Digital Commons Network^™

Theory Of Nucleation Of Water Properties Of Some Clathrate Like Cluster Structures, Mehdi Daee

Doctoral Dissertations

"The tranquility of classical homogeneous nucleation theory has been disturbed by the introduction of statistical mechanical correction factors to a basically thermodynamic theory. These factors, which appear to be essential, destroy much of the agreement with experiment in the case of water vapor. A molecular model for the pre-nucleation water clusters is proposed with a view toward resolving some of these difficulties. As a first step, the Properties of a few specific cluster configurations have been examined. Clathrate-like structures containing 16 to 57 water molecules are discussed. The hydrogen bonds were treated as simple harmonic oscillators for the purpose of …

Homogeneous Nucleation Of Water Vapor In Inert Gas Atmospheres, Arthur Henry Biermann

Doctoral Dissertations

"The homogeneous nucleation of water vapor in atmospheres of helium, neon, argon, krypton, and xenon was studied using an expansion type cloud chamber. A strong dependence of the nucleation rate on the particular inert carrier gas was observed. At present the only dependence upon the nature of the carrier gas included in classical nucleation theories is a small factor arising from kinetic considerations which is in the wrong direction to explain the observations. To explain the dependence of the rate on the nature of the carrier gas, a molecular cluster model is assumed allowing inert gas atoms to occupy the …

Synthesis, X-Ray Characterization, Structural And Magnetic Studies Of A New Class Of Iso-Structural Bimo₃ Compounds, Joseph Donato Bucci

Doctoral Dissertations

"This dissertation consists of four sections. The first part is a temperature dependent X-ray study of the lattice parameters of BiFeo₃. The synthesis and subsequent X-ray characterization of BiCo₃, BiAlO₃, BiMnO₃ , BiScO₃, BiCo₁₋ₓFeₓO₃ , and BiAl₁₋ₓFeₓO₃ are reported in the second part. These compounds all crystallize in the body centered cubic (BCC) structure with a~10.2Å. Single crystal Precession and Weissenberg photographs confirmed the BCC structure. In part three, the results of the magnetic studies on BiCoO₃ and biAl.₉FE.₁ are presented. The magnetic data for BiCoO₃ are substantiated by X-ray thermal expansion studies. In the last part the compound BiCo.₉FE.₁O₃ …

Photoionization Of Photoexcited Cesium, Robert E. Hebner

Doctoral Dissertations

"A new method for obtaining the cross section for photoionization of photoexcited cesium is presented. The salient feature of this experiment is to use three crossed beams, i.e., two light beams intersecting a beam of cesium atoms. The cross section is determined by counting the ions produced by the two step process: Cs (6S) + h[upsilon]₁ --> Cs (6P) ; Cs (6P) + [upsilon]₂ --> Cs⁺ + e⁻ The relative cross section for the second step has been obtained from threshold (5060 Å) to 2500 Å. The excitation light source used in obtaining this cross section was a rf resonance …

Modeling The Visual Pathway For Interactive Diagnosis Of Visual Fields, Chiam Geoffrey Goldbogen

Doctoral Dissertations

"Visual fields are an important tool for the ophthalmologist in the detection, diagnosis, and monitoring of certain diseases and maladies of the visual pathway. The aim of the present research is to build a computer system which utilizes a learning machine to develop a mathematical model of the visual pathway. It is hoped that this system may be used in the field of ophthalmology as a teaching aid, or may assist in various aspects of diagnosis. Faults corresponding to blind or impaired areas of visual fields are extracted from medical records of a patient's condition. The structure of the model …

