Digital Commons Network^™

Effects Of Water Chemistry On Interaction Between Organic Contaminants And Microplastics And Their Passage In Microfiltration Membrane, Chutiporn Inchana

Chulalongkorn University Theses and Dissertations (Chula ETD)

The agricultural activity is a critical source of organic contaminants and microplastics (MPs). Typically, the agricultural soil is contaminated by an abundance of MPs, leaching chemicals during weathering process, and pesticides, which subsequently end up in surface water through agricultural runoff. Polymers that are most frequently used in crop production and detected in surface water are PE and PET MPs. Bisphenol (A) and atrazine are frequently detected in surface water. Nevertheless, the fate and distribution of organic pollutants in water treatment as a consequent on MP-aided transport is constrained by little knowledge on photoaged PE and PET MPs. In this …

Large Offshore Wind Farms Have Minimal Direct Impacts On Air Quality, Maryam Golbazi, Cristina L. Archer

Data Science Faculty Publications

Wind power has rapidly grown over the past decade because it is clean, renewable, and abundant. However, wind farms can affect local weather and possibly alter the transport, diffusion, and concentration of air pollutants. Given the unprecedented expansion of offshore wind farms planned along the U.S. East Coast by the Bureau of Ocean Energy Management (BOEM), this study aims to investigate if and how those future offshore wind farms might directly affect air pollution along the densely populated East Coast, in particular, the concentrations of ozone (O₃), fine particulate matter (PM_2.5), sulfur dioxide (SO₂), …

Investigating Factors Contributing To Differences In Air Pollutants Between Metropolitan Areas In The Us, Ellen Hu

Scripps Senior Theses

Densely populated regions around the United States exhibit varying concentrations of air pollutants that can impact the health of urban populations and surrounding ecosystems. Understanding why these differences exist can be important in addressing health issues as the human population continues to increase and communities across the globe move to accommodate these trends. To investigate the impact of natural processes and anthropogenic sources on pollutant concentrations, EPA daily fine particulate matter (PM_2.5), nitrogen dioxide (NO₂), and ozone (O₃) pollutant concentrations from seven metropolitan regions across the US for 2018-2022 were used. A Spearman Rank-Order …

Nitrate Contamination In Two California Groundwater Basins: What Creates Disparities?, Catherine Protiva

Scripps Senior Theses

Nitrate contamination is a major problem within California groundwater basins. A form of nitrogen, nitrates leach into groundwater aquifers from the surface where they remain for many decades. The most common source for the contaminant is agricultural sources like nitrogen fertilizer. Consequently, the problem is concentrated in regions of the state with a history of large-scale agricultural production. When water is pulled from contaminated basins and used as drinking water, the nitrates can cause serious negative health consequences, most commonly methemoglobinemia, also known as blue baby syndrome. In this thesis, I will examine what factors contribute to a region’s ability …

Climate Change's Effect On Flow Regime, Alexander Ialenti

Williams Honors College, Honors Research Projects

This project will test to see if there is a percent increase in non-perennial streams sampled from 2003-2021. Using data provided by The Cleveland Metroparks, sampling events will be separated by date, flow regime classification, and rain data. Current literature supports the claim that many perennial streams, streams that flow year-round, will become non-perennial streams over time. This shift is predicted to be caused by a change in rain patterns. Both the interval between rain events and the intensity of rainfall per event are predicted to increase. My hypothesis is that there will be an increase in the percentage of …

Crossing The “Valley Of Death”: How Climate Technology Entrepreneurs Navigate Relationships With Venture Capital Investors, Allison Lucas

Wayne State University Dissertations

As the world faces the ongoing and intensifying impacts of climate change, a group of innovative changemakers known as climate tech entrepreneurs (CTEs) are working on climate adaptation, mitigation, and/or resilience efforts by brining innovative technologies to the global market (UNFCC, 2018; Endeavor 2022). To realize the full potential of these technologies—tools, techniques, specialized knowledge or skillsets—they must be developed, deployed, and implemented at scale (IPCC, 2000). To do this, CTEs require external funding support, especially during a crucial period of the start-up lifecycle known as the “valley of death”. In this period between development and commercialization, production costs and …

