Digital Commons Network^™

Tools For Predicting Emulsification Capacity Of Crude Oil Exposed To Sunlight: Impact Of Photoproduced Carboxylic Acids On Emulsion Stability, Chaka Nacaya Brown

LSU New Orleans Theses and Dissertations

The role of acids in the formation of emulsions from sunlight exposed petroleum is not well understood. To elucidate the impact of sunlight on the formation of emulsions from petroleum, Macondo, its surrogate and NIST 1619b and 2717a were separately exposed to simulated sunlight for up to 48 hours as a film dispersed into a quartz dish, or a film spread on water. Emulsion stability was scored from 0-5. All exposures demonstrated a correlation between emulsion stability and sunlight exposure with no observable emulsification in absence of photoproduction due to sunlight exposure. Aqueous studies of DOC_HC (dissolved organic carbon …

Iowa Waste Reduction Center Newsletter, December 2022, University Of Northern Iowa. Iowa Waste Reduction Center.

Iowa Waste Reduction Center Newsletter

Contents:

--- Best Wishes for the New Year
--- The Impact of the Inflation Reduction Act on the Energy Industry - Webinar Recording
--- Air Permit Applications & Emissions Inventory Reporting - Electronic Reporting Submittal Requirements begin Jan. 1, 2023
--- January 31, 2023 Reporting Deadlines - Grain Facility PM10 PTE
--- January 31, 2023 Reporting Deadlines - 6X Certification and Compliance Report
--- Goodbye Megan and Devon
--- Free Energy Assessments
--- Industry News
--- Connect with Us

Status Of The Western Australian Pastoral Rangelands 2022: Total Vegetative Cover And Cover Risk, Department Of Primary Industries And Regional Development

Natural resources published reports

The Department of Primary Industries and Regional Development monitors and reports on the vegetation condition of pastoral rangelands in Western Australia. This 2022 short report uses remotely sensed total vegetative cover data available to the end of October 2022, rainfall data to November 2022 and Stock Return data reported in 2021 (the most recent available) to determine cover risk. Cover risk at the land conservation district (LCD) level is an indicator of the likelihood of total cover declining to, or remaining at, Low or Very low levels. Total cover and cover risk may not be indicative of vegetation condition and …

Geology, Soils And Climate Of Western Australia's Wine Regions, Peter J. Tille, Angela Stuart-Street, Peter S. Gardiner

Bulletins 4000 -

This bulletin details what is special and unique about the geology, soil and climate of the south-west of Western Australia (WA), an area that encompasses the state’s 9 wine regions.

We have arranged the information into 2 parts:

• In Part 1, we broadly describe the special geological, soil and climate features of the south-west of WA to provide context for the wine regions.

• In Part 2, we describe the geology, soil and climate of the regions and subregions of the Geographical Indications (GI) scheme (administered by Wine Australia) for WA.

Through this work we have found that the wine regions …

Using Landsat Satellite Imagery To Estimate Groundcover In The Grainbelt Of Western Australia, Justin Laycock, Nick Middleton, Karen Holmes

Resource management technical reports

Maintaining vegetative groundcover is an important component of sustainable agricultural systems and plays a critical function for soil and land conservation in Western Australia’s (WA) grainbelt (the south-west cropping region). This report describes how satellite imagery can be used to quantitatively and objectively estimate total vegetative groundcover, both in near real time and historically across large areas. We used the Landsat seasonal fractional groundcover products developed by the Joint Remote Sensing Research Program from the extensive archive of Landsat imagery. These products provide an estimate of the percentage of green vegetation, non-green vegetation and bare soil for each 30 m …

Dynamic Soil Properties In The Lower Rio Grande Valley: Carbon And Nitrogen Responses To Different Tillage Practices, Luzyannet Ballesteros Gonzalez

Theses and Dissertations

There has been increased attention in utilizing agriculture for carbon sequestration. Soil carbon and nitrogen are two dynamic soil properties (DSPs) that are indicators of soil health and function and have overlapping cycles. These soil properties change frequently as a result of environmental conditions and agricultural management practices. This study focuses on the impact of tillage practices in unirrigated agricultural fields in Hidalgo and Willacy counties located in South Texas on Hidalgo Sandy Clay Loam; With a particular focus on Soil Total Carbon (TC), Soil Inorganic Carbon (SIC), Permanganate Oxidizable Carbon (POXC), Carbon and Nitrogen ratio (C:N), Soil Organic Matter …

