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Volatile Organic Compound Analysis Of Humboldt Penguin (Spheniscus Humboldti) Preen Oil: A Pilot Study, Dante E. Rojas, Mitchell M. Mccartney, Eva Borras, Michael O. Eze, Abigail Pietrow, Jennifer J. Valvo, Cristina E. Davis

Chemistry Faculty Research & Creative Works

Avian olfaction has gained prominence in recent decades for its roles in social communication and behavior. In penguins, the chemical characterization of preen oil remains limited. In this exploratory study, we characterized the volatile organic compound (VOC) profile of preen oil from Humboldt Penguins (Spheniscus humboldti). Preen oil from 12 captive individuals was analyzed using headspace sorptive extraction (HSSE) coupled to gas chromatography–mass spectrometry (GC–MS). Chemometric analyses examined variation in VOC profiles by sex, age class, and breeding activity. We detected 54 compounds (20 tentatively identified), including linear alcohols, methyl ketones, carboxylic acids, saturated hydrocarbons, oxygenated and nitrogen-containing organics, prenolipids, …

Lessons On Generative Artificial Intelligence From The American Association Of Dental Editors And Journalists (Aadej), Christopher J. Smiley

Journal of the American College of Dentists

The American Association of Dental Editors and Journalists (AADEJ) recently released "Guidance for Authors, Editors and Publishers on the Use of Generative AI". Developed by an 11-member stakeholder panel, this guidance paper serves a dual purpose: It provides practical strategies for mitigating the risks that generative artificial intelligence (GAI) poses to professional writing and explains how GAI creates these risks. Understanding both the underlying vulnerabilities of GAI and how to address them is critical for users at all levels, from authors and reviewers to editors, publishers, and general users, to maintain the validity and reliability of their written work. This …

Improving Human Dimensions Of Conservation Planning: Challenges And Opportunities For Sustainable Conservation Outcomes, Vivian Hulugh

Electronic Theses and Dissertations

Conservation planning is important to ensure both ecological and social benefits of natural resources, including the maintenance of functional ecosystems and stable wildlife populations as well as the provision of resources that communities rely on. Yet, the integration of the human dimensions of conservation planning remains limited in practice. This thesis examines conservation planning in South Dakota and within Joint Venture (JV) partnerships, using qualitative methods to identify challenges and opportunities for more effective and coordinated planning. In chapter one, I examine how collaboration, public participation, and the use of climate information are integrated conservation planning in South Dakota and …

Chemical Load: An Unseen Herbicide Filter In Restored Prairies?, Rylie Franklin

Electronic Theses and Dissertations

Community Assembly Theory is a framework used to describe the process by which species from a regional species pool disperse and encounter various abiotic and biotic conditions that act as filters, limiting which species will populate a specific local community. Prairie restoration success can be improved by understanding abiotic and biotic filters. As agricultural practices have adopted integrated weed management plans, that include the use of both chemical and non-chemical techniques, another filter needs to be considered during restoration: the chemical load of soils, i.e., herbicide residue from recent on-site applications and herbicide drift from adjacent areas. To examine the …

Ecological And Evolutionary Divergence Of A Shared Sympatric Color Polymorphism In Paracirrhites Hawkfish, Samuel Greaves

Graduate Studies Theses and Dissertations 2026

Color polymorphism provides a tractable window into how selection, gene flow, and ecology interact to maintain phenotypic diversity and initiate divergence. I investigate the ecological and genomic basis of sympatric light and melanistic morphs in two reef hawkfishes, Paracirrhites arcatus and P. hemistictus, across Guam and Hawai‘i. This study aims to determine whether the color morphs of these hawkfishes are a stable polymorphism or have begun the process of ecological speciation. For P. arcatus revealed substantially lower density on Guam (0.086 ind/m²) than reported for Hawai‘i (0.292 ind/m²) and a strong skew away from the melanistic morph on Guam …

Energy-Efficient Security For Narrowband Iot Using Blockchain And Ep-Cumac, Hafizullah Kakar

UNF Graduate Theses and Dissertations

The Narrowband Internet of Things (NB-IoT) continues to expand but faces challenges such as cryptographic overhead and energy consumption. Security frameworks such as blockchain and Energy-Performance Cumulative Message Authentication Codes (EP-CuMAC) rely heavily on SHA-256, which is not optimized for energy-limited devices.

