Digital Commons Network^™

Use Of Carbonation For Treatment Of Coal Mine Drainage To Increase Limestone Dissolution And Generate Alkalinity, Dietrich Henry Kuhlmann Iv

Graduate Theses, Dissertations, and Problem Reports (ETD)

Abstract

Use of Carbonation for Treatment of Coal Mine Drainage to Increase Limestone Dissolution and Generate Alkalinity

Dietrich Kuhlmann IV

Anoxic limestone drains (ALDs) are a common component used within passive treatment systems for coal mine drainage (CMD). Contact between limestone aggregate and CMD results in limestone dissolution, producing carbonate alkalinity. Though ALDs are one of the least expensive CMD treatment technologies, alkalinity generation is limited by limestone solubility. This necessitates a long retention time (>12 hours) and sometimes results in net acidic effluent which requires additional alkalinity generation steps downstream. One way to increase calcite dissolution and alkalinity …

The Uncertain Future Of Landscapes Subjected To Mountaintop Removal Mining, Samuel James Bower

Graduate Theses, Dissertations, and Problem Reports (ETD)

Increased erosion following human land disturbance is a global issue for ecosystem health and land management. Mountaintop removal (MTR) mining – a type of surface mining predominately found in the Central Appalachian Coalfields region – is one of the most significant examples of human perturbation to a natural landscape. A post-MTR landscape, when compared to its natural state, has significantly different erosive potential due to the rearrangement of topography from mining and reclamation practices. Removal of vegetation and alterations to soil further influence erosion by raising the effective erodibility of substrate subjected to MTR. We quantify the changes in erosion …

Bedrock Channel Geometry: Meter To Micron Scale Controls On Fluvial Incision, Nicholas J. Colaianne

Graduate Theses, Dissertations, and Problem Reports (ETD)

The relative resistance of various rock types to incisional processes vary widely and the properties governing bedrock erodibility are poorly understood. Lithologic properties influencing erodibility are the culmination of a rock’s depositional, diagenetic, and exhumation processes. Difficulty identifying a convenient physical proxy for erodibility suggests examining evidence of these processes holistically may offer insight into the role of each in setting a rock’s resistance to incisional forces. In this study we use measured channel geometries along a short stretch of the Dry Fork, WV hosting three distinct lithologic settings to infer relative erodibility against measured and observed fluvial, lithologic, and …

Continental Saline Environments Interpreted From Bedded Gypsum Of The Triassic Red Peak Formation (Chugwater Group), Northcentral Wyoming, Maya Yamei Bradford

Graduate Theses, Dissertations, and Problem Reports (ETD)

Bedded evaporites and associated red bed siliciclastics record saline lake and groundwater systems from Permo-Triassic Pangea. A major component of these red bed and evaporite systems is bedded gypsum. However, little attention has been paid to the textures of ancient gypsum. Observations of gypsum textures can refine interpretations of depositional environment and diagenetic history. This project describes textures of bedded gypsum from an outcrop of the Triassic Red Peak Formation (Chugwater Group) near Greybull, Wyoming.

This thesis uses fieldwork, petrography, and x-ray diffraction to describe an outcrop of the upper Red Peak Formation, with a focus on textures of bedded …

Natural Fracture Evolution: Investigations Into The Middle Devonian Marcellus Shale, Appalachian Basin, Usa, Natalie Abigail Mitchell

Graduate Theses, Dissertations, and Problem Reports (ETD)

Optimizing recovery from unconventional shale reservoirs has generated considerable research into optimal recovery methods through hydraulic fracturing design and shale reservoir characterization in the development of long-term hydrocarbon producers. Permeability at multiple scales from nanometer-scale pore sizes and nano-darcy permeability to completion-induced fractures defining a 100’s of meter stimulated reservoir volume plays a significant role in hydrocarbon flow during production in shale reservoirs. Preexisting cemented fractures in unconventional shale reservoirs are abundant and preferentially reactivate during induced hydraulic fracturing treatment to create necessary large-scale permeability. While previous investigations have significantly improved our knowledge of shale reservoirs, it has also highlighted …

