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The Ias Bulletin, V5n6, November 1971, Iowa Academy Of Science

IAS Bulletin

In this issue:

--- Officers, Directors, and Section Chairmen, 1971-72
--- An Open Letter from the President to the Members of the Iowa Academy of Science
--- Manuscripts for the Proceedings Invited
--- News from the Fall Directors' Meeting
--- Plans for 1972 Spring Meeting Shaping Up
--- Call for Papers for the 1972 Spring Meeting
--- Archeology Section Now Anthropology Section
--- What Ever Became of the Articulation Effort?
--- Future Meetings of the Academy
--- Geology Monograph Widely Distributed
--- New Officers of ISTS
--- Special Summer Study Opportunity Available
--- Do-It-Yourself Kit for Activists
--- 56% of …

Mössbauer-Effect Studies Of The Phase Transitions In Antiferroelectric Pbzro₃ And Ferroelectric Pbti₀.₀₂Zr₀.₈O₃, James P. Canner, C. M. Yagnik, Robert Gerson, William Joseph James

Physics Faculty Research & Creative Works

The Mössbauer spectra were studied for the antiferroelectric compound PbZrO₃ and for the closely related ferroelectric PbTi_0.2Zr_0.8O₃. In both cases, a substitution of 5-mol% BiFeO₃ was made to permit the Mössbauer measurements. Little difference was found in the isomer shift in these compounds, whether they were in the ferroelectric, antiferroelectric, or cubic state, indicating that the bonding character is not affected by the transitions among the states. There was a pronounced and approximately equivalent dip in the recoil-free fraction at the Curie points of both the antiferroelectric and ferroelectric materials, associated with …

Cellular Inactivation By Heavy Ions, Neutrons, And Pions, Robert Katz, S. C. Sharma, M. Hamayoonfar

Robert Katz Publications

The delta-ray theory of the inactivation of cells by energetic heavy ions describes cellular survival after heavy ion bombardment through a two-component survival model, in which 4 operational parameters (E₀,m₀, σ₀, and κ) describe the response of a particular cellular variety in a particular ambient condition, for an arbitrary radiation environment. The quantities m and E₀ are the extrapolation number and extrapolated D-37 dose of the survival curve after gamma-ray irradiation. The quantities σ₀ and κ are found from the initial slope of survival curves after irradiation with ions of different LET, …

Special Studies, Walter A. Lawrance

Walter Lawrance Papers

No abstract provided.

Nuclear-Magnetic-Resonance Studies Of The Semiconductor-To-Metal Transition In Chlorine-Doped Cadmium Sulfide, Frank D. Adams, David C. Look, Carlton L. Brown, Donald R. Locker

Physics Faculty Publications

Spin-lattice relaxation times (T₁) and Knight shifts were measured for Cd¹¹³ nuclei in 12 CdS crystals doped with various amounts of chlorine. Hall coefficients were measured in order to estimate conduction-electron concentrations. Data were obtained for all samples at 300 °K and for some highly doped samples at 77, 4.2, and 2.13 °K. Metallic properties were observed in all samples having electron concentrations n>2×10¹⁸ cm^-3. At 300 °K, we find 1/T₁∝n for nonmetallic samples and 1/T₁∝n^2/3 when samples are metallic. The latter proportionality continues to hold at lower …

Comment On Electron Scattering In The Image Potential Well, Pavel Smejtek, M. Silver

Physics Faculty Publications and Presentations

Comments are made on the model of electron injection into SiO₂ proposed by Berglund and Powell. Their assumptions on electron scattering, disregarding the change of the escape cone with the distance from the emitter, lead to serious underestimation of the injected current. Two alternative models of electron injection, based solely on elastic scattering are discussed and do not predict the experimental results. We suggest that observed field dependence of the injected current into SiO₂ indicates that energy relaxation associated with the injected electrons is responsible for the voltage dependence of the current.

Detection And Identification Of Molecular Water Pollutants By Laser Raman Spectroscopy, Eugene B. Bradley, Charles A. Frenzel, John Reeves, Robert Mcconnell, Kay Lane

KWRRI Research Reports

Laser Raman spectroscopy is evolving into a primary tool for the Identification of molecular water pollutants. This study pushes the limits of detectivity of carbon disulfide and benzene to ~ 20 ppm in water solutions using a high-resolution Raman spectrometer, cooled detectors, and photon counting techniques. The primary limiting factors were found to be the low throughput and the scattered light performance of the monochromator as well as insufficient laser energy.

