Digital Commons Network^™

Expanded Scorpionate And Siderophore-Inspired Ligands: From Foundational Designs To Modern Applications, Austin Winfield Medley, Trandon Allen Bender

Chemistry & Biochemistry Faculty Publications

Scorpionate ligands have been advanced significantly through systematic modifications of their apical atoms and heterocyclic arms, expanding their structural diversity and chemical reactivity. Recent biologically inspired variants now enable accurate modeling of complex bioinorganic motifs, such as the Fe₄S₄ clusters of nitrogenase, and support enzyme‐like reactivity under mild aqueous conditions. These developments have broadened the impact of scorpionate chemistry across bioinorganic modeling, homogeneous catalysis, and biorthogonal transformations. In particular, expanded tripodal scaffolds provide modular, tunable platforms for mimicking enzyme active sites and probing biological nitrogen fixation pathways. Beyond fundamental insight, these ligands present practical opportunities for sustainable catalysis by enabling …

Learning Design To Advance Human-Ai Collaboration In K-12 Education, Wing Sha Chan, Jinhee Kim, Seongryeong Yu, Rita Kay Detrick

STEMPS Faculty Publications

This chapter explores key components for designing effective Human-AI Collaboration (HAC) in K–12 education, addressing the current lack of theoretical and conceptual frameworks for structuring and implementing HAC in teaching and learning. It examines four essential areas: curriculum design, student and teacher–AI interaction, learning environments, and the evolution of HAC over time. The chapter introduces the concept of HAC in K–12 contexts, highlighting how humans and AI can leverage each other's strengths through co-evolutionary processes that foster mutual learning and collaboration. It reviews current HAC practices in schools and discusses their contributions to both teaching and learning. Finally, it presents …

Wearable Sensor-Based Phase Segmentation Analysis Of Front Crawl Swimming: A Scoping Review, Jonathan Simoes, Samuel Aylward, Daniel Hamze, Daniel James Goble, Daniel M. Russell, Joshua Haworth

Exercise Science Faculty Publications

Front crawl swimming stroke phase segmentation has historically relied on video analysis, but the development of wearable sensor technology has created new opportunities for automated phase segmentation. This scoping review mapped the available evidence on wearable sensor-based stroke phase segmentation methods in front crawl swimming, following PRISMA-ScR guidelines. A systematic search of SPORTDiscus, Web of Science, and IEEE Xplore conducted from January to June 2026, identified 15 eligible peer-reviewed studies published between 2000 and 2024. The review revealed an emerging field of research that has converged methodologically around inertial measurement units (IMUs) and the Chollet phase segmentation framework while remaining …

Amorphous Selenium Photodetectors For Liquid Noble Detectors, Michael Rooks

Physics Dissertations - Archive

Physics offers a way to connect deeply with the mysteries that surround us. Advances in detector physics, particularly in neutrino experiments and rare-event searches, have expanded our ability to probe phenomena that challenge how we describe the universe. Each discovery brings us closer to understanding the unknown, returning us to a sense of wonder that motivates exploration. My work on detector technology was inspired by a concept paper from Professor David Nygren, in which he noted the speculative possibility of integrating photon detection into a charge readout for pixelated liquid argon time projection chambers (LArTPCs) using the photoconductor amorphous selenium …

Neighborhood Embeddings And Scalable Learning For Optimal Transport And Unbalanced Optimal Transport, Muhammad S. Rana

Mathematics Dissertations - Archive

Dimensionality reduction techniques are developed from the assumption that high-dimensional data often arises from low-dimensional structures embedded into the high-dimensional ambient space. Classical dimensionality reduction methods rely on the Euclidean distance, which may fail to capture the geometric structures of the datasets. This dissertation includes alternative metrics for dimensionality reduction techniques and challenges in applying these techniques.

First, we investigate the Wasserstein distance based neighbor embeddings for dimensionality reduction methods and compare the classification and clustering performance with the classical Euclidean based methods. The Wasserstein distance models the data as probability distributions and compares two distributions applying optimal transport (OT) …

Using Camera-Based Unmarked Spatial Capture-Recapture Modeling To Estimate Reintroduced Elk (Cervus Canadensis) Population Parameters And Distribution In Southeastern Kentucky, Claire Marie Muia

