Digital Commons Network^™

Rhenium Catalyzed Hydrogenation Of Maleic Anhydride And Crotonaldehyde, William Russel Dixon

Theses and Dissertations

The preparation of a number of supported rhenium catalysts is reported. The determination of their activity and selectivity and of optimal reaction parameters for the reduction of maleic anhydride and crotonaldehyde is reported. Optimal time of hydrogenation was chosen as one hour and pressures were chosen as 2000 psig for crotonaldehyde and 3000 psig for maleic anhydride. Quantitative reduction of maleic anhydride to tetrahydrofuran occurred at 275° with charcoal supported rhenium catalysts. Lower temperatures (ca. 200°) produce quantitative amounts of butyrolactone. Unsupported catalysts at low temperatures (100°) selectively reduce crotonaldehyde to crotyl alcohol, but at very low conversion rates. Temperatures …

Toward Hydrogen Bonds Of Predictable Geometry, Robert Shao-Chih Hsu

Theses and Dissertations

A literature review on the geometry of hydrogen bonding showed that the geometry is often de-emphasized or even ignored, probably because of the inherent flexibility of many systems studied. Examination of molecular models suggested the geometrically constrained bicyclo [2, 2, 1] heptane system wherein hydrogen bond distances and angles might be more easily predicted. Dihydroboration-oxidation of norbornadiene was shown to yield exo, exo-2,5-norbornadiol, thus clarifying uncertainties in the literature. 2, 5-Norbornadiol was oxidized to the corresponding dione, heretofore inadequately characterized. Several derivatives of the dione were prepared, and spectral data were accumulated for the dione, its precursor, and its derivatives. …

Assisting Mothers To Successfully Breast Feed Their Babies, Annabelle Moore

Loma Linda University Electronic Theses, Dissertations & Projects

This experimental study tested the effect of a teaching program on success of a group of mothers desiring to breast feed their babies. It was hypothesized that mothers receiving specific instructions on the physiology of lactation and the proper sucking technique would have greater success than mothers not so instructed.

To be categorized as successful the mothers had to have an adequate supply of milk and had to express satisfaction with breast feeding. Criteria for adequacy of milk supply consisted of weight gain of the infant within accepted norms without use of supplementary formula.

Twenty breast feeding mothers who delivered …

A Clinical Comparison Of Six Orthodontic Techniques, Erik H. Madsen

Loma Linda University Electronic Theses, Dissertations & Projects

Controversy exists concerning the relative superiority of various orthodontic techniques because of the difficulties encountered in making comparative clinical studies of these techniques which are scientific and statistically meaningful. The purpose of this study was to clinically compare six different orthodontic techniques which are currently being taught, relative to a number of criteria, and to do it in a scientifically significant manner.

In order to eliminate as many of the irrelevant variables as possible, the patients were required to pass a relatively stringent screening to participate. Among other things, the patients had to have first molars in Class I relation …

Two Emotional Factors And Weight Loss Among Females Attending A Weight Control Class, Karen Lynn Carrigg, Eileen Rae Wangerin

Loma Linda University Electronic Theses, Dissertations & Projects

A descriptive study was conducted on twenty-four females attending a weight control class to discover the effect of weight loss upon levels of self-esteem and anxiety, as an understanding of the relation of these factors to reduction and control of weight would prove helpful to community health nurses in counseling with overweight and obese persons in the community.

The entire sample was tested for self-esteem (TSCS) and A-State and A-Trait anxiety levels at the initial class of the weight control program sponsored by the Health Education Department of Loma Linda University Medical Center, and again after seven weeks of class …

Selected Factors Related To Ability To Regain Bladder Function Following Indwelling Catheterization, Jongkolnee Padmasiri

Loma Linda University Electronic Theses, Dissertations & Projects

This exploratory retrospective study was designed to evaluate selected factors, including the ability to regain bladder function related to post indwelling urethral catheterization in an acute general hospital population.

The records of 107 patients who met the study criteria became the study population. These patients had three-way urethral catheters, continuous antibacterial irrigation and closed drainage system. Twenty patients died (19 percent) before the catheter was removed. Of the 87 patients who were alive, 37 percent (32 patients) had in-adequate bladder function. Of these 32 patients, no attempt was made to remove the catheter from 15 prior to their hospital discharge. …

Some Physical Characteristics Of A Small Agricultural Watershed In East-Central Illinois, Ruth Laurence Davis

Senior Honors Papers / Undergraduate Theses

No abstract provided.