An optomized design for a pollution-measuring instrument is suggested, and a prototype has been built which is useful with any value of excitation energy short of sample degrading. The …

An Evaluation Of A Stable Isotope Of Dysprosium For Labeling And Tracing Sedimentary Particles, Charles Glenn Boone

OES Theses and Dissertations

An evaluation of the application of dysprosium oxide as a tracer coating to surface label sedimentary particles is made. Physical and chemical properties of the labeled sand are studied. Effective diameters and settling properties of the tracer sand are compared with unlabeled sand. A total of 8.51 kg of labeled sand was placed on the beach at Camp Pendleton. Dispersal patterns obtained 1 and 4 hours after tracer injection indicate a general down current mean tracer migration rate of 0.21 cm/sec (0.42ft/sec). An absolute detection limit of 4 or 5 parts per 100,000 and a real detection limit, after field …

Gravity Investigations Over A Salt Structure Near Lübbecke, Northern Germany, Reinhard K. Frohlich

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

A detailed gravity survey was conducted parallel to the “Wiehengebirge” northwest of Minden in Northern Germany. The survey localized between Liibbecke and Levern a salt deposit, which is known as “Münder Mergel” salt of the Upper Jurassic. The salt deposit forms a cylindrical structure with an axis striking NWW. With a deep drill hole detailed interpretation was possible using the polygon method of TALWANI, WORZEL and LANDISMAN [1959], The section shapes of salt bodies under eight profiles show asymmetrical figures of two salt units. Both increase in thickness strongly to the northeast, where the salt is interrupted by a fault …

Geophysical And Geological Analysis Of A Fault-Like Linearity In The Lower Clackamas River Area, Clackamas County, Oregon, Ronald Jay Schmela

Dissertations and Theses

A fault-like linearity along the lower Clackamas River is evaluated by analysis of physiographic and structural alignments, geological relationships, and by gravity and magnetic data. The study has resulted in the verification of a structural feature extending along the Clackamas River and the eastern front of the Portland Hills.

Physiographic alignments were examined in twelve 15 minute and two 7-1/2 minute quadrangle maps. A significant northeasterly morphologic trend, N. 20⁰ W. and N. 40° W., and other secondary trends, namely, the N-S, E-W, and N. 50-60° E., has developed in the Portland area. The consistent northwest trend is observed throughout …

Terminal Talk - The Wofford Connection - September 1971, Wofford College Computer Center

Terminal Talk

No abstract provided.

The Ias Bulletin, V5n5, September 1971, Iowa Academy Of Science

IAS Bulletin

In this issue:

--- Officers, Directors, and Section Chairmen, 1971-72
--- Proceedings Progress
--- Business Manager for Proceedings Appointed
--- Submit Manuscripts for Proceedings at Any Time
--- Iowa Science Teachers Journal Will Have Limited Distribution
--- Staff Changes at Drake Involve Academy "Activists"
--- Status of the Iowa State Preserves Advisory Board Uncertain
--- Darling Foundation Issues Catalog of Conversation Education Facilities
--- Are you a Member of AAAS?
--- AAAS Research Grants Awarded
--- AAAS Governance Changes Being Proposed
--- Guide to Upper Iowa River Published By George Knudson of Luther College
--- AAPT-Iowa Section
--- Student Programs …

Evidence For The Existence Of Two Stable Sites For Cobalt Impurity Atoms In Aluminum, Arun Venkatachar

Dissertations and Theses

Using Fe⁵⁷Mössbauer spectroscopy, two alternative sites occupied by cobalt (10^-4 at. % ) impurity atoms in aluminum have been isolated. The substitutional site A is the stable position after annealing the sample above 840 K, followed by a rapid quench. The impurity atoms in site A are characterized by a single line Mössbauer spectrum (indicative of a cubic environment), a room-temperature f = 0.502 (r. m. s. displ. 0.071 A) and an I. S. (reI. to Fe) = -0.421 mm/sec. For anneals below 770 K the cobalt atoms migrate to site B, which is characterized by a …

Application Of The Method Of Lattice Statics To Vacancies In Aluminum, Larry Boyer, John R. Hardy

John R. Hardy Papers

In this paper the method of lattice statics is applied to the calculation of the atomic displacements about a vacancy in aluminum using a fifth-neighbor force-constant model for the dynamical matrix and the vacancy-host lattice interaction. The strain-field interaction energy between two vacancies is similarly calculated. The main object of this work is to demonstrate the important modifications of earlier results, obtained for a first- and second-neighbor force-constant model, when one uses the fifth-neighbor model designed to give a significantly better fit to the measured phonon dispersion curves. In particular it is demonstrated that the displacements about the vacancy continue …

13th Annual Rocky Mountain Spectroscopy Conference

Rocky Mountain Conference on Magnetic Resonance

Program and abstracts from the 13th annual meeting of the Rocky Mountain Spectroscopy Conference, hosted by the Rocky Mountain Section of the Society for Applied Spectroscopy. Held in Denver, Colorado, August 9-10, 1971.