Theses and Dissertations--Forestry and Natural Resources

Estimation of population parameters is important for wildlife management decisions. Elk reintroduced to southeastern Kentucky experienced early irruptive population growth and are currently monitored using a statewide harvest-based statistical population reconstruction model (SPR) across the Kentucky Elk Restoration Zone (KERZ). Because the SPR model is spatially coarse and difficult to scale to the smaller management units comprising the KERZ, we conducted a spatially explicit capture-recapture study using a clustered camera-trapping array deployed for 10 weeks from June–August 2024 to estimate elk population parameters within Management Unit 4. Due to a lack of resights of GPS-marked elk, population parameters were estimated …

Memoryart: Enhancing Llms Via Multi-Memory Models With Adaptive Resonance Theory For Healthcare Agents, Renke Dai, Hebin Hu, Jiahui Zhang, Yilin Kang, Ah-Hwee Tan

Research Collection School Of Computing and Information Systems

Though promising in healthcare consultation applications, large language models (LLMs) face critical limitations in retaining and utilizing long-term memory across multiturn interactions. In particular, existing memory enhancing paradigms are constrained by limited context windows and embedding-based retrieval, often failing to maintain task relevance and still suffering from memory prototype collapse in multi-turn healthcare consultation. To address these challenges, we propose a cognitively-inspired memory framework named MemoryART, which is grounded in Adaptive Resonance Theory (ART)—a cognitive and learning theory of how humans and animals adapt to dynamic environments. MemoryART employs three memory modules—working memory, episodic memory, and semantic memory to support …

Clique Annealing: Semi-Supervised Community Detection Under Crystallization Kinetics, Ling Cheng, Jiashu Pu, Ruicheng Liang, Qian Shao, Hezhe Qiao, Feida Zhu

Research Collection School Of Computing and Information Systems

Semi-supervised community detection seeks to find a specified community type when only few communities are labeled. Existing "select-then-refine" pipelines often start from mis-aligned cores and rely on Reinforcement-Learning or Generative Adversarial Network, increasing computational cost and limiting scalability. We address these issues with a unified energy framework under crystallization kinetics that jointly models energy, structure, and growth. Based on this perspective, we propose CLique ANNealing (CLANN), which first employs Nucleus Proposer to select candidate clique as community core under four physics-inspired criteria. A learning-free Transitive Annealer then iteratively merges neighboring cliques and repositions the nucleus, enabling spontaneous, scalable community growth. …

Potent But Stealthy: Rethink Profile Pollution Against Sequential Recommendation Via Bi-Level Constrained Reinforcement Paradigm, Jiajie Su, Zihan Nan, Yunshan Ma, Xiaobo Xia, Xiaohua Feng, Weiming Liu, Xiang Chen, Xiaolin Zheng, Chaochao Chen

Research Collection School Of Computing and Information Systems

Sequential Recommenders, which exploit dynamic user intents through interaction sequences, are vulnerable to adversarial attacks. While existing attacks primarily rely on data poisoning, they require large-scale user access or fake profiles, thus lacking practicality. In this paper, we focus on the Profile Pollution Attack that subtly contaminates partial user interactions to induce targeted mispredictions. Previous PPA methods suffer from two limitations, i.e., i) overreliance on sequence horizon impact restricts fine-grained perturbations on item transitions, and ii) holistic modifications cause detectable distribution shifts. To address these challenges, we propose a constrained reinforcement driven attack CREAT that synergizes a bi-level optimization framework …

Machine Learning For Predicting Prosthetic Limb Movements, Jessica Alexandra Cegarra Arraiz

Theses and Dissertations

This thesis develops and evaluates a deep learning-based prediction model capable of identifying intended limb movement from surfaced electromyography (sEMG) signals using sequence learning techniques. sEMG signals change over time due to multiple factors such as muscle fatigue or user variability. Traditional prosthetics control methods rely on static feature extraction, ignoring how signals change over time, thereby limiting their ability to capture the temporal changes of muscle activity. As a result, these approaches often lead to poor accuracy, robustness, and generalization. Limited experimental validation has been conducted on sequence-based machine learning approaches using temporal sEMG data from publicly available datasets …

Evaluating Hybrid Quantum-Classical Models For Image Classification In The Nisq Era, Utku Binkanat

Theses and Dissertations

This thesis presents a systematic empirical evaluation of quantum machine learning performance under noisy intermediate-scale quantum (NISQ) era constraints. Through 670 controlled experiments, it evaluated quantum kernel support vector machines and variational quantum classifiers against classical baselines on MNIST binary and multiclass classification tasks with systematic variation of problem difficulty, feature dimensionality (4, 8 qubits), and training set size (n ∈{100, 250, 400, 500, 2000, 4000}). Statistical rigor was ensured through five random seeds per condition and comprehensive significance testing. During the testing with binary datasets, classical methods (SVM, logistic regression, k-NN, neural networks) achieved 85.9% to 99.6% accuracy with …

