Open Access. Powered by Scholars. Published by Universities.®
- Institution
-
- Singapore Management University (9338)
- Missouri University of Science and Technology (7188)
- City University of New York (CUNY) (3688)
- University of Nevada, Las Vegas (3616)
- Brigham Young University (2703)
-
- University of South Florida (2433)
- University of New Mexico (1990)
- University of Texas at Arlington (1989)
- University of Central Florida (1817)
- University of South Carolina (1789)
- Portland State University (1482)
- Syracuse University (1144)
- Chulalongkorn University (1139)
- University of Nebraska - Lincoln (963)
- University at Albany, State University of New York (862)
- Washington University in St. Louis (740)
- TÜBİTAK (643)
- The Texas Medical Center Library (550)
- Claremont Colleges (430)
- Loma Linda University (399)
- University of Denver (376)
- Old Dominion University (367)
- Utah State University (314)
- University of Kentucky (309)
- Wright State University (268)
- California State University, Monterey Bay (265)
- Regis University (260)
- Louisiana State University (257)
- Western Kentucky University (243)
- SIT Graduate Institute/SIT Study Abroad (238)
- Keyword
-
- Machine learning (746)
- Mathematics (481)
- 2014 International Conference on Hydroinformatics HIC (464)
- Artificial intelligence (433)
- Deep learning (401)
-
- Humans (355)
- Machine Learning (346)
- Climate change (262)
- College for Professional Studies (253)
- Chemistry (242)
- Sustainability (239)
- Education (236)
- School of Computer & Information Science (236)
- Agriculture (230)
- Deep Learning (217)
- Artificial Intelligence (216)
- College of Natural Science and Mathematics (209)
- Natural language processing (208)
- Security (205)
- Chemistry and Biochemistry (196)
- Algorithms (195)
- Mathematics Research (195)
- Statistics (194)
- Computer Science (193)
- Natural resources (183)
- Optimization (181)
- Geology (180)
- Atmospheric chemistry (166)
- Early California maps (165)
- Emissions (165)
- Publication Year
- Publication
-
- Research Collection School Of Computing and Information Systems (8519)
- Theses and Dissertations (3384)
- Physics Faculty Research & Creative Works (1959)
- Faculty Publications (1607)
- Electronic Theses and Dissertations (1404)
-
- Publications and Research (1350)
- UNLV Theses, Dissertations, Professional Papers, and Capstones (1270)
- Dissertations and Theses (1250)
- Chulalongkorn University Theses and Dissertations (Chula ETD) (1117)
- Chemistry Faculty Research & Creative Works (939)
- Masters Theses (938)
- Computer Science Faculty Research & Creative Works (907)
- International Journal of Speleology (906)
- Dissertations, Theses, and Capstone Projects (836)
- Doctoral Dissertations (743)
- Legacy Theses & Dissertations (2009 - 2024) (741)
- Branch Mathematics and Statistics Faculty and Staff Publications (712)
- USF Tampa Graduate Theses and Dissertations (628)
- Physics - All Scholarship (554)
- Faculty, Staff and Student Publications (525)
- Open Educational Resources (473)
- International Conference on Hydroinformatics (464)
- Mathematics and Statistics Faculty Research & Creative Works (461)
- Arts & Sciences Graduate Student Theses and Dissertations (425)
- Computer Science Technical Reports (411)
- Loma Linda University Electronic Theses, Dissertations & Projects (399)
- Computer Science and Engineering Theses - Archive (365)
- School of Geosciences Faculty and Staff Publications (350)
- Mathematics Technical Papers - Archive (343)
- Earth and Planetary Sciences ETDs (317)
- Publication Type
Articles 1531 - 1560 of 58460
Full-Text Articles in Entire DC Network
Revisiting The Canonicalization For Fast And Accurate Crystal Tensor Property Prediction, Haowei Hua Hua, Jingwen Yang, Wanyu Lin, Pan Zhou
Revisiting The Canonicalization For Fast And Accurate Crystal Tensor Property Prediction, Haowei Hua Hua, Jingwen Yang, Wanyu Lin, Pan Zhou
Research Collection School Of Computing and Information Systems
