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The Pesticide Reregistration Process: Collections Of Human Health Hazards Data For 3-Chloro-P-Toluidine Hydrochloride (Drc-1339), Ray T. Sterner, Donald J. Elias, Daniel R. Cervin

Vertebrate Pest Conference Proceedings: 15th (1992)

The 1988 Amendments to the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA) accelerated the reregistration schedule for pesticide products registered with the Environmental Protection Agency (EPA) prior to 1984. The compound 3-chloro-p-toluidine hydrochloride (DRC-1339), an avicide registered to control 14 pest bird species, was included on Pesticide List B published by EPA. For the reregistration of DRC-1339,44 studies were required — 22 product chemistry, 7 wildlife/aquatic hazards, 8 human/domestic animal hazards, 5 environmental fate, and 2 residue chemistry studies. In 5 acute human-health-hazards studies, DRC-1339 was found to: (1) have an oral LD₅₀ of 330 (272-401) mg/kg in rats, …

Reconnaissance Survey Of Nitrate Concentrations In Ground Water In Howard And Pike Counties, Arkansas, Travis Thornton, Kenneth F. Steele

Arkansas Water Resources Center Technical Reports

In recent years, the rapid growth of poultry and hog production in Arkansas has caused concern regarding nitrate contamination of the ground water. In the study area of Pike and Howard Counties, the number of hogs has increased from 3,300 hogs in 1970 to 75,000 hogs in 1990. Poultr¥ production for the area has increased from 38,933,000 per year 1n 1970 to 62,774,000 per year in 1990. As animal production increases, so does the amount of animal waste that must be disposed. Hog production is of particular concern. Typical hog operations store concentrated animal waste in lagoons prior to land …

The Denver Wildlife Research Center: An Update, Richard D. Curnow

Great Plains Wildlife Damage Control Workshop Proceedings

The Denver Wildlife Research Center (DWRC) has progressed as part of the U.S. Department of Agriculture's Animal and Plant Health Inspection Service (APHIS) in its capability to support the APHIS Animal Damage Control (ADC) program and provide the agency and the public with expanded knowledge and new or alternative tools to reduce wildlife conflicts with agriculture and other human endeavors. As a result of this increased capability, the DWRC conducts research and provides data that conform to the Environmental Protection Agency's (EPA) Good Laboratory Practice Standards for pesticide registration and reregistration and to the guidelines of the Animal Welfare Act …

The Probe, Issue 107 - January/February 1991

The Probe: Newsletter of the National Animal Damage Control Association

Contents:
Registration of Alpha-Chloralose
Rice Seed Repellents
Perimeter Netting of Catfish Ponds
Frightening Devices for Coyotes
DRC-1339 Registration
DRC-1339 For Raven Control
Zinc Phosphide Registration
Coyote Attractant Research
Gas Cartridges
Coyote Bait Acceptance
Trapping is a Profession, Not a Sport
Bovine TB in Elk
NADCA Secretary Objects to Predator Article
Heart Transplants for Rats
Gallup Poll on Public Opinion of Animal Rightists Reaffirmed
Personnel Changes
Prevention and Control Tips: Tree Squirrels
Upcoming Meetings
President’s Corner
NADCA Official Sponsor of Fifth Eastern Wildlife Damage Control Conference
Information on Snaring Needed by Maine Reader

Ua66/7/2 Hilltopper News, Wku Chemistry

WKU Administration Documents

Newsletter created by and about the WKU Chemistry department.

The Kinetic Study Of Degradation Of The Azo Dyes By Photolytic Ozonation And Photolytic Hydorgen Peroxide Oxidation, Hung-Yee Shu

Theses

The experiments which study the decomposition of azo dyes such as acid red 1 and acid yellow 23 by using ozonation, photolytic ozonation and photolytic hydrogen peroxide oxidation have been studied in laboratory sized reactor and pilot scale reactor to determine the reaction rate constants.

The rate constants and mass transfer coefficients were obtained by a series of experiments of varying complexity. A reaction kinetic model which describes the contemplated experiments was developed and exercised using the Rosenbrock Hillclimb Optimization Algorithm with the Forth-Order Runge-Kutta method. The effects between different hydrogen peroxide dosages and pH level were also analyzed.

