Digital Commons Network^™

Evaluating Reclaimed Mines And Heavy Metal Soil Contamination, Torin A. Matthews

ATU Scholars Symposium

Arkansas has a rich history of lead and zinc mining. While there are still some active mines, many historical mines have been abandoned and/or reclaimed. Although most reclamation procedures result in the burial and containment of target minerals, accessory minerals and elements can be leached out of waste materials/tailings piles and include heavy metals (i.e., Pb, As, Cd). We aim to evaluate the soil and watershed of a few abandoned/reclaimed mines in Pope County, AR, for the presence of heavy metals/source minerals. Soil and stream sediment geochemistry will be conducted using a portable x-ray fluorescence analyzer. Field work and sampling …

Phighting Phosphorus: The Effects Of Sedimentary Phosphorus On The Macatawa Watershed, Elizabeth Kelley, Rachel Fusik, Jake Lyon

23rd Annual A. Paul and Carol C. Schaap Celebration of Undergraduate Research and Creative Activity (2024)

Lake Macatawa experiences severe eutrophication and algal blooms that negatively impact the native species and recreational usage of the lake. There have been several previously completed studies on phosphorus pollution in the water by the Hope College Day1 Watershed Group. However, these measurements do not include lake sediments, which could also be a significant reservoir of phosphorus. Our research group decided to test the sediment at the same three lake locations tested by the Watershed Group, taking two core samples at each location. These samples were dried, combusted in a muffle oven, weighed, digested from solid to liquid, and then …

Potential Non-Carbonate Buffering In An Interdunal Wetland/Slack Along Lake Michigan, Faith Huff

23rd Annual A. Paul and Carol C. Schaap Celebration of Undergraduate Research and Creative Activity (2024)

Interdunal wetlands/slacks occur in Lake Michigan's coastal dunes where the wind scours the sand to the water table. Since May 2016 we have performed ecohydrological studies on the largest interdunal wetlands/slack, ~1.25 ha in size, lying within a deflated parabolic dune east of Lake Michigan at the Saugatuck Harbor Natural Area, Michigan. The slack’s hydrology is influenced by Lake Michigan-Huron, appearing and increasing in size and water depth with rising lake levels and decreasing in size to drying with low levels. Prior to 2014, the slack was completely dry and dominated by upland dune species due to low lake levels. …

Development Of A Liquid Chromatography Method For The Quantification Of Carbohydrates In Peat Soils, Christopher Klaver, Parker Diaz, Abigail Brewer, Gael Figueroa-Enriquez, Madison Smith

23rd Annual A. Paul and Carol C. Schaap Celebration of Undergraduate Research and Creative Activity (2024)

Peatlands are an important carbon sink. However, climate change threatens to cause the peatlands to release their stored-up carbon. This would result in lots of carbon dioxide and methane to be released into the atmosphere due to the increased peat decomposition. This would end up forming a positive feedback loop, and thus resulting in more and more carbon lost from the peat. The biochemical composition of the peat is an indicator of the degradation state of the peat as well as its ongoing vulnerability to decomposition. In this study, we developed an HPLC method for analyzing the carbohydrate composition of …

No "Butts" About It: The Heavy Metal Impact Of Cigarette Litter, Faith Huff, Connor Monson, Spencer Whittington

23rd Annual A. Paul and Carol C. Schaap Celebration of Undergraduate Research and Creative Activity (2024)

Cigarettes are the most common litter globally. Following smoking, the filter is left with carcinogenic compounds, tar and metals. All of which are highly toxic for wildlife, affecting reproduction, behavior and mortality rate in animals. The heavy metals that are left within the filter also have potential to leach from the cigarettes and enter the groundwater system. As these heavy metals enter the system, it leads to adverse effects on the environment and can cause detrimental health effects in humans, such as cell damage, induced carcinogenic processes and loss of cellular functions. Much research that exists currently only focuses on …

Temperature Sensitivity Of Nitrogen Mineralization In Peat From Bogs Across A Michigan Transect, Madison Smith, Hannah Sturgeon, Abigail Brewer, Gael Figueroa-Enriquez, Christopher Klaver

23rd Annual A. Paul and Carol C. Schaap Celebration of Undergraduate Research and Creative Activity (2024)

In this study, seven peat bogs across a latitudinal transect of Michigan were used to analyze inorganic nitrogen (nitrate and ammonium) release from peat to predict the impact that climate warming has on peatland nitrogen cycle. More nitrogen release is expected in samples kept at warmer temperatures (simulated climate warming) and also from samples from lower latitudes in the transect. 1-m peat core samples were taken at each site. 20 g of acid washed sand was added to upper chambers of microlysimeters (two-chambered filter towers). 50 g of peat was added onto the sand and was left to equilibrate for …