Noble Gases Anomalies In Terrestrial Ores And Meteorites, B. Srinivasan

Doctoral Dissertations

"Analyses of the content and isotopic composition of xenon and krypton in terrestiral ores containing tellurium, selenium or iodine resulted in the following conclusions: 1. The double beta-decay half-life for ¹³⁰Te is 2.51 x 10²¹ years from analysis of tellurobismuthite from Boliden, Sweden and 2.83 x 10²¹ years from analysis of tellurides from Kalgoorlie, Australia. 2. The ratio of the double beta-decay half-life of ¹²⁸Te relative to that of ¹³⁰Te is ≥ 108 and ≥ 293 for Boliden tellurobismuthite and Kalgoorlie tellurides, respectively. 3. Selenium minerals and tellurium ores containing selenium exhibit ⁸²Kr excess attributed to the double beta-decay of …

Absolute Cross Sections For Excitation Of Neon By Impact Of 20-180 Kev H , H₂ And He Ions, George William York

Doctoral Dissertations

"The technique of heavy-ion energy-loss spectrometry has been used to measure excitation cross sections for the (2p⁵)3s and (2p⁵)3p electronic configurations of Neon. The incident particles used were H⁺ , H⁺₂ and He⁺ at impact energies from 20-180 keV. The results are compared with previous optical measurements of the emission cross sections of lines from these levels as excited by H⁺ and He⁺ impact. Agreement is not good, either in shape or in absolute magnitude for excitation of the (2p⁵)3s configuration. However, agreement is surprisingly good for excitation of the (2p⁵)3p configuration. A curve fitting technique has been applied to …

Distribution Of Trace Elements In Olivines And Proxenes - An Experimental Study, Melvin Leroy Bird

Doctoral Dissertations

"Olivine, pyroxene,and spinel were crystallized in the ternary system anorthite-forsterite-silica to which trace amounts of the transition metal ions Cr³⁺, Fe²⁺, Mn²⁺, Co²⁺, Ni²⁺, and Cu²⁺ had been added. The resulting concentrations of the transition metal ions in the liquid and crystalline phases were determined using the electron microprobe. The results, given as free energies and partition functions, indicate the order of substitution of the dipositive ions in all crystals to be Ni²⁺, Co²⁺, Mn²⁺, Cu²⁺, and Fe²⁺ according to the predictions of crystal field theory. The ion Cr³⁺ substituted in greater or lesser quantities depending on the crystalline phase. …

Some Statistical Inferences For The Bivariate Exponential Distribution, Bruce Mohr Bemis

Doctoral Dissertations

"The bivariate exponential distribution is neither absolutely continuous nor discrete due to the property that there is a positive probability that the two random variables may be equal. Basic properties of the distribution are presented as well as methods of parameter estimation including maximum likelihood. The distribution is shown to satisfy the usual regularity conditions in spite of its possession of a singularity. The maximum likelihood estimates are asymptotically efficient. Two other methods of estimation are compared with the maximum likelihood method in terms of efficiency. Tests of the hypothesis that two random variables each have independent exponential distributions versus …

X-Ray And Mössbauer Spectroscopy Studies Of The Silicon-Antimony And Bismuth-Antimony Alloys, James Ralph Teague

Doctoral Dissertations

"X-ray and Mossbauer spectroscopy were used to investigate two antimony alloys, Bi-Sb and Si-Sb, showing semiconductorsemimetallic transitions or vice versa, depending on the antimony concentration in the host lattice. Resistivity and density measurements were found to be helpful in the analysis of the results. X-ray studies for dislocation-free antimony-doped silicon showed that the lattice constant of the alloy increased as the antimony concentration increased from 10¹⁸ to 10¹⁹ Sb atoms/cc. Rather good agreement was found between theoretical and experimental changes in lattice constant for dislocation-free silicon. Mössbauer studies showed that the isomer shift decreased linearly with increasing antimony concentration, which …

Fossil Stromgren Spheres From Supernova Explosions, Menas Kafatos, P. Morrison

Mathematics, Physics, and Computer Science Faculty Articles and Research

Brandt ci at. have shown that consistency in the combined observations of the Gum Nebula requires a giant H ii region, presumably formed by the Vela X supernova explosion. Mouison and Sartori had concluded on the basis of their He ii fluorescence theory of Type I supernovae that a giant H ii region would be formed as result of the ultraviolet burst. (Bottcher ci at., by integrating over the light curve, expect a smaller H ii region.) We present here in brief some consequences of the fluorescence model as illustrated by the Vela X and the Tycho supernovae. We conclude …