Predicting the tensor properties of crystalline materials is a fundamental task in materials science. Unlike single-value property prediction, which is inherently invariant, tensor property prediction requires maintaining O(3) group tensor equivariance. Such equivariance constraint often requires specialized architecture designs to achieve effective predictions, inevitably introducing tremendous computational costs. Canonicalization, a classical technique for geometry, has recently been explored for efficient learning with symmetry. In this work, we revisit the problem of crystal tensor property prediction through the lens of canonicalization. Specifically, we demonstrate how polar decomposition, a simple yet efficient algebraic method, can serve as a form of canonicalization and …
Tempo: Training-Time Equilibration Of Modalities For Per-Sample Optimization In Multimodal Sentiment, Yi Zhao, Erik Cambria, Xiaosong E, Xianxun Zhu
Tempo: Training-Time Equilibration Of Modalities For Per-Sample Optimization In Multimodal Sentiment, Yi Zhao, Erik Cambria, Xiaosong E, Xianxun Zhu
Research Collection School Of Computing and Information Systems
Multimodal sentiment models often become over-reliant on the “easiest” modality (typically text), leading to three coupled sub-problems: (i) representation-level dominance, where weaker modalities contribute little to the fused representation; (ii) optimization-level dominance, where the strongest modality drives most gradient updates and suppresses learning in others; and (iii) robustness degradation, where audio or vision fail under noise or missing inputs at test time. We present TEMPO, a plug-and-play training framework that mitigates these issues by rebalancing learning pressure across modalities while leaving inference unchanged. For each mini-batch, TEMPO estimates relative modality strength and applies two synchronized, training-only controls: selective forward attenuation …
Purified Zero-Shot Sketch-Based Image Retrieval, Yang Zhou, Jingru Yang, Jin Wang, Kaixiang Huang, Guodong Lu, Shengfeng He
Purified Zero-Shot Sketch-Based Image Retrieval, Yang Zhou, Jingru Yang, Jin Wang, Kaixiang Huang, Guodong Lu, Shengfeng He
Research Collection School Of Computing and Information Systems
Sketches, as a new solution in multimedia systems that can replace natural language, are characterized by sparse visual cues such as simple strokes that differ significantly from natural images containing complex elements such as background, foreground, and texture. This misalignment poses substantial challenges for zero-shot sketch-based image retrieval (ZS-SBIR). Prior approaches match sketches to full images and tend to overlook redundant elements in natural images, leading to model distraction and semantic ambiguity. To address this issue, we introduce a distraction-agnostic framework, purified cross-domain matching (PuXIM), which operates on a straightforward principle: masking and matching. We devise a visual-cross-linguistic (VxL) sampler …
Portfoliopilot: An Agentic Platform For Financial Portfolio Management Algorithm Development And Evaluation, Jared Chan Xu Yang, Haokai Ma, Yunshan Ma
Portfoliopilot: An Agentic Platform For Financial Portfolio Management Algorithm Development And Evaluation, Jared Chan Xu Yang, Haokai Ma, Yunshan Ma
Research Collection School Of Computing and Information Systems
Developing new portfolio-management algorithms typically demands substantial programming effort, limiting rapid experimentation and excluding finance professionals without coding skills. Current robo-advisory tools offer pre-built but rigid strategies, restricting customization and experimentation. We introduce PortfolioPilot, an open-source, agentic platform that enables users to generate bespoke portfolio through natural-language descriptions. Leveraging the Anthropic Claude API, PortfolioPilot dynamically synthesizes executable TypeScript algorithms that run in the frontend with security validation. The system integrates real-time backtesting with historical market data, classical optimization algorithms (Markowitz, LSTM, ARIMA), and interactive performance visualizations.