Stream-Borne Floating Mismanaged Waste In Holland, Michigan: Focus On Foam, Sam J. Haakenson, Reina A. Duron

23rd Annual A. Paul and Carol C. Schaap Celebration of Undergraduate Research and Creative Activity (2024)

Streams and storm drain systems link terrestrial roadside litter to rivers and lakes, which eventually supply floating debris to the global ocean. To better understand this linkage, we evaluated the kinds and quantity of floating mismanaged solid waste being transported in five streams within the Lake Macatawa watershed in the environs of Holland, Michigan. We deployed floating litter booms in the four smallest streams. These consisted of a rip-stop nylon sleeve encasing pool noodle floats strung on a wire rope. These were placed diagonally across the stream and anchored to fence posts set into the stream banks. In the largest …

Investigating Geomorphic Controls On The Luminescence Properties Of Quartz Sand In A River System, Jenna Mills

Student Research Symposium

Optically Stimulated Luminescence (OSL) dating of quartz sand grains is used to date young deposits across disciplines in geology and archaeology. OSL dating requires that the quartz mineral is sensitized, or pre-conditioned to produce a luminescence signal following exposure to ionizing radiation. The geological processes that enhance the OSL sensitivity (photons released per given radiation dose and sediment mass) remain uncertain. Our Research Objectives are to investigate the geomorphic controls (bedrock source, fluvial transport, and hillslope processes) on OSL sensitivity using sediment collected along the Pagliara River in NE Sicily.

The Pagliara catchment (13km²) is tectonically active and …

Glacial Resource Analysis – Castner Glacier, Alaska, Logan Erichsen

SACAD: Scholarly Activities

Glaciers cover much of the 49th U.S. state of Alaska. While many of these are deep blues, just as many are “rock” glaciers which means the glacier is covered in sediment. This sediment can be transported many miles through the mountain ranges. With the current climate melting these glaciers they are receding. Sediment and rock samples can now be safely collected from different locations where glaciers have released sediment that was locked in the ice for an untold number of years. Much of the USGS data comes from the 1940’s through 1960’s due to the size and remoteness of Alaska. …

Volcanic Ash In Lincoln County, Kansas, Logan Erichsen

SACAD: Scholarly Activities

This report outlines the analysis of Pearlette volcanic ash in Lincoln County Kansas. Both field and lab methods were used to compile this report. Fort Hays State University alumni Dr. Ron Whitmer allowed use of his property on which the ash is found. Auguring was utilized as the main form of field work which allowed mapping of the subsurface ash layer. The ash was analyzed by UMKC using their scanning electron microscope (SEM). At Fort Hays, the SEM reports were compared to thin sections of the ash using plane and cross polarized light in petrographic microscopes. The ash is comprised …

Revolutionizing Ecosystems: Innovative Planting Machines Combating Desertification, Sunghun Park, Jeanne Sumrall

SACAD: Scholarly Activities

An important environmental issue that has a profound effect on human welfare, socioeconomic stability, and global ecosystems is desertification. A little over 12 million hectares of land perish year due to the damaging impacts of desertification, which is made worse by overgrazing, deforestation, and inadequate water management. This not only results in a significant loss of arable land, capable of producing 20 million tons of grain, but also in substantial economic repercussions, with estimated annual losses reaching USD 42 billion (UNCCD, 2020). The enormity of the problem emphasizes how urgently we need practical, long-term solutions to stop and reverse the …

Qualitative Analysis Of Selected Hydrocarbon Produced In Kansas Using Ftir: An Oil-Oil Correlation Study, Oluwaseun Omoyemi, Henry Agbogun, James Titah

SACAD: Scholarly Activities

Hydrocarbons have been produced in Kansas since the 1860s, however, the properties and characteristics of the produced oil are still poorly understood.

