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Multi-Cater Pack Heat Sealer, Ivan Medina-Zepeda, Laurent Hirakata, Donovan Furtado, Cody Ngan Dec 2025

Multi-Cater Pack Heat Sealer, Ivan Medina-Zepeda, Laurent Hirakata, Donovan Furtado, Cody Ngan

Mechanical Engineering

The Multi-Cater Pack Heat Sealer was developed to support Achievement House, a non-profit organization that employs adults with intellectual and physical disabilities and is facing increasing demand for sealed cater packs. Existing single-pack sealers limited both throughput and accessibility, which led to the creation of a 3D printed attachment for a 40-inch impulse heat sealer. The attachment allows nine packs to be sealed at the same time and includes a tray-style trapdoor that allows for quick unloading. The need for accessibility and usability guided the design throughout the process. Alignment guides improve placement consistency, and the ergonomic layout accommodates both …


Enhancing Tribological Performance Of Graphite Coatings Through Spray Deposition And Adhesion-Promoting Polydopamine Underlayers, Adedoyin Ayomide Abe Dec 2025

Enhancing Tribological Performance Of Graphite Coatings Through Spray Deposition And Adhesion-Promoting Polydopamine Underlayers, Adedoyin Ayomide Abe

Graduate Theses and Dissertations

Graphite is a widely studied solid lubricant valued for its low friction and layered structure. However, its application as a durable coating remains constrained by poor adhesion to metal substrates and limited wear resistance under sliding. This dissertation presents a systematic approach to overcoming these limitations by integrating deposition process optimization with surface chemistry modification to develop scalable, high-performance graphite coatings. Unlike many prior studies that focus on polished or idealized surfaces, this work targets steel substrates with elevated roughness levels (Sa ≥ 1 μm), aligning with conditions found in practical engineering components. The first phase of research begins by …


Residential Hvac Installation Faults: Field Prevalence, Drivers, And Energy Impacts, Seyed Ali Rooholghodos Dec 2025

Residential Hvac Installation Faults: Field Prevalence, Drivers, And Energy Impacts, Seyed Ali Rooholghodos

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

Faults in residential comfort systems can have detrimental effects on the performance of the system, reducing the energy efficiency, affecting indoor comfort, and shortening equipment lifespan. Many of the faults occur at installation. However, there has not previously been a systematic and nationally representative study to indicate the prevalence of the faults, meaning the distribution of faults by fault type and fault intensity. Understanding true fault prevalence is essential to be able to identify derivers, and to assess the incremental electricity consumption of the new installation systems.

This study presents on-site data from 341 new central cooling systems—air conditioners and …


Experimental Characterization Of An Additively Manufactured Porous Gyroid Air-Cooled Heat Sink, Grant S. Resler Dec 2025

Experimental Characterization Of An Additively Manufactured Porous Gyroid Air-Cooled Heat Sink, Grant S. Resler

Mechanical Engineering Undergraduate Honors Theses

This paper presents the development of a ducted test facility designed to evaluate heat sinks efficiency at varying air velocities. This enables the evaluation of both heat transfer and pressure drop performance. These metrics are essential to the overall efficiency of heat sinks and help identify the optimal air velocity to achieve the desired thermal performance. A standard plate fin heat sink was used as a control for comparison to a novel heat sink. The specialized heat sink geometry was generated using nTop, a generative design software focused on additive manufacturing. This design was fabricated via Direct Metal Laser Sintering …


Exploratory Diver Geotechnical Equipment (Edge), Angel Villicana, Merrick Zellers, Erik Heuchert, Lucas Heuchert Dec 2025

Exploratory Diver Geotechnical Equipment (Edge), Angel Villicana, Merrick Zellers, Erik Heuchert, Lucas Heuchert