A Pipeline For Creating Obfuscated Binary Samples To Train Ai-Powered Detection Models, Luka R.H. Wilmink

Theses and Dissertations

The analysis of binary files is a critical component of antivirus software and is one of the most important tools for incident response teams across the industry. In the field, malware is often obfuscated, a practice in which the compilation process is transformed with different techniques to hinder decompilation and reverse engineering. Artificial Intelligence and Machine Learning techniques can assist, but models need to be trained on well constructed datasets first. This paper outlines a pipeline for creating such a dataset and builds a proof-of-concept machine learning classification model. All associated data and code are supplied in the project GitHub …

Understanding Phishing Susceptibility Through Expert Consensus Using Digital Marketing Parallels And A Machine Learning-Based Implementation, Mansoor Ahmad

All Graduate Theses, Dissertations, and Other Capstone Projects

Phishing remains one of the most effective attack vectors for gaining unauthorized access to organizational systems, yet defenders often lack systematic methods to assess their exposure before an attack. This study develops a framework that uses machine learning to encode the collective expertise of cybersecurity practitioners into a portable phishing susceptibility assessment tool, with the goal to help security teams proactively identify patterns, prioritize awareness training, and strengthen detection controls. The study surveyed 27 practitioners with extensive experience in social engineering, red teaming, penetration testing, and threat analysis to identify which factors most influence phishing susceptibility. Practitioners provided quantitative ratings …

Solving High-Dimensional Differential Equations Using Recurrent And Residual Neural Network Architectures, Hind Khaled Kolaib

Knowledge Engineering and Data Science

High-dimensional Partial Differential Equations (PDEs) form the foundation of complex process modeling in various scientific and engineering applications, including finance, physics, and optimal control. However, classical numerical methods are adversely affected by the curse of dimensionality, making them inapplicable for large-scale problems. Recently, however, deep learning-based approaches have provided a new toolbox for these high-dimensional PDEs, including methods such as the Deep Backward Stochastic Differential Equation (Deep BSDE) method. Our approach draws on a more sophisticated deep learning backbone, using neural networks (in our case, a Residual Neural Network and a Long Short-Term Memory network (LSTM) integrated into the Deep …

Woody Ryno Farms Native Prairie Plant Restoration & Invasive Management Conservation Management Report, Jezebel Kenny, Rowan Haeger, Ian Mendonca, Annika Weihl

Environmental Science & Management Senior Capstones

Coastal prairies are biodiverse and sensitive landscapes that support a variety of grassland species in mediterranean climates. Hedgerows may act as a natural barrier for coastal prairies or agricultural regions, aiding in natural protection and support for biodiversity. Humboldt County, California, hosts a number of agricultural regions, including Woody Ryno Farms, a small-scale agricultural operation, on the edge of Dows Prairie near the coast of Mckinleyville. This project aims to continue restoration activity being conducted on the site, helping to increase native biodiversity and agricultural productivity. Project objectives include conducting a plant assessment, applying treatments to individual plants where necessary, …

Machine Learning System For Cereal Yield Prediction In South America., Victor Gabriel Oliveira, Kelvin Henrique Ferreira Dumas

ICT

This project developed a machine learning solution to predict cereal yield in South America using FAOSTAT agricultural data. The objective was to estimate yield in kg/ha for rice, maize, and wheat based on variables such as country, crop type, year, harvested area, producer price, pesticide use, and nutrient indicators.

The project followed the CRISP-DM methodology, covering business understanding, data understanding, data preparation, modelling, evaluation, and deployment. Several regression models were tested, including Random Forest, Gradient Boosting, AdaBoost, XGBoost, KNN, and SVR.

The models were evaluated using MAE, MSE, RMSE, and R² score. The results showed that tree-based ensemble models performed …

Understanding Host Behaviour And Property Review Characteristics Using New York City Airbnb Dataset, Anna Szkwara

ICT

This project applies strategic thinking and the CRISP-DM methodology to analyse Airbnb listings in New York City and identify patterns associated with host performance and market vulnerability. Airbnb has become a major global accommodation platform, creating opportunities for individual hosts while also increasing competition within the short-term rental market. The project focuses on whether data-driven analysis can identify factors that may influence host success and provide useful insights for hosts with less experience or expertise than larger hospitality organisations. The dataset contains 85 variables, many of which require careful evaluation due to redundancy, high cardinality, sensitivity, or limited relevance to …