This work unifies two complementary approaches, a hybrid blockchain-based NB-IoT framework and an EP-CuMAC-based framework, by engineering their cryptographic core with an Energy Complexity Model-optimized SHA-256 (ECM-SHA256). ECM applies parallel memory-bank mapping and block-level access optimization to reduce redundant power usage while preserving algorithmic integrity.

Experimental evaluation on identical Intel DDR3 systems using pyRAPL shows energy savings of …

Growth And Dielectric Characterization Of Epitaxial Sr1-Xmgxtio3 Thin Films, Richard Badu

UNF Graduate Theses and Dissertations

Complex oxide materials with ferroelectric ground states remain promising candi dates for next-generation high-capacitance and nonlinear microelectronic applica tions. One of those materials is SrTiO3 (STO). However, STO is an incipient fer roelectric with anomalously high dielectric permittivity at low temperatures. STO crystals possess a highly polarizable lattice that is sensitive to even small amounts of impurities. Substituting Mg into the STO matrix is predicted to induce a corre lation between ferroelectric and relaxor behavior. In this thesis, we demonstrated the growth of a series of epitaxial STO and Sr1-xMgxTiO3 thin films using molec ular beam epitaxy. The surface evolution …

Advancing Multi-Modal Learning, Swetha Sirnam

Graduate Studies Theses and Dissertations 2026

Multimodal learning aims to develop systems that understand and reason across multiple sources of information such as images, videos, audio, and text. These capabilities are central to applications including visual search, digital assistants, robotics, and visual question answering. Despite recent progress in multimodal large language models, current approaches struggle to capture the structured complexity of real-world visual data. Fine-grained visual details are often lost during multimodal alignment, models frequently fail to capture nuanced human intent, and existing methods remain limited in understanding long-form videos with complex temporal dynamics. Furthermore, many evaluation benchmarks rely heavily on explicit visual cues, which can …

Federated Learning In The Era Of Foundation Models, Guangyu Sun

Graduate Studies Theses and Dissertations 2026

The emergence of large-scale foundation models has reshaped computer vision and multi-modal learning, but their substantial computational and communication demands pose significant challenges for deployment in federated learning (FL) systems. Federated learning enables collaborative model training across decentralized clients without sharing raw data, offering strong privacy guarantees. However, adapting foundation models in FL remains difficult due to communication bottlenecks, heterogeneous data distributions, limited device resources, and scarce labeled data. This dissertation presents a unified line of research that addresses these challenges through four complementary frameworks, progressively advancing the efficiency, personalization, and practicality of foundation model adaptation in federated settings.

First, …

High Intensity Ablation By Laser Filaments At Standoff Distances, Owen Thome

Graduate Studies Theses and Dissertations 2026

The high-power densities delivered to a target material by a laser allow for melting and vaporization to occur, a process called laser ablation. At higher intensities, plasma formation occurs and more complex material removal mechanisms take place. As laser power increases, nonlinear effects occur during propagation. One such effect, Kerr self-focusing, leads to beam collapse and ionization, resulting in a channel of plasma and region of high intensity light referred to as a laser filament. Filaments carry intensities on the order of 10¹³ W/cm² to significant distances without the use of large-scale focusing optics. Laser filament ablation is …

Watch Your Step, Mind The Crowd: Socially Compliant Navigation In Unstructured Environments, Jack Vice