Synthesis And Metal Coordination Properties Of Some Cyclic Polyethers And Polythioethers, Barry Lant Haymore

Theses and Dissertations

Thermodynamic values for cation-cyclic polyether interactions for several systems are reported and discussed in light of ligand geometry, cation selectivity, solvent effects, structure, stoichiometry and the nature of the coordinate bond. Cyclic polyethers are shown to be remarkably good ligands even in water and to have marked selectivity for d0, d10 and d10 s2 cations. Syntheses of one new cyclic polyether and several new mixed cyclic polyether-thioethers are reported. Cyclic chelates with smaller rings are shown to prefer smaller cations, but this selectivity is masked by the hydration energy of the cation. Except for thiophillic cations such as Hg2+ and …

Enzymatic Synthesis Of Oligoribonucleotides Of Defined Base Sequence, Mark J. Rowe

Theses and Dissertations

The synthetic reaction of ribonuclease T_1 has been studied as to its potential for the synthesis of oligoribonucleotides of defined base sequence. Conditions have been determined for maximum synthesis with respect to percentage incorporation of both guanosine 2',3'-cyclic phosphate (donor), and cytidine (acceptor). With regard to maximum acceptor incorporation, a donor blocked at the 5'-hydroxyl has been used to drive the reaction. It has also been shown that acceptor incorporation decreases as the chain-length increases up to the hexanucleotide. Synthesis of a 3'-blocked substrate for polynucleotide phosphorylase for use in chain termination studies was attempted using adenylate kinase. In this …

Molecular Model For Prenucleation Water Clusters, P. L. M. Plummer, Barbara N. Hale

Physics Faculty Research & Creative Works

A molecular model applicable to prenucleation water clusters is described. As an illustration the model is applied to water clusters having clathrate-like structures composed of five-menibered rings. This work was motivated by the apparent inadequacies of the corrected liquid drop model which (in addition to applying bulk properties to small clusters) predicts nucleation rates which may be as much as 10¹⁷ larger than experiment. We present the "energy of formation" at a temperature of 277°K for our molecular model for clusters ranging in size from 5 to 57 molecules. These results agree qualitatively with experiment and, we believe, provide …

Acid-Base Titrations In Sulfolane, Francine O. Lawrence

Chemistry and Chemical Biology ETDs

A study of the solvent effects of sulfolane (tetrahydrothiophene 1, 1-dioxide, tetramethylene sulfone) upon a series of acids and several bases has been conducted. A procedure is presented for purifying sulfolane which results in a solvent of very low water content (5 x 10^-4 M) and very few impurities, as shown by its cooling curve. Potentiometric and conductometric measurements of additions of acids and bases to purified sulfolane and of various acid-base titrations were made. The series of carboxylic acids included benzoic, orthomethoxybenzoic, and three different monochlorobenzoic acids. The bases investigated included sodium methoxide, pyridine, and diphenylguanidine. Interpretation of …

A Maximum Principle For Time-Lag Control Problems With Bounded States, Gary R. Bunce

Mathematics & Statistics ETDs

A maximum principle is obtained for control problems involving system equations with a constant time lag in the control and state variables. The arcs under consideration are subject to constraints of the form

The results are obtained using the method of M. R. Hestenes.

Operators As Elements In A Partially Ordered Linear Algebra., Edward Wayne Davenport

Mathematics & Statistics ETDs

R. DeMarr {unpublished) has begun a study of linear operators as elements in a Dedekind O-complete partially ordered linear algebra {dsc-pola). The order structure necessary to produce elements in a dsc-pola which behave as specific operators on a specific space of functions is studied.

84th Session Of The Iowa Academy Of Science, April 28-29, 1972, Iowa Academy Of Science

Iowa Academy of Science Documents

No abstract provided.

Diurnal Studies At A Station On An Urban Estuary In Norfolk, Virginia, Burton Marc Golue

Biological Sciences Theses & Dissertations

No abstract.

Continuous Wave Co2 Laser Degradation And Mass Spectrometric Analysis Of Organic Polymers, Stanley G. Coloff

Chemistry and Chemical Biology ETDs

Previous laser-mass spectrometer and laser-gas-chromatographic instruments for study of organic polymer degradation have used high power pulsed lasers (ruby, Nd-glass) which limit sample characterization due to extensive fragmentation. A new experimental technique has been developed for high temperature pyrolysis and rapid analysis of organic polymers. The experimental technique combines a low power continuous wave CO₂ laser for sample pyrolysis and a time-of-flight mass spectrometer to analyze degradation products. The laser built for use in this study was a continuous flow CO₂ gas-molecular laser excited by high voltage direct current with maximum power of 10 watts at a wavelength …

Decoding By Sequential Code Reduction, Luther D. Rudolph, Carlos R.P. Hartmann

Electrical Engineering and Computer Science - Technical Reports

A general decoding method for cyclic codes is presented which gives promise of substantially reducing the complexity of decoders at the cost of a modest increase in decoding time (or delay). Significant reductions in decoder complexity for binary cyclic finite-geometry codes are demonstrated, and two decoding options for the Golay code are presented.