Active Galactic Nuclei Across Scales: From Blazar Jets To Dark Matter Halos, Stephanie Ann Podjed

Dartmouth College Ph.D Dissertations

Within ΛCDM, galaxies form and evolve within dark matter halos, with both central and satellite galaxies contributing to the total stellar mass content. Virtually every massive galaxy harbors a supermassive black hole (SMBH) at its center, with a small fraction of the population growing by actively accreting material; we call this an active galactic nucleus (AGN). The processes giving rise to an AGN phase (i.e., growth of a SMBH) releases enormous amounts of energy in the form of radiation, outflows, and relativistic jets that are able to significantly affect the formation and evolution of galaxies. Blazars are an extreme class …

Designing Narrative-Based Ai Assistance For Sensemaking In Collaborative Environments: Case Studies In Education And Dementia Care, Dylan Edward Moore

Dartmouth College Ph.D Dissertations

This thesis addresses a gap in the human-computer interaction literature regarding the design, development, and evaluation of narrative-based AI assistance for collaborative, complex problem solving. I explore this design space through three case studies across the domains of education and dementia care. This work encompasses multi-year industry partnerships and longitudinal fieldwork, user-centered design, dataset curation, model training, and system evaluation.

Specifically, the first case study considers a story-based web platform for teaching AI literacy through peer-generated, personalized narrative scaffolding. Learners on the platform showed significant knowledge gains and other learning-related outcomes. To describe the novel design of this system, I …

Doikayt And The Ethics Of Belonging: Lessons In Place-Making From The Jewish Labor Bund, Zoë L. Jacobs

Scripps Senior Theses

This thesis traces the evolution of doikayt—the Bundist principle of hereness—from its origins in the Jewish Labor Bund to contemporary applications in North America. Rooted in a refusal of both assimilation and nationalist escape, doikayt emphasizes cultivating safety, solidarity, and belonging through collective responsibility rather than territorial claims.

Building on this foundation, the exploration situates hereness within a settler-colonial context, where ethical dwelling is complicated by Indigenous dispossession. Drawing on Alexis Shotwell alongside Indigenous thinkers Vanessa Watts and Kyle Whyte, I examine how inhabiting place requires confronting historical injustices and ongoing relational responsibilities. Chapter 3 analyzes Linke Fligl (2016–2022) as …

Real Interpolation: An Approximate Introduction, Madeline Anderson

Scripps Senior Theses

This thesis provides an introduction to real interpolation. We establish

relevant notions in functional analysis first, and use these concepts to study

real interpolation using J. Peetre’s 𝐾-functional in some detail. We also

explore the basics of approximation theory, in particular the connection

between approximation and interpolation results.

Rate Response Of Curlyleaf Pondweed And Native Plants To Flumioxazin In Minnesota Lakes, Pearl J. Jensen

All Graduate Theses, Dissertations, and Other Capstone Projects

Curlyleaf pondweed (Potamogeton crispus L.) is an invasive aquatic plant present across the United States that causes significant recreational issues, outcompetes native plant species, and depletes water quality. Before senescing in mid-summer, curlyleaf pondweed forms a large number of turions that can lay dormant in the sediment for several years. Typical herbicide management of this species occurs in early spring to target the plant before turion production occurs and while native plants are dormant. Flumioxazin has shown potential in curlyleaf pondweed management in small scale studies, but its effects have not been assessed in operational management. In this study, treatments …

Comprehensive Analytical Investigation Of Tetrahydro-4h-Chromene And Dihydropyridine Derivatives, Ryan J. Burk

Chemistry & Biochemistry Dissertations

Novel calcium channel blockers (CCBs) with dihydropyridine (DHP) or tetrahydro-4H-chromene moieties are often chiral, so effective enantiomer separation methods are needed for continued drug development. The purpose of this dissertation is to outline a comprehensive method development model for the chiral separations of DHPs and tetrahydro-4H-chromene derivatives. The scope of this dissertation is to address analytical challenges during initial synthesis, chiral separations, and data analysis during post-processing for this class of chiral compounds. The first section focuses on the method development strategies for separations of DHPs in the sub/supercritical fluid (SFC) and normal phase modes with the 2-hydroxypropyl-β-cyclodextrin stationary phase. …