Nondeterministic Polynomial-Time Problem Challenge: An Ever-Scaling Reasoning Benchmark For Llms, Chang Yang, Ruiyu Wang, Junzhe Jiang, Qi Jiang, Qinggang Zhang, Yanchen Deng, Shuxin Li, Shuyue Hu, Bo Li, Florian T. Pokorny, Xiao Huang, Xinrun Wang
Nondeterministic Polynomial-Time Problem Challenge: An Ever-Scaling Reasoning Benchmark For Llms, Chang Yang, Ruiyu Wang, Junzhe Jiang, Qi Jiang, Qinggang Zhang, Yanchen Deng, Shuxin Li, Shuyue Hu, Bo Li, Florian T. Pokorny, Xiao Huang, Xinrun Wang
Research Collection School Of Computing and Information Systems
Reasoning is the fundamental capability of large language models (LLMs). Due to the rapid progress of LLMs, there are two main issues of current benchmarks: i) these benchmarks can be crushed in a short time (less than 1 year), and ii) these benchmarks may be easily hacked. To handle these issues, we propose the ever-scalingness for building the benchmarks which are scaling over complexity against crushing, instance against hacking and exploitation, oversight for easy verification, and coverage for real-world relevance. This paper presents Nondeterministic Polynomial-time Problem Challenge (NPPC), an ever-scaling reasoning benchmark for LLMs. Specifically, the NPPC has three main …
Evaluating Large Language Models For Line-Level Vulnerability Localization, Jian Zhang, Chong Wang, Anran Li, Weisong Sun, Cen Zhang, Wei Ma, Yang Liu
Evaluating Large Language Models For Line-Level Vulnerability Localization, Jian Zhang, Chong Wang, Anran Li, Weisong Sun, Cen Zhang, Wei Ma, Yang Liu
Research Collection School Of Computing and Information Systems
Recently, Automated Vulnerability Localization (AVL) has attracted growing attention, aiming to facilitate diagnosis by pinpointing the specific lines of code responsible for vulnerabilities. Large Language Models (LLMs) have shown potential in various domains, yet their effectiveness in line-level vulnerability localization remains underexplored. In this work, we present the first comprehensive empirical evaluation of LLMs for AVL. Our study examines 19 leading LLMs suitable for code analysis, including ChatGPT and multiple open-source models, spanning encoder-only, encoder-decoder, and decoder-only architectures, with model sizes from 60M to 70B parameters. We evaluate three paradigms including few-shot prompting, discriminative fine-tuning, and generative fine-tuning with and …
Interpretable Multimodal Zero Shot Ecg Diagnosis Via Structured Clinical Knowledge Alignment, Jialu Tang, Hung Manh Pham, Ignace De Lathauwer, Henk S. Schipper, Yuan Lu, Dong Ma, Aaqib Saeed
Interpretable Multimodal Zero Shot Ecg Diagnosis Via Structured Clinical Knowledge Alignment, Jialu Tang, Hung Manh Pham, Ignace De Lathauwer, Henk S. Schipper, Yuan Lu, Dong Ma, Aaqib Saeed
Research Collection School Of Computing and Information Systems
Electrocardiogram (ECG) interpretation is essential for cardiovascular disease diagnosis, but current automated systems often struggle with transparency and generalization to unseen conditions. To address this, we introduce ZETA, a zero-shot multimodal framework designed for interpretable ECG diagnosis aligned with clinical workflows. ZETA uniquely compares ECG signals against structured positive and negative clinical observations, which are curated through an LLM-assisted, expertvalidated process, thereby mimicking differential diagnosis. Our approach leverages a pre-trained multimodal model to align ECG and text embeddings without disease-specific fine-tuning. Empirical evaluations demonstrate ZETA’s competitive zero-shot classification performance and, importantly, provide qualitative and quantitative evidence of enhanced interpretability, grounding …
Examining Inclusive Computing Education For Blind Students In India, Akshay Kolgar Nayak, Yash Prakash, Md Javedul Ferdous, Sampath Jayarathna, Hae-Na Lee, Vikas Ashok
Examining Inclusive Computing Education For Blind Students In India, Akshay Kolgar Nayak, Yash Prakash, Md Javedul Ferdous, Sampath Jayarathna, Hae-Na Lee, Vikas Ashok
Computer Science Faculty Publications
The growing demand for computer professionals, driven by the expanding Information Technology industry, has led to numerous inclusive computing education efforts. These efforts have even included blind or visually-impaired (BVI) students, who are being increasingly encouraged to pursue education and a career in computing, despite the visually-oriented nature of the discipline. Extant literature has predominantly focused on identifying and addressing the accessibility barriers faced by BVI students to promote more inclusive learning environments. While few studies have also investigated the accessibility of computing education from the perspectives of BVI learners and instructors, these have been primarily situated in the Global …
An Explainable Transformer Framework For Sentiment Analysis In Aviation Workforce Data, Sovon Chakraborty, Protiva Das, Fahmid Al Farid, Fuyad Hasan Bhoyan, Farig Yousuf Sadeque, Jia Uddin, Hezerul Abdul Karim
