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Geometric Structure In High-Dimensional Representations: Theory And Applications To Language, Jiayi Chen
Geometric Structure In High-Dimensional Representations: Theory And Applications To Language, Jiayi Chen
Dartmouth College Ph.D Dissertations
This thesis develops a geometric perspective on high-dimensional representations, motivated by applications to language. Rather than treating representations solely as inputs to predictive models, we view them as structured objects whose geometry encodes meaningful information. In particular, we argue that such representations exhibit organization at multiple scales: at a global level, metric and clustering structure capture relationships such as genre, authorship, and discourse; at a local level, geometric quantities such as intrinsic dimension and curvature describe how these relationships vary across the space.
To study these phenomena, we combine empirical analysis with theoretical development. On the empirical side, we examine …
Unquaint Pigs’ Stakeholder Perspectives On Wild Swine In Central Western Florida, Tyler Koerner
Unquaint Pigs’ Stakeholder Perspectives On Wild Swine In Central Western Florida, Tyler Koerner
USF Tampa Graduate Theses and Dissertations
The Anthropocene presents important questions for how to address the continuous transferal of new species into new spaces and the cascading impacts of environmental transformations. Novel ecosystems present one such outline for conservation that acknowledges the modification of historic ecosystems and the social entanglements that arrive with new species. I argue that novel ecosystems can benefit from further anthropological integrations that aid in describing the entanglements of introduced species and the pursuit of best managerial outcomes. For wild swine in Florida, the adoption of a novel approach is especially relevant because of entanglements with historic and modern Floridian stakeholders and …
A Quantum Phase Space Description Of Local Noise In Atomic Ensembles, Andrew Kolmer Forbes
A Quantum Phase Space Description Of Local Noise In Atomic Ensembles, Andrew Kolmer Forbes
Physics & Astronomy ETDs
Nonclassicality in quantum sensors can improve sensitivity, but often increases susceptibility to noise. Thus, modeling physically relevant noise sources and analyzing their effect on quantum metrology are both of importance to the field of quantum sensing. In this dissertation, I demonstrate that local noise sources, which are present in almost all many-spin systems, can be tractably modeled when assuming permutation symmetry of the noise, and we show that many common local noise sources can be mapped to a Fokker-Planck equation on quantum phase space. We apply this description of noise to study quantum sensing using noisy probe states and establish …
Optical Nuclear Spin Detection In Diamond And Varifocal Metasurface Optics, Maxwell D. Aiello
Optical Nuclear Spin Detection In Diamond And Varifocal Metasurface Optics, Maxwell D. Aiello
Physics & Astronomy ETDs
This dissertation presents two experimental investigations at the intersection of quantum sensing and precision optical instrumentation. The primary project demonstrates optically detected nuclear magnetic resonance (NMR) of 13C nuclear spins in diamond, using state-selective Landau-Zener transitions under microwave frequency sweeping to bidirectionally transfer spin polarization between nitrogen-vacancy (NV) electron spins and remote 13C nuclear spins. This enables optical polarization and readout of large ensembles of polarized nuclear spins at low magnetic fields and room temperature, with spin dephasing times limited by longitudinal relaxation of nearby NV electron spins. The secondary project reports the design, fabrication, and characterization of …
Quantifying Co2 And Ch4 Fluxes In A Semi-Arid Floodplain: Assessing Spatial And Temporal Drivers, Miles E. Kelsey
Quantifying Co2 And Ch4 Fluxes In A Semi-Arid Floodplain: Assessing Spatial And Temporal Drivers, Miles E. Kelsey
Earth and Planetary Sciences ETDs
Rivers transport sediment and carbon across Earth’s surface, and their floodplains can store carbon over decades to millennia, making them important to terrestrial carbon management. While soil carbon can persist long term, it may be released as greenhouse gases through processes like methanogenesis and heterotrophic respiration. Environmental controls on these fluxes remain poorly constrained across floodplains in different climate and geomorphic setting, but especially in semi-arid systems where measurements are limited. To address this gap, we quantified CO₂ and CH₄ fluxes along the Middle Rio Grande (New Mexico, USA) using 227 chamber measurements collected May to November 2025 at three …
Continuous Polygenic Trait Evolution Under Brownian Motion With Gaussian Mixture Models, Mary S. Hopkins
Continuous Polygenic Trait Evolution Under Brownian Motion With Gaussian Mixture Models, Mary S. Hopkins
Mathematics & Statistics ETDs