A Study Of Phytoplankton Dynamics In Lake Fayetteville As A Means Of Assessing Water Quality, Richard L. Meyer

Arkansas Water Resources Center Technical Reports

Phytoplankton community was analyzed for seasonal and vertical distribution in Lake Fayetteville. This northwest Arkansas reservoir maintains a stable water level and chemical input with a relatively constant, slow overflow. Its source is groundwater seepage through a calcareous substrate with little contribution from the limited drainage basin. Phytoplankton community development with its associations and assemblages, chlorophylls -a, -b and c, and biomass distribution are described. The seasonal cycles of the chemical parameters NH4-N, NO2-N, NO3-N, ortho-phosphate, silicon, pH, HCO3- and total-alkalinity plus oxygen are described and discussed. The physical parameters of temperature, light and climate are included. The interaction of …

On The Molecular Theory Of Dielectric Polarization In Rigid‐Dipole Fluids, John D. Ramshaw

Physics Faculty Publications and Presentations

A molecular theory is developed for the polarization P(r) produced by a weak position‐dependent external electric field E₀(r) in a finite fluid system, of arbitrary shape, composed of rigid polar molecules. The theory differs from earlier work in that no assumption is made concerning the form of the electrostatic constitutive relation. [The usual assumption in this regard is that P(r) = (ε–1) E(r) / 4π, where E(r) is the total Maxwell electric field. The “dielectric constant” ε is well defined only if the relation between P(r) and E(r) …

A Study Of A Divalent Cation-Selective Electrode, William Stanhope Ryan Jr.

Master's Theses

The ion-selective membrane electrode, recently introduced commercially, has shown excellent promise as a tool for determining ionic activities and concentrations in solution. It was the intent of the author to study the Orion divalent cation-selective electrode with two objectives.

The first objective of this research was to characterize the response of the divalent cation-selective electrode to calcium and magnesium ions in aqueous solutions. The effect of anions, monovalent cations; and pH upon this response was investigated. An examination was made of the response of this electrode to other divalent cations and of the effect of organic solvents on the membrane …

The Thermal Decomposition Of 2,2'-Azoisobutane, Mervin Dewain Atwood

Theses and Dissertations

Nitrogen, isobutane, isobutylene and 2,2,3,3-tetramethylbutane are the only products found in the thermal decomposition of 2,2'-azoisobutane. They are the results of the direct free radical dimerization and disproportionation. Ratio of the rate constants of disproportionation to dimerization was found to be 1.9 at 268°C and 4.5% azobutane in helium. This compared with Blackham and Eatough's value of 1.4 at 243°C and 3.6 at 290°C with 4% azobutane in helium. The ratio of the disproportionation to dimerization increased with an increase in temperature. A change in contact time affected the ratio at lower reaction temperatures but had little effect on it …

An Investigation Of Some Free Radicals.|Ni.|Pdecomposition Of Nitrosyl Disulfonate Ion In Polar Non-Aqueous Solvents.|Nii.|Preaction Between 2,2-Diphenyl -1- Picryl Hydrazyl And Nitrosyl Disulfonate Ion Free Radicals, Janan Mary Hayes

Theses and Dissertations

Part I reports the stud y of the decomposition of nitrosyl disulfonate ion in DMSO, acetonitrile, and dichloromethane. A multi-step mechanism involving sulfite ion, sulfite ion radical, and nitrosyl monosulfonate radical as intermediates is proposed. The products of the decomposition are nitrosonium ion, hydroxylamine disulfonate ion, and hydroxylamine trisulfonate ion. A competitive chain reaction was observed when the decomposition occurred in DMSO. The chain reaction was insignificant in carefully dried acetonitrile and dichloromethane. Part II reports the study of the reaction between 2,2-diphenyl-1-picryl hydrazyl (DPPH) and nitrosyl disulfonate ion. Product analysis and kinetic data obtained from stopped-flow procedures suggest that …

An Extension Of The Cochran Q Test, Soo-Young Cho

Loma Linda University Electronic Theses, Dissertations & Projects

The familiar x ² test is ordinarily used to compare percentage distributions of categorical data for two or more independent samples. A more accurate com parison of the percentages is sometimes obtained if the samples consist of matched individuals. The NcNemar test is generally used when comparing only two related samples. Where there are three or more samples the Cochran Q test is used. Both of these tests apply only to the case of dichotomized responses. This thesis extends the Cochran Q test to the case where the responses are multinomial. A generalized statistic corresponding to Cochran's result is obtained. …

A Comparative Investigation Of The Effects Of Frequent Testing Upon Achievement In Secondary Advanced Algebra, John Thomas Fullerton