An Explainable Transformer Framework For Sentiment Analysis In Aviation Workforce Data, Sovon Chakraborty, Protiva Das, Fahmid Al Farid, Fuyad Hasan Bhoyan, Farig Yousuf Sadeque, Jia Uddin, Hezerul Abdul Karim
Computer Science Faculty Publications
Aviation is one of the predominant sectors that contribute significantly to the global economy. With the advent of technology, this industry is witnessing a paradigm shift towards data-driven approaches. The morale of the airline employees is barely noticed, which causes fatigue and depression. Furthermore, these mental health issues can be active reasons for destructive accidents. In this research, the authors are focused on collecting insightful information on aviation employees from Glassdoor.com. Moreover, the authors focus on analyzing the sentiments of the employees of renowned aviation companies. Primarily, the authors scraped necessary data from Glassdoor.com and created a dataset named JetJobJoy …
Finding The Signal In The Noise: An Exploratory Study On Assessing The Effectiveness Of Ai And Accessibility Forums For Blind Users' Support Needs, Satwik Ram Kodandaram, Jiawei Zhou, Xiaojun Bi, Iv Ramakrishnan, Vikas Ashok
Finding The Signal In The Noise: An Exploratory Study On Assessing The Effectiveness Of Ai And Accessibility Forums For Blind Users' Support Needs, Satwik Ram Kodandaram, Jiawei Zhou, Xiaojun Bi, Iv Ramakrishnan, Vikas Ashok
Computer Science Faculty Publications
Accessibility forums and, more recently, generative AI tools have become vital resources for blind users seeking solutions to computer-interaction issues and learning about new assistive technologies, screen reader features, tutorials, and software updates. Understanding user experiences with these resources is essential for identifying and addressing persistent support gaps. Towards this, we interviewed 14 blind users who regularly engage with forums and GenAI tools. Findings revealed that forums often overwhelm users with multiple overlapping topics, redundant or irrelevant content, and fragmented responses that must be mentally pieced together, increasing cognitive load. GenAI tools, while offering more direct assistance, introduce new barriers …
Lost In Instructions: Study Of Blind Users' Experiences With Diy Manuals And Ai-Rewritten Instructions For Assembly, Operation, And Troubleshooting Of Tangible Products, Monalika Padma Reddy, Aruna Balasubramanian, Jiawei Zhou, Xiaojun Bi, Iv Ramakrishnan, Vikas Ashok
Lost In Instructions: Study Of Blind Users' Experiences With Diy Manuals And Ai-Rewritten Instructions For Assembly, Operation, And Troubleshooting Of Tangible Products, Monalika Padma Reddy, Aruna Balasubramanian, Jiawei Zhou, Xiaojun Bi, Iv Ramakrishnan, Vikas Ashok
Computer Science Faculty Publications
AI tools like ChatGPT and Be-My-AI are increasingly being used by blind individuals. Although prior work has explored their use in some Do-It-Yourself (DIY) tasks by blind individuals, little is known about how they use these tools and the available product-manual resources to assemble, operate, and troubleshoot physical/tangible products – tasks requiring spatial reasoning, structural understanding, and precise execution. We address this knowledge gap via an interview study and a usability study with blind participants, investigating how they leverage AI tools and product manuals for DIY tasks with physical products. Findings show that manuals are essential resources, but product-manual instructions …
Contextual Scaffolding And Self-Efficacy: Supporting Computer Skill Development Among Blind Learners In India, Akshay Kolgar Nayak, Yash Prakash, Sampath Jayarathna, Hae-Na Lee, Vikas Ashok
Contextual Scaffolding And Self-Efficacy: Supporting Computer Skill Development Among Blind Learners In India, Akshay Kolgar Nayak, Yash Prakash, Sampath Jayarathna, Hae-Na Lee, Vikas Ashok
Computer Science Faculty Publications
Inclusive computer literacy education efforts, broadening the participation of blind or visually impaired (BVI) individuals, have gained traction in recent years. Existing literature investigating these efforts primarily draws evidence from affluent Global North contexts, where accessibility resources and legal frameworks are relatively more mature. Little is known about the in-situ teaching and learning challenges faced by trainers and BVI students, respectively, in resource-constrained, multicultural Global South countries like India. To address this knowledge gap, we conducted a four-month contextual inquiry at two computer training centers catering to 94 BVI students in India. We notably observed a rigid, experience-driven training environment …
Voxvista: Enhancing Screen Reading Experience For Online User Comments, Yash Prakash, Akshay Kolgar Nayak, Mohammed Shoaib Alyaan, Sampath Jayarathna, Hae-Na Lee, Vikas Ashok
Voxvista: Enhancing Screen Reading Experience For Online User Comments, Yash Prakash, Akshay Kolgar Nayak, Mohammed Shoaib Alyaan, Sampath Jayarathna, Hae-Na Lee, Vikas Ashok
Computer Science Faculty Publications