Mechanical Engineering

The goal of this report is to showcase how our final Core Sampler design and prototype address the needs of Navy Divers. Geotechnical equipment for Navy divers has not been updated since the early to mid-1980s, resulting in imprecise and outdated sampling methods. The primary purpose of this project is to enhance, modernize, and redesign a tool to collect a minimally disturbed core sample of the seabed for geotechnical evaluation. This report presents the full development of our project from concept to verification and final outcomes. It begins with the statement of disclaimer, followed by a four-panel executive summary and …


Mechanical Properties Of Sintered Lunar Regolith Simulant Lhs-1 When Moulded Under Different Temperatures And Time At Constant Pressure, Jasper Stevens Dec 2025

Mechanical Properties Of Sintered Lunar Regolith Simulant Lhs-1 When Moulded Under Different Temperatures And Time At Constant Pressure, Jasper Stevens

The Plymouth Student Scientist

Humans are returning to the Moon for the first time since 1972. And when they arrive, In-Situ resource Utilisation (ISRU), the philosophy of using local materials and resources will be required to help maintain a more permanent presence on the Moon. Lunar regolith is the homogenous layer of inorganic ‘soil’ that covers nearly the entire Lunar surface, making it the most readily available material for ISRU. This report investigates the effect of changing time and temperature applied to samples of lunar regolith simulant LHS-1 formed as freestanding samples under constant pressure, before sintering into a consolidated sample. Compressive testing on …


Application And Suitability Of Using Paraffin Wax In A Thermal Store For Residential Buildings In The Uk, Cameron Edwards Dec 2025

Application And Suitability Of Using Paraffin Wax In A Thermal Store For Residential Buildings In The Uk, Cameron Edwards

The Plymouth Student Scientist

Heating costs and pressure to reduce carbon emissions are rapidly increasing. A possible solution is the implementation of efficient energy storage systems for UK residential buildings. Paraffin wax-based thermal energy storage offers a promising solution due to its low-cost, high-energy density, and long-term stability. However, its low thermal conductivity significantly reduces its practicality. Multiple upgrades, such as implementing highly conductive particles and nanotubes, have been previously studied but lack the inclusion of cost-effectiveness and real-world feasibility. This paper reviews current research and develops a numerical model using the Enthalpy method and a 2D finite difference approach, utilised in Python. It …


Boundary-Layer Mechanisms In Flow Over Triangular Porous-Textured Flat Plates: A Computational Fluid Dynamics Study, Luis Angel Alvarez Dec 2025

Boundary-Layer Mechanisms In Flow Over Triangular Porous-Textured Flat Plates: A Computational Fluid Dynamics Study, Luis Angel Alvarez

Theses and Dissertations

Growing demand for energy-efficient vehicles drives research into flow control strategies that mitigate aerodynamic drag. Active devices such as morphing flaps or plasma actuators offer real-time authority but require external power. Passive concepts, including riblets, tubercles, porous coatings, and miniature vortex generators, reshape the boundary layer without additional energy input. We propose an integrated passive solution called Triangular Porous Texturing (TPT). TPT combines the two mechanisms: a periodic array of triangular prisms that generate controlled streamwise vortices, and an embedded porous matrix that locally adjusts pressure gradients near the wall. Acting synergistically, these features attenuate near-wall turbulence, redistribute momentum, and …


Development And Testing Of A Prototype Erbium-Doped Lithium Tantalate Based Sensor For Infrastructure Crack Detection And Measurement, Alejandro Barrera Dec 2025

Development And Testing Of A Prototype Erbium-Doped Lithium Tantalate Based Sensor For Infrastructure Crack Detection And Measurement, Alejandro Barrera

Theses and Dissertations

Ensuring the safety and longevity of infrastructure is crucial to safeguarding communities and preserving economic stability. In this study, the development of a novel sensor for detecting and characterizing cracks in infrastructure, particularly suited for deployment on Unmanned Aerial Vehicles (UAVs), is presented. The device utilizes a laser (operating at 980 nm) for excitation of erbium-doped lithium tantalate nanoparticles that emit 1550 nm wavelength, which stimulates a photodiode for data collection. The data was utilized to collect, process, and reconstruct topological information. The synthesized lithium tantalate nanoparticle samples vary in erbium doping percentages of 0.5%, 3%, and 10%. Experimental evaluation …