Natural Selection On Feralization Genes Contributed To The Invasive Spread Of Wild Pigs Throughout The United States, Niek W. G. Barmentlo, Patrick G. Meirmans, William H. Stiver, Joseph G. Yarkovich, Blake E. Mccann, Antoinette J. Piaggio, Dominic Wright, Timothy J. Smyser, Mirte Bosse

United States Department of Agriculture Wildlife Services: Staff Publications

Despite a long presence in the contiguous United States (US), the distribution of invasive wild pigs (Sus scrofa × domesticus) has expanded rapidly since the 1980s, suggesting a more recent evolutionary shift towards greater invasiveness. Contemporary populations of wild pigs represent exoferal hybrid descendants of domestic pigs and European wild boar, with such hybridization expected to enrich genetic diversity and increase the adaptive potential of populations. Our objective was to characterize how genetic enrichment through hybridization increases the invasiveness of populations by identifying signals of selection and the ancestral origins of selected loci. Our study focused on invasive …

Influence Of Habitat And Baiting Strategy On Oral Rabies Vaccine Bait Uptake By Raccoons In The Southeastern United States, Jacob E. Hill, Madison L. Miller, Richard B. Chipman, Amy T. Gilbert, James C. Beasley, Guha Dharmarajan, Olin E. Rhodea

United States Department of Agriculture Wildlife Services: Staff Publications

terrestrial wildlife species. However, there is currently a limited understanding of how different baiting strategies influence raccoon (Procyon lotor) uptake of ORV baits in non-agricultural habitats in the Southeastern United States, which may hinder the refinement of ORV management for raccoons in this region. Using a combination of new and existing data, we investigated the role of baited area (0.16 vs 3 km²), bait density (75 versus 150 baits/km²) and season (spring versus fall) on placebo ORV bait uptake by raccoons in four rural, non-agricultural habitats in the southeastern United States (bottomland hardwood forest, …

Prevalence Of Avian Influenza Virus In Atypical Wild Birds Host Groups During An Outbreak Of Highly Pathogenic Strain Ea/Am H5n1, Jourdan M. Ringenberg, Kelsey Weir, Lee Humberg, Carl Voglewede, Mitch Oswald, J. Jeffrey Root, Krista Dilione, Even Casey, Michael Milleson, Timothy Linder, Juliann Lenoch

United States Department of Agriculture Wildlife Services: Staff Publications

The global outbreak of highly pathogenic avian influenza (HPAI) H5N1 Eurasian lineage goose/Guangdong clade 2.3.4.4b virus that was detected in North America in 2021 is the largest in history and has significantly impacted wild bird populations and domestic poultry across the continent. Synanthropic birds may play an important role in transmitting the virus laterally to other wild bird species and domestic poultry. Understanding the dynamics of HPAI in atypical, or nonreservoir, wild bird hosts may help inform management decisions and potential risk factors to both wild and domestic bird populations. Following the confirmation of infections of HPAI H5N1 in domestic …

Evaluation Of Mitigation Translocation As A Management Tool To Reduce Conflicts Between Humans And American Kestrels, Brian E. Washburn

United States Department of Agriculture Wildlife Services: Staff Publications

Raptor‐aircraft collisions (bird strikes) pose a serious safety risk to civil aircraft. Even smaller raptors, such as American kestrels (Falco sparverius), can be problematic within airport environments. Given widespread declines in kestrel populations, public interest, logistical and financial constraints, and other factors, managing kestrels at airports presents some unique challenges. I conducted a study to determine which biological (e.g., age and sex of the bird) and logistical factors (e.g., month and translocation distance) might influence the return of American kestrels live‐captured and translocated from 42 civil airports and military airbases within the contiguous USA during 2016–2021. American kestrels …

Discovery Of A Novel Invasive Rodent Species On Wake Atoll With A Desert Southwest Usa Origin, Antoinette J. Piaggio, Eric Lanners, Daniel R. Taylor, Aaron B. Shiels, Marjorie Matocq, John Eisemann

