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Vapor Pressures & Relative Stabilities Of Certain Double Flourides, Walter L. Gage

Missouri School of Mines and Metallurgy Reports

The vapor pressures and relative stabilities of certain double fluorides such as sodium titanium fluoride and strontium titanium fluoride will be investigated by heating them under vacuum to determine the extent of evaporation or decomposition.

Determination Of Progressive Corrosion Of Clay Flux Blocks, Ved Prakash Maheshwary

Doctoral Dissertations

"The Problem. Corrosion of refractories by molten corrosive liquids like molten slags and glasses is of general occurrence in those parts of the furnaces where they come in contact with the liquids. The life of a furnace generally depends upon the progressive rate of corrosion of the refractories by the slags and glasses. There have been various methods used by the investigators to ascertain the useful life of a refractory product before its use in the furnaces, but the problem is so complex that even after decades of research work by the research engineers and technologists a satisfactory and easy …

Direct Reduction Of Zinc Sulfide Under Vacuum, Merritt E. Langston

Masters Theses

"The present work is a continuation of the previous investigations of Gross and Warrington and Liu in which the effect of various reducing agents on the vacuum reduction of zinc sulfide was studied. The author became interested in this topic while reading the papers by these investigators in which they recommended that further work be performed in an attempt to prevent zinc sulfide from distilling over during reduction, thereby contaminating the zinc condensate. The original plan was to perform a few runs for the purpose of duplicating the results that were reported by Liu, and from this point carry on …

Autographic Determination Of Thermally-Induced Linear Changes In Ceramic Bodies, William Dean Mckee Jr.

Masters Theses

"The determination of changes in length of ceramic compositions as a function of temperature is frequently required in ceramic research and testing. With the use of an observer, excellent means are available for determination of changes in length over moderate ranges of temperature. However, the extended period required for some tests makes desirable the automatic recording of length change as a function of temperature.

There has been in use in the Ceramic Engineering Department a furnace arranged for determination of length changes; this furnace, shown in Figure 1, is so arranged that change in sample length causes linear displacement of …

Dissociation And Relative Stability Of Sodium Fluotitanate, Walter L. Gage

Masters Theses

"Titanium is urgently needed in the armament industry especially as a substitute for 18-8 stainless steel. There would be an almost inexhaustible supply of ores of titanium if high-purity titanium metal could be produced economically in large quantities. The use of titanium would permit much of the scarce nickel and chromium to be made available for other important uses.

It has been found by H. C. Kawecki and E. J. Bielecki that high-purity Na₂TiF₆, K₂TiF₆, and (NH4)₂TiF₆ can be produced from iron-bearing titaniferous raw material, ilmenite ores, or a …

An Investigation Of The Deformation Textures Of Titanium, Dean Nesbit Williams

Doctoral Dissertations

"With the increase in production of titanium in recent years has come a great interest in the mechanical properties and in the possible uses of this metal. Due to the affinity of titanium for oxygen, nitrogen, carbon, and hydrogen, and the market effect of these elements on the mechanical properties, much of the work previously reported is unreliable. As purer commercial grades of titanium and high purity iodide titanium have become available for examination, research has been undertaken to correct and expand the knowledge of the properties of titanium. Although the uses of titanium are limited at the present time, …

A Study Of The Dissolution Of Titanium In Acids With Ammonium Fluoride Added, Charles Burroughs Gill

Doctoral Dissertations

"Titanium can no longer be considered a rare metal, even though the modern era of its production came into being only a few years ago. The first discovery of titanium was in 1791 by an English clergyman, the Reverend William Gregor, and the name titanium became universally adopted when so called by a German mineralogist, Martin Klaproth, who rediscovered titanium three years later. Not until 1887 was the relatively pure, 75 percent, metal prepared by L. F. Nilson and O. Pettersson, whose experiments were repeated in 1910 by M. A. Hunter. Hunter is given credit for producing the first metallic …

Activation Energy For Recrystallization In Rolled Silver, Krishan Kumar Tangri

Masters Theses

"In several metals the process of recrystallization is accompanied by a change in the orientation of the recrystallized material with respect to the cold rolled material. If the change is sufficiently large, the changing position of the crystals can be determined by measuring the change in the intensity of the characteristic Bragg-reflection with a Geiger counter x-ray spectrometer. Recent determinations of the activation energies of copper and a 50/50 iron-nickel alloy have been made by using this x-ray technique. Both of these metals show a decided shift in the orientation as the material is recrystallized.

Silver was examined to find …

X-Ray Studies Of Zirconium Cyanonitride, John T. Ballass

Masters Theses

"The purpose of this research was to study, by means of x-ray and metallographic analysis, a material reported to be zirconium cyanonitride.