Online discussions have become integral to how people exchange ideas, form opinions, and participate in collective deliberation. While sighted users can comfortably engage with online discussions, blind users who are dependent on screen readers are forced to listen to long threads narrated in a single, monotonic voice that lacks prosodic variation, rhythm, or emotion. This robotic auditory experience not only deteriorates the user engagement with the content but also increases cognitive strain, by making it difficult to remain attentive and discern meaning beyond literal words. In an interview study, most blind participants reported that monotonous narration hindered their ability to …
Memebuddy: Dialog-Style Audio Representations For Engaging Non-Visual Meme Experiences, Chirag Bhansali, Vikas Ashok, Hae-Na Lee
Memebuddy: Dialog-Style Audio Representations For Engaging Non-Visual Meme Experiences, Chirag Bhansali, Vikas Ashok, Hae-Na Lee
Computer Science Faculty Publications
Image memes are a pervasive form of online communication, widely used to convey humor, opinions, and cultural references. Prior work has explored making memes accessible to blind users, primarily through auto-generated descriptive captions. While these approaches improve comprehensibility and sometimes incorporate prosodic or emotional cues, they often fail to capture the humor, narrative structure, and contextual nuances that make memes engaging. We present MemeBuddy, a system that models memes as dialog, generating structured, multi-turn audio representations using role-based speakers. MemeBuddy reinterprets a meme as a conversation between two speakers, integrating extracted meme text with contextual knowledge implicitly inferred by a …
Environmental Pesticide Exposure In The Etiology Of Pediatric Brain Tumors And Leukemia: A Scoping Review Of Epidemiological Studies, G. N. Vandesteeg, A. R. Russman, M. R. Sandbulte, E. G. Rogan, M. G. Rhodes
Environmental Pesticide Exposure In The Etiology Of Pediatric Brain Tumors And Leukemia: A Scoping Review Of Epidemiological Studies, G. N. Vandesteeg, A. R. Russman, M. R. Sandbulte, E. G. Rogan, M. G. Rhodes
School of Natural Resources: Faculty Publications
No abstract provided.
Tree-Based Graph Neura Networks For Natural Language Inference: From Structure-Only To Hybrid Architectures, Jason P. Lunder
Tree-Based Graph Neura Networks For Natural Language Inference: From Structure-Only To Hybrid Architectures, Jason P. Lunder
EWU Masters Thesis Collection
Large transformer models achieve strong performance on natural language understanding tasks but require hundreds of millions of parameters and extensive pretraining. This thesis investigates whether graph neural networks operating on dependency parse trees can provide more parameter-efficient sentence representations for natural language inference, evaluated on two NLI tasks: entailment classification and semantic textual similarity.
Tree Matching Networks (TMN) adapt Graph Matching Networks to linguistic dependency trees with rich node and edge features, evaluated against a BERT baseline at matched parameter counts on identical training data. Tree Transformer Networks (TTN) extend TMN with transformer-based aggregation and tree-aware positional encodings, with component …
Automated Writer And Acquisition-Condition Classification Of Digitally Captured Handwriting Using Statistical Dynamic Features And Support Vector Machines, Long-Huang Tsai, Hsiang-Ju Lai, Wen-Chao Yang, Jiajun Jiang, Chung-Hao Chen
Automated Writer And Acquisition-Condition Classification Of Digitally Captured Handwriting Using Statistical Dynamic Features And Support Vector Machines, Long-Huang Tsai, Hsiang-Ju Lai, Wen-Chao Yang, Jiajun Jiang, Chung-Hao Chen
Electrical & Computer Engineering Faculty Publications
Digitally captured handwriting preserves pen trajectories and dynamic signals, but it also records hardware- and input-dependent properties that can confound forensic interpretation. This study revises a support vector machine (SVM) screening framework using 16,500 samples from 30 writers, 11 writing-content categories, and five acquisition conditions spanning three tablets and stylus or finger input. Twenty-four raw and derived time-series variables were summarized by maximum, minimum, mean, median, and standard deviation, yielding 120 features; the mode statistic was removed. Writing direction and angular velocity were recalculated with atan2-based vector formulas. Unavailable device/API channels were encoded as zero, and Z-score parameters were estimated …
Empirical-Based Model Of Spatio-Temporal Errors, Godwin Naaba Ndaa
Empirical-Based Model Of Spatio-Temporal Errors, Godwin Naaba Ndaa
Masters Theses
This research develops an empirical model to characterize spatial-temporal InSAR errors and improve the accuracy of deformation time-series analysis. Using standardized Sentinel-1 HyP3 products and MintPy, the study quantifies how correlated noise affects velocity precision and validates the results against continuous GNSS velocities.