Ground Water Of The Uncompahgre Valley Montrose County, Colorado, Ted William Craig

Masters Theses

"Data from water quality tests of 50 wells and from general well information of 309 wells registered with the Colorado Division of Water Resources are presented for the area of Montrose County, Colorado, drained by the Uncompahgre River. This information, along with other pertinent information such as water laws and costs, is evaluated to determine the feasibility of increasing the use of ground water in the area. The drainage basin of the Uncompahgre River within the Montrose area bas three main geologic structures: the Uncompahgre uplift, the Montrose syncline, and the Gunnison uplift. All formations exposed in the area are …

Quantitative Geomorphology And Hydrology Of The Cass River Basin, New Zealand, Frank J. Schulte

Theses and Dissertations

The Cass River drainage basin is in the Southern Alps in the central part of the South Island of New Zealand. The Alps are composed of complexly folded greywacke which is still actively rising. The basin has been modified by several glacial advances during Pleistocene time.

The Cass basin has a temperate climate characterized by a steep precipitation gradient. Its vegetation includes plants of the forest grassland, shrubland, swamp, rock, and river-bed associations.

The Cass basin may be divided into four geomorphic areas: bedrock areas, high-angle fans, moderate-angle fans, and a low-angle fan. The bedrock areas consist of fractured greywacke; …

Barbara Ward, Barbara Ward

Stevenson Lecture Series

Barbara Ward is the six speaker in the Adlai Stevenson series; she is a British political Scientis and autho, and is also known as Lady Jackson, wife of Sir Robert Jackson. This speech is titled "Survival in the Seventies."

The Prairie Naturalist Volume 2, Nos. 3 And 4 September–December, 1970

The Prairie Naturalist

EDITORIAL: Ecology and Environmental Education ▪ Keith R. Stamm

PEOPLE IN PERIL ▪ Thomas L. Kimball

MEN IN MAN'S ENVIRONMENT ▪ Robert L. Burgess

ENERGY AND MAN'S ENVIRONMENT ▪ Dale Henegar

MINERALS AND SOILS IN MAN'S ENVIRONMENT ▪ Wilson M. Laird

WATER IN MAN'S ENVIRONMENT ▪ Norman Peterson

THE ATMOSPHERE IN MAN'S ENVIRONMENT ▪ Gene A. Christianson

WHY ENVIRONMENTAL EDUCATION IN THE LIFE SCIENCES? ▪ James R. Reilly

ECOLOGICAL EDUCATION IN THE PHYSICAL SCIENCES ▪ William P. Eastwood

MASS MEDIA AND ENVIRONMENTAL EDUCATION ▪ Richard Palmer

THE JUDGMENT OF THE JACKAL ▪ C. Benson Thomerson

THE ROLE OF COLLEGES AND …

Cell-Free Amino Acid-Incorporating Systems From Mesofhilic And Thermophilic Species Of The Genus Bacillus, Nisson Schechter

Dissertations

No abstract provided.

Nuclear Orientation Of 253Es In Neodymium Ethylsulfate, A. J. Soinski, Richard B. Frankel, Q. O. Navarro, D. A. Shirley

Physics

Einsteinium-253 nuclei were oriented at low temperatures in a neodymium ethylsulfate lattice. From the temperature-dependent α-particle angular distribution a nuclear magnetic moment |μ|=(2.7±1.3)μ_N was deduced. From the values for the angular distribution function at the lowest temperatures it was possible to test the predictions of the Mang shell-model theory for the relative phases and amplitudes of the α-partial waves. As predicted, the waves of angular momentum L=0 and 2 are in phase, and the L=0 and 4 waves are out of phase. The predicted wave amplitudes are in error, especially that of the L …

Cobalt(Iii) Complexes With 1,2-Propanediaminediacetic Acid, Paul John Magnell

Masters Theses

Introduction

Aminocarboxylic acid cobalt(III) complexes have been of interest to inorganic chemists since 1909 when Ley and Winkler isolated violet and rose colored geometric isomers of tris amino acid complexes of glycine and alanine.¹ More recently, considerable interest has been shown in the study of the stereochemistry and optical activity arising from configurational and vicinal interactions of these complexes. Nuclear magnetic resonance of the methylene protons on the carboxylate portion of the coordinated ligand has also been studied.