Water Resources News, Volume 4, No. 3, March 1972

Water Current Newsletter

1972 Annual Meeting of UCOWR
Summer Short Course Planned
Simulation of Water Resources Systems
Institute on Applications of Stochastic Methods in Civil Engineering
Institute on River Mechanics
Water Resources Systems - Short Course
International Symposium on Mathematical Modelling Techniques in Water Resources Systems
Seminar on Advances in Practical Hydrology
NWRA Resolutions
EPA to Be Advised By Experts on Sewage Plant Construction
GAO Questions EPA Insistence on Clean Waste Water
Study on Water Subsidies
EPA Bias for Sewage Hinders Farm Cleanup
Land Use Planning
Rural Development Act (HR 12931) Passed by House
Saline Water Bill Goes to House
1973 USGS Budget …

Studies Of Bistable Fluid Devices For Particle Flow Control, Gerald H. Hogland

Dissertations and Theses

This study was directed toward the development of a bistable wall attachment Flip-Flop device which was capable of directionally controlling particle flow. The particles were transported by a fluid stream which under the influence of wall attachment. The dominant criteria in the development of the device was the achievement of the highest recovery of particles at the active output, without destroying the wall attachment of the fluid stream The experiment was conducted in several distinct stages; each of which was concerned with at least one aspect of wa1l attachment or particle flow. Results derived from one test were used to …

Some Results On The Best Match Problem, Luther D. Rudolph, Kishan Mehrotra, Ralph J. Longobardi

Electrical Engineering and Computer Science - Technical Reports

The "best-match problem" is concerned with the complexity of finding the best match between a randomly chosen query word and the members of a randomly chosen set of data words. Of principal interest is whether it is possible to significantly reduce the search time required, as compared to exhaustive comparison, by use of memory redundancy (file structure). Minskv and Papert conjecture that "the speed-up values of large memory redundancies is very small, and for large data sets with long word lengths there are no practical alternatives to large searches that inspect large parts of memory". For this report we present …

Catechol Effected Dissolution Of Silicate Minerals, James Maurice Kelley

Dissertations and Theses

The chemical properties of guanidinium tris(catecholato)siliconate, [(H₂N)₂C=NH₂]₂[Si(C₆H₄O₂)₃]·XH₂O (0 < X < 1), precipitated from an ammoniacal solution of silica and catechol by adding guanidinium hydrochloride, (H₂N)₂C=NH·HC1, were studied, and infrared, nmr, x-ray powder diffraction, and analytical data were gathered.

This same compound was, upon addition of' (H₂N)₂C=NH·HC1, isolated from 0.25, M aqueous catechol solutions buffered at pH 10 and containing the silicate minerals albite, andradite, muscovite, pyrophyllite, talc, and wollastonite, and also from unbuffered catechol solutions containing wollastonite and andradite.

It is concluded from this work that the formation of an anionic catechol-silicon complex, Si(C₆H₄O₂)₃²⁻, is largely responsible for the dissolution of the minerals mentioned above. From this conclusion, it is proposed that naturally occurring members of the class of organic compounds to which catechol belongs, the aromatic v̲i̲̲c̲-diols, may play …

On The Mechanism Of Low-Temperature Termolecular Atomic Recombination, Russell T. Pack, Richard L. Snow, Wesley D. Smith

Faculty Publications

A simple theory of gas-phase termolecular atomic recombination kinetics is presented which treats the bound-complex (BC) mechanism in a fashion which parallels the Roberts, Bernstein, and Curtiss resonance theory of the energy-transfer (ET) mechanism. The ET rate constant has a low temperature maximum, but the BC rate constant does not. The contributions of the two mechanisms to the low-temperature recombination of hydrogen atoms, with He, Ar, and H2 as third bodies, are estimated and compared. The presence (absence) of a low-temperature maximum in the observable total rate constant is determined by absence (presence) of bound vibrational levels of the hydrogen-third …

Historic Resource Study: Cattle Raising In The Canyons, James Sheire

Elusive Documents

No abstract provided.

The U.S. Merchant Fleet: Patterns For The Seventies (U), Glenn Edward Whisler Jr.