All Master's Theses

Relatively speaking, few studies have concerned themselves with the problem of frequent testing, and as Keys pointed out, empirical evidence, uncomplicated by differences in the amount of testing material employed, on the effects of frequent testing is, at best, scarce (14:427). Also many studies used tests and test results for direct instruction, thus introducing additional variables. Furthermore, the choice of subjects and disciplines has been limited, the better part being taken from college psychology and sociology classes or high school science classes. This investigation was not an attempt to modify previous experiments, nor was it an attempt to identify which …

A Kinetic Analysis Of The Iodination Of Pyruvic Acid And Pyruvate Esters, Mohamed M. Fahmi Hegazi

All Master's Theses

In the present work the relative rates of iodination of pyruvic acid and ethyl and methyl pyruvate have been compared at 25.0° C. These studies allow the determination of the respective free energies of activation for these processes. Measurements have also been carried out at various temperatures to determine the enthalpies and entropies of activation for the spontaneous and base catalysed iodinations of these pyruvate systems. The present thesis also includes a comparison of the solvent deuterium isotope effects associated with the spontaneous rate of iodination of pyruvic acid and the alkyl pyruvates. Also, the catalytic rate coefficients associated with …

Synthesis And Characterization Of Some Dioxane Complexes, James Donald Satterlee

All Master's Theses

The boron trifluoride, tin (IV) fluoride and titanium (IV) fluoride complexes with 1,4-dioxane have been prepared and studied using infrared techniques. The compositions of the complexes have been determined and correspond to the 1:1 adducts in the case of the tin and titanium compounds. The boron trifluoride adduct is a 2:1 (acid:base) adduct. Infrared spectra in the region 1300 cm.-1 to 550 cm.-1 are given and the effects of coordination upon the ligand vibrations are described.

Studies Of Pig Brain Thiamin Pyrophosphokinase, James Weldon Peterson

Theses and Dissertations

Pig brain thiamin pyrophosphokinase (TPK) (ATP: thiamin pyrophosphotransferase, EC 2.7.6.2) was purified 260-fold over extracts of brain acetone powder. The purification was followed using a direct, radiometric assay. As determined in an analytical ultracentrifuge and by disc-gel electrophoresis, the most highly purified enzyme preparations were not homogeneous. The purified enzyme has a broad pH optimum extending from 8.3 to 9.3 in phosphate-glycylglycine buffer. It has an isoelectric point at about pH 4.2. For optimal enzymatic activity, the ratio of magnesium to ATP must be 0.6. Any deviation from this ratio causes a rapid drop in enzymatic activity. A study of …

Energy Calibration Of The Western Michigan University Model En Tandem Accelerator, Michael Joseph Parrott

Masters Theses

No abstract provided.

An Application Of Spectroscopic Techniques To The Measurement Of Electron Density And Temperature In A Brush Cathode Plasma, Ramabhai M. Patel

Physics Theses & Dissertations

A brief review of the Langmuir probe, microwave and spectroscopic techniques most commonly used to make measurements .of plasma electron temperature and density is presented. Of these various methods, certain spectroscopic methods are applied to the measurements of electron density and temperature in a helium brush cathode plasma. The density measurement is based on the manner in which a series of Stark broadened spectral lines merges into an apparent continuum before the normal series limit is reached. This approach met with only limited success in that the density could be determined only by extrapolating the data obtained. Primarily because of …

Laser Induced Optical Modulation In Zinc Selenide, Donald Edward Everett

Master's Theses

The experiments reported here with zinc selenide have a two-fold purpose. First, by using basically the same experimental set-up as Conway did, we are attempting to duplicate this LIMA using zinc selenide instead of cadium sulfide. Unlike his set-up, primarily one laser chopping frequency was used. Also, only one laser wavelength, 632.8 nanometers, was available, where Conway used lasers of wave­ lengths 647.1 nanometers and 530.8 nanometers. Another main difference is that in earlier works by Conway, laser pulse duration was of the order of 40 milliseconds, whereas the present duration is approximately 2.5 milliseconds. It was observed that the …

Water Resources News, Volume 3, No. 6, Summer Issue 1971

Water Current Newsletter

Summer Institutes A Success
Dr. William Garner Named Research Specialist for EPA
Title II Program for FY 1973
American Water Resources Association
Soil Erosion Contributes to Water Pollution
UCLA to Grant Doctor of the Environmental Studies
Multiple Objectives Opposed by OMB
It's in the Bag, or Bottle, or Carton
National Environmental Laboratory Act
Oak Ridge National Laboratory Gets New Ecology Facility
Conference Roundup

An Axiom System For The Weak Monadic Second Order Theory Of Two Successors, Dirk Siefkes

Department of Computer Science Technical Reports

No abstract provided.