Experimental And Numerical Study On The Influence Of Carbon Fiber Reinforcement On The In-Plane Compressive Properties Of 3d Printed Hexagonal Honeycomb Core Structures, Deon Wallace Dec 2025

Experimental And Numerical Study On The Influence Of Carbon Fiber Reinforcement On The In-Plane Compressive Properties Of 3d Printed Hexagonal Honeycomb Core Structures, Deon Wallace

All Theses

There is difficulty with numerically replicating the behavior of composite honeycomb core structures numerically due to the trouble of gathering material properties from a hollow structure. Also, complex part geometries and carbon fiber reinforcement strategies can lead to unwanted structural weaknesses and variance in material properties that may not be reflected in numerical analysis when the part is additively manufactured. In this study, edgewise compressive testing is used to characterize the mechanical behavior and performance characteristics of these structures. The experimental results indicate an increase in the Young’s moduli of the honeycomb core structures as carbon fiber concentration increases. However, …


Capillary Imbibition Of Shear-Thinning Xanthan Gum Solutions, Aimee Sayster Dec 2025

Capillary Imbibition Of Shear-Thinning Xanthan Gum Solutions, Aimee Sayster

All Theses

Capillary rise in confined geometries plays a critical role in numerous natural and industrial processes. While classical models such as the Lucas–Washburn equation accurately describe the dynamics of Newtonian fluids, they fail to capture the complex behavior of shear-thinning, non- Newtonian fluids whose viscosity varies with shear rate. This research investigates the capillary rise dynamics of shear-thinning xanthan gum polymer solutions in capillary tubes. The rheological behavior of each fluid is characterized using the Ellis model, which accounts for shear-thinning effects through three key parameters: zero-shear viscosity μ0, characteristic shear stress τ1/2 and viscosity index α. Experimental data was collected …


Study On The Knock Resistance Offered By Thermally Stratifying Water Injections In A Single Cylinder Spark Ignition Engine, Aditya Datar Dec 2025

Study On The Knock Resistance Offered By Thermally Stratifying Water Injections In A Single Cylinder Spark Ignition Engine, Aditya Datar

All Theses

Stochastic end-gas autoignition in SI engines, commonly called ‘knock’, limits attainable engine efficiencies. Multiple pathways to extend SI engine operation into knock-limited regions have been studied, including direct water injection (DWI). This study employs single-cylinder engine experiments and modeling to investigate the knock resistance offered by compression stroke water injections, which have shown to thermally stratify the cylinder in HCCI. In SI, thermally stratifying injections are expected to forcibly widen the cylinder temperature distribution by preferentially cooling the cylinder periphery. The end-gas is in the cylinder periphery; therefore, a cooler end-gas would result in longer ignition delays, thus providing knock …


Tradespace Exploration For Multiple Collaborative Vehicles, Mrunal Deshmukh Dec 2025

Tradespace Exploration For Multiple Collaborative Vehicles, Mrunal Deshmukh

All Theses

Modern military operations demand systems that adapt to uncertain, rapidly changing missions across diverse terrains. Traditional single-platform vehicle design is insufficient for such complexity. This research introduces a hierarchical tradespace exploration framework for designing and evaluating families of heterogeneous ground vehicles under a System-of-Systems (SoS) architecture. The framework treats vehicle design as a co-optimization problem, where a “parent” vehicle (e.g., a Squad Multipurpose Equipment Transport) coordinates specialized “child” vehicles for reconnaissance, amphibious tasks, terrain traversal, and stealth missions. Unlike conventional approaches that optimize vehicles individually, this study emphasizes collaborative performance, resource sharing, and adaptability at the family level. Central to …