United States Department of Agriculture Wildlife Services: Staff Publications

Invasive species, particularly omnivorous rodents, have damaged island ecosystems around the world. The unique flora and fauna of island systems have typically not evolved with omnivorous rodents and are heavily impacted by their introduction. Wake Atoll of the southern Pacific Ocean is a 707-hectare coral island complex of three islands managed by the United States Department of Defense (DoD). DoD restricts civilian access to the atoll but aircraft and seacraft regularly visit the island to transport military equipment and to sustain the year-round military and contractor personnel stationed on the atoll. Wake Atoll had been invaded by Rattus rattus complex …

Efficacy Of Gonacon Fertility Control Against Prairie Dogs And Potential For Uses On Other Rodent Species, Aaron B. Shiels, Emily W. Ruell, Jason E. Bruemmer

United States Department of Agriculture Wildlife Services: Staff Publications

Use of a contraceptive (i.e., fertility control) is attractive for rodent management where lethal control is unwanted. Although population reduction is generally unachievable with small-scale, short-term contraceptive use, reduced juvenile recruitment is achievable. The injectable immunocontraceptive vaccine GonaCon (active ingredient: gonadotropin releasing hormone [GnRH]) was registered in 2022 by the United States Environmental Protection Agency (EPA) for controlling fertility of female prairie dogs (Cynomys, a type of ground squirrel) in urban/suburban settings. Here we: 1) describe past research, including a replicated field study in Colorado (GonaCon treatment vs. control sites) testing efficacy of GonaCon in prairie dogs, which …

Agricultural And Ecological Resources Safeguarded By The Prevention Of Wild Pig Population Expansion, Colin Jareb, Kim M. Pepin, Ryan S. Miller, Stephanie A. Shwiff, Sophie C. Mckee

United States Department of Agriculture Wildlife Services: Staff Publications

Wild pigs (Sus scrofa) are one of the most destructive invasive species in the United States, known for causing extensive damage to agricultural commodities, natural resources, and property, and for transmitting diseases to livestock. Following the establishment of the National Feral Swine Damage Management Program (NFSDMP) in 2014, the expansion of wild pig populations has been successfully slowed. This paper combines two modeling approaches across eight separate models to characterize the expansion of wild pig populations in the absence of intervention by the NFSDMP and forecasts the value of a subset of resources safeguarded from the threat of …

Oral Rabies Vaccination Of Raccoons (Procyon Lotor) Across A Development Intensity Gradient In Burlington, Vermont, Usa, 2015–2017, Emily M. Beasley, Kathleen M. Nelson, Dennis Slate, Amy T. Gilbert, Frederick E. Pogmore, Richard B. Chipman, Amy J. Davis

United States Department of Agriculture Wildlife Services: Staff Publications

Management of the raccoon rabies virus variant in North America is conducted primarily using oral rabies vaccination (ORV). When a sufficient proportion of the population is vaccinated (60%), rabies transmission can be eliminated. To date, ORV programs have successfully controlled and eliminated raccoon rabies in rural areas, but there has been less success in urban areas. We studied the proportions of rabies virus neutralizing antibodies (RVNA) in a raccoon (Procyon lotor) population during a 3-year ORV trial in developed areas of Burlington, Vermont, United States. We used a modified N-mixture model to estimate raccoon abundance, RVNA seroprevalence, and …

Distribution And Prevalence Of Antibodies To Trichinella Spp. And Toxoplasma Gondii In Wild Pigs (Sus Scrofa) In The United States, Christopher A. Cleveland, Ellen Haynes, Katherine C. Callaghan, Alinde Fojtik, Sarah Coker, Emily Doub, Vienna R. Brown, Ania A. Majewska, Michael J. Yabsley

United States Department of Agriculture Wildlife Services: Staff Publications

Invasive wild pigs (Sus scrofa) are a reservoir for over 100 viral, bacterial, and parasitic pathogens that are transmissible to humans, livestock, domestic animals, and wildlife in North America. Numerous historical local surveys and results from a nation-wide survey (2006–2010) indicated that wild pigs in the United States act as reservoirs for Trichinella spp. and Toxoplasma gondii, two zoonotic pathogens of importance for human and animal health. Since that time, wild pig populations have expanded and increased in density in many areas. Population expansion of wild pigs creates opportunities for the introduction of pathogens to new areas …