In …

Politics And Economics Of Maintaining Pesticide Registrations, Kathleen A. Fagerstone, Roger W. Bullard, Craig A. Ramey

Vertebrate Pest Conference Proceedings: 14th (1990)

The Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA) was amended in 1988 to require the reregistration of all pesticides registered before 1984 within 9 years. The FIFRA 88 required that all pesticide active ingredients must meet current registration standards, suspended the previous fee structure, and imposed a one-time registration fee and annual maintenance fees. New data generated because of FIFRA 88 must conform to EPA's Good Laboratory Practice Standards and animal studies must follow guidelines of the Animal Welfare Act. FIFRA 88 has significantly increased data requirements, data costs, and other pesticide registration and reregistration costs for most pesticides. The …

The Chemistry Of Sulfonyl Fluorides: Sf5 And/Or So2f Containing Compounds As Precursors To Sulfonic Acids, Robin Joyce Terjeson

Dissertations and Theses

Sulfonyl fluoride systems and their derivatives, RS0₂F, where R represents hydrocarbon/fluorocarbon moieties continue to be of considerable interest. The incorporation of the sulfonyl fluoride group (S0₂F) into molecular systems can lead to compounds that are useful as ion-exchange resins, surface active agents, fuel cell electrolytes, and strong sulfonic acids/salts.

Interest in preparing SF₅ containing sulfonyl fluorides led to the synthesis of the ᵝ-sultone, SF₅CHCF₂0S0₂, and its rearranged product. Hydrolysis of the sultone gave SF₅CH₂S0₂F which led to the sulfonic acid and salt, SF …

Analytical Chemistry Applications Of Synchrotron Radiation, Juana Acrivos

Faculty Publications, Chemistry

Lecture given at the University of California at Berkeley as NSF Woman Chemistry Professor.

Effects Of A Dispersed And Undispersed Crude Oil On Mangroves, Seagrasses And Corals, T. G. Ballou, Richard E. Dodge, S. C. Hess, A. H. Knap, Thomas D. Sleeter

Marine & Environmental Sciences Faculty Reports

The primary objective of this study was to evaluate the application of dispersant to spilled oil as a means of reducing adverse environmental effects of oil spills in nearshore, tropical waters. The results of numerous laboratory and field studies have suggested that dispersants may play a useful role in reducing adverse impacts on sensitive and valued environments such as mangroves, seagrasses, and corals. However, the use of dispersants has not been allowed thus far in most situations because of a lack of direct experimental data on the various effects of dispersants and the environmental trade-offs presumed to occur as a …

Petrology Of Pliocene (?) Basalts Of Curlew Valley (Box Elder Co.), Utah, Steven Brent Kerr

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Basalt outcrops in Curlew Valley consist of several flow remnants and eruptive centers situated along the valley margins. Basalt is also found in association with salic rocks that erupted in the central portion of the valley. The basalts are of probable Pliocene age and were erupted during a period of active extensional tectonics. Since their emplacement, the basalts have been extensively eroded and downfaulted. The present morphology reflects the erosional and depositional processes of prehistoric Lake Bonneville.

Twelve samples were analyzed chemically for major oxides, trace elements, and rare-earth elements. The basalts form a hypersthene normative series ranging from olivine …

Tropical Oil Pollution Investigations In Coastal Systems (Tropics): Final Report, T. G. Ballou, Richard E. Dodge, S. C. Hess, A. H. Knap, T. D. Sleeter

Marine & Environmental Sciences Faculty Reports

No abstract provided.

The Fricke Dosimeter As A 1-Hit Detector, Robert Katz, G. L. Sinclair, M. P. R. Waligorski

Robert Katz Publications

A fit to the experimental data for the response of the Fricke dosimeter to energetic heavy ions is obtained using a calculation of the relative effectiveness of a 1-hit detector, from track theory. We use 2 fitted parameters, the target size, a₀, which may be thought to represent a “diffusion length,” and E₀, the dose of gamma-rays at which there is an average of one hit per target (the D-37 dose), and a new algorithm for the average radial distribution of dose in liquid water from the passing ion. The G value for ions is then …

Interspecific Correlations Of Harvest And Price For Arkansas Furbearers: A Cautionary Note, James H. Peck, Gary A. Heidt, Anita J. Giggleman

Journal of the Arkansas Academy of Science

No abstract provided.

Artificial Intelligence: Myths And Realities, Hugo D'Alarcao

Bridgewater Review

Artificial intelligence the name conjures images of mechanical monsters, the Golem, Dr. Frankenstein’s creation and the rebellious computer Hal. We have always been fascinated by the possibility of creating a machine in our image, but this fascination is often accompanied by apprehension. We fear losing control of our creation and suspect that it might turn against us. It is this duality, this conflict between the desire to create and the fear of the consequences of the creation that has been so successfully exploited by writers. It is also, in part, this fascination that has recently brought the field of Artificial …

Chemistry, Norman Kulevsky

UND Departmental Histories

This departmental history was written on the occasion of the UND Centennial in 1983.