An oil-oil correlation analysis has been conducted on twelve hydrocarbon samples from three subbasins and from five producing intervals within the State of Kansas. Fourier Transform Infrared Radiation (FTIR) was used to characterize the organic functional groups present within the samples and Thin Layer Chromatography (TLC) was used to assess the hydrocarbon fractions in the samples. The FTIR spectrum of all the samples exhibit similar peaks implying similar functionally groups were present in all the samples. The TLC …

Dispersion Of Artificial Tracers In Ventilated Caves, Claudio Pastore, Eric Weber, Frédéric Doumenc, Pierre-Yves Jeannin, Marc Lütscher

International Journal of Speleology

Artificial CO₂ was used as a tracer along ventilated karst conduits to infer airflow and investigate tracer dispersion. In the karst vadose zone, cave ventilation is an efficient mode of transport for heat, gases and aerosols and thus drives the spatial distribution of airborne particles. Modelling this airborne transport requires geometrical and physical parameters of the conduit system, including the cross-sectional areas, the airflow and average air speed, as well as the longitudinal dispersion coefficient which describes the spreading of a solute. Four gauging tests were carried out in one mine (artificial conduit) and two ventilated caves (natural conduits). …

Beach Processes Controlling Erosional Hotspots And Their Influences On Beach Nourishment Performances: A Case Study Along West-Central Florida Barrier Island Beaches, Sophia Gutierrez

USF Tampa Graduate Theses and Dissertations

This study examines the long-term performance of repeated beach nourishment over an approximately 35-year period at two barrier islands, Sand Key and Treasure Island along the west-central Florida coast, USA. Five cycles of beach nourishment on Sand Key and six on Treasure Island were conducted during the study period. Three erosional hotspots were identified along a combined 14-km stretch of the nourished beach. The processes that cause the erosional hotspot were examined through numerical modeling of nearshore wave and current fields.

The most recent three nourishments since 2006 were monitored systematically by this study. Beach profiles were surveyed bimonthly to …

Applied Depositional Geosystems Of The Coos Bay Basin, Oregon: Organic Geochemistry, Maturation, Paleoenvironmental Reconstruction And Biostratigraphy Of The Coaledo Delta During The Middle Eocene Climatic Optimum (Meco), Allison K. Barbato

LSU Doctoral Dissertations

The Coos Bay Basin on the southwestern coast of Oregon is a forearc basin that contains exceptionally preserved Eocene to Miocene, tidal to wave-dominated, shallow deltaic to deep marine sediments of the Coaledo Delta. Coastal depositional environments are known to host source, reservoir, and seal rocks. Climate, topographic relief, and geographical position all play an important role in regional vegetation development and oceanic setting. This study assesses 84 outcrop and 12 core samples from Coos Bay for their organic geochemical characteristics and microfossil assemblage to provide source rock characterization information, organofacies descriptions, environmental reconstructions, and age control.

Results indicate the …

A Petrological Characterization Of The Iutzi Member Of Lucas Formation, Michigan Basin, Moira Burns

Honors Theses

It is thought that most Phanerozoic dolomites form via the replacement of precursor calcium carbonate [CaCO₃] with dolomite [CaMg(CO₃)₂] through a dissolution-precipitation reaction with a Mg-bearing fluid. Although this may be widely accepted, the timing, conditions, settings, and mechanisms associated with the dolomitization process are still strongly debated, resulting in the proposal of various dolomitization models. The association between evaporite minerals and dolomite in the rock record is common and has led many to propose a model genetically associating evaporative fluids and dolomitization. The evaporative model posits as marine fluids evaporate and become more …

Unearthing The Past: A Comprehensive Study Of Natural And Anthropogenic Changes At An Archaeological Site Through Hydrogeologic Connectivity Utilizing Gis, Mehlich Ii Phosphorus Extractant, And Ph, Dana L. F. Herren

Theses

This thesis aims to thoroughly analyze the Mehlich II Phosphorus Extractant and pH levels at the Bains Gap Village Site in Anniston, AL., while examining the impact of various environmental factors and human activities on them. Phosphorus is often used in archaeology as an indicator of human activity. Soil core samples were collected to analyze anomalies in phosphorus levels.

To establish any relationships, phosphorus and pH levels from soil cores were correlated with findings from past excavation units and features. The potential effects of hydrogeologic connectivity on soil phosphorus and pH levels were investigated. Geospatial technologies were used to manage …

Subsurface Mapping Of Intra-Arbuckle Shale In North-West Kansas Using Well Log Data, Cole M. Denny

SACAD: Scholarly Activities

The aim of this research was to enhance knowledge of Intra-Arbuckle Shale (IAS) distribution and structure through new maps, cross sections, and well log correlations. Understanding the shale(s) ultimately advances the discernment of complex Arbuckle reservoirs that are critical to the Kansas petroleum industry. IAS has been intercepted by oil wells throughout Kansas, but this study focuses on their presence in portions of Ellis, Rooks, Graham, and Trego counties. To study the distribution and structure of IAS, data from micro-resistivity and gamma ray well logs were collected from more than three hundred Arbuckle oil and gas wells. On each well …