Optimal Control Of Human Exercise Using An Individualized Physiological Three-Tank Model And Dynamic Programming, Asal Lotfi Dec 2025

Optimal Control Of Human Exercise Using An Individualized Physiological Three-Tank Model And Dynamic Programming, Asal Lotfi

All Theses

This thesis develops a physiologically inspired three-tank model of human bioenergetics to describe and optimize fatigue and recovery during exercise. The aerobic, phosphagen, and glycogen systems are modeled as coupled reservoirs whose states constrain instantaneous power output. Building on this representation, dynamic programming is used to compute pacing strategies that respect physiological limits while maximizing task-specific goals such as peak power or total work over a fixed duration, enabling individualized, goal-driven exercise prescriptions. The three-tank dynamics are formulated in continuous time and then discretized under a zero-order-hold assumption for simulation and optimal control. Model parameters are linked to standard field …


Understanding Policy Transfer Under Decomposition And Coordination: Sequential Reinforcement Learning With Relaxation-Based Feasibility Control, Aannand Lal Dec 2025

Understanding Policy Transfer Under Decomposition And Coordination: Sequential Reinforcement Learning With Relaxation-Based Feasibility Control, Aannand Lal

All Theses

This thesis investigates how decomposition and coordination (D&C) choices influence exploration, learning, and transfer in reinforcement learning (RL) based design frameworks. A unified methodology is developed to evaluate generality under decomposition and to demonstrate sequential coordination on a representative physical task. The generality study holds the underlying physics constant while varying problem presentation - specifically scalarization weights, objective orientations, and feasibility handling. A train-evaluate matrix is constructed in which each trained policy is assessed across all alternative decompositions. Set-based diagnostics quantify generality through exact-match identity, Jaccard similarity of distinct feasible states, total feasible coverage, and Pareto-front quality. Results show that …


Dynamic Modeling And Simulation Of A Power Generation Steam Rankine Cycle For A Fluoride Salt-Cooled High-Temperature Reactor Nuclear Power Plant, William R. Ton Dec 2025

Dynamic Modeling And Simulation Of A Power Generation Steam Rankine Cycle For A Fluoride Salt-Cooled High-Temperature Reactor Nuclear Power Plant, William R. Ton

Master's Theses

Nuclear Fluoride Salt-Cooled High-Temperature Reactors (FHRs) have the potential to greatly improve nuclear technology in terms of safety and cost. By combining molten salt coolant technology from the Molten Salt Reactor (MSR) and TRISO fuel technology from the Very High Temperature Gas Reactor (VHTR), FHRs may operate at significantly lower pressures than Light Water Reactors (LWRs) and with a more robust fuel source that is excellent at containing fission products. However, as no FHR has been built, there are still many design questions to address. This thesis uses transient computer modeling and simulation to investigate how an FHR could potentially …


Real Time Markerless 3d Hand Tracking For Intuitive Robotic Arm Control, Dylan G. Featherson Dec 2025

Real Time Markerless 3d Hand Tracking For Intuitive Robotic Arm Control, Dylan G. Featherson

Master's Theses

This thesis presents a real-time, markerless motion-capture system for intuitive control of a multi-degree-of-freedom robotic arm. Using two synchronized RGB cameras and stereo-vision triangulation, the system reconstructs the three-dimensional position of a user’s hand without the need for physical markers or wearable sensors. The reconstructed 3D coordinates are mapped directly to the end-effector position of the Quanser QArm, a four-degree-of-freedom educational manipulator. Developed entirely in Python, the system integrates stereo camera calibration, 3D hand tracking with MediaPipe, coordinate transformation, and inverse kinematics into a unified real-time control pipeline operating at approximately 200 Hz. Calibration is performed through a checkerboard-based stereo …