The x-ray analysis had a three fold purpose, the determination of the symmetry of the constituents, the number of phases present, and the crystal structure type. Metallography was used to confirm some of the results obtained by x-ray analysis establishing certain definite phase relationships present in the microstructure.

The sample investigated contained three principal elements namely zirconium, nitrogen, and carbon. On the basis of constitution this work is a contribution toward the development of the three component equilibrum …

The Effect Of Impeller Speed And Air-Volume On The Flotation Rate With Respect To Particle Size, William Edward Horst

Masters Theses

"Today the ore being mined is low grade and the mineralization has become very complex. In order to concentrate a complex ore, the requirement of grinding the ore very fine is imposed. The process of flotation was developed to concentrate the finely ground ore particles; however, the finer size fractions of the ore still present a concentrating problem.

The fact has been established that the flotation rate which is the recovery that can be attained during a given time interval varies with particle size. The flotation rate increases with an increase in particle size until the maximum flotation rate is …

Direct Reduction Of Zinc Sulfide Under Vacuum -- Course Work, Merritt E. Langston

Missouri School of Mines and Metallurgy Reports

A study of the reduction of zinc sulfide under vacuum by such reducing agents as iron, calcium oxide and carbon, graphite, and iron and carbon.

An attempt to refine the impure zinc metal condensates obtained from the above reductions under under by the mechanism of a differential displacement of the volatile constituents.

Progress Report: Reduction Of Zinc Sulfide, Merritt E. Langston

Missouri School of Mines and Metallurgy Reports

To date the work which has been completed has been concerned with an attempt to duplicate the results reported by Liu in his thesis. In short, little can be said in comparing the two separate investigations because there does not seem to be any apparent similarity, even though the operating conditions were kept as nearly the same as possible. Figure 1 shows the lack of agreement for the amount of total zinc distilled, expressed as weight percent....

Microfauna Of The Colorado Shale In The Sunburst Dome Area, Montana, Merle W. Emmert

Bachelors Theses and Reports, 1928 - 1970

It has been hoped that a micropaleontological study of the shales of the Upper Cretaceous Colorado Group in northern Montana would reveal certain faunal zones which would serve as markers in an otherwise drab, undifferentiated, 1800 feet of grey, fissile shale. This paper presents the results of a study of the microfauna in certain samples from this shale in the Sunburst Dome area north of Shelby, Montana.

The Elkhorn Mine Of Jefferson County, Montana, David D. Walker

Bachelors Theses and Reports, 1928 - 1970

In 1901, after yielding metals valued in excess of five million dollars, it was considered worked out. Since that time the mine has passed through the hands of several own­ers, none of whom have failed to realize a profit from it. Although at no time since its zenith did it ever regain its once great production, it did provide a livelihood for those who worked it. Now with the American Smelting and Refining Company interested in it, perhaps it will once again become an important producer.

The Occurrences Of Non-Metallic Minerals In Montana, Samuel T. Mitchell

Bachelors Theses and Reports, 1928 - 1970

This thesis is essentially an abstract of the literature concerning occurrences in Montana of minerals with a non-metallic luster. The dis­cussions give a general description of the occurrences of minerals as reported by the various references, but is not complete as less than 40 percent of the non-metallic minerals known to exist in Montana are discussed.

Sulphidizing Of Cerussite, Emil A. Kovacevich

Bachelors Theses and Reports, 1928 - 1970

The oxide minerals, such as cerussite, are not as amen­able to flotation as the sulphide minerals. Sulphidization is the usual means used today to increase the recovery of an oxide flotation; however, sulphidization under the most ad­vantageous conditions does not yield very satisfactory re­coveries.

Faunal Studies Of The Lower Jefferson Limestones, James L. Eymann

Bachelors Theses and Reports, 1928 - 1970

The exact geologic age of the Jefferson limestone in Montana has not been definitely determined, other than it is probably of upper, but possibly in part of middle Devonian age. Although not of immediate or apparent economic importance, the determination of the exact age of the Jefferson limestone may be of much value in connection with the discoveries of large quantities of oil in Devonian strata in the northern Great Plains and, in particular, with the extensive deep drilling in northeastern Montana which is anticipated during the summer of 1951.

A Mineralogical Investigation Of Some Montana Hydrobiotites, John W. Baker

Bachelors Theses and Reports, 1928 - 1970

Vermiculite is one of the most recent important nonmetallic minerals to be exploited for use in the industrial world. For this reason, the fund of knowledge relating to this mineral is rather limited. This paper represents the results of laboratory studies that were undertaken to contribute data to this fund of knowledge.