Remote Sensing Techniques To Determine Volcanic Gas Components And Fluxes: Application For Lascar, Chile And Fagradalsfjall, Iceland Volcanos., Felipe S. Rojas Vilches

Earth and Planetary Sciences ETDs

Volcanic plumes allow us to understand different aspects of a volcanic system including magma movements, dynamics, mass transfer, overall gas emissions to the atmosphere, and many processes that impact human life. However, the H₂O gas is poorly constrained due to the intrinsic difficulties of this gas, with high background values and easily dispersed/integrated into the background. In this work we study the gas emissions from Lascar volcano, and Fagradalsfjall volcano, in Chile and Iceland, respectively, using a combination of different ground-based remote sensing techniques and in situ plume measurements, we measure H₂O, SO₂, CO₂, CO, and H₂S from longer and …

Adhesive Force Of Minerals And Substrates, Cynthia Domergue

Posters - 2024

Traditional processing for the separation and concentration of minerals requires a large volume of water to process ores to produce metals and other mineral resources. Furthermore, most copper mines in the US are in the southwest, particularly Arizona and New Mexico, which both have arid climates (Fig. 1). Therefore, sustainable practices need to be developed to maintain the production of metals. Objectives:

• Examine the contact angle of mica and silica at varying surface treatment • Determine the average adhesive forces for each sample

• Compare the average adhesive forces for each sample based on the surface treatment and mineral …

Remote, Rugged Field Scenarios For Archaeology And The Field Sciences: Object Avoidance And 3d Flight Planning With Suas Photogrammetry, Carla Klehm, Malcolm D. Williamson, Leland C. Bement, Brandi Bethke

Center for Advanced Spatial Technologies Publications and Presentations

Advances built into recent sUASs (drones) offer a compelling possibility for field-based data collection in logistically challenging and GPS-denied environments. sUASs-based photogrammetry generates 3D models of features and landscapes, used extensively in archaeology as well as other field sciences. Until recently, navigation has been limited by the expertise of the pilot, as objects, like trees, and vertical or complex environments, such as cliffs, create significant risks to successful documentation. This article assesses sUASs’ capability for autonomous obstacle avoidance and 3D flight planning using data collection scenarios carried out in Black Mesa, Oklahoma. Imagery processed using commercial software confirmed that the …

Evidence Of Seattle Fault Earthquakes From Patterns In Deep-Seated Landslides, Erich Herzig, Alison Duvall, Adam Booth, Ian Stone, Erin Wirth, Sean Lahusen, Joseph Wartman, Alex Grant

Geology Faculty Publications and Presentations

Earthquake‐induced landslides can record information about the seismic shaking that generated them. In this study, we present new mapping, Light Detection and Ranging‐derived roughness dating, and analysis of over 1000 deep‐seated landslides from the Puget Lowlands of Washington, U.S.A., to probe the landscape for past Seattle fault earthquake information. With this new landslide inventory, we observe spatial and temporal evidence of landsliding related to the last major earthquake on the Seattle fault ∼1100 yr before present. We find spatial clusters of landslides that correlate with ground motions from recent 3D kinematic models of Seattle fault earthquakes. We also find temporal …

Tungsten Stable Isotope Composition Of The Upper Continental Crust, Sarah E. Mazza, Richard M. Gaschnig, Roberta L. Rudnick, Thorsten Kleine

Geosciences: Faculty Publications

Tungsten (W) stable isotope data for twenty-four composites made from the fine-grained matrix of glacial diamictites, deposited between the Mesoarchean and the Paleozoic, as well as two Archean tonalite-trondhjemite-granodiorites (TTG) are used to refine the W isotope compositions (expressed as δ186W deviations from the NIST 3163 W standard) of the upper continental crust (UCC). To do this we evaluate W isotope fractionation in the diamictites as the result of both magmatic and low-temperature processes. The δ186W values of the diamictites are heterogeneous (0.017 ± 0.011 ‰, 2SE to 0.182 ± 0.007 ‰, 2SE), encompassing the range of previously published values …

Enhancing Landslide Susceptibility Modelling Through A Novel Non-Landslide Sampling Method And Ensemble Learning Technique, Chao Zhou, Yue Wang, Ying Cao, Ramesh P. Singh, Bayes Ahmed, Mahdi Motagh, Yang Wang, Ling Chen, Guangchao Tan, Shanshan Li