Graduate Studies Theses and Dissertations 2026

Autonomous mobile robots increasingly operate in complex real-world environments characterized by uneven terrain, dynamic obstacles, and human presence. This dissertation addresses the fundamental challenge of developing adaptive navigation strategies that enable robots to safely and effectively traverse unstructured outdoor environments including construction sites, agricultural fields, and disaster areas while maintaining social compliance around people. We advance this capability through five complementary contributions that collectively target dynamic, unstructured, human-occupied environments. First, we demonstrate evolutionary optimization of legged mobility for uneven terrain. Second, we propose using a spatiotemporal autoencoder to learn the temporal dynamics of moving people and objects. Third, we introduce …

Charge Transport Modeling Of Multifunctional Molecular Transistors, Romena Akter

Graduate Studies Theses and Dissertations 2026

Distinguishing between the current–voltage characteristic curves associated with different transport mechanisms in a molecular electronic device and an artifact arising from device-level disorder is a central challenge in the study of molecular electronics. Characterizing these mechanisms and connecting them qualitatively to molecular-level orbital alignment, electrode coupling, voltage division, energetic disorder, and reorganization energy requires not only experimental data but also a rigorous theoretical framework for extracting physically meaningful parameters from measured transfer characteristics. This dissertation addresses this challenge in Chapters 2, 3, and 4 by developing and applying four complementary transport models —Simmons tunneling, single-level Landauer, Marcus hopping, and McConnell …

Making Unsafe Sequences Unexecutable: Formal Protocol Enforcement For Cyber-Physical Systems, Arthur Amorim

Graduate Studies Theses and Dissertations 2026

Cyber-physical systems execute physical actions in response to software commands, making their communication protocols a primary attack surface. A stealthy attack is a sequence of individually valid messages that violates a required ordering, driving the system into an unsafe state without malware or protocol violation. Existing defenses examine messages or physical state in isolation, not protocol level sequences, and cannot prevent them. Preventing them requires enforcement that makes unsafe sequences unexecutable at the communication boundary.

Formal methods offer a principled path to enforcement, but no tool spans specification to safe deployed hardware. Model checking automates proofs but has no certified …

Connecting The Existing Fiber Infrastructure To The Future With Antiresonant Hollow Core Fibers, Timothy Bate

Graduate Studies Theses and Dissertations 2026

Optical fiber systems based on solid-core silica waveguides underpin modern telecommunications, high-power laser delivery, precision sensing, and coherent optical systems. However, nonlinear effects, material absorption, and thermal limitations within silica increasingly constrain further scaling in both optical power and transmission performance. Antiresonant hollow-core fibers provide a promising alternative by guiding light predominantly in air, substantially reducing nonlinear interactions, latency, and optical damage while enabling transmission regimes inaccessible to conventional solid-core fibers. Despite rapid advances in antiresonant hollow-core fiber attenuation and power handling, one of the largest remaining barriers to widespread adoption is reliable integration with the existing solid-core fiber ecosystem. …

A Systematic Review And Characterization Of Privacy Noncompliance In Real-World Applications, Alexander E. Charkiewicz

Graduate Studies Theses and Dissertations 2026

Software applications increasingly rely on user data to provide their functionality, but improper handling of such data can lead to serious privacy noncompliance with applicable regulations and policies. A prominent example is the Facebook–Cambridge Analytica scandal, in which a third-party application collected the personal data of approximately 87 million Facebook users without users' consent. Despite growing attention to privacy compliance, two key challenges hinder the systematic understanding and analysis of privacy noncompliance. First, unlike security vulnerabilities, which have been systematically categorized through taxonomies such as the Common Weakness Enumeration (CWE), privacy noncompliance lacks a technical taxonomy describing how it manifests …

An Empirical Comparison Of K-Nearest-Neighbors And Logistic Regression Classification Models, Jackson Cushing