Residual velocities are near-Gaussian, with σ ~0.92–2.04 cm/yr and ~1 cm/yr on average. Variograms show power-law spatial structure with a non-zero nugget implicating troposphere and decorrelation while errors drop exponentially with more acquisitions; spatial uncertainty is strongly affected by unwrapping errors, coherence, and tropospheric noise, not simply troposphere.
A comparative assessment of on-demand cloud processing with other …
Transformer-Based Language Models For Bitcoin Market Prediction And Interpretation, Erich Gozebina
Transformer-Based Language Models For Bitcoin Market Prediction And Interpretation, Erich Gozebina
Masters Theses
"In the context of a Master's thesis in applied mathematics, this work investigates compact transformer-based language models as an instrument for Bitcoin-related predictions and decision support. The work connects three topics: the structure of the Bitcoin system and its data, the mathematical and algorithmic foundations of deep autoregressive transformers, and the design of practical training pipelines for financial applications. On this foundation, a reproducible ETL pipeline for Bitcoin data is developed and two forecasting experiments are conducted with the compact language model nanochat. The first experiment approaches the prediction of next-day price movements through autoregressive next-token generation based on structured …
Non-Destructive Characterization Of Variously Colored Gypsum And Aragonite/Calcite Speleothems From The Cigalère Cave (Ariège, France), Martin Vlieghe, Johan Wouters, Gérald Fanuel, Jean-François Drion Du Chapois, Anne Gallez, Stéphane Pire-Stevenne, Gaëtan Rochez, Johan Yans
Non-Destructive Characterization Of Variously Colored Gypsum And Aragonite/Calcite Speleothems From The Cigalère Cave (Ariège, France), Martin Vlieghe, Johan Wouters, Gérald Fanuel, Jean-François Drion Du Chapois, Anne Gallez, Stéphane Pire-Stevenne, Gaëtan Rochez, Johan Yans
International Journal of Speleology
The Cigalère Cave is a 21 km-long karstic cave located in the Ariège Department, in the French Pyrenees, and underlies directly the Bentaillou Pb-Zn-Fe sulfide ores. The cave hosts abundant gypsum mineralizations, some of them exhibiting various colorations including blue, yellow, purple, orange and black. Due to strict preservation policies, these colored mineralizations have not been studied much. Here we propose a non-destructive characterization of five distinct gypsum or carbonate speleothem structures from the Cigalère, exhibiting different colorations. To comply with the preservation policies, no sample was taken from the cave, and all speleothems were analyzed in situ using portable …
Recent Climatology And Changes In Precipitating Storm Characteristics Over Conus, Tyler Landsparger
Recent Climatology And Changes In Precipitating Storm Characteristics Over Conus, Tyler Landsparger
Electronic Theses & Dissertations (2024 - present)
As anthropogenic greenhouse gas emissions continue to warm the global climate system, improving our understanding of how precipitating storms are responding in the real world has become increasingly important. This study leverages 22 years of high-resolution hourly precipitation data from the NCEP Stage IV dataset to produce a seasonal climatology and long-term trend analysis of precipitating storm frequency, duration, area, and intensity across the Contiguous United States (CONUS) from March 2002 through February 2024. Storms were identified and tracked using an object-tracking algorithm and their characteristics were computed for each season, from which 22-year climatology and trends were derived. The …
Investigation Of Fine-Grain Cu And Cu Alloys For Low-Temperature Hybrid Bonding Applications, Sarabjot Singh
Investigation Of Fine-Grain Cu And Cu Alloys For Low-Temperature Hybrid Bonding Applications, Sarabjot Singh
Electronic Theses & Dissertations (2024 - present)
Hybrid bonding has emerged as a key enabler for next-generation three-dimensional (3D) integration, offering fine-pitch interconnects and improved electrical performance. However, conventional Cu–Cu hybrid bonding typically requires elevated temperatures to achieve sufficient diffusion and interface quality, posing challenges for temperature-sensitive device integration and process compatibility. This work investigates materials engineering approaches to enable low-temperature Cu–Cu bonding through both microstructure design and alloying strategies.