Of immediate interest to this study is the stereo-chemistry of complexes containing flexible tetradentate ligands. A tetradentate ligand may be constructed …

Synthesis And Structure Proof Of Cis-6,6-Dichloro-2-Diphenylmethylene- Bicyclo [3.2.0] Hept-3-Ene-7-One And Cis-2,2- Dichloro- 1,2,2a,7a-Tetrahydro- 7-Diphenylmethylene-Cyclobut (A) Inden-1-0ne, William Douglas Barta

Masters Theses

Introduction

The purpose of this research endeavor was to determine the structures of the adducts of dichloroketene with diphenylfulvene and benzodiphenylfulvene. Structure elucidation was attempted by chemical degradation and nmr analysis.

The structures of the adducts of dichloroketene with cyclopentadiene^1,2 and indene^3,4 have been determined by previous workers. The influence of the exocyclic double bond on the mode of cycloaddition is unknown.

The Fishes Of The Nemaha Basin, Nebraska, Larry Witt

Nebraska Game and Parks Commission: Staff Research Publications

The possible effects of proposed watershed management practices on fish resources of the Nemaha Basin were poorly understood; thus, a study was undertaken to ascertain the species of fish present and their relative abundance and distribution within the basin. Thirty-five species were collected, 34 of them from the Big Nemaha River system and 28 from the Little Nemaha River system. These data may be used as a basis for future studies of fish population changes in the Nemaha Basin and possibly as a basis for studies in other watersheds.

The Ias Bulletin, V4n5, November 1970, Iowa Academy Of Science

IAS Bulletin

In this issue:

--- Officers, Directors, and Section Chairmen, 1970-71
--- Important Board Action Concerning Proceedings
--- Annual Meeting Plans
--- Governor's Conference on Environmental Systems
--- "Public Lands and the People" Conference
--- IAS to Seek NSF Support for State Government-Academy Cooperation
--- IAS Receives NSF Grant to Help Finance Junior Academy Research Symposium
--- New Standing Committees Asked to Meet
--- Iowa Academy-State of Iowa Connections
--- Survey of Interest in the Iowa Science Teachers Journal
--- Back Issues of the Proceedings Available
--- Changes in Farm Management
--- Legislative Advisory Committee to be Appointed
--- Invitations for …

Water Resources News, Volume 2, No. 10, November 1970

Water Current Newsletter

NWRRI Director Named Executive Secretary of Universities Council on Water Resources
1971 Summer Institutes Planned
Research and Development Sources Sought
NWRRI Proposals Submitted
FWQA Booklet on Fish Mortalities
Urban Wastewater Renovation Through Agriculture
Control of Oil Pollution
Environmental Education Bill to White House
Title II Awards for FY 1971
Case Studies in Water Resources Systems Analysis
National Environmental Pollution Conference
UCOWR Annual Meeting Held in Virginia
Reorganizational Plans for Environmental Programs
National Water Commission Studies
Research Review
New Publications Received by the Institute - November

Press Reports, Walter Lawrance

Walter Lawrance Papers

No abstract provided.