Graduate Studies Theses and Dissertations 2026

This thesis presents an empirical comparison of two classification methods: Logistic Regression and K Nearest Neighbors (KNN). The primary objective of this research is to evaluate the strengths and limitations of each method when applied to real-world datasets. Several publicly available datasets on diabetes, breast cancer, heart attack risk, and cardiovascular disease, were analyzed. For each dataset, K Nearest Neighbors models were implemented in the same way logistic regression had already been applied. The results demonstrate that while logistic regression offers interpretable parameter estimates and performs well when the underlying predictor and outcome relationship is approximately linear, however KNN can …

Integrated Optical Probes For Confocal Scanning Imaging And Adjustable Coherent-Gated Dynamic Sensing, Yonglin Huang

Graduate Studies Theses and Dissertations 2026

Optics and photonics have been one of the most important sciences and technologies that impact modern human life in a big way. For example, fiber-optics for communications and artificial intelligence. Optical probes are critical components for optical imaging and optical sensing technologies that have been actively researched and developed in the past decades. Advanced fiber-optic sensor probes with smaller size, better performance, lower noise, higher photon efficiency, rapid sensing time, and lower cost are needed in many applications, such as nanoscale material science, chemistry, and biomedical fields, etc.  In this project, new fiber-optic sensor probe technologies and integrated micro-optic devices …

Advances In Active And Passive Integrated Photonic Devices On Thin-Film Lithium Niobate, Pooja S. Kulkarni

Graduate Studies Theses and Dissertations 2026

Thin-film lithium niobate (TFLN) has emerged as a powerful platform for integrated photonics, combining the exceptional electro-optic, nonlinear, and optical properties of bulk lithium niobate with the scalability and compactness of planar nanophotonic technologies. Building on these principles, advanced device architectures such as adiabatic dichroic filters have demonstrated exceptional spectral performance spanning over two octaves of bandwidth on the TFLN platform. Beyond reciprocal devices, it also offers promising pathways toward integrated nonreciprocal components. By leveraging broadband filtering structures and advanced nonlinear photonic design strategies, compact and monolithic optical isolators can be envisioned without relying on traditional magneto-optic materials. In the …

Visual Cues Of Human-Likeness, Not Salience, Impact Trust-Related Human-Computer Interaction, Jordan Schotz

Graduate Studies Theses and Dissertations 2026

As interactions with digital agents become increasingly integrated into daily life, understanding how visual representations influence social decision-making is critical. Previous research in human-computer interaction has frequently confounded the psychological effects of an agent's perceived human-likeness with the underlying visual salience of the stimuli. To address these persistent gaps, the present study systematically isolated the effects of human-likeness and visual cue trustworthiness on trust behavior while controlling for objective image properties. The present study expanded on and normed the Virtual Avatar Facial Stimuli Set (VAFSS), a comprehensive database comprising hundreds of identity-matched photographs and computer-generated avatars varying across a spectrum …

Investigation Of Exotic Phenomena In Topological Quantum Materials, Iftakhar Bin Elius

Graduate Studies Theses and Dissertations 2026

he First Quantum Revolution established quantum mechanics as the foundation of modern physics, enabling transformative technologies such as semiconductors, lasers, and transistors through prin-ciples of quantization, wave-particle duality, and uncertainty. The ongoing Second Quantum Rev-olution harnesses entanglement, superposition, and coherence to advance quantum computation, communication, simulation, and sensing. Central to this endeavor is the study of quantum mate-rials hosting novel electronic structures and emergent phases, including topological insulators and Dirac, Weyl, and nodal-line semimetals. In this thesis, using angle-resolved photoemission spec-troscopy (ARPES), transport measurements, and density functional theory (DFT) calculations, we investigate three classes of materials: (i) magnetic topological semimetals, …

Computational Regolith Mechanics And Instrumentation Development For Lunar Exploration And Resource Utilization, Jared M. Long-Fox