This work begins by examining grain refinement in Cu as a pathway to enhance diffusion through increased grain boundary density, providing efficient atomic transport without introducing additional elements. Three Cu-based systems Cu–Co, Cu–Ag, and Cu–Al were systematically …
Photo And Spatial Control Of Rna Structures And Functions: Exploring Positional Effects And Photo-Responsiveness Of Azobenzene Modified Nucleotides, Jinxi Du
Electronic Theses & Dissertations (2024 - present)
RNA molecules perform many important biological functions by forming complex three-dimensional structures stabilized by base pairing, tertiary interactions, and metal ion coordination. Because RNA function depends strongly on its structure, methods that allow reversible control of RNA conformation and activity are important for understanding RNA behavior and for potential therapeutic applications. However, achieving reversible and site-specific control of RNA structure, especially at the single-nucleotide level, remains challenging. In this dissertation, I developed and applied azobenzene-modified nucleotides as a chemical tool to enable optical and spatial control of RNA structure and function.
The first part of this dissertation focuses on establishing …
Spectral Analysis Of Traffic Accidents In New York's Capital Region, Michael Barr
Spectral Analysis Of Traffic Accidents In New York's Capital Region, Michael Barr
Electronic Theses & Dissertations (2024 - present)
In this paper we estimate the spectral density of traffic accident events in the Capital Distict, NY area using a band-pass filter known as the Kolmogorov-Zurbenko Fourier Transform (KZFT). The source data is provided by Moosavi, et al. (2019) and originally captured from various public entities and sensors in the road network. Spectral density estimation with KZFT suppresses noise to reveal the constituent frequencies embedded in the noisy signal. Signal reconstruction based on KZFT produces an approximate weekly accident arrivals for this noisy signal, or in other words a pattern which is proportionate to the event expectation viewed over a …
Historical Changes In The Seasonality And Variability Of Daily Surface Air Temperature In Era5 And Cmip6 Models, Zirui Wan
Electronic Theses & Dissertations (2024 - present)
This thesis investigates historical changes in the seasonality and daily variability of near-surface air temperature (Tas) during 1950–2024 using ERA5 reanalysis and simulations from 21 CMIP6 models. ERA5 and CMIP6 show broadly similar climatological structures of the Tas seasonal cycle and variability, with considerable inter-model discrepancies. Both ERA5 and CMIP6 show decreasing Tas variability over northern mid-high latitudes, while Tas variability increases in the low latitudes in ERA5 but changes little in CMIP6 multi-model mean (MMM) due to different change patterns among the models. To investigate the mechanisms of historical Tas variability changes, I analyzed the relationships between Tas variability …
The Chemistry Of Red Lipstick: The Impact Red Lipstick Has On Society, Lilliana Weldeslassie
The Chemistry Of Red Lipstick: The Impact Red Lipstick Has On Society, Lilliana Weldeslassie
Electronic Theses & Dissertations (2024 - present)
Cosmetic chemistry is deeply embedded in everyday life, shaping the products people use from morning to night. Among these, red lipstick stands out as a formulation that blends complex chemistry with a cultural meaning. This thesis examines the scientific foundations of red lipstick through its chemical composition, pigment structure, toxicological history, analytical methods, and evolving sustainability practices. Historically, red lipsticks relied on high-risk ingredients such as lead, mercury, and other toxic metals, reflecting an era before chemical safety and regulatory oversight were incorporated.21 Modern formulations have established safer synthetic dyes, natural waxes, plant-based oils, and stabilizers created to optimize …
Development Of Photolabile Coumarin Linker For Rna Synthesis And Crisprcas9 Applications, Ian Mcclain
Development Of Photolabile Coumarin Linker For Rna Synthesis And Crisprcas9 Applications, Ian Mcclain
Electronic Theses & Dissertations (2024 - present)