Gaussian mixed-models (GMMs) show promise as a tool for modeling polygenic trait evolution for multiple taxa with established phylogenetic comparative methods (PCMs). When phenotypic traits are influenced by more than one gene, neither a gene tree nor a species tree may be completely adequate to model specific cross-taxa dependencies. In such cases common solutions include using trees inferred from concatenated DNA sequences [35, 95] and consensus gene trees [35]. The GMM-based model, first proposed by Jiang in 2017 [55] allows traits to evolve on more than one tree with distinct topologies. This approach provides a framework for trait evolutionary modeling …
Bayesian Designs For Two-Arm Clinical Trials With Time-To-Event Endpoints: Incorporating Historical Data Through Power Priors, Sara Hajraf H. Almutiri
Bayesian Designs For Two-Arm Clinical Trials With Time-To-Event Endpoints: Incorporating Historical Data Through Power Priors, Sara Hajraf H. Almutiri
Mathematics & Statistics ETDs
Bayesian methods provide a flexible framework for time-to-event analysis by incorporating prior information. The power prior offers a systematic way to borrow information from historical data. This approach is especially valuable in clinical research, where historical data can enhance inference in early-phase trials with limited sample sizes. This dissertation develops Bayesian approaches for two-arm survival studies using both closed-form and simulation-based methods. The closed-form inference is derived under exponential and Weibull survival models. Under the proportional hazards framework, the posterior is derived through a normal approximation to the log hazard ratio, allowing inference on the treatment effect when the variance …
Shaping Emergent Competitive And Cooperative Behaviors In Multi-Agent General-Sum Games, Ethan F. Erickson
Shaping Emergent Competitive And Cooperative Behaviors In Multi-Agent General-Sum Games, Ethan F. Erickson
Honors Projects
Reinforcement learning (RL) algorithms can train agents to solve problems in environments using complex behaviors that are not explicitly programmed, known as emergent behaviors. The goal of our research is to investigate how different RL reward values influence the emergence of competitive and cooperative behaviors in games with teams of multiple agents. Specifically, we focus on general-sum games, in which the sum of gains and losses of each team may be non-zero, allowing situations for agents to mutually benefit or mutually fail. Using Unity’s ML-Agents Toolkit to train agents with RL self-play in bounded 2D environments, we identify high-level behaviors …
Marine Geophysical Studies Of Coupled Tectonic And Sedimentary Processes At Active Plate Boundaries, Sarah R. Rysanek
Marine Geophysical Studies Of Coupled Tectonic And Sedimentary Processes At Active Plate Boundaries, Sarah R. Rysanek
Earth and Planetary Sciences ETDs
Deep-sea and convergent margin sedimentary systems preserve critical records of tectonic and climatic processes that shape Earth’s surface. This dissertation investigates source-to-sink sediment routing and forearc deformation to better constrain the interplay between sedimentary and tectonic processes, through investigations of a deep-sea fan system, and the forearc geomorphology offshore Nicaragua. In the Gulf of Alaska, we integrate ultra-long-offset and regional multi-channel seismic reflection data, multi-resolution bathymetry, and plate reconstructions to remap the Baranof Fan system. Results show that the fan is larger than previously recognized and constructed by two primary depocenters linked to distinct glacial sediment pathways, with accommodation space …
Quantum Control Protocols For Robust Quantum Computing, Leeseok Kim
Quantum Control Protocols For Robust Quantum Computing, Leeseok Kim
Electrical and Computer Engineering ETDs
The fundamental goal of quantum computing is to precisely control quantum systems to perform meaningful tasks, including implementing high-fidelity quantum gates for reliable quantum computation and accurately simulating complex quantum many- body dynamics. In this dissertation, we develop improved quantum control protocols for three distinct objectives, quantum error suppression, quantum optimal control, and analog quantum algorithms, achieving performance beyond standard approaches. First, we introduce new dynamical decoupling protocols, including both determin- istic and randomized constructions, that can substantially outperform conventional deterministic sequences. We then extend the randomized approach to dynamically corrected gates. Second, we propose a randomized quantum optimal control …
Constraining Magmatic Processes In The Central American Arc Using Melt Inclusion Vapor Bubble Analysis And Triple Oxygen Isotope Modeling And Exploration Of Volatile Contributions To The Production Of Continual Radio Frequency (Crf) Lightning Events, John M. Hamilton
Earth and Planetary Sciences ETDs
Magmatic volatiles are key to determining the processes happening in the subsurface that we cannot directly sample. Advances in measuring volatile and isotope contents from erupted volcanic samples have given us the ability to understand magmatic processes, mixing components that produce the bulk magma composition and potentially precursors to eruptive hazards, such as lightning.
