Digital Commons Network^™

Radicals Transforming Organic Matter: Implications For Non-Pyrogenic Black Carbon And Nitrogen Formation, Molecular Dynamics In Tropical Soils, And Lignin Valorization, João Vitor Dos Santos

Chemistry & Biochemistry Theses & Dissertations

Radicals drive the transformation of organic matter in natural and engineered systems, altering its structure, reactivity, and stability. Condensed aromatic carbon (ConAC) and condensed aromatic nitrogen (ConAN) are among the most persistent forms of organic matter in soils and are traditionally interpreted as products of biomass burning. This dissertation challenges the long-standing assumption that these materials are exclusively pyrogenic, showing that iron-mediated radical chemistry can generate condensed aromatic structures under ambient conditions.

Chapters II and III show that Fenton-like radical oxidation of lignin-rich biomass produces condensed aromatic structures compositionally similar to pyrogenic black carbon and black nitrogen when assessed with …

Draft Final Silver Bow Creek Conservation Area Materials Management Plan Revision 1, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Final Silver Bow Creek Conservation Area (Sbcca) Construction Quality Assurance Plan (Cqap), Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

High-Resolution Monitoring Of Intra-Seasonal Agricultural Drought Using Sentinel-2 And Machine Learning Across Bimodal Growing Seasons In Kenya, S. Mohammad Mirmazloumi, Harison Kipkulei, Rose Waswa, Tobias Landmann, Tom Dienya, Maximilian Schwarz, Fabrizio Ramoino, Clément Albergel, Gohar Ghazaryan

All Peer-Reviewed Publications

Drought presents significant challenges to agriculture, threatening food security and livelihoods, across many regions. In Kenya, recurrent droughts across diverse agro-ecological zones emphasize the urgent need for reliable and scalable drought assessment methods. Although drought assessment with various datasets has been carried out for this region, many of them often use course or moderate resolution data. This study uses high-resolution Sentinel-2 observations and machine learning to monitor intra-seasonal crop conditions and assess drought impacts across bimodal growing seasons. Using pixel-based supervised random forest models trained with multiple vegetation indices as input, we classify croplands into drought-affected and unaffected areas. The …

Draft Final Butte Priority Soils Operable Unit (Bpsou) Insufficiently Reclaimed Sites Sister Dump (Bres No. 38) Remedial Action Work Plan (Rawp), Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Final Quarterly Operations And Maintenance Report Butte Treatment Lagoon System – First Quarter 2025, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Multiscale Effects Of Landscape Structure, Biodiversity, And Chronic Physiological Stress In Atlantic Forest Small Mammals, Lizette Arroyo

Theses and Dissertations from DePaul University

Habitat loss and fragmentation are major drivers of biodiversity decline and can alter the physiological condition of wildlife through changes in habitat quality, resource availability, and community composition. The Atlantic Forest of South America is one of the world’s most threatened biodiversity hotspots. This study examined relationships among biodiversity, landscape structure, and chronic stress in nonvolant small mammals within the Reserva Natural Tapytá in eastern Paraguay using hair glucocorticoid concentrations as indicators of long-term physiological stress. Small mammals were sampled from forest fragments representing multiple patch sizes between 2023 and 2025. Hair cortisol and corticosterone concentrations were quantified using enzyme …

Downstream Effects Of Post Aerobic Digestion And Divalent Cation Treatment: Dewaterability, Phosphorus Mitigation, And Process Odors, Maya Marisol Quijano Garcia

Civil & Environmental Engineering Theses & Dissertations

This study evaluated post-aerobic digestion (PAD) with aeration, mixing, and divalent cation addition to improve phosphorus capture, dewaterability, and odor control in thermal hydrolysis process (THP)–treated anaerobic digestate at the Hampton Roads Sanitation District’s Atlantic Treatment Plant. A three-day PAD process was operated under constant air flow (5 LPM) and dissolved oxygen (DO)-setpoint (0.2 mg/L) aeration conditions with Ca(OH)₂ or Mg(OH)₂ dosing. Aeration and mixing alone increased polymer demand by 14–46 % relative to untreated influent, indicating enhanced extracellular polymeric substance release. Chemical conditioning partially mitigated this increase but did not restore polymer demand to baseline levels. Dewatered cake total …

Quantifying Nutrient Fluxes Across The Sediment-Water Interface In The Lafayette River Estuary, Adriana E. Amrhein

OES Theses and Dissertations

The Lafayette River, a shallow, eutrophic tributary of the Chesapeake Bay, experiences seasonal harmful algal blooms (HABs). While management efforts focus on reducing external nutrient inputs, internal loading from benthic sediments remains poorly constrained. This study quantifies spatial and seasonal variability in nutrient and radium isotope fluxes across the sediment–water interface at three sites where HABs are known to initiate and represent contrasting sediment textures and hydrodynamic conditions. Sediment cores and porewater samples were collected in summer 2023 and winter 2024 to measure grain size, porosity, dissolved nutrients (NH₄⁺, NOₓ⁻, PO₄³⁻), and radionuclide activities (²²⁴Ra and ²²⁸Th). Radium isotope disequilibrium …

Forest Fires Increase Vulnerability To Midwinter Rain-On-Snow Snowmelt In The Western Oregon Cascades, Sage C. Ebel, Kelly Gleason

Environmental Science and Management Faculty Publications and Presentations

Forest fires and rain-on-snow events in the seasonal snow zone of the Pacific Northwest are increasing in frequency and magnitude, yet the combined impacts of these events on snowpack and water resources remain poorly understood. We show that forest fires doubled midwinter snowmelt proportions in 2023 and 2024 compared to unburned reference sites in the western Oregon Cascades. Data from snow monitoring and micrometeorological stations installed across an elevational gradient revealed increased snowpack vulnerability during midwinter rain-on-snow events, where we observed more snowmelt per rain-on-snow event in the burned forest, indicating higher vulnerability of these snowpacks to rapid melt, increasing …

Recovery Of Bioenergy From Industrial Wastewater Using Microbial Fuel Cell, Syed Wamiq Ali, Ghulam Mujtaba, Manzoor Ahmed Sanjrani, Falak Shad

Journal of Bioresource Management

Water problems and Energy demands are increasing particularly in developing countries. Researchers are looking for sustainable technologies that can address increasing energy and environmental concerns. Major reasons behind those emerging concerns are industrialization and rapid development. There is need of sustainable technology which can solve wastewater issues and fulfill energy demand. One of the emerging technologies that have been studied comprehensively is Microbial Fuel Cell (MFC). It is a bio-electrochemical conversion technology that converts organic substrate into electrical energy. Chemical Oxygen Demand (COD) is removed as a result of microbial metabolism of organic substrate. Even through technical and economic aspects …

Changes In Land, Ocean, Atmospheric Parameters Associated With The 2025 Myanmar (Mw 7.7) Earthquake, Feng Jing, Akshansa Chauhan, Ashwani Raju, Ramesh P. Singh

Mathematics, Physics, and Computer Science Faculty Articles and Research

Multiple parameters associated with the land, atmosphere, and ocean were analyzed to study short-term and immediate pre-earthquake changes associated with the 28 March 2025 Myanmar earthquake (Mw 7.7). Anomalous clear-sky outgoing longwave radiation (ClrOLR) and trace gases (CH₄, CO, and O₃) were detected within two months prior to the mainshock. Vertical changes at different pressure levels suggest a possible underground source. High-temporal-resolution observations of the infrared brightness temperature and surface air pressure revealed short-lived fluctuations shortly before the earthquake, which may reflect localized stress adjustments and surface latent heat flux release during the final stage of earthquake preparation. In the …

Sprinkler Package Runoff Risk Tool For Center Pivot Irrigation Systems, Will Bowers

Spring Runoff Conference

Center pivots in Utah 

• 403,524 acres = 67% of sprinkler irrigated fields in the open in Utah 
• Considered one of the most effective sprinkler systems available with technological advancements over the years

Evaluating Alternative Water Conservation Scenarios For Alfalfa In The Great Salt Lake Basin Using Integrated Climate Model Projections, Saddy Pineda-Castellanos, Masoumeh Hashemi

Spring Runoff Conference

Elevation of Great Salt Lake North and South Arms (1903-2026)

An Estimation Of Crop Evapotranspiration Using Soil Water Balance In Vineyards, Tarique Aziz, Burdette Barker, Michael Caron, Michael Pace

Spring Runoff Conference

Breakout Session presentation given at the 2026 Spring Runoff Conference

Immersive Modeling To Generate Holistic Strategies To Get More Water To Great Salt Lake, Hadia Akbar

Spring Runoff Conference

How to get more water to GSL?

Must Address

• Complex water rights
• Competing water needs
• Historical legacies
• Variable and arid hydrology
• Infrastructure limitations and opportunities
• Lack of trust

What Makes Smart Irrigation Work? Lessons From Producers In The Upper Colorado River Basin, Tejinder Singh, Matt Yost, Elisa Flint, Burdette Barker, Jessica Ulrich-Schad, Silas Ekadu

Spring Runoff Conference

Colorado River Basin Water Crisis

• Water allocations in the Colorado River Basin were set during wetter periods and now exceed current river flows, creating a gap between water supply (12.5 maf yr^-1) and demand (15 maf yr^-1).
• River flow has declined 19% since 2000.

Making Water Visible: Neutral, Verification-First Infrastructure For Basin-Scale Water Accountability, Eric Mcculley

Spring Runoff Conference

Every Tool Tells You What the Lake Level WAS.

None Tell You What It WILL BE.

• Current monitoring is retrospective — USGS gauges and DWR reports show only historical data
• Decision lag: By the time you see the problem, it’s too late to adjust
• 2024–2025 season: GSL dropped to record lows before upstream conservation kicked in
• Agricultural users, municipalities, and GSL all compete for limited supply with imperfect information

Leasing Water For Great Salt Lake: Water Savings And Producer Impacts, Conner Harwood

Spring Runoff Conference

Great Salt Lake Water Leasing

• Utah is working to increase inflows to GSL through voluntary water leasing from agriculture
• But key information is missing:
• How much water can leases save at the field level?
• At what price should farmers be compensated?
• This project:

1. Estimates field-level consumptive water use
2. Estimates the value of water in agricultural production
3. Evaluates water savings and producer impacts across leasing strategies

Meteorological Monitoring With Real-Time Data Processing Using Uas, Htoo Poe Sar, Cal Coopmans, Sierra Young

Spring Runoff Conference

Background and Motivation 

• Agricultural water management requires information about crop water use and water consumption 
• Remote sensing methods are used to model and estimate environmental processes – but they require weather data 

Utah Prototype For Visualizing Vulnerabilities Downstream Of Dams, Courtney Flint, Michael Englert, Nicolas Holden

Spring Runoff Conference

The climate question 

• Overtopping = 1/3^rd of all dam failures (ASDSO) 
• Drought concerns and supply uncertainty motivate keeping reservoirs full 
• Overtopping likelier if extreme storm when reservoir full 
• Over much of the country the probability of the annual daily maximum rainfall > 100-year event and the preceding 30-day rainfall >10-year event are going up (Hwang & Lall 2024) 

The Reform Of Prior Appropriation And The Fate Of Great Salt Lake, Christopher L. Lant, Rocky Seeley, Beth Parker, Andrew Follett

Spring Runoff Conference

Legal Issues Raised by the Decline of Great Salt Lake

• Violations of Clean Air Act from dust threaten federal intervention
• Petition to list Wilson’s Phalarope as an endangered species

Nutrient Inputs, Crop Removal, And Residual Soil Nitrogen Under Automated Surge Irrigation In Northen Utah, Ngoni Mufute

Spring Runoff Conference

Introduction

• Increasing pressure on already water scarce resources due to

• Climate Change and or variability

• Increasing demand and competition for water. E.g. due to -urban expansion

• Environmental concerns (Especially concerning the Great Salt Lake (GSL)-

• the shrinking of water levels in the GSL,

• increasing pollution levels in the GSL and

• the impact of these issues on industry,

• dust from the drying lakebed,

• increasing threat to both aquatic life and land animals

The Physical, Legal, And Modeling Infrastructure For Water Resource Management Has Reached A Tipping Point, Paul Brooks

Spring Runoff Conference

Addressing these challenges requires improved predictions of water supply

Supporting The Great Salt Lake: M&I Water Conservation Opportunities, Easton Hopkins

Spring Runoff Conference

Analysis of historical M&I water use, depletion, and conservation strategies to reduce anthropogenic impact on Great Salt Lake (GSL) while supporting M&I water needs.

Impacts Of Biochar And Fe/Zn-Doped Biochar On The Degradation And Transformation Of Pfas In Wastewater Biosolids Compost, Chase