Origami-Inspired Pneumatic Soft Robotic Gripper, Conor J. Schott Dec 2025

Origami-Inspired Pneumatic Soft Robotic Gripper, Conor J. Schott

Master's Theses

This thesis presents the design and evaluation of a vacuum-actuated, origami-based soft robotic gripper. A custom Sea Urchin crease pattern forms a lightweight folding skeleton that collapses radially under vacuum. The system emphasizes low cost and accessibility through laser cutting, 3D printing, and silicone molding. The Sea Urchin geometry was selected after digital and physical screening of candidate crease patterns for smooth folding, low strain concentration, and uniform inward motion. The folding skeleton is laser cut from 4 mil drafting film and folded into a compliant core. Four membrane configurations were developed: an origami gripper with a 36-inch balloon (Design …


Porous Triboelectric Nanogenerator For Load Sensing Of Total Knee Replacement, Elham Mahmoudi, Adam Garry Redgrift, Emre Salman, Milutin Stanacevic, Ryan Willing, Shahrzad Towfighian Dec 2025

Porous Triboelectric Nanogenerator For Load Sensing Of Total Knee Replacement, Elham Mahmoudi, Adam Garry Redgrift, Emre Salman, Milutin Stanacevic, Ryan Willing, Shahrzad Towfighian

Mechanical Engineering Faculty Scholarship

This study addresses the critical need for self-powered, durable pressure sensors in Total Knee Replacement (TKR) implants to enable the collection of post-operative information. The scope of this research encompasses the design, development, and testing of a triboelectric nanogenerator (TENG) integrated into an instrumented knee implant for energy harvesting and pressure sensing. The authors’ unique approach involves utilizing a porous silicone rubber as a dielectric material. This allows the TENG to withstand forces up to 2000 N and generate a maximum power output of 18 μW. Theoretical modeling combined with experimental validation provides deeper insight into the fundamental operating principles. …


Robust Data-Driven Predictive Control Of Nonlinear Systems Under Modeling Uncertainty, Pegah Ghafghanbari Dec 2025

Robust Data-Driven Predictive Control Of Nonlinear Systems Under Modeling Uncertainty, Pegah Ghafghanbari

All Dissertations

Data-driven predictive control enables designing controllers directly from data, making it attractive for complex systems with hard-to-model dynamics. However, practical deployment is challenged by modeling inaccuracies and changing operating conditions. This dissertation develops predictive control frameworks that incorporate robustness and adaptability to address these issues in uncertain nonlinear systems.

The first part employs the Linear Parameter-Varying (LPV) framework, which represents nonlinear dynamics through simple linear form representation. To characterize the plant-model-mismatch often caused by limited data and numerical calculations, Bayesian Neural Networks (BNNs) are used, and their uncertainty estimates are integrated into two robust control approaches. The first is a …


When Textures Trim Drag: Micro-Structures For Adaptive Drag Reduction And Flow Authority, Miguel Angel Olvera Dec 2025

When Textures Trim Drag: Micro-Structures For Adaptive Drag Reduction And Flow Authority, Miguel Angel Olvera

Theses and Dissertations

Turbulent boundary layers are a major source of drag and performance loss. This thesis investigates Triangular Porous Texturing (TPT), apex-forward microstructures with optional bleed channels, as a passive concept for simultaneously reducing skin friction and strengthening boundary layer momentum near separation. Low-speed wind tunnel tests are conducted over tripped turbulent boundary layers on flat plates with three surfaces: a smooth baseline, a solid-crest TPT array isolating the knife-edge “slip-cut” effect, and a porous-bleed TPT array whose paired micro-channels vent a small fraction of the free stream. Time-resolved PIV provides wall-normal velocity fields; skin friction is inferred from near-wall shear, and …


Coupling Material Formulation Strategies To Tailor Piezoelectric Properties Of Ceramic Lattices, Amanda Lauren Borgaro Dec 2025

Coupling Material Formulation Strategies To Tailor Piezoelectric Properties Of Ceramic Lattices, Amanda Lauren Borgaro