Through analysis of melt inclusions that sample the melt at depth and triple oxygen isotope quantification of olivine crystals from multiple volcanic edifices, the three following studies display how I have utilized these analytical techniques to help unravel processes happening in the subsurface that lead volcanic …
Computational Design Of Peptides And Proteins Through Machine Learning Approaches, Emily J. Hendrix
Computational Design Of Peptides And Proteins Through Machine Learning Approaches, Emily J. Hendrix
Chemistry and Chemical Biology ETDs
Advancements in machine learning have emerged as a pivotal tool in computational biochemistry, offering new advancements to address challenges in protein structure and function. However, current machine-learning approaches offer limited insight in understanding protein dynamics. The purpose of this work is to combine traditional physics-based computational tools, such as molecular dynamics and coarse-grained simulations, with recently developed AI-driven computational tools to bridge gaps and advance the understanding of proteins in both structural and dynamic aspects. I investigated several approaches such as (i) traditional physics-based methods to study protein conformation and ensembles; (ii) identifying a peptide inhibitor for the PICK1 PDZ …
Computing Certificates Of Members In Archimedean Quadratic Modules In A[X] And Certifying The Emptiness In Inconsistent Monogenic Archimedean Quadratic Modules In A[X_1, ..., X_N], Jose A. Castellanos Joo
Computing Certificates Of Members In Archimedean Quadratic Modules In A[X] And Certifying The Emptiness In Inconsistent Monogenic Archimedean Quadratic Modules In A[X_1, ..., X_N], Jose A. Castellanos Joo
Computer Science ETDs
Polynomials have been found to be a powerful tool over hundreds of years for modeling problems in numerous applications in science, engineering, medicine, and other domains. In the context of formal methods, polynomials arise in modeling in aerospace software and robotics, cyber-physical and hybrid systems, autonomous vehicles and controllers based on neural networks.
A quadratic module is a linear combination of polynomials in a set of generators (including the constant 1) with sum of squares polynomials as multipliers. The membership problem for a finitely generated quadratic module can be decided; however, computing a certificate exhibiting why it is nonnegative under …
Design, Fabrication, And Characterization Of Silicon Nitride Microresonator Optical Frequency Combs, Lala Rukh
Design, Fabrication, And Characterization Of Silicon Nitride Microresonator Optical Frequency Combs, Lala Rukh
Optical Science and Engineering ETDs
Optical frequency combs consist of equidistant optical frequencies and have numerous applications ranging from optical metrology to medical diagnostics. Initially, frequency combs were based on bulky mode-locked lasers, but advancements in integrated photonics enabled the generation of frequency combs in chip-scale resonators (microcombs) using Kerr nonlinearity. These miniaturized systems present various challenges, including increased propagation losses, enhanced thermal effects, and the extension of microcombs to visible wavelengths. In this dissertation, I will focus on addressing these challenges in silicon nitride (SiN) resonators. First, this thesis focuses on the fabrication of high-Q SiN resonators and the impact of fabrication parameters on …
Stochastic Derivative-Free Deep Learning Methods For Solving High Dimensional Partial Differential Equations, Qing He Mr.
Stochastic Derivative-Free Deep Learning Methods For Solving High Dimensional Partial Differential Equations, Qing He Mr.
Mathematics Theses and Dissertations
Solving high-dimensional partial differential equations (PDEs) is a fundamental challenge in scientific computing, with applications ranging from quantum chemistry and computational finance to statistical physics and stochastic optimal control. Classical numerical methods such as finite element or finite difference schemes suffer from the curse of dimensionality, rendering them computationally infeasible when the dimension $d$ exceeds a handful. Physics-informed neural network (PINN) methods alleviate this by embedding the PDE residual directly into a loss function, but they require computing derivatives of the network with respect to its spatial inputs---an operation that scales poorly in high dimensions and demands that the approximate …
From Sparse To Precise: Modeling Beam Profiles Using Wavelet-Based Implicit Neural Network (Winn) For Linear Accelerator Commissioning And Quality Assurance, Maryam Ali Albuainin
From Sparse To Precise: Modeling Beam Profiles Using Wavelet-Based Implicit Neural Network (Winn) For Linear Accelerator Commissioning And Quality Assurance, Maryam Ali Albuainin
Computer Science ETDs
Commissioning and routine quality assurance (QA) in radiotherapy require extensive measurements using bulky water tank systems, making the process time-consuming and costly. This research proposes an efficient framework for radiotherapy commissioning and QA by generating complete LINAC physics data from sparse measurements and developing a portable solid-water detector with embedded diodes for high-resolution dosimetry.