Novel Methods For Environmental Fluoride Measurement, Cable Warren

Chemistry & Biochemistry Dissertations

Fluoride analysis has been an important focus of analytical analysis for many years and will continue to be so going forward. Today, fluorinated compounds, specifically per/polyfluoroalkyl substances (PFAS), better known as “forever chemicals” have captured the moment and are the subject of vast research and regulation. Under this context, I have researched new methods of fluoride separation and concentration in complex media as well as a novel method of PFAS destruction and total organic fluorine analysis for screening of PFAS in aqueous samples. Through research and work on micro-scale detection methods, an understanding of the state of the art and …

The Forensic Implications Of Hydrochloric Acid (Hcl) Exposure On Dna Preservation In Human Teeth, Shaelyn Lee Zimmerman

Graduate Student Theses, Dissertations, & Professional Papers

Identity is a human right, and forensic anthropological methods are often aimed at returning identity to decedents. Three main pathways are used for the identification of human remains: fingerprints, dental records, and DNA analysis. Identification efforts may be hindered when perpetrators attempt to obscure the victim’s identity. In cases where corrosive substances, such as hydrochloric acid (HCl) are used, dental comparison and fingerprinting often fail and genetic analysis becomes the best chance of achieving personal identification.

Previous studies have shown teeth are an excellent source of DNA. Large, multi-rooted teeth, such as molars, are often preferred because they contain the …

Climate And Seasonal Influences On Indo-Pacific Sea Level: Insights From 30 Years Of Satellite And Tide Gauge Data, Karlina Triana

ASEAN Journal on Science and Technology for Development

We analyze Indo-Pacific sea-level variability using monthly satellite altimetry (1993–2025) validated against records from 16 tide-gauge stations. Cross-comparisons show strong agreement, especially in the western Pacific, confirming the reliability of altimetry for regional assessments. Seasonal SLA variability is largest in the Bay of Bengal and South China Sea and reflects monsoonal forcing, whereas interannual fluctuations in the eastern Indian and western Pacific oceans are dominated by ENSO and modulated by PDO. Harmonic decomposition isolates annual and semi-annual cycles, and an EOF/PCA framework identifies the leading modes: EOF1 (30.8%) captures basin-scale interannual variability and EOF2 (20.9%) reflects the seasonal cycle. Spectral …

Adversarial Robustness In Biomedical Time-Series Models, Rohan Tiwari

Bioengineering Theses

This study investigates adversarial vulnerabilities in deep learning models for biomedical time-series classification across two clinically important modalities: electrocardiography (ECG) and electroencephalography (EEG). Using the MIT-BIH Arrhythmia and CHB-MIT seizure datasets, I evaluate time-domain attacks (FGSM, PGD), Fourier-domain constrained attacks, and learned spectral perturbations designed to reveal modality-specific sensitivity patterns. Across both tasks, a consistent trend emerges low-frequency components (0–5 Hz) constitute a dominant axis of adversarial vulnerability, with perturbations in this range producing the steepest degradation in classification performance. In ECG models, protecting the physiologically relevant QRS band (5–20 Hz) significantly improves robustness, whereas EEG models remain highly sensitive …

Artificial Intelligence–Enabled Revenue Cycle Management And Financial Performance In Healthcare Organizations, K’Reesa Webster

Theses, Dissertations and Capstones

The purpose of this review was to examine how artificial intelligence–enabled revenue cycle management (AI-enabled RCM) systems have been associated with financial performance outcomes in healthcare organizations. A literature review following a systematic process consistent with PRISMA 2020 guidelines was conducted to identify quantitative studies published between 2015 and 2026. Eligible studies were required to report at least one financial outcome related to claim denial rate, days in accounts receivable, or operating margin. Twenty-seven studies met all inclusion criteria. Findings across these studies indicated that AI-enabled RCM systems have been associated with lower denial rates, shorter accounts receivable timelines, and …

Distilling The Complexity Of Agent-Based Simulations Into Textual Explanations Via Large Language Models, Noé Y. Flandre, Philippe J. Giabbanelli

VMASC Publications

Communicating the design and results of agent-based models (ABMs) to subject matter experts is challenging, which hinders participation and limits trust in simulation-based decision support. Large language models (LLMs) can communicate ABMs as textual summaries, thus complementing traditional disclosure through statistical and visualization techniques. While prior work translated the structure of conceptual models into narratives via LLMs, our extension covers the dynamics of simulation models via an automated simulation-to-text method that extracts contextual information from NetLogo ABMs, performs repeated simulations, and generates narrative descriptions (including the model’s purpose, parameters, and simulation dynamics) using mutimodal LLMs. Furthermore, four summarization algorithms spanning …

Mat 1500 Calculus I Syllabus, Tian Cai

Open Educational Resources

No abstract provided.