Open Access Theses & Dissertations

This thesis examines the material formulation and infiltration processes required to create interpenetrating ceramic composites with a particular focus on developing piezoelectric ceramic-epoxy lattice structures (PCELS). Following this, a high–solid loading barium titanite photopolymer resin (BT40) was developed to produce BTO scaffolds with controlled porosity suitable for metal infusion. The resin’s shear-thinning behavior and scattering-dominated curing response enabled the formation of stable, uniform ceramic structures whose pore networks directly influence infiltration behavior. Building on this foundation, a low-temperature Field’s Metal (FM) infiltration method was established using controlled thermal equilibration and the melting of pre-formed alloy rods. By maintaining the ceramic …


Design And Validation Of Model Predictive Controllers For Lateral Vehicle Control, Keren Flores Dec 2025

Design And Validation Of Model Predictive Controllers For Lateral Vehicle Control, Keren Flores

Open Access Theses & Dissertations

This thesis develops, implements, and evaluates a Model Predictive Control (MPC) framework for lateral vehicle guidance using a linearized bicycle model. The complete control architecture is formulated from first principles, beginning with the derivation of the continuous-time planar dynamics and their conversion into a discrete-time state-space representation suitable for real-time control. The MPC problem is constructed explicitly through the development of prediction models, output selection matrices, and quadratic cost formulations. The controller is evaluated through a Python simulation environment that includes reference trajectory generation, nonlinear vehicle propagation, and constraint handling. Robustness is examined using systematic perturbations to vehicle mass, tire …


Comparison Of Ti-6al-4v Powder And Bulk Specimen Properties Across Manufacturers In Laser Powder-Blown Ded, Alejandro Javier Hernandez Dec 2025

Comparison Of Ti-6al-4v Powder And Bulk Specimen Properties Across Manufacturers In Laser Powder-Blown Ded, Alejandro Javier Hernandez

Open Access Theses & Dissertations

The investigation and comparison of 4 different Ti64 powder feedstocks from 3 different manufacturers was done to determine if the quality of the powder had a profound effect on the properties of the bulk specimens despite using the same processing parameters. The characteristics of the powder observed are the atomization process used, particle size distribution, flowability, and its density. The Ti64 printing parameters for directed energy deposition that were kept consistent were the feed rate, scanning speed, and laser power. Coupons with varying build angles (0-30°) were printed to measure the impact of overhangs on bulk specimen properties (ultimate tensile …


Efficient Adaptive Spline-Based Path Planning For In-Space Servicing, Assembly, And Manufacturing Applications, Christian Lozoya Dec 2025

Efficient Adaptive Spline-Based Path Planning For In-Space Servicing, Assembly, And Manufacturing Applications, Christian Lozoya

Open Access Theses & Dissertations

Autonomous robotic systems operating in cluttered and partially observed environments require trajectory generation methods that produce smooth and dynamically feasible motion while reacting to locally sensed obstacles. This requirement is especially pronounced for free-flyer and in-space servicing, assembly, and manufacturing (ISAM) platforms, where onboard sensing is sparse, global environmental information is unavailable, and communication or computational resources are constrained. In such settings, motion plans must be updated online using incomplete and rapidly changing local observations, while avoiding excessive replanning that can lead to oscillatory or unstable behavior. Many existing approaches either rely on dense optimization over extended horizons, which is …


Powder Degradation Analysis In Reused Pure Tungsten For Electron Beam Melting (Ebm), Hernan Valenzuela Dec 2025

Powder Degradation Analysis In Reused Pure Tungsten For Electron Beam Melting (Ebm), Hernan Valenzuela

Open Access Theses & Dissertations

Additive manufacturing (AM) enables unparalleled design freedom and geometric complexity, driving its adoption in aerospace and medical fields. A major advantage of metal powder AM technologies, such as Electron Beam Melting (EBM), is its ability to reuse unused metal powder, reducing material waste and costs. However, reusing powder repeatedly alters its properties, affecting the final product. Despite its significance, research on powder degradation remains limited, primarily focusing on alloys like Ti-6Al-4V. This thesis investigates the degradation of pure tungsten powder reused over multiple Electron Beam Melting (EBM) cycles. A literature review revealed general powder-reuse mechanisms across additive manufacturing (AM) technologies …