A Study Of Accidental Daughter Crystals In Fluid Inclusions In Bedded Halite From The Permian Opeche Shale And Cedar Hills Sandstone Of The Midcontinental United States, Ryan James Prchlik

Graduate Theses, Dissertations, and Problem Reports (ETD)

Ancient acid-saline lakes of the midcontinental United States deposited bedded halite during Permian time. These deposits are not typically preserved at the surface, but drill cores of the Opeche Shale of North Dakota and Cedar Hills Sandstone of Kansas contain preserved beds of halite. Halite from these ancient lakes have primary fluid inclusions that contain Permian lake water. Also included are accidental daughter crystals that were trapped inside the fluid inclusions at time of halite precipitation. Both the fluid and daughter crystals inside bedded halite can tell us about the geochemistry of original lake waters of Pangea.

Petrography and laser …

Textural And Mineral Analysis Of Pegmatites From The Pala And Mesa Grande Districts In San Diego, California, Gabrielle Potter

Williams Honors College, Honors Research Projects

San Diego pegmatites of the Pala and Mesa Grande mining districts are world renowned for their gem-quality minerals and their Li-bearing mineral phases. Pegmatite genesis, especially in San Diego mines, has been a debated topic since the 1900’s (Morgan and London, 2012). Pegmatite genesis is caused by partial melting processes and fractional crystallization that form granitic melts with high concentrations of rare earth elements (REE), such as lithium. Assessing the exact mineralogy and determining the overall textures can provide insight into the crystallization history of pegmatites. In the San Diego pegmatites, lithium-bearing phases, such as lepidolite and pink elbaite (a …

Applied Geochemistry, Geochronology And Biostratigraphy: Case Studies From The 38th Parallel Structures In Missouri And Orange Basin, Offshore Western South Africa, Marissa Kay Spencer

Doctoral Dissertations

"The unique alignment of the Decaturville, Crooked Creek, and Weaubleau geological structures in central Missouri, three of nine known such structures along the 38th parallel in Illinois, Missouri, and Kansas, has puzzled geoscientists for decades. Research using palynology (palynomorphs and particulate organic matter) and radiometric dating of impact spherules were used to constrain age and a relationship between these enigmatic structures and infer their paleoenvironmental conditions. Novel melting damages, unique to impact, were documented in the palynomorphs in all the three structures. Early Ordovician acritarchs with melted processes correlate with ⁴⁰Ar-³⁹Ar stepwise heating age of impact spherules …

Integrating Lidar, Aeromagnetic, And Geological Field Data To Identify Structural-Lithologic Elements Within The Archean Carney Lake Gneiss Complex, Ian M. Gannon

Dissertations, Master's Theses and Master's Reports

The Archean Carney Lake Gneiss Complex (CLGC) is a suite of rocks on the southern margin of the Superior Province and within the Minnesota River Valley subprovince. It is one of many gneissic domes in Michigan, Wisconsin, and Minnesota whose complex geology is poorly understood due to a previous lack of economic interest in gneissic terranes and significant challenges to their investigation. As a consequence, the CLGC and other gneissic domes in the region are represented on geologic maps as undifferentiated masses surrounded by better defined and understood Paleoproterozoic supracrustal rocks and igneous intrusions. Within the last ten years, however, …

Land Systems, Soils And Vegetation Of The Southern Goldfields And Great Western Woodlands Of Western Australia - Volume 1, Peter-Jon A. Waddell, Paul Galloway

Technical Bulletins

This technical bulletin defines and maps the land resources of the southern Goldfields region of Western Australia (WA). The southern Goldfields region, as featured in this bulletin, covers 151,753 km². The western and eastern borders are variable because they align with various cadastral boundaries. The western survey border, which in part follows the WA State Barrier Fence, demarcates cleared agricultural land from the intact, western extent of the Great Western Woodlands. The eastern border abuts the westernmost Nullarbor pastoral lease boundaries, except for the north-easternmost and south-easternmost edges which continue into Crown land. Major towns are Coolgardie, Kalgoorlie …