Marine Affairs Theses and Major Papers

An analysis of recent U.S. maritime legislation in order to predict the possible effect it may have on our merchant fleet growth patterns for the seventies. Major attention is devoted to the Merchant Marine Act of 1970 which the Administration and Congress hopes will halt the continuing decline of the U.S. merchant fleet. The investigation is limited to the shipbuilding industry and is concerned primarily with government incentives, provided to both shipbuilders and shipowners, designed to stimulate new building programs. This study finds that the U.S. merchant fleet will experience a healthy growth during this decade as a result of …

The Geology Of The Southeast Quarter Of The Bone Mountain Quadrangle, Oregon, Richard Cortland Kent

Dissertations and Theses

This thesis is a study of the geology of the southeast quarter of the Bone Mountain Quadrangle. The bedrock geology mapped includes about 56 square miles.The Klamath Mountain and Coast Range Provinces of southwestern Oregon are represented in the area. Rocks in the area include the Rogue, Dothan Riddle, Days Creek, upper member of the Umpqua and Tyee Formations. The ages of these rocks range from Late Jurassic to middle Eocene. Late Jurassic ultramafic and mafic intrusive rocks associated with the Rogue Formation occur in the Klamath Province. The metavolcanics of the Rogue Format ion and an associated linear belt …

Some Quasi-Uniform Space Examples, Troy L. Hicks, J. W. Carlson

Mathematics and Statistics Faculty Research & Creative Works

No abstract provided.

Water Resources Of Part Of Canyonlands National Park, Southeastern Utah, C. T. Sumsion, E. L. Bolke

Canyonlands Research Bibliography

Canyonlands National Park is in about the center of the Canyon Lands section of the Colorado Plateaus physiographic province in southeastern Utah. The part of the park discussed embraces an area of about 400 square miles comprising isolated mesas, precipitous canyons, and dissected broad benches near the confluence of the Green and Colorado Rivers, the only perennial streams in the area. The climate is arid to semiarid; normal annual precipitation ranges from less than 8 to about 10 inches. Potential evapotranspiration is about 41 inches annually.

Geology of the park is characterized by nearly horizontal strata that dip gently northward. …

Trend Surface Analysis As An Aid In Exploration For Mississippi Valley Type Ore Deposits, John Siegfried Trapp

Doctoral Dissertations

"The conditions necessary for emplacement of Mississippi Valley-type mineral deposits can be expressed using mathematical symbols as a function of the pre-depositional topography of the host formation and post-depositional structure. These conditions can be observed and analyzed in the Missouri region from residual maps of trend surface analysis of the Precambrian surface. In areas where the topography prior to deposition of the ore bearing horizon has been strongly altered by the deposition of the basal Paleozoic formation the Lamotte Formation residual maps from trend surface analysis of the top of the Lamotte better illustrate these conditions. The Lamotte Formation in …

Selected First Row Transition Metal Coordination Compounds Of 2-(N-Aminomethyl)-3-Quinuclidinone Chelates, Richard Cecil Dickinson

Doctoral Dissertations

"As part of a project directed towards elucidating the characteristics of ligands which coordinate to give complexes having tetrahedral structures, a study of chelates containing the bulky quinuclidine group has been made. With 2-(N-morpholinylmethyl)-3-quinuclidinone (MQN), complexes having the general formula M(MQN)X₂ were prepared where the metal ion was Co(II), Ni(II), Fe(II), Cu(II), and Mn(II). The ligands 2-(N-piperidinylmethyl)-3-quinuclidinone (PQN) and 2-(N-dimethylaminomethyl)-3-quinuclidinone (DQN) were prepared along with the analogous cobalt(II) chloride complexes. The series of complexes Co(MQN)X₂ where X = Cl, Br, or I were prepared, and magnetic susceptibilities and spectral data obtained. They have room temperature magnetic moments in the range …

Structure Of Zero Divisors, And Other Algebraic Structures, In Higher Dimensional Real Cayley-Dickson Algebras, Harmon Caril Brown

Doctoral Dissertations

"Real Cayley-Dickson algebras are a class of 2ⁿ-dimensional real algebras containing the real numbers, complex numbers, quaternions, and the octonions (Cayley numbers) as special cases. Each real Cayley-Dickson algebra of dimension greater than eight (a higher dimensional real Cayley-Dickson algebra) is a real normed algebra containing a multiplicative identity and an inverse for each nonzero element. In addition, each element a in the algebra has defined for it a conjugate element ā analogous to the conjugate in the complex numbers. These algebras are not alternative, but are flexible and satisfy the noncommutative Jordan identity. Each element in these algebras can …