Conjunctive Management For Groundwater-Surface Water Resources: Numerical Modeling And Potential Assessment Of Managed Aquifer Recharge (Mar) At Lower Rio Grande Valley In South Texas, Dwight Zedric Q. Capus

Theses and Dissertations

Texas is well known to frequent floods and droughts, and yet has mounting concerns in very imbalanced water availability and water demands from growth in population and economical activities. Capturing and storing water is essential to long-term and climate-smart management of the “already-scarce” water resources. This study aimed to apply numerical modeling to evaluate potentials and impacts of Managed Aquifer Recharge (MAR) to regional groundwater systems in the Lower Rio Grande Valley. Using Visual MODFLOW Flex 3D package, different scenarios were simulated for groundwater flow patterns and storage capacities. Water injections tested ranged between 7.30x105 ft3 to 3.65x109 ft3 , …

Influence Of Pretreatments On Physiological Status And Post-Planting Survival Of Thornforest Seedlings In A Restoration Context, Douglas E. Mainhart

Theses and Dissertations

Semi-arid ecosystems across the globe have faced land conversion posing a threat to the important ecosystem services they provide. Revegetation-centered restoration efforts in arid regions have low success due to limited water availability and higher temperatures. Typically, practitioners utilize methods that modify field conditions around seedlings to mitigate these stressors. I evaluated the efficacy of in-nursery treatments to improve plant water status. Three pretreatments were applied: elevated CO2, drought hardening, and an antitranspirant foliar spray. My goal was to understand how these pretreatments would impact survival and growth in the field and what physiological traits they altered. Elevated CO2 and …

Investigating The Relationship Between Dissolved Oxygen And Nitrate Concentration As A Proxy For Marine Ecosystem Health, Natalia M. Moore

Theses and Dissertations

Coastal environments such as seagrass meadows span a wide range of spatial scales and can experience disturbances that cause rapid shifts to ecosystem dynamics. Increased pressure to the coastal zone has highlighted the need for constant, real-time monitoring to monitor current ecosystem status. A custom, low cost, high resolution, in situ sensor network was designed and tested in the Lower Laguna Madre, Texas to characterize primary productivity in seagrass meadows through gradient patterns of dissolved oxygen concentration, with the purpose of determining whether seagrass or phytoplankton were the more dominant primary producer. There was a distinct vertical and horizontal gradient …

Incorporating Native Plants In Insectary Strips To Promote Insect Diversity And Below-Ground Beneficial Microbes In South Texas, Lindsey N. Richards

Theses and Dissertations

Farm edges are generally the most undisturbed areas in a farm with diverse vegetation and can enhance agrobiodiversity and provide crucial food and shelter for wildlife, insects, and soil biota. Planting native wildflowers with the ability to reseed and withstand local climatic conditions for semi-permanent vegetation around farm edges or in between crops has potential to biologically control pests. To test this, we ran a two-year study and installed three different flowering insectary strips on a certified organic vegetable farm in South Texas during the winter season. The treatments were: 1) a commercially sourced 17-species native wildflower seed mix; 2) …

Weather Parameters Influencing The Incidence Of Citrus Canker Caused By Aw Strain In The Rio Grande Valley, Amit Sharma

Theses and Dissertations

Citrus canker caused by bacterium Xanthomonas citri subsp. citri (Xcc) seriously affects the citrus industry by making the fruit unmarketable due to unsightly lesions on the fruit. Canker caused by Aw strain of Xcc was reported in the citrus trees located in the residential areas of the Rio Grande Valley (RGV). Canker severity differs amongst cultivars/varieties, and it is influenced by prevailing environmental conditions. Multiple regression modeling of the disease incidence with the environmental variables such as temperature, humidity, windspeed, wind gust, and rainfall was performed to understand the environmental conditions that are favorable for spread of citrus …

Divergent Serpentoviruses In Free-Ranging Invasive Pythons And Native Colubrids In Southern Florida, United States, Steven B. Tillis, Jillian M. Josimovich, Melissa A. Miller, Laura L. Hoon-Hanks, Arik M. Hartmann, Natalie M. Claunch, Marley E. Iredale, Tracey D. Logan, Amy A. Yackel Adams, Ian A. Bartoszek, John S. Humphrey, Bryan M. Kluever, Mark D. Stenglein, Robert N. Reed, Christina M. Romagosa, James F.X. Wellehan, Robert J. Ossiboff