The scope of RNA-based therapeutics continues to expand as more siRNA, mRNA, and CRISPR-based treatments are approved for various medical applications. Purification of synthetic RNA drugs is inherently challenging and requires considerable time and resources. New cost-effective and efficient purification strategies will expedite drug development process and will lower the drug costs. In this thesis I describe two generations of photolabile linkers for the non-chromatographic purification of therapeutic RNAs. In addition, the photolabile linker was utilized for regulation CRISPR-Cas9 gene editing. In the first part of the thesis, I describe the first generation of the photolabile coumarin-based linker for non-chromatographic …
An Evaluation Of Current And Future Extreme Precipitation Events In The South American Altiplano Using Convective-Permitting Model Simulations, Karen R. Conron Chamberlain
An Evaluation Of Current And Future Extreme Precipitation Events In The South American Altiplano Using Convective-Permitting Model Simulations, Karen R. Conron Chamberlain
Electronic Theses & Dissertations (2024 - present)
Extreme precipitation events in the South American Altiplano present significant hazards to communities in the Andean region, yet their future characteristics under anthropogenic climate change remain uncertain because of complex terrain and limitations of course-resolution climate models. This study evaluates the ability of South America Affinity Group Weather Research and Forecasting (SAAG-WRF) model with 4-km grid-spacing to reproduce 2000-2015 temperature, precipitation, and extreme precipitation events over the Altiplano. Examination of projected future changes is completed using the SAAG-WRF pseudo global warming (WRF PGW) simulation representing an approximately 3°C warmer global climate. The historical/control simulation (WRF CTL) was evaluated against DECADE …
Concerted Proton Transfer In Homogeneous And Heterogeneous Cyclic Hydrogen-Bonded Clusters Of H2o, Hf, And Hcl, Max R. Tucker, Yuan Xue, Nathan R. Speake, Eden Nickolson, Jeremy M. Carr, Gregory S. Tschumper
Concerted Proton Transfer In Homogeneous And Heterogeneous Cyclic Hydrogen-Bonded Clusters Of H2o, Hf, And Hcl, Max R. Tucker, Yuan Xue, Nathan R. Speake, Eden Nickolson, Jeremy M. Carr, Gregory S. Tschumper
Chemistry Faculty Research & Creative Works
This work examines various homogeneous and heterogeneous clusters of hydrogen-bonded (HF)x(H2O)y(HCl)z complexes, where x + y + z = 3 or 4. For each unique cyclic structure associated with the xyz permutations, the geometries of the reactant, product, and transition state (TS) for concerted proton transfer (CPT) were fully optimized using second-order Møller-Plesset perturbation theory (MP2) with a mixed basis set consisting of cc-pVTZ for H atoms and aug-cc-pVTZ for O, Cl, and F atoms (denoted haTZ). Harmonic vibrational frequencies were also computed at the same level of theory to verify the nature of the stationary points. Intrinsic …
Scalable Transfer Of Dna Origami–Directed Nanoparticle Arrays Onto Functional Surfaces Using Thermal Release Tape, Yuwei Zhang, Chikadibia Genevieve Edward, Ethan Keuhn, Shelley D. Minteer, Risheng Wang
Scalable Transfer Of Dna Origami–Directed Nanoparticle Arrays Onto Functional Surfaces Using Thermal Release Tape, Yuwei Zhang, Chikadibia Genevieve Edward, Ethan Keuhn, Shelley D. Minteer, Risheng Wang
Chemistry Faculty Research & Creative Works
Precise integration of DNA origami nanostructures onto functional substrates is essential for advancing electronics, photonics, and biosensing. However, most surface-assembly methods are highly sensitive to substrate type, limiting their broader applications. Here, we introduce a thermal release tape (TRT)-assisted transfer method that enables efficient, large-area printing of DNA origami-guided gold nanoparticle (AuNP-DNA origami) arrays from mica onto diverse surfaces. The method relies on differential adhesion: AuNP-DNA origami arrays form strong electrostatic and hydrogen-bonding interactions with 3-aminopropyltriethoxysilane (APTES)-functionalized receiver substrates, while the TRT adhesive weakens upon heating to 120°C, allowing release from the tape. Using this approach, well-ordered AuNP-DNA origami arrays …