Reconnaissance Of Sediment-Phosphorus Relationships In Some Utah Reservoirs, Jay J. Messer, Jean M. Ihnat

Reports

Introduction: Phosphorus inputs to lakes and reservoirs from tributary streams and non-point sources are well-known contributors to nuisance algal growths that degrade water quality for potable and recreational uses in lakes and reservoirs. However, phosphours inputs to the euphotic zone may also occur from within the lake itself, as a result of releases from both oxic and anoxid sediments. Such releases may originate from phosphorus inputs to a lake or reservoir during high runoff periods in the previous winder or spring, or they may represent phosphorus trapped in the sediment many years earlier, when phosphorus contributions from natural or anthropogenic …

A Study Of Selected Variables For Prediction Of Success And Placement In General Chemistry At Western Michigan University, Stephen M. Yekeson

Dissertations

Chapter I

The Problem

Introduction

The traditional philosophy that a college-or a university is an exclusive institution in which only highly selected individuals receive a concentrated training in the traditional liberal arts no longer exists. In America, for instance, as early as 1870, Harvard, the colonial college with a narrow curriculum, was transformed rather rapidly into a modern university with many new subjects and the elective system (Garrett, 1949). Also, since 1642, when the first entrance requirements were instituted for American higher education, a continuing debate has developed over what constitutes a sound curriculum for education. There are those who …

A Survey Of The Water Quality And Fishes Of Rocky Branch Nature Preserve, Clark County, Illinois, Larry J. Decker

Masters Theses

No abstract provided.

Groundwater Of The Spiritwood Lake Area, Stutsman County, North Dakota, Frank J. Schulte

Theses and Dissertations

The Spiritwood Lake study area is in a generally undulating to rolling glacial plain 17 miles north and east of Jamestown, North Dakota. Spiritwood Lake is about 50 feet below the surface of the bedrock plain in a former melt-water channel. In the study area, glacial drift unconformably overlies the Pierre Shale, the youngest pre-Pleistocene sediment. The boundary between the two units is marked by a zone of shattered Pierre Shale. The top of this shattered zone forms a plain of moderate relief which probably was the preglacial surface of the study area.

Two large valleys can be distinguished in …

On The Mechanism Of The Diels-Alder Reaction--Dimerization Of Trans-Phenylbutadiene, Michael Ward Mcnicholas

Dissertations and Theses

The Diels-Alder dimerization of trans-1-substituted butadienes is expected to yield a cyclohexene adduct with the substituents in the 3 and 4 positions cis to one another. This prediction is based on past observations of other Diels-Alder additions. The cis-isomer is the only one consistent with a two-stage mechanism proposed by Woodward and Katz.

In the case of trans-phenylbutadiene, the expected adduct is cis-3-phenyl 1-4-(trans-styry1) cyclohexene. Alder, Haydn and Vogt, however, reported that the corresponding trans-isomer is the dimerization product. There is reason to believe that the observation of the trans-isomer may have been the result of product isomerization during purification. …

Micronutrients And Biological Patterns In Lake Mead, Hasan K. Qashu, Lorne G. Everett, J. S. Carlson, Bureau Of Reclamation

Publications (WR)

Progressive increases in concentration of dissolved solids in the Colorado River water from Lake Powell to Imperial Dam seem to alter plankton dynamics and biological productivity of the river. Also, changes in biological productivity and micronutrients concentrations occur within the same reservoir. Development of a digital simulation model to predict micronutrients concentrations and biological productivity is necessary for diagnosing changes in plankton population and effluent-carrying capacity of the system. The objectives of the study are: (1) to determine trace metal balance at different locations in Lake Mead, (2) to measure biological productivity and conduct plankton population counts at each sampling …

Cyclization Studies Involving The Synthesis Of 5-Substituted-1-Naphthol, Clark Keelock Chow

Dissertations and Theses

The γ-o-substituted-phenylparaconic acids were prepared by a method patterned after that of Fuson. These paraconic acids were prepared in good yield. A re-investigation of the Perkin and Fittig methods of preparing γ-phenylisocrotonic acid was carried out without success.