United States Department of Agriculture Wildlife Services: Staff Publications

Burmese python (Python bivittatus) is an invasive snake that has significantly affected ecosystems in southern Florida, United States. Aside from direct predation and competition, invasive species can also introduce nonnative pathogens that can adversely affect native species. The subfamily Serpentovirinae (order Nidovirales) is composed of positive-sense RNA viruses primarily found in reptiles. Some serpentoviruses, such as shingleback nidovirus, are associated with mortalities in wild populations, while others, including ball python nidovirus and green tree python nidovirus can be a major cause of disease and mortality in captive animals. To determine if serpentoviruses were present in invasive Burmese …

Chromophoric Dissolved Organic Matter And Dissolved Organic Carbon In Lakes Across An Elevational Gradient From The Mountains To The Sea, Kyle Juetten, Angela L. Strecker, Aaron Harrison, Zachary Landram, Warren J. De Bruyn, Catherine D. Clark

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Dissolved organic matter (DOM) in lakes across elevation gradients is a complex function of topography, climate, vegetation coverage, land use, and lake properties. To examine sources and processing of DOM from sea level to mountain lakes (3–1,574 m), we measured dissolved organic carbon (DOC) concentrations and chromophoric dissolved organic matter (CDOM) optical properties, lake characteristics, and water quality parameters in 62 freshwater lakes in the Pacific Northwest, USA. Higher elevation lakes had lower DOC concentrations and absorbance. These lakes had higher forest cover and minimal wetlands in their watershed, in addition to low nutrients, water temperatures, and chlorophyll a in …

South Texas Wildlife Activity Across A Fragmented Landscape And Road Mitigation Corridor, Caitlin K. Brett

Theses and Dissertations

Wildlife crossing structures (WCS) and roadside fencing are commonly installed to mitigate habitat fragmentation, wildlife road mortalities, and other negative effects that roads can have on the surrounding landscape. Eight such WCS were constructed below Farm-to-Market (FM)106 in Cameron County, Texas, across a 16 km corridor transecting the Laguna Atascosa National Wildlife Refuge. These WCS, paired with adjacent roadside fencing, were intended to prevent road mortalities of the endangered ocelot (Leopardus pardalis) and to mitigate the barrier effect of FM106 on this and other meso-mammal species. This study will analyze camera trap data from roadside and habitat reference …

Estimating Sewage Flow Rate In Jefferson County, Kentucky, Using Machine Learning For Wastewater-Based Epidemiology Applications., Dhiraj Kanneganti, Lauren E. Reinersman, Rochelle H. Holm, Ted Smith

Faculty and Staff Scholarship

Direct measurement of the flow rate in sanitary sewer lines is not always feasible and is an important parameter for the normalization of data used in wastewater-based epidemiology applications. Machine learning to estimate past wastewater influent flow rates supporting public health applications has not been studied. The aim of this study was to assess wastewater treatment plant influent flow rates when compared with weather data and to retrospectively estimate flow rates in Louisville, Kentucky (USA), based on other data types using machine learning. A random forest model was trained using a range of variables, such as feces-related indicators, weather data …

Green On The Map - The Influence Of Conservation Easements On The Naturalness Of Landscapes In The United States, Nakisha Fouch

All Dissertations

Large protected areas have long been the cornerstone of conservation biology, however, in an era branded by the human dominance of ecosystems, regional landscape structure and function are often a consequence of accumulated land-use decisions that may or may not include a nod to conservation planning. With underrepresentation of habitats in publicly protected areas, attention has focused on the function of alternative land conservation mechanisms. Private conservation easements (CEs) have proliferated in the United States, yet assessing landscape-level function is confounded by holder and donor intent, national and regional policy, regional landscape contexts, varying extents, resolution, and temporal scale. Over …

Glacier Segmentation From Remote Sensing Imagery Using Deep Learning, Bibek Aryal

Open Access Theses & Dissertations

Large-scale study of glaciers improves our understanding of global glacier change and is imperative for monitoring the ecological environment, preventing disasters, and studying the effects of global climate change. In recent years, remote sensing imagery has been preferred over riskier and resource-intensive field visits for tracking landscape level changes like glaciers. However, periodic manual labeling of glaciers over a large area is not feasible due to the considerable amount of time it requires while automatic segmentation of glaciers has its own set of challenges. Our work aims to study the challenges associated with segmentation of glaciers from remote sensing imagery …

Transportation Asset Management For The Electric Road System, Kamalen Maria Santos Diaz