Ethyl-Iophenoxic Acid As A Serum Marker For Oral Baiting Of Tasmanian Devils, Ruth Pye, David Nichols, Sally A. Nofs, Amy T. Gilbert, Andrew S. Flies

United States Department of Agriculture Wildlife Services: Staff Publications

Oral baits containing vaccines, medicants or toxicants have been delivered to a broad range of wildlife species to protect against or treat disease, or suppress populations. Ethyl-Iophenoxic acid (Et-IPA) is used as a biomarker to determine oral bait consumption by wildlife species to assess and refine baiting strategies. Et-IPA is a persistent biomarker in many eutherian mammal species but not in the two marsupial species, swamp wallaby (Wallabia bicolor) and brushtail possum (Trichosurus vulpecula), tested to date. Et-IPA has not previously been evaluated in carnivorous marsupials. The Tasmanian devil (Sarcophilus harrisii), the largest extant …

Estimating Landscape Spread Of A Low-Prevalence Disease Using Multiple Surveillance Methods, Abigail Feuka, Aakash Pandey, Melinda Cosgrove, Megan Moriarty, Anthony Duffiney, Henry Campa Iii, Kurt C. Vercuteren, Kimberly M. Pepin

United States Department of Agriculture Wildlife Services: Staff Publications

1. Diseases occurring at low prevalence in free-ranging wildlife can be difficult to study and predict at a landscape scale. This problem is compounded by imperfect pathogen detection.

2. We used data from multiple surveillance methods to determine factors influencing spread of a low-prevalence disease, bovine tuberculosis (bTB), among white-tailed deer (Odocoileus virginianus) in a bTB endemic area over a 10-year period. We fit dynamic occupancy models to predict spatial spread of bTB through a county in Michigan, USA, within the bTB endemic area, while accounting for imperfect detection and a suite of ecological processes potentially driving bTB …

Effects Of The Immunocontraceptive Gonacon On Pregnancy In Brucella-Seropositive American Bison (Bison Bison), Rebecca K. Frey, Morgan E. Wehtje, Pauline Nol, Patrick R. Clarke, Jack C. Rhyan, Matthew P. Mccollum, Lowell A. Miller, Douglas C. Eckery

United States Department of Agriculture Wildlife Services: Staff Publications

The purpose of this study was to determine if the number of pregnancies in naturally infected Brucella abortus-positive bison (Bison bison) cows would be reduced over a period of 5 yr after one treatment with 3000 mg gonadotropin-releasing hormone immunocontraceptive (GonaCon) compared to a similar group of naturally infected B. abortus-positive bison cows not treated with GonaCon. In each of the 5 yr, GonaCon-treated cows produced fewer offspring in relation to number of cows than the nontreated cows. Fisher’s Exact test comparing offspring produced during the first reproductive season showed a significant difference between the …

Efficacy Of X-Ray Phytosanitary Irradiation On The Infectivity And Reproduction Of Angiostrongylus Cantonensis In Experimentally Infected Rats, Susan I. Jarvi, Lisa M. Kaluna, Steven C. Hess, Lindsey Hamilton, Carmen Antaky, Robert T. Sugihara, Israel L. Leinbach, Yaeko Tagami, Argon Steel, Kathleen Howe, Steven Jacquier, Forrest Cookman, Jocelyn Diaz, John Jacob, Peter Follett

United States Department of Agriculture Wildlife Services: Staff Publications

Angiostrongylus cantonensis is a globally distributed nematode and the leading cause of eosinophilic meningitis in humans. As a global hotspot for this disease, Hawaii’s agricultural exports may be contributing to the spread of A. cantonensis. Phytosanitary irradiation doses of 150 or 400 Gy provide quarantine security against multiple insect pests. We evaluated the in vitro and in vivo effects of phytosanitary irradiation on infectious, third-stage A. cantonensis juveniles. In vitro experiments directly exposed juveniles to irradiation doses ranging from 200 to 1,000 Gy. Results showed low mortality and no dose response across all treatments 27 days post-irradiation. …

Interannual Growth-Climate Relationships Of Western Larch After Wildfire In The Northwest, Junior Burks