At the core of the framework is a Wavelet-based Implicit Neural Network (WINN) that reconstructs full measurement datasets from limited inputs while maintaining clinical accuracy. The model achieves gamma passing rates above 95% (1%/1 mm) and mean absolute errors below 0.5%, while reducing parameters by 99.46% …
Realizing The Long Wavelength Array Swarm, Craig Anthony Taylor
Realizing The Long Wavelength Array Swarm, Craig Anthony Taylor
Physics & Astronomy ETDs
Sensitive modern radio interferometers are costly to build and operate at the university level. The `swarm telescope' concept addresses this challenge by enabling the collaborative use of individual telescope systems, overseen by separate institutions, that come together to form a more powerful and manageable facility. This dissertation focuses on demonstrating this concept using the Long Wavelength Array (LWA) by commissioning an aperture synthesis telescope consisting of interconnected LWA stations, called the LWA Swarm. The presented work details building a cost-efficient prototype LWA platform -- the LWA--North Arm station -- to enable synthesis imaging using the 3-element interferometer comprised of LWA1, …
Classification Of Hif Detection In Nev Profile Using Wavelet Transform And Convolution Neural Network, Abdul Hafiz Kassim, Mohd Abdul Talib Mat Yusoh, Aster Smith Valentinie Wilson Nottelmarc, Ahmad Farid Abidin, Sim Sy Yi, Daw Saleh Sasi Mohammed
Classification Of Hif Detection In Nev Profile Using Wavelet Transform And Convolution Neural Network, Abdul Hafiz Kassim, Mohd Abdul Talib Mat Yusoh, Aster Smith Valentinie Wilson Nottelmarc, Ahmad Farid Abidin, Sim Sy Yi, Daw Saleh Sasi Mohammed
Turkish Journal of Electrical Engineering and Computer Sciences
High impedance faults (HIFs) present a critical challenge in power systems due to their subtle signal characteristics, which often remain undetected by conventional protection methods. These faults typically do not produce significant phase disturbances, making reliable detection difficult. However, analysis of the neutral-to-earth voltage (NEV) profile under fault conditions provides a promising alternative for fault identification. Existing approaches for detecting and classifying HIFs using NEV signals remain limited and may result in inaccurate maintenance decisions. This paper proposes a fault classification framework for multiple fault types, including HIF, three-phase fault, three-phase fault to ground, double line, double line to ground, …
Degrees Of Access: The Role Of Family Education In Applying To Graduate School, Emma Tweed
Degrees Of Access: The Role Of Family Education In Applying To Graduate School, Emma Tweed
Math and Computer Science Honors Theses
Access to graduate education in the United States remains heavily stratified by structural, financial, and informational barriers. While undergraduate first-generation student outcomes are widely studied, fewer structural analyses examine how graduate-level “educational inheritance” shapes prospective applicants' navigational capital, particularly within competitive STEM fields like mathematics. Drawing upon theories of social capital and the “hidden curriculum,” this study investigates the relationship between an individual's knowledge of the graduate school application process and the highest level of education attained by an immediate family member.