Open Access Theses & Dissertations

Electric road systems (ERS) have been presented as a new solution towards a sustainable transportation future, fueling the widespread adoption of electric vehicles by eliminating range anxiety, reducing battery size, and being regional friendly. These systems consist of four components: electric power supply, roads, vehicles, and operations. Much of the early research conducted on ERS has been on how to initially construct these systems by focusing on the first three components, however, there is limited knowledge on how ERS will impact traditional road operations after the systems are in place. Transportation Asset Management (TAM), a major focus within the transportation …

The Qualification Of Sealability And Creep Relaxation Of Additively Manufactured Zytel Gaskets For Pem Fuel Cells, Robert Lazarin

Open Access Theses & Dissertations

The purpose of this thesis is to study the feasibility of low-cost additive manufacturing of gaskets for proton exchange membrane fuel cells exposed to extreme temperature conditions ranging from -55°C to 100°C. With the growing popularity and decreasing costs of additive manufacturing technologies, specifically Material Extrusion (ME), research is being conducted to determine the feasibility of ME components. Thermally cycled PEMFCs may exhibit accelerated gasket deterioration, therefore, the mechanical stability of material extruded gaskets following a harsh thermal cycle must be assessed. The feasibility of the material extruded gaskets will be proven by manufacturing optimization and mechanical testing. The target …

A Case Study In Design, Construction, And Operation Of A Meromictic Solar Pond In Texas, Usa, Bianca Paola Meneses Brassea

Open Access Theses & Dissertations

Over the last four decades, meromictic solar ponds have been the subject of limnological studies and engineering research. A case of practical interest is the salinity gradient solar pond (SGSP). SGSP science and technologies have been systemically advanced in El Paso, Texas. This dissertation aims to share lessons learned in designing, constructing, and operating the El Paso Solar Pond, a NaCl-based solar pond that achieved high-temperature performance over two decades, commencing in 1984. Many of the practical lessons learned have not been published and are thus not readily available in archival journals, and this contribution provides a remedy. The value …

Insights On The Behavior Of Nano-Copper In The Agroecosystem: Mycorrhizal Associations With Spearmint (Mentha Spicata), Suzanne Annette Apodaca

Open Access Theses & Dissertations

Nanotechnology offers significant potential benefits to our society, including the agriculture sector. With the advancement of nano-enabled agrochemicals towards sustainable and efficient agricultural practices, it is essential to address environmental issues associated with the use of nanoscale materials. The same properties that give promise to applications of nanotechnology in modern agriculture could have unintended consequences on ecosystem dynamics. A point of concern for risk management is the impact of engineered nanomaterials (ENMs) to beneficial microbial communities, which support a variety of ecosystem services.

Use of copper (Cu) products in agriculture are based on their abundance, role as a micronutrient, and …

Oil Particle Analysis Using Machine Learning And Holography Imaging, Daniel Cruz

Open Access Theses & Dissertations

Holographic cameras show potential as a sensor to monitor oil spills. Holographic cameras record the light interference from particles in a volume of space, producing an image called a hologram. Processing these holograms is known as hologram reconstruction. It produces a representation of particles located in three-dimensional space. These cameras can record precise shapes and sizes of particles in a volume of water. However, it is very time-consuming and resource-intensive to process the images. Most algorithms that perform particle analysis require the hologram reconstruction step. The well-documented hybrid method is one such algorithm. Machine learning is one possible technique that …

Infiltration-Controlled Combustion Of Lithium And Magnesium Powders And Reactions Of Lithium With Oxygen And Carbon Dioxide, Kevin Samuel Estala Rodriguez

Open Access Theses & Dissertations

Chemical heat integrated power systems are of great interest for space missions where solar energy, nuclear energy, and batteries are not available or are not practical to use. A new concept of a power system is a metal combustor coupled with a chemical oxygen generator, where the generated oxygen infiltrates through the metal powder or combustion products. The combustion of lithium and magnesium powders under these conditions has not been studied yet. The present work investigates combustion of magnesium powder and stabilized lithium metal powder (SLMP) ignited by a laser inside a closed chamber filled with O2 or CO2. It …

Sulfonated Styrene Grafted Sebs/Abs Made By Additive Manufacturing For Ion Exchange Applications, Avianna Elaine Gallegos

Open Access Theses & Dissertations

An interpenetrating polymer network (IPN) for cation exchange applications was synthesized from a blend of styrene-ethylene/butylene-styrene (SEBS) and acrylonitrile butadiene styrene (ABS), which was 3D printed, grafted with crosslinked polystyrene (PS), and sulfonated. A method for styrene grafting was applied to reduce the damage to polymer phases caused by the sulfonation reaction. Styrene and divinylbenzene monomers were introduced to the IPN and induced with heat treatment to polymerize in situ. The graft copolymerization reaction was enhanced with varying quantities of benzoyl peroxide as a chemical initiator. The samples were subsequently sulfonated with chlorosulfonic acid in dichloroethane and functionalized for ion …