Advancing Aerospace Materials: 3d Printing Of Fiber Reinforced Cyanate Ester Ipns And Uhtcmcs, Saqlain Zaman Dec 2025

Advancing Aerospace Materials: 3d Printing Of Fiber Reinforced Cyanate Ester Ipns And Uhtcmcs, Saqlain Zaman

Open Access Theses & Dissertations

Additive manufacturing (AM) is rapidly reshaping the landscape of advanced materials for aerospace, hypersonic, and extreme-environment systems. However, AM of high-temperature polymer and ceramic composites, especially those reinforced with continuous or aligned fibers, remains limited by challenges in rheological control, in situ fiber impregnation, curing compatibility, densification, and achieving directional multifunctional properties. This dissertation advances a unified Direct Ink Writing (DIW) framework enabling the processing of architected, high-performance composite materials across polymer and ceramic systems. Three research thrusts collectively establish scalable pathways for fabricating fiber-reinforced cyanate ester interpenetrating polymer networks (IPNs) and ultra-high-temperature ceramic matrix composites (UHTCMCs). First, a dual-curable …


Further Evaluation Of Speed Tables On Roadway Curves: Simulation And Expeditionary Deployments, Nathan Reineke Dec 2025

Further Evaluation Of Speed Tables On Roadway Curves: Simulation And Expeditionary Deployments, Nathan Reineke

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

The road network leading up to a United States military base is known as an Entry Control Facility, or ECF. Entry control facilities are used to shield military installations by monitoring vehicles and refusing access to unauthorized vehicles. Passive control devices, including speed tables, are used to disrupt or delay threat vehicles attempting to navigate ECFs at high speeds. The purpose of this research was to recommend optimized configurations of speed tables in combination with roadway curves which allow safe, efficient traversal for authorized vehicles and disruption or delay for threat vehicles.

First, an analytical model of a Tesla Model …


Scalable Carbon-Based Electrodes For Hole-Transport Layer-Free Perovskite Solar Cells., Sharmin Akter Dec 2025

Scalable Carbon-Based Electrodes For Hole-Transport Layer-Free Perovskite Solar Cells., Sharmin Akter

Electronic Theses and Dissertations

Perovskite solar cells (PSCs) have rapidly reached certified single-junction efficiencies near 26%, but deployment is still limited by operational instability, scale-up challenges, and the cost and complexity of typical device stacks. This dissertation explores a simpler, scalable approach: HTL-free PSCs using low-cost, chemically robust carbon (e.g., carbon black) counter electrodes compatible with low-temperature, solution processing. This work demonstrates how carbon-ink formulation, scalable deposition (blade vs. slot-die), and work-function-tuning additives control film quality, interfacial energetics, and device performance. Carbon inks were developed for both coating methods by systematically varying carbon-to-binder ratio, polymer chemistry, and solvent system. Among the binders screened, ethyl …


Investigation Of Laser Based Flow Diagnostics With Metastable Argon, Sterling S. Gordon Dec 2025

Investigation Of Laser Based Flow Diagnostics With Metastable Argon, Sterling S. Gordon

Physics Theses & Dissertations

The overarching motivation of this work is the development of seedless, non-intrusive, laser-based diagnostics for supersonic airflow in wind tunnels. To advance this goal, this dissertation fo-cuses on three-photon excitation in a research-grade argon beam within a tabletop vacuum system, which offers a controlled environment for testing and refining the approach. The chosen excitation scheme drives argon atoms to the 3d[5/2]₃ state using a pulsed Ti:Sapphire laser system, enabling time-of-flight (ToF) measurements on atoms that subsequently undergo a multi-step decay to the metastable 4s[3/2]₂ state. Although full realization of this excitation scheme was hindered by technical …