Graduate Studies Theses and Dissertations 2026

Sustained exploration of the Moon requires quantitative understanding of lunar regolith properties to support scientific investigation, in situ resource utilization, excavation, and infrastructure development. This dissertation examines the mechanical interaction between robotic excavation systems and lunar regolith, emphasizing how regolith behavior both enables and constrains exploration-focused and exploration-enabled science. Computational excavation models were compared to laboratory data to evaluate prediction of excavation forces and to develop metrics of excavation efficiency. Laboratory experiments using high-fidelity lunar regolith simulants were conducted to characterize pressure-sinkage behavior, shear strength, and angle of repose across a range of material states. Common analytical excavation and terramechanics …

Revolution In The Age Of Social Media: A Mathematical Model For Information, Dissent, And Stability, Killian Muollo

Graduate Studies Theses and Dissertations 2026

Revolutions, defined by Skocpol as rapid transformations in class, state, and/or social structures, are important world events that can cause civil wars, spark international trends, and result in transitions toward democratic and autocratic regimes alike. They are characterized largely by the mechanism of mass mobilization, which is increasingly facilitated by online networks and digital communication. In this dissertation, we investigate such means and outcomes of revolutions as dynamical systems. We construct three models describing separate but complementary aspects of revolution, beginning at the smallest unit of analysis and then moving outward in scope. First, we construct a graph-based model to …

Report On A Gpr Survey Of The Copper Harbor Cemetery, Copper Harbor, Michigan, Grace Griffin

Dissertations, Master's Theses and Master's Reports

The Copper Harbor Cemetery in Grant Township, Michigan, is one of the oldest settler cemeteries in the Keweenaw, with the earliest burial dating back to 1853. The cemetery is also still used by the community today. However, consistent burial records have not been maintained throughout the cemetery's entire history, leading to some doubt about which areas of the cemetery can be opened for new burials and where excavation should be avoided. For this reason, Grant Township commissioned a ground penetrating radar (GPR) survey of the cemetery, primarily to locate anomalies indicating possible unmarked graves and possible buried headstones. The survey …

First-Principles Investigation Of Quasi-One-Dimensional Van Der Waals Magnets For Advancing Low-Dimensional Spintronics, Alyssa Horne

Dissertations, Master's Theses and Master's Reports

Van der Waals (vdW) magnets have been of great interest for advancing low- dimensional spintronics. A notable example is the quasi-one-dimensional (Q1D) vdW CrSbSe₃, as it is composed of individual one-dimensional units that are held together by the vdW forces. Finding other Q1D vdW magnets that exhibit non-metallic behavior together with long range ferromagnetic ordering is critical in developing next generation spintronics. Here in, using first-principles density functional theory (DFT), we investigate the compositional effects on electronic and magnetic behavior of Cr_1–xMn_xSbSe₃ (x = 0, 0.5, 1). When 50% of Cr is replaced …

An Investigation On Downwind Impacts Of The Keweenaw Peninsula On Lake-Effect Snow Events, Thomas M. Pavell

Dissertations, Master's Theses and Master's Reports

Lake-effect snow (LES) produces copious amounts of snow across the Great Lakes region. While mechanisms and impacts are well-understood, they remain difficult to observe and study over Lake Superior and the Upper Peninsula of Michigan due to a large gap in radar coverage and sparse in-situ measurements. The goal of this project aimed to characterize variables present across Lake Superior and counties on and downstream of the Keweenaw Peninsula that contribute to the formation and evolution of lake-effect snowbands. Nine different lake-effect snow events were analyzed in this project, identifying structures and features resulting from upstream passage over the Keweenaw …

Fabrication Of Urea With Amorphous Silica To Increase Rice Growth In Saline Soils, Thi Ha Chi Nguyen, Thi Hang Thuc Ha, Minh Phuong Nguyen, Ngoc Chuc Pham, Quang Bac Nguyen, Nguyen Huy Tuan Do, Ngoc Nhiem Dao, Trung Kien Nguyen