The synthesis of γ-o-halophenylisocrotonic acids by thermal, and catalyzed decarboxylation of γ-o-halophenylparaconic acid, have been carried out in good yield. An effective catalyst, optimum temperature and reaction period of decarboxylation of the γ-o-halophenylparaconic acids have been determined. Infrared absorptions have characterized the γ-o-halophenylisocrotonic acids formed to be in the stable trans form. …

Absolute Specification Of X-Ray Spectra By Laplace Transform Analysis Of Attenuation Data, Gerald Robert Lusk

Masters Theses

"A well characterized, variable plate separation ion chamber was utilized as a detector to collect x-ray attenuation data for generating information on the Laplace transform predicted spectrum of a 50 KvCP conventional x-ray tube. The variable plate separation feature allows one to include a wavelength dependent correction to the detector response which is associated with the hardening of the x-ray spectrum as it traverses the attenuating material. With this correction, the conventional two-term Laplace transform was shown to approximate independently the bremsstrahlung and characteristic L radiation from the tungsten target. The detector provides an absolute statement of the target-referenced x-ray …

Absolute Soft X-Ray Dosimetry For Radiation Chemistry Studies, Howard Sajon Joyner

Masters Theses

"A homogeneous, variable plate separation ion chamber consisting of a polyethylene body and employing flowing ethylene as the cavity gas has been designed and tested for the specification soft x-ray (<75kV) energy deposition in typical hydrocarbons. The variable plate separation feature provided primary data on the differential specific ionization originating within the cavity gas occupying the effective collector volume which is independent of inherent chamber inhomogeneities associated with the electrically conducting films comprizing the chamber electrodes. These data demonstrated that charged particle equilibrium is established within the first few ten thousandths of an inch in typical solid hydrocarbons irradiated with this class of sources. Comparison of this type of chamber with a fixed plate separation, static cavity gas mode of operation showed that the latter may predict dose rates with inherent errors exceeding 100%. With the quality of electronic readout accessories presently available, the variable plate separation chamber yielded dose rate data exhibiting a probable error of 3.8 percent (plus the unknown uncertainty in the literature data on the energy required to form an ion pair), and an ultimate limiting error of less than 2 percent appears feasible"--Abstract, page ii.

Water Chemistry Survey Of Boulder Basin, Lake Mead, P. R. Tramutt, Bureau Of Reclamation

Publications (WR)

The survey results indicate that the impoundment of water behind Hoover Dam has not adversely affected the dissolved oxygen (DO) content and that water quality and DO content were uniform regardless of depth. The study made in April-May 1964 will provide water quality data of Lake Mead prior to releases from Lake Powell as a basis for evaluating Lake Powell's effect on water quality and limnology of Lake Mead. The performance of a DO analyzer was tested and found unsatisfactory at depths below 150 ft. Parameters tested by standard chemical analyses of water samples in the Denver Laboratory and by …

Chelation Of The Transition Metal Ions With A Series Of Polyhodrozyamine Compounds, William Percy Moore

Master's Theses

Chelation was reviewed with emphasis on the work done by contemporary workers.

The following polyhydroxyamine compounds were synthesized, purified and· analyzed:

1,2-bis[tris(hydroxymethyl)methylamino]ethane dihydrochloride

1,3-b1s[tris(hydroxymethyl)methylamino]propane dihydrochloride

1,3-b1s[tris(hydroxymethyl)methylamino]-2-propanone dihydrochloride

1,2,3-tris[tris(hydroxymethyl)methylamino)propane tri­ hydrochloride

The latter two compounds have not been reported in the literature.

Chelates were prepared by reacting the above compounds, and 1-3bis[tris(hydroxymethyl)methylamino]-2-propanol dihydrochloride ("disec") and the "disec" free base, with the ions of the first transition metals. Stability cons­tants were obtained where appreciable coordination occurred before precipitation of the metallic ion took place . A list of the metal ions studied with one or more chelating agents follows: Cu⁺², …

Collector-Depressant Equilibria For The Flotation System Potassium Ethyl Xanthate-Potassium Cyanide-Molybdenite, Connell Bolton Roberts

Theses and Dissertations

This dissertation involves a study of the collector-depressant equilibria of the flotation system potassium ethyl xanthate-potassium cyanide-molybdenite, based upon mineral-air bubble contact measurements made by a modified captive bubble technique. The Cook theory of single site free acid adsorption is used to interpret the data. The standard free energies of adsorption of ethyl xanthic acid and hydrocyanic acid on molybdenite are calculated.

The Pressing Need Of A Practical Non-Technical Course In High School Chemistry, P. M. Glasoe

Journal of the Minnesota Academy of Science

No abstract provided.