Undergraduate Theses, Professional Papers, and Capstone Artifacts

Montane and mixed-conifer forests in the northwestern United States are burning at rates greater than any time in recent decades, due to the combined impacts of global warming and historical and contemporary land use and land management. Western larch (Larix occidentalis) is a tree of high regional significance, exhibiting a variety of traits that make it resistant and resilient to fire. Because seedlings are more sensitive to environmental stressors than adults, the impacts of climate change are expected to be detectable first in juvenile trees. Recent research shows that the natural regeneration of western larch after wildfires has …

Supporting Dataset For The Influence Of Tile-Water On Groundwater Nitrate Concentrations Within A Saturated Riparian Buffer Zone, Aminat Tosin Abdulsalam, Eric Wade Peterson

Faculty Publications - Geography, Geology, and the Environment

In the U.S. Midwest, where fertile soils with high water retention are prevalent, the installation of tile drainage networks have become a common practice to drain excess soil water, which enhances plant growth and increases crop productivity. However, tile drainage networks coupled with the use of inorganic fertilizers have significant implications on water quality, contributing to eutrophication, leading to harmful algal blooms, and resulting in hypoxic conditions in surface water bodies. To mitigate excess nutrient exports to surface water bodies, edge-of-field practices have been introduced. One such practice is the saturated riparian buffer (SRB), which utilizes a diversion system to …

Transport And Fate Of Nitrate In A Saturated Buffer Zone As Assessed With A Chloride Tracer Test, Alhassan Sahad, Eric W. Peterson

Faculty Publications - Geography, Geology, and the Environment

The Upper Mississippi Basin, which includes Illinois, has highly fertile soils and experiences intensive agricultural practices. Although fertile, the soils do not drain well, resulting in the installation of tile-drainage systems. The practices of tile systems coupled with the application of nitrogen-rich fertilizers have led to the excessive export of nitrate from the agricultural fields into surface waters, contributing to eutrophication and the development of hypoxic zones in aquatic environments. Saturated riparian buffer zones (SRBs) have been proposed as a means to reduce the amount of nitrate discharged from tile-drained waters into streams. Previous works show a reduction in the …

Seismic Refraction Mapping Of The Pre-Glacial Teays River Valley In West Central Ohio Using A Seismic Reflection Dataset, Matthew L. Klempp Ii

Browse all Theses and Dissertations

The Teays River Valley is an ancient river valley system that existed before the Pleistocene Ice Age and spanned present-day Illinois, Indiana, Ohio, West Virginia, and Virginia. During the Pleistocene Ice Age, the Teays River Valley was buried by advancing continental glaciers and meltwater throughout most of its length. Due to the Teays’ average width of roughly 2 miles and burial depth of approximately 200 meters (656 feet), the Ohio Geological Survey has been pursuing geophysical methods to map the location and depth of the Teays River Valley in Ohio. The present study is a refraction analysis using the first …

Distribution And Fate Of Selected Non-Point Source Pollutants In The Dayton Streams And Tributaries: Effect Of Land Use In An Urban Watershed, Smriti Bastakoti

Browse all Theses and Dissertations

This study investigates the distribution of water pollutants in the urban and suburban watershed (Beavercreek Sub-watershed (BCS) and Little Beavercreek Sub-watershed (LBS)) of Dayton, Ohio USA focusing on the relationship between water quality and land use types based on 2021 land use maps obtained from MRLC. These watersheds are home for aquatic life and regulate the flow of surface water and recharge groundwater so, it is crucial to maintain good water quality by balancing urbanization and farmland within these two watersheds. We analyzed chloride, nitrate, and sulfate using ion chromatography (IC) and orthophosphate using UV/Vis Spectrophotometry. Additionally, three pesticides (Atrazine, …

Electrochemical-Thermal Model Of A Lithium-Ion Battery, Paul Kalungi

Browse all Theses and Dissertations

Lithium-ion batteries are an integral component of energy storage systems for renewable energy applications owing to their high energy density. Extensive research has therefore been carried out, utilizing both experimental and computational methods, to aid in a deeper understanding of lithium-ion batteries. Challenges related to efficiency, safety and thermal management persist, particularly during high current draw, extreme temperature conditions and extreme dynamic current operation such as in electric vehicles. This thesis work presents an electrochemical-thermal model of a lithium-ion battery that simulates and analyzes the variation of electrical behavior, chemical behavior and thermal behavior. The electrochemical model is developed by …