Applied Environmental Research

In recent decades, the decrease in rice cultivation areas in Vietnam, particularly in the Mekong River Delta, caused by climate change and soil salinization, has posed serious challenges for sustainable development. In addition to irrigation and agronomic practices, fertilizers that sustain rice growth under saline conditions play a crucial role in improving crop productivity. Amorphous silica has been reported to increase plant tolerance to drought, salinity, and heavy metal stress. In this study, nanosilica-coated urea (UCS) fertilizers were synthesized by coating urea granules with 1–5 wt% amorphous silica. The products were characterized by SEM, XRD, FTIR, TG‒DSC, and EDX to …

Spatial Modeling Of Natural Disaster Risk By Integrating Hazard, Vulnerability, And Exposure Factors Using Geospatial Techniques : Evidence From Mueang Tak District, Thailand, Suphatphong Ruthamnong

Applied Environmental Research

This study presents a comprehensive multihazard risk assessment for Mueang Tak District, Thailand, that integrates hazard, vulnerability, and exposure (H-V-E) dimensions. By utilizing geographic information systems (GIS) and remote sensing, the analytic hierarchy process (AHP) was employed to prioritize critical risk factors. GIS analysis integrated multisource spatial data, including Landsat 9 and Sentinel-2 imagery, CHIRPS precipitation, and SRTM-derived topography, while AHP weights were established on the basis of expert judgment and socioeconomic indices such as the relative wealth index (RWI) and population statistics. The results delineate distinct spatial risk clusters: high landslide potential is concentrated in the steep terrain of …

Evaluation Of Soil Moisture Content, Ph, And Dominant Microorganisms In Crude Oil–Contaminated Soil Treated With Cow Dung, Indole-3-Acetic Acid (Iaa), And Simulated Microgravity, Amenze Ovenseri, Tawari-Fufeyin P.

Applied Environmental Research

Crude oil negatively affects soil physicochemical properties and microbial activity, thereby hindering plant growth and posing notable environmental and agricultural issues. The combined effects of cow dung, indole-3-acetic acid (IAA), and simulated microgravity on the recovery of soil degraded by crude oil were explored using Zea mays as the test plant. Soil was contaminated with crude oil at different concentrations (0%, 1%, 3%, and 5% v/w), with each concentration comprising eight treatments: cow dung, Zea mays seeds exposed to microgravity, and IAA alone or in combination. Changes in plant height, soil pH, soil moisture content, and soil microbial diversity were …

Evaluating Sediment Control Strategies Using Swat Based Bmp Assessment In A Tropical Highland Watershed, Northern Thailand, ฺBanchongsak Faksomboon, Wilailak Suanmali

Applied Environmental Research

Soil erosion remains a critical environmental challenge in the tropical highland watersheds of Southeast Asia, where steep terrain, intense monsoonal rainfall, and intensive land use interact to accelerate sediment generation and downstream degradation. This study aims to quantify spatial patterns of sediment yield and to systematically evaluate the effectiveness of individual and combined best management practices (BMPs) at both the watershed and subwatershed (SWW) scales using the Soil and Water Assessment Tool (SWAT) in a tropical highland watershed in northern Thailand. Baseline simulations reveal pronounced spatial heterogeneity in erosion severity, with substantial portions of the watershed exhibiting moderate to extreme …

Exploring Consumers’ Intention And Behavior In The Circular Economy : Evidence From Vietnam, Tuan Hoang Nguyen, Vo Minh Thang Phan

Applied Environmental Research

This study aims to address the key gaps in understanding the factors influencing the intention–behavior relationship of consumers in the context of the circular economy (CE). Grounded in the theory of planned behavior (TPB), this research extends the framework by integrating social pressure, attitudes toward green consumption, and the availability of CE products as crucial components that shape intention and behavior. Data were collected from 603 Vietnamese consumers and analyzed using partial least squares structural equation modeling (PLS-SEM). The results confirm the core TPB constructs, with perceived behavioral control emerging as the most influential factor. Notably, attitude toward green consumption …