Preliminary Indicators Of Income/Wealth Redistribution Associated With Bureau Of Reclamation Projects, Reed Willis, Allen Lebaron, Herbert Fullerton

Reports

Social well-being is an accepted subset of water investment feasibility criteria. Our attempt is to isolate income redistribution impacts conferred by the U.S. Bureau of Reclamation projects. Four project sites have been utilized to yield both pre and post project estimates of farm income and wealth. Production functions of the Cobb-Douglas type were estimated to yield information about factor shares, and thus enable inferences to be made about distribution of total product. Lorenz curves were developed to show changes in distribution of wealth and net income in terms of family enterprise, per acre, and per irrigated acre. Listing of individual …

Some Results On The Distance Properties Of Convolutional Codes, Luther D. Rudolph, Alexander Miczo

Electrical Engineering and Computer Science - Technical Reports

Rate 1/2 binary convolutional codes are analyzed and a lower bound on free distance in terms of the minimum distances of two associated cyclic codes ìs derived. Next, the complexity of computing the free distance is discussed and a counterexample to a conjecture on the relationship of row distance to free distance for systematic codes Ìs presented. Finally, an improved Gilbert bound for definite decoding is derived.

Doppler Shift In Frequency In The Transport Of Electromagnetic Waves Through An Underdense Plasma, Jerry Peacher, Kenneth M. Watson

Physics Faculty Research & Creative Works

In an earlier publication, the validity of the radiation transport theory was studied for the calculation of multiple scattering of electromagnetic waves by a turbulent plasma. In the present paper, we extend the transport theory to include a description of the Doppler shift in frequency caused by electron motion.

Territorial Male Red-Winged Blackbird Distribution In Wood County, Ohio, M. I. Dyer

Bird Control Seminars Proceedings

Red-winged blackbirds (Agelaius phoneiceus) have been studied intensively in the United States and Canada by research biologists of the Bureau of Sport Fisheries and Wildlife for more than a decade. The detailed information on popula¬tion dynamics of the species that has been acquired is now being assembled and assessed. Definite patterns in the distribution of some of the eastern and mid-western populations have become apparent (Dyer et al., 1072; Power, 1069, 1970). A very complex distribution of territorial densities occurs in the western Lake Erie Basin of the U.S. and Canada (Dyer et al., 1972), where there are significant differences …

The Effects Of Ornitrol On Wild Populations Of Red-Winged Blackbirds And Grackles, Robert C. Fringer, Philip Granett

Bird Control Seminars Proceedings

For the past three years the New Jersey Department of Agriculture, in coop¬eration with the New Jersey Agricultural Experiment Station, has conducted field evaluations on the effects of reproductive suppressants on wild populations of red-winged blackbirds. These studies have been performed in conjunction with the North East 49 (a Federally sponsored regional project which presently has nine states in the North East and Ohio cooperating to develop means to combat bird damage to agricultural crops) regional project on control of bird depredations.

Field evaluations in 1968 and 1969 centered around the effects of TEM (tri-ethylene melamine) on the reproductive rates …

Physiological Interpretations Of Morphological Variation In The Red-Winged Blackbird, Dennis M. Power

Bird Control Seminars Proceedings

A number of widespread species vary morphologically throughout their range. Ultimately such geographic variation appears to be adaptive and represents local evolutionary responses to the pressures of natural selection. Detailed knowledge of size, shape and color variation in species such as the Red-winged Blackbird (Agelaius phoeniceus) may eventually allow the identification of breeding localities of autumn and winter flocks simply from morphological evidence. Knowledge of variation in behavioral and physiological parameters also will be useful in assessing the effect of various control devices.

The present study stems from an attempt to elucidate the adaptive significance of geographic variation of redwings …

Outlook For Ornitrol, M. R. Woulfe

Bird Control Seminars Proceedings

My comments at this point will concern the application and uses of Ornitrol. My comments are aimed at people who are engaged in actual control work, people in public health departments and PCO's.

Ornitrol is a chemosterilant--one of the first ones which has been registered for sale. It inhibits egg production apparently in most avians. We know it does this in pigeons, sparrows, grackles, blackbirds, and chickens. It is reasonable to assume that it will do this in many other species, and this generalized action is one of the reasons why it has got to be handled very carefully where …