Using the Knowledge-GAP survey instrument funded by the National Science Foundation, data were collected from a diverse sample …
The Extraction And Chemical Characterization Of The Avian Pigments Turacin And Turacoverdin, Sarah R. Bekkali
The Extraction And Chemical Characterization Of The Avian Pigments Turacin And Turacoverdin, Sarah R. Bekkali
Honors Scholar Theses
Bird coloration is a trait that extends beyond mere aesthetics as it has an extensive range of biological significance. Plumage patterns and hues can influence camouflage, mate choice, social dominance, and physiological performance. Bird fitness, their ability to survive and reproduce, is greatly dependent on color. Melanins, carotenoids, and pterins are well-studied pigment systems that are commonly found across many avian species’. Alternatively, porphyrin-based pigments are rare and less-studied as they only found in turacos a sub-Saharan African bird belonging to the family Musophagidae. This thesis focuses on two pigments of interest: turacin, the deep crimson-red pigment found in …
From Natural Language To Cryptographic Protocol Specifications: Evaluating Llms For Cpsa Generation, Martin Duclos
From Natural Language To Cryptographic Protocol Specifications: Evaluating Llms For Cpsa Generation, Martin Duclos
Theses and Dissertations
Formal verification can prove the security properties of cryptographic protocols, but translating natural language specifications into formal models requires specialized expertise, limiting the broader adoption of formal verification methods. This dissertation investigates whether large language models (LLMs) can lower this barrier by automatically generating Cryptographic Protocol Shapes Analyzer (CPSA) models from natural language protocol specifications. We evaluate three complementary strategies for improving LLM-based CPSA code generation through systematic experimentation across 104 protocols and 15 language models. First, we analyze prompt engineering and find that moderate structured guidance yields the most accurate outputs, while excessive prompt complexity degrades performance. Second, we …
A Modified Maximum Likelihood Estimation Algorithm For Modeling Threshold Exceedances With The Generalized Pareto Distribution, Jeffrey Harkness
A Modified Maximum Likelihood Estimation Algorithm For Modeling Threshold Exceedances With The Generalized Pareto Distribution, Jeffrey Harkness
UNLV Theses, Dissertations, Professional Papers, and Capstones
A modified maximum likelihood estimation (MLE) algorithm is proposed for modeling threshold exceedances with the generalized Pareto distribution (GPD). The algorithm addresses multiple issues with an approach originally published in the Journal Computational Statistics and Data Analysis (Castillo and Serra, 2015). The modified algorithm is intended to be comparatively simple to understand and implement, accurate in the handling of boundary conditions, relatively fast and reliable for most data sets, and relatively easy to transfer between computer languages by leveraging existing optimization routines.
A reproducibility study of work in recent literature published in the journal Extremes (Belzile, et al., 2023) is …
An Evaluation Of Artificial Intelligence Chatbots As Alternatives To Specialized Software In Teaching Bayesian Pharmacokinetic Analysis, Reza Mehvar
Pharmacy Faculty Articles and Research
Objective
To investigate the accuracy and reliability of artificial intelligence chatbots in estimating pharmacokinetic parameters from limited patient samples and population data for potential application in teaching Bayesian concepts.Methods
Two plasma concentration–time data sets after a single intravenous dose, along with population values for volume of distribution (V) and elimination rate constant (k), were entered into free versions of ChatGPT and Gemini. Three prompts were engineered to assess and improve the accuracy and consistency of patient-only (based on plasma concentrations) and Bayesian (based on plasma concentrations and population data) estimates of V and k. …Accuracy Of Parameter Estimation For A Simple Gene Regulatory Network Model Is Sensitive To Network Motif, Number Of Parameters Estimated, And Magnitude And Direction Of Regulatory Relationships, Nikki C. Chun, Kam Dahlquist
Accuracy Of Parameter Estimation For A Simple Gene Regulatory Network Model Is Sensitive To Network Motif, Number Of Parameters Estimated, And Magnitude And Direction Of Regulatory Relationships, Nikki C. Chun, Kam Dahlquist
Honors Thesis
A gene regulatory network (GRN) is a set of transcription factors that regulate the expression of genes encoding other transcription factors. The dynamics of a GRN explain how gene expression changes over time. GRNmap is a MATLAB software package that uses ordinary differential equations to model dynamics of small-scale GRNs. We used the program to estimate production rates, expression thresholds, and regulatory weights for each transcription factor in three related literature-derived GRNs based on yeast cold shock microarray data previously collected in the Dahlquist Lab. We noticed large differences in estimated weight values when 1-2% of the expression values were …
Digital Literacy And Language Proficiency As Factors Of Accessible Digital Training In The Hospitality Industry: Employee Perspectives Of Training And Working In A Diverse Industry, Gillian Bowden
UNLV Theses, Dissertations, Professional Papers, and Capstones
This explanatory sequential mixed methods study explored how digital literacy and language proficiency impact employees’ access to and engagement with digital training, as well as how these experiences influence their perceptions of training and the organization. In the quantitative phase, survey data were collected from hourly employees at a large foodservice corporation (n=67). Four constructs were assessed: digital literacy, language proficiency, accessibility, and engagement. Results indicated strong, statistically significant relationships with higher levels of digital literacy and language proficiency associated with greater accessibility and increased engagement with digital training materials. The large effect sizes suggest these competencies play a meaningful …
Iterative Silver-Label Refinement For Temporal Information Extraction In Biomedical Literature, Chan Lee
Iterative Silver-Label Refinement For Temporal Information Extraction In Biomedical Literature, Chan Lee
UNLV Theses, Dissertations, Professional Papers, and Capstones
Temporal information extraction plays a critical role in the biomedical domain, where the ability to identify events and their temporal relationships is central to interpreting research findings. However, annotated corpora for this task remain scarce and costly to produce and the existing models developed for clinical text do not transfer well. This work bridges that gap through iterative silver-label refinement. A temporal model originally trained on news-domain data is adapted to biomedical text through cycles of automatic labeling, targeted correction, and retraining without the need for comprehensive manual annotation.