Mathematics, Physics, and Computer Science Faculty Articles and Research

In recent years, several catastrophic landslide events have been observed throughout the globe, threatening to lives and infrastructures. To minimize the impact of landslides, the need of landslide susceptibility map is important. The study aims to extract high-quality non-landslide samples and improve the accuracy of landslide susceptibility modelling (LSM) outcomes by applying a coupled method of ensemble learning and Machine Learning (ML). The Zigui-Badong section of the Three Gorges Reservoir area (TGRA) in China was considered in the present study. Twelve influencing factors were selected as inputs for LSM, and the relationship between each causal factor and landslide spatial development …

A Micrometeor Impact - Lake Wilson, Kansas?, Kenneth R. Neuhauser

SACAD: Scholarly Activities

Much ado about ‘nothing’ was raised when a suspect ‘object’ hit near Lake Wilson, Kansas on August 10, 2006. After a field investigation, a magnetometer survey, thin section analysis, shotgun field tests, and neutron activation analyses (NAA), no 100% conclusive physical evidence exists as to what caused the impact. However, enough NAA chemical evidence was found to suggest a micro-meteor was what created an 18” wide and 12” deep ‘crater’ at the site.

Investigating Gulf Coast Aquifer System: Stratigraphy Reconstruction, Inverse Modeling, And Groundwater Stress Assessment, Shuo Yang

LSU Doctoral Dissertations

The Mississippi Embayment aquifer system (MEAS) and the Coastal Lowlands aquifer system (CLAS) provide substantial groundwater resources for human activities in the U.S. Gulf Coastal Plain. However, the overexploitation has led to groundwater depletion in the MEAS and the CLAS, threatening sustainable groundwater use. Such concern highlights the crucial need for an advanced understanding of stratigraphy and groundwater in these aquifer systems, which is essential for effective regional groundwater management. This dissertation presents a comprehensive investigation of MEAS and CLAS in the Louisiana and southwestern Mississippi region, encompassing three fundamental dimensions: stratigraphy reconstruction, groundwater modeling, and groundwater stress assessments. A …

Investigating The Causes Of Lake Level Variability On A Modern Carbonate Platform, Natalie M. Salazar

USF Tampa Graduate Theses and Dissertations

Lakes on carbonate islands are known to reduce freshwater lens volumes and alter freshwater lens distribution; however, the magnitude and controlling factors between lake and freshwater lens interactions remain poorly understood. Since freshwater lenses are thin and can be fragmented by lakes in small carbonate islands, it is important to understand the magnitude of exchange between lakes and the freshwater lens to understand potential groundwater depletion. This study utilized high temporal resolution water levels and meteorological data to quantify monthly water budgets for seven lakes on San Salvador Island, The Bahamas. The monthly water budgets accounted for rainfall, potential evaporation, …

Comparative Life Cycle Assessment Of Copper Production, Xiaohan Wu

Graduate Industrial Research Symposium

Copper demand will surge significantly in the context of global renewable energy technology implementation, but its production is an energy-intensive process. It is crucial to choose the best production method to reduce environmental damage in terms of the enormous copper supply. This research develops a multi-criteria life cycle assessment model for the three main copper production routes- pyrometallurgy, hydrometallurgy, and bioleaching. We complied material and energy flow data to assess each route's life cycle greenhouse gas (GHG) emissions, cost, and resource efficiency. Results indicate bioleaching emits the least GHG emissions (4.09 kg-CO2 eq/kg copper) among the three routes. Hydrometallurgy is …

Enriched Regions Of 228Ra Along The U.S. Geotraces Pacific Meridional Transect (Gp15), Willard S. Moore, Matt Charette, Paul Henderson, Doug Hammond, Nathaniel Kemnitz, Emilie Leroy, Eun Young Kwon, Mikael Hult

Faculty Publications

The half‐life of 228Ra (5.7 years) aligns well with near‐surface and near‐bottom ocean mixing timescales. Because 228Ra is sourced from sediments, regions of enhanced activity represent water that has recently interacted with sediments on the continental margin or seabed. The GP15 meridional transect from Alaska to Tahiti along152°W encountered several regions in the upper ocean where 228Ra was enriched. These enrichments follow surface and subsurface ocean current patterns and pair with earlier measurements of 228Ra and transient radionuclides to reveal the origins of these enriched regions. An enriched region at Alaska margin stations 1–3 was sourced locally but did not …

Publications And Other Works By R. F. Diffendal, Jr., Robert F. Diffendal Jr.

School of Natural Resources: Faculty Publications

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Updated March 2024