The Central Nacimiento Mountains, New Mexico, William H. Kaufman

Earth and Planetary Sciences ETDs

The mapped area is in Sandoval and Rio Arriba Counties, New Mexico, 3 mi southeast of Cuba and includes the eastern margin of the San Juan Basin and the western margin of the Nacimiento Mountains. The emphasis of this report is on the stratigraphy, structure, and ore deposits of this area.

The Precambrian quartz monzonite basement rock is non-conformably overlain by approximately 6000 ft of sedimentary rocks, which range in age from Pennsylvanian to Cretaceous. The Pennsylvanian Madera Formation is predominantly marine limestone and is overlain by the clastic Permian Abo and Yeso Formations. A maximum of 1050 ft of …

Analysis Of Littoral Transport By Wave Energy: Cape Henry, Virginia To The Virginia, North Carolina Border, Zvi Henry Weinman

OES Theses and Dissertations

An investigation of the rate of littoral transport by an analysis of wave energy for the area from Cape Henry, Virginia to the Virginia, North Carolina border is made. Wave refraction diagrams are done by digital computer. Total upcoast (northerly) transport is determined to be 2.05 x 10⁶ yds³/year. Total downcoast (southerly) transport is determined to be 1.07 x 10⁶ yds³/year. Net transport is determined to be 9.8 x 10⁵ yds³/year in an upcoast (northerly) direction. The values obtained are compared with those of similar areas. The general efficacy of the …

Observations On The Hydraulic Regime Of The Ridge And Swale Topography Of The Inner Virginia Shelf, Barry W. Holliday

OES Theses and Dissertations

The Virginia inner shelf is dominated by southwest-trending sand ridges. Wavelengths are 2 to 4 km; amplitudes are up to 10 m; crests can be traced for up to 10 cm, Nearshore ridges trend southwest into the shore face and merge with it at depths as shoal as 5 m. The ridges have been examined by bathymetric mapping, grab sampling, coring, seismic profiling, SCUBA diving, and current monitoring. They are hemi-cylindrical sand bodies of recent age, resting on a pre-recent substrate. In troughs a thin, medium- to coarse-gained, pebbly lag veneers the substrate. Crests consist of a better sorted, medium- …

Umr Journal: Alaska -- Its Mineral Potentials And Environmental Challenges, University Of Missouri--Rolla

UMR Journal -- V. H. McNutt Colloquium Series

No abstract provided.

Arctic Ecology: A Decade Of Experience, John F. Schindler

UMR Journal -- V. H. McNutt Colloquium Series

A quick glance at the title of this presentation and the reader braces himself for another antipollution or “save-the-sod” type of discourse that has become so popular these days. I do not wish to detract from the importance or the need for such efforts but I would like to address myself to the the broader meaning of the term.

Ecology--the word comes from the Greek root “oikos” which means house or household. What I’d like to do is to tell you about this “house” I’ve been living in for the past 10 years.