Development Of Sulfur-Based N-Heterocyclic Carbenes And Their Potential Energy Applications, Kalpana Sampath

Browse all Theses and Dissertations

N-heterocyclic carbenes (NHCs), a characteristic 5-membered ring structure, contain a carbene carbon and at least one nitrogen atom. The presence of nitrogen atoms in the cyclic structure has two effects on its electronic structure: it withdraws σ-electrons and donates π-electrons to the carbene carbon, significantly enhancing the electronic richness and stability of the carbene center. Incorporating heteroatoms like sulfur, oxygen, or phosphorus into the NHC framework has paved the way for advanced developments in their structural properties. The incorporation of additional aromatic ring/heteroatom into NHC offers novel pathways for functionalization, ultimately broadening its scope of potential applications. The primary goal …

Functionalized 1,4-Naphthoquinone-Annulated N-Heterocyclic Carbenes For Biomedical Applications, Dilsha Samanali Wickramasinghe

Browse all Theses and Dissertations

Gold has long been recognized for its medicinal applications, dating back centuries. The use of N-heterocyclic carbenes (NHCs), stable, tunable ligands, has revolutionized the development of metal complexes, particularly those involving gold. Among these, Au-NHC complexes have shown significant promise in treating various diseases, especially arthritis and cancer. More recently, our research has focused on synthesizing dual-targeting naphthoquinone-annulated NHC-based gold(I) complexes, which have demonstrated impressive therapeutic potential in cancer treatment. This emphasizes the growing importance of gold-based complexes in developing more selective and effective cancer therapies. By strategically tuning the electronic and steric properties of these complexes, we have explored …

Hydrologic Pathways Of A Northern Hardwood Catchment In The Great Lakes Basin Using End Member Mixing Analysis, Cory C. Burkwald

Dissertations, Master's Theses and Master's Reports

This study investigated the seasonality of hydrologic pathways, the role of wetlands in streamflow generation, and how hydrologic pathways affect the export of nutrients by streamflow in the Sturgeon River using endmember mixing analysis. The results indicated that streamflow consists of three main components: shallow subsurface water from wetland soils, shallow groundwater, and surface runoff from precipitation. Snowmelt plays a dominating role in regulating stream water chemistry (~80% volume at peak) during the snowmelt season and likely also after that. Wetland soils store snowmelt, together with rainwater though the fraction is unknown, and then gradually release through summer in the …

Empowering Communities Through Education Creating The School Of Green, Kyle Martin

Senior Honors Theses and Projects

The School of Green initiative aims to foster environmental stewardship through community-driven STEM education programs. This paper evaluates the initiative’s impact, critiques its planning, and strategizes for future success. It discusses the evolution of the School of Green Series, its community impact, and future directions. The paper also provides a contextual framework reflective analysis and outlines personal motivations and aspirations. Through meticulous documentation and archival research methods, this project aims to detail the significance of the School of Green Series in promoting environmental education and inclusivity. The comprehensive event report will not only analyze successes and areas for improvement but …

Putting Biomonitors To Work: Native Moss As A Screening Tool For Solid Waste Incineration, Sarah Jovan, Eleonore Jacobson, Jason M. Unrine, Nasser Jalili‑Jahani, Bruce Mccune

Markey Cancer Center Faculty Publications

Solid waste incineration (SWI) can release numerous air pollutants although the geographic reach of emissions is not routinely monitored. While many studies use moss and lichens for biomonitoring trace elements, including around SWIs, few investigate the complex, multi-element footprint expected from SWI emissions. This study develops using native moss as a screening tool for SWI while also informing community concerns about an aging incinerator in rural Oregon, USA. Trained community volunteers helped collect 36 composite samples of epiphytic moss (Orthotrichum s.l.) along a 32-km transect from the SWI. We used ICP-MS to measure 40 elements in moss, including 14 rare …