Black And Brown Carbon Optical Characterization In The El Paso - Ciudad Juarez Airshed, Pamela I. Lara

Open Access Theses & Dissertations

Black (EBC) and Brown (BrC) Carbon are ubiquitous constituents of atmospheric particulate matter that affect peopleâ??s health, disrupt ecosystems, and modulate local and global climate. Tracking the local deposition and sources of these aerosol particles is essential to better understanding their multidimensional environmental impact. The main goal of the current study is to measure the absorption coefficient (Babs) of particles within the Planetary Boundary Layer (PBL) of the El Paso (US)–Ciudad Juárez (Mexico) airshed and assess the contribution of black and brown carbon particles to the total optical absorption. Measurements were taken during winter (January, 2022), spring (May, 2022), and …

Fabrication And Characterization Of Iron-Based Catalysts For The Dehydrogenation Of Fossil Fuels, Victoria Isabel Reyes

Open Access Theses & Dissertations

For a prosperous and sustainable future, hydrogen is an encouraging solution due to its simple transition for industrial decarbonization and synergy for economic development. Paradoxically, current hydrogen production pathways release substantial amount of greenhouse gases into the atmosphere contributing to climate change. To keep up with increasing demand, hydrogen could be produced through microwave-assisted thermocatalytic dehydrogenation of fossil fuels without emitting carbon dioxide. This requires specified catalysts to meet the requirements of hydrogen yield and selectivity. The objective of the present research is to fabricate, characterize, and compare iron-based alumina (FeAl_x O_y) catalysts produced via solution combustion synthesis and iron-based …

Human Appropriation Of Net Primary Production Through Crops, Grazing, And Forestry In The U.S. From 1997 To 2012, Suman Paudel

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This dissertation conducts a county-level analysis of human appropriation of net primary production (HANPP) harvested from crops, timber and grazing in the conterminous United States in the years 1997, 2002, 2007 and 2012. This study consists of three manuscripts (Chapters 2, 3, and 4). The first study quantifies net primary production in US counties in 1997, 2002, 2007 and 2012. The detailed HANPP study conducted concludes that HANPP is a valuable footprint tool for analyzing land use intensity and agricultural ecosystems. The second manuscript shows how HANPP is an improved or modernized ecological footprint and is a sustainable indicator as …

River Response To Sediment Supply: The Sand Bed Case, Christina M. Leonard

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Effective management of in-channel and floodplain habitat requires an ability to forecast river response to changes in water and sediment supply. These changes may result from dam construction/decommissioning, changes in reservoir operations, or changes in grazing or forestry practices. If a change in water and sediment supply causes sediment to be delivered faster than the channel’s capacity to transport it, sediment will accumulate in the reach, leading to changes in channel form and increasing the potential for flooding. A decrease in sediment supply relative to transport capacity can lead to channel incision. The extent and timing of sediment accumulation or …

Old-Growth Forest Dynamics After Fire And Drought In The Sierra Nevada, California, Usa, Kendall M.L. Becker

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Understanding forest ecosystems is important because forests cover approximately one-third of Earth’s land area, store half of Earth’s carbon, shelter half of Earth’s species, and absorb a quarter of new anthropogenic carbon emissions, slowing climate change. This dissertation provides insight into future forest habitat, fuels, species composition, and structure by investigating what happens to snags, seedlings, and trees in an old-growth forest after a low- to moderate-severity fire.

Chapter II explores how low- to moderate-severity fire changes snag fall rates. Predicting how long snags will remain standing after fire is essential for managing habitat, understanding chemical cycling in forests, and …

Normative Evaluations Of Resource Conditions: The Influence Of Visitor Characteristics And Implications For Recreation Management In Urban-Proximate Parks, Jordan E. Nesbitt

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Urban-proximate parks and protected areas provide a unique recreation landscape to individuals living in and near urban centers. They have been shown to provide similar recreation experiences to traditionally studied parks and protected areas such as National Parks, National Forests and Wilderness areas. This study takes place in a set of four urban-proximate parks in Orange County, California, USA. These parks are designated as urban-proximate because they are located within 100 miles of an urban center with 1 million or more people. Using norm theory, a well vetted social science theory, this work sought to identify thresholds of acceptability for …