Key contributions include a practical iterative refinement methodology demonstrating that the …
From Flight To Hatching: Adult Sexual Dimorphism, Life History, And Egg-Stage Ecology Of Pseudocotalpa Giulianii, Mandylene Mountain
From Flight To Hatching: Adult Sexual Dimorphism, Life History, And Egg-Stage Ecology Of Pseudocotalpa Giulianii, Mandylene Mountain
UNLV Theses, Dissertations, Professional Papers, and Capstones
The Nevada endemic dune beetle Pseudocotalpa giulianii is currently known only from two dune systems in Amargosa Valley, Nevada, yet much of its life cycle occurs below the sand surface and remains poorly documented. This thesis addresses key gaps in adult-stage biology and egg-stage development that are relevant to understanding reproduction, vulnerability, and habitat requirements in this dunerestricted species.
To characterize adult sexual dimorphism and life history, I quantified morphological differences between males and females and measured sex-specific adult survival under laboratory conditions relative to the aboveground flight season. Males and females overlapped broadly in external body size, but tarsal …
At The Crossroads Of Traditional And Nuclear Forensics: Decontaminating Radiologically Contaminated Dna Evidence Using Magnetic Beads, Rin Nyx Ruby
UNLV Theses, Dissertations, Professional Papers, and Capstones
Known for its impressive discriminatory power, deoxyribonucleic acid (DNA) fingerprinting stands as the “gold standard” of forensic investigation. However, complications arise when such evidence is contaminated with radioactive material. Though biological samples exposed to ionizing radiation can still yield comprehensive DNA profiles, most forensic laboratories lack the facilities which meet the safety and security requirements necessary for handling radioactive material. While nuclear facilities can decontaminate samples prior to forensic analysis, conventional methods for radiological decontamination – such as mechanical cleaning and chemical washes – may degrade the quality of the forensic evidence. The purpose of this study is to evaluate …
2d And 3d Insights Into The Formation And Emplacement Of Martian Meteorites, Sierra Rhaye Ramsey
2d And 3d Insights Into The Formation And Emplacement Of Martian Meteorites, Sierra Rhaye Ramsey
UNLV Theses, Dissertations, Professional Papers, and Capstones
Martian meteorites are the only samples currently available from Mars, making their study critical for understanding martian igneous processes. Despite extensive study over the last five decades, the formation (e.g., mantle sources, crystallization pressures), emplacement (e.g., intrusive versus extrusive), and shock histories of these rocks remain uncertain due to their innate lack of geologic context and limited petrologic tools calibrated for martian conditions. This dissertation analyzes a large suite of 22 igneous martian meteorites using complementary 2D and 3D analytical methods to better constrain the magmatic, emplacement, and shock processes responsible for their formation and ejection from Mars.
Chapters 2 …
Phase Identification Of (La, Sr)Coo3 Solid Oxide Cell Electrode Films Using Dft Based Exafs, Musab A. Siddiqui
Phase Identification Of (La, Sr)Coo3 Solid Oxide Cell Electrode Films Using Dft Based Exafs, Musab A. Siddiqui
Seton Hall University Dissertations and Theses (ETDs)
Perovskite structured mixed ionic electronic conductor (MIEC) materials formed as films by metal-organic precursor deposition have excellent electrochemical performance in solid oxide cell (SOC) air electrode applications due to the large surface area provided by the manufacturing approach. MIEC films created by metal organic precursor deposition are often multi-phased due to low heat treatment temperatures and locally generated low oxygen partial pressures caused by the release of carbonaceous gases during the drying step of the fabrication process. In this work, we use extended x-ray absorption fine structure spectroscopy (EXAFS) to examine the phase contents of La0.8Sr0.2CoO3 (LSC82) and La0.6Sr0.4CoO3 (LSC64) …