Differential Thermal Analysis Of Some Carbonate Minerals, Paul L. Vandeveer

Bachelors Theses and Reports, 1928 - 1970

Thermal analysis is a relatively new method of determining the general composition of certain mineral substances. As is demonstrated by much of the literature previously written, clays and carbonates are especially adaptable to this method. The full importance of the method is not as yet realized, but it is rapidly approaching that point.

The Influence Of Copper Upon The Age Hardening Properties Of Steel, Andre Rey

Bachelors Theses and Reports, 1928 - 1970

The virtues of alloy steels have been widely publi­cized in both technical literature and everyday adver­tising. Nearly everyone possessing a slight knowledge of metallurgy knows the beneficial effects of chromium in the manufacture of stainless steels, or the importance of nickel, molybdenum, vanadium, and other common elements used to alloy steels.

The Electrolytic Purification Of An Impure Cadmium Sulfate Solution With A Cell Utilizing A Mercury Cathode And A Lead Anode, W. D. Mcmaster

Bachelors Theses and Reports, 1928 - 1970

Cadmium is produced solely as a by-product and all cadmium of commerce is obtained from zinc ores. It is a rare occurrence when zinc deposits are found which do not contain some cadmium.

Benefication Of A Tungsten Ore, James Alexander Shaffer Jr.

Bachelors Theses and Reports, 1928 - 1970

Tungsten is a metal of high strategic value in the defense effort. It is used chiefly to improve creep strength in steels, although a significant percentage enters into the manufacture of cemented carbide tool bits. Therefore, in this age of mechanized warfare, quality and quantity of defense production depend greatly on tungsten.

The Gallium-Indium Constitutional Diagram, Richard E. Gaffney

Bachelors Theses and Reports, 1928 - 1970

Because of the discrepancy as to whether there is solid solubility in the gallium-indium system, and the fact that no alloys with less than 1% indium were ever investigated; the possibility of solid solubility in either or both ends of the diagram was not overlooked. According to Hume-Rothery, two alloys with the same relative positions on the Periodic Chart should have about the same alloying habits.

Electrowinning With Amalgam Electrode, Ralph V. Anderson Jr.

Bachelors Theses and Reports, 1928 - 1970

Amalgam Metallurgy, a relatively new expression in the technology of metal extraction, was first chosen to describe certain new processes developed at the Duisburg Copper Works in Germany. The idea of using mercury, a costly and poisonous metal, as an intermediate in heavy chemical industry and in polarography are of recent origin; with the exception of a series of patents of little signif­icance and occasional comments in the literature, the work is hardly known.

Chemical Analysis Of Igneous Rocks And Variation Diagrams Of Petrographic Provinces Of Montana, Frederick M. Hilpert

Bachelors Theses and Reports, 1928 - 1970

A total of 179 chemical analyses of igneous rocks are avail­able for the state of Montana, but these analyses do not cover the entire state in a satisfactory manner. There has been an emphasis on the central part of the state, and an almost complete lack of interest in the southern portion of Montana.

Polarographic Analysis Applied To Metallurgical Solutions And Products, Donald W. Johnson

Bachelors Theses and Reports, 1928 - 1970

The polarograph has been applied to a large number of chemical and metallurgical analyses, and is especially applicable to solution control analysis and to the deter­mination of minute quantities of ions in the presence of large amounts of other ions.

Metal Production From Ore Deposits In Different Host Rocks In Montana, Robert F. Gale

Bachelors Theses and Reports, 1928 - 1970

It is known that many different kinds of rocks serve as host to the ore deposits of Montana, but the relative importance of each of these kinds of rock as a host for ore deposits has never been described in any published report.

Determination Of The Activities Of Indium And Mercury And The Vapor Pressures Of Mercury Over These Amalgams From 0.00216 To 0.02494 Mole Fraction Indium At 25 C And From 0.00067 To 0.02410 Mole Fraction Indium At 70 C By Electromotive Force Measurements, Arthur H. Lutts

Bachelors Theses and Reports, 1928 - 1970

This work was performed to determine by experimental means the activities of both indium and mercury and the vapor pressures of mercury over these amalgams at 25 and 70 C.

Vacuum Distillation Of Zinc And Cadmium From Zinc Leach Purification Cake, Stiles R. Slosson

Bachelors Theses and Reports, 1928 - 1970

The term "vacuum distillation" is used to des­cribe the process employed when certain elements are separated either from their mother compounds or from one another by distilling them under reduced atmos­pheric pressure.

Electrowinning Versus Electrorefining Of Blister Copper, Frank J. Vorell

Bachelors Theses and Reports, 1928 - 1970

In the following sections of this report, I will discuss as fully as possible both the theo­retical and practical aspects of the roasting, leaching, and electrowinning steps, as well as the economic considerations of the process. The results of my laboratory work will, of course, be integrated to the process.