Land Systems, Soils And Vegetation Of The Southern Goldfields And Great Western Woodlands Of Western Australia - Volume 2, Peter-Jon A. Waddell, Paul Galloway

Technical Bulletins

This technical bulletin defines and maps the land resources of the southern Goldfields region of Western Australia (WA). The southern Goldfields region, as featured in this bulletin, covers 151,753 km². The western and eastern borders are variable because they align with various cadastral boundaries. The western survey border, which in part follows the WA State Barrier Fence, demarcates cleared agricultural land from the intact, western extent of the Great Western Woodlands. The eastern border abuts the westernmost Nullarbor pastoral lease boundaries, except for the north-easternmost and south-easternmost edges which continue into Crown land. Major towns are Coolgardie, Kalgoorlie …

Hydrogeologic Field Trip Of Northeast Nebraska, Sue Olafsen Lackey, Kathleen Cameron, Matt Marxsen

Conservation and Survey Division: Faculty and Staff Publications

No abstract provided.

2023 Nebraska Water Leaders Academy, Mark E. Burbach, Robert Matthew Joeckel

Conservation and Survey Division: Faculty and Staff Publications

Eighteen participants completed the 2023 Water Leaders Academy bringing the total number of graduates to 186 since the inception of the program in 2011. Assessments of participants’ transformational leadership skills, champion of innovation skills, water knowledge, engagement with water issues, civic capacity, entrepreneurial leadership behaviors, boundary spanning skills, and curiosity increased significantly over the course of the year, according to both the participants and their raters. Feedback from the participants was highly positive and constructive. Academy planners are addressing participant concerns. Results of the program assessment indicate that the curriculum is meeting the Academy’s objectives. Therefore, only minor changes are …

Telescopic Megafans On The High Plains, Usa Were Signal Buffers In A Major Source-To-Sink System, Jesse T. Korus Dr., Robert Matthew Joeckel

Conservation and Survey Division: Faculty and Staff Publications

No abstract provided.

3d Hydrostratigraphic And Hydraulic Conductivity Modeling Using Supervised Machine Learning, T. A. Tilahun, Jesse T. Korus Dr.

Conservation and Survey Division: Faculty and Staff Publications

No abstract provided.

Nebraska's Water, Nawaraj Shrestha, Ann Briggs, Aaron R. Young, Robert Matthew Joeckel

Conservation and Survey Division: Faculty and Staff Publications

No abstract provided.

Conservation And Survey Division 2023 Annual Report, R. M. Joeckel, M. M. Waszgis

Conservation and Survey Division: Faculty and Staff Publications

No abstract provided.

Analysis Of Chemical Elements In Basalts Using Mislabeled Data, A Machine Learning Approach, Jenifer Vivar

Dissertations and Theses

Scientists use basalt chemistry to discriminate among different tectonic settings. There are well-known chemical elements used to classify tectonic settings. An exploration of new features is done using Logistic Regression and Random Forest to discover any new elements of interest. The models were used with other tools, such as recursive feature elimination and permutations, to increase reliability. Among the scarcely explored chemical elements are Terbium (Tb), Holmium (Ho), Samarium (Sm), and Erbium (Er). The data used for the exploration contained many outliers. Therefore, an ensemble model was created to explore the location and composition of such outliers. The ensemble was …

A Novel Technique For The Quantitative Determination Of Wettability Of A Severely Heterogeneous Tight Carbonate Reservoir, Saleh Al-Sayegh, Ralph E. Flori, Waleed Al-Bazzaz, Abdulaziz Abbas, Ali Qubian, Hasan Al-Saedi

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The objective of this study is to accurately measure the wettability contact angle of a cretaceous carbonate reservoir in a vertical well set-up known for as an unconventional tight carbonate oil reservoir. Also, to investigate the relative heterogeneity of these samples using digitally captured images; these images accurately capture natural pore-system in this carbonate rock samples and their wettability performance attributed towards building a vertical depth wettability/heterogeneity model. To capture, measure and model natural tight matrix static contact angle wettability in order to understand their new physics that will advance unconventional tight oil reservoir characterization. Entire vertical well depth reservoir …

Practical Imaging Applications Of Wettability Contact Angles On Kuwaiti Tight Carbonate Reservoir With Different Rock Types, Saleh Al-Sayegh, Ralph E. Flori, Waleed Al-Bazzaz, Sohaib Kholosy, Hasan Al-Saedi, Abdulaziz Abbas, Ali Qubian

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

This study focuses on a tight carbonate reservoir which is located in Northern Kuwait and is classified as an unconventional reservoir. A practical imaging technique of wettability contact angle (θ°) presents "big data" as well as relative-permeability (Krw and Kro) measurements. Also, modeling, through rock image technology, the vast well-documented grain/pore boundary morphology available inside fresh rock fragments have achieved good results. Conventional laboratory relative-permeability experiments are expensive and time-consuming. This study introduces a novel method to measure/calculate relative permeability through fast, less expensive, non-destructive, and environmentally friendly techniques of imaging technology. One tight carbonate reservoir is selected, imaged, processed, …

Ongoing Fragmentation Of The Subducting Cocos Slab, Central America, Tu Xue, Diandian Peng, Kelly H. Liu, Jonathan Obrist-Farner, Marek Locmelis, Stephen S. Gao, Lijun Liu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Fundamental to plate tectonics is the subduction of cold and mechanically strong oceanic plates. While the subducted plates are conventionally regarded to be impermeable to mantle flow and separate the mantle wedge and the sub slab region, isolated openings have been proposed. by combining new shear wave splitting measurements with results from geodynamic modeling and recent seismic tomography and geochemical observations, we show that the upper ~200 km of the Cocos slab in northern Central America is intensively fractured. the slab there is strong enough to produce typical arc volcanoes and Benioff Zone earthquakes but allows mantle flow to traverse …

Bibliography, Leslie North

Faculty/Staff Personal Papers

Bibliography of publications by Leslie North.

Sedimentological Characteristics Of Storm Deposits Induced By The Tropical Storm Pa Buk Along The Western Coast Of The Gulf Of Thailand, Chanakan Ketthong

Chulalongkorn University Theses and Dissertations (Chula ETD)

Tropical storm Pabuk (TS-Pabuk) attacked the western coast of the Gulf of Thailand (W-GOT) on January 4th, 2019, generating high storm surge levels, high wave height and leaving washover sediments along the coastal areas. Soon after the storm, an initial survey was set up for 44 localions to described sedimentary characteristics, measured beach topography, hydrodynamic intensities and geomorphological conditions. Then, the 4 main locations including Chao Samran beach (CSR), Ban Thung Noi (BTN), Thung Tako (TTK), and Talumphuk (TLP) were selected to study sedimentary detail, ground penetrating radar (GPR) with 3 frequencies and diatom analysis on their storm deposits. These …

Structural Geology And Deformation History In Klaeng Area, Rayong Province, Kittichai Chansom

Chulalongkorn University Theses and Dissertations (Chula ETD)

The geology of the Klaeng fault zone comprises of Ordovician metagranite, middle-late Paleozoic clastic sedimentary rocks, Triassic quartz-rich granites (west), Mesozoic redbed sandstones, Eocene granite (east), and mylonitic and low-to-medium-grade metamorphic rocks. In this study, four deformation events (D1-D4) are identified based on our new field observation and structural analysis in macroscale, mesoscale, and microscale. D1 (Late Triassic) characterizes tight folds in response to Triassic E-W Indosinian compression. D2 (Mesozoic) features gentle dips and open folds in redbeds due to E-W compression from regional transpression deformation. D3 (middle Eocene) exhibits a sinistral ductile shear in Eocene granite, which is dominated …

Structural Evolution Of The Phu Kradung Formation By Calcite Veins Characterization, South Of Lam Sonthi District, Lopburi Province., Ausa Nonthason

Chulalongkorn University Theses and Dissertations (Chula ETD)

Calcite veins in Mesozoic sedimentary rock localities are found in the southern part of Lam Sonthi district, Lopburi province, in central Thailand, near the Loei-Petchabun fold belt regions. The vein’s host rocks are siliciclastic rocks, primarily mudstone and sandstone. The main aim of this study is to learn more about calcite vein geometry and development, as well as the structural evolution of calcite veins in the Phu Kradung formation in the Lam Sonthi area of Lopburi province. A petrographic and structural analysis of the veins was performed to examine the kinematics and geological structures of the calcite vein in the …

Geophysical Characteristics Of Kuan Kreng Peat Swamp Forest At Thale Noi Area, Theethach Phiranram

Chulalongkorn University Theses and Dissertations (Chula ETD)

Peatlands, as an important carbon sink, store a large amount of atmospheric carbon. However, peatlands are vulnerable to environmental alteration due to anthropogenic and natural processes. While peatlands are degraded, carbon dioxide emissions arise. The Kuan Kreng peat swamp forest is the second largest peatland in Thailand and is in coastal wetland serving for carbon stock in the subsurface. To assess carbon stock in peatland, the thickness and distribution of the peat layer are necessary. This study determines physical and chemical characteristics of the peatlands in the coastal wetland, southern Thailand by conventional core study and geophysical surveys, including ground …

Insights Into Initial Continental Rifting Of Marginal Seas From Seismic Evidence For Slab Relics In The Mid-Mantle Of The Woodlark Rift, Southwestern Pacific, Youqiang Yu, Frederik Tilmann, Stephen S. Gao, Kelly H. Liu, Jiaji Xi

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The initiation and evolution of marginal seas, especially those developing under a convergent setting, is one of the more enigmatic aspects of plate tectonics. Here, we report the presence of slab relics in the mid-mantle of the Woodlark rift in the southwestern Pacific based on a new map of the topography of the mantle discontinuities from a receiver function analysis and evidence from body-wave tomography. the widespread mantle transition-zone thickening rules out active mantle upwelling, and the revealed slab relics in both the upper and middle mantle may hydrate the upper mantle, which can be expected to further weaken the …

Insights To Surfactant Huff-Puff Design In Carbonate Reservoirs Based On Machine Learning Modeling, Ya Yao, Yue Qiu, Yue Cui, Mingzhen Wei, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Surfactants could react with adsorbates on carbonate rock surface to alter wettability from oil-wetness to water-wetness, which is effective to enhance oil recovery. Surfactant huff-puff treatment is mostly applied for this purpose and the resulting surfactant performance is the outcome of complex interfacial processes. Currently, the effect of important parameters on surfactant performance is not completely reported and the contribution of each parameter to surfactant performance is hard to be quantified. Traditional methods to optimize surfactant performance are time-consuming and show strong dependency on extensive experiments. in this paper, we address these problems from machine learning (ML) perspectives. Several ML …

Erratum: New Estimates Of The Magnitude Of The Sea-Level Jump During The 8.2 Ka Event, (Geology (2022), 50(1), (86–90), (10.1130/G49296.1)), Jonathan Obrist-Farner, Mark Brenner, Jeffery R. Stone, Marta Wojewódka-Przybył, Thorsten Bauersachs, Andreas Eckert, Marek Locmelis, Jason H. Curtis, Susan R.H. Zimmerman, Alex Correa-Metrio, Lorenz Schwark, Edward Duarte, Antje Schwalb, Etienne Niewerth, Paula Gabriela Echeverría-Galindo, Liseth Pérez

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

No abstract provided.

Investigating Pore Body, Pore Throat, Nano-Pore Wettability Preference In Several Unconventional Kuwaiti Carbonate Reservoirs, Saleh Al-Sayegh, Ralph E. Flori, Hussain Alajaj, Waleed Hussien Al-Bazzaz

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

This study will investigate measuring the wettability contact angles of native unconventional tight carbonate as well as other unconventional pore system reservoir samples that hosts varied pore shapes and subsequent wettability contact angle distributions in both reservoir matrix and possible natural fractures. Also, the investigation will include validation of the grain/ pore-wall wettability regions and classify the natural wettability preference available inside pores of the rock and their overall wettability performance and recovery efficiency contributions. Further investigation will include modeling pore throat contact angle wettability, and to understand their new physics that will advance reservoir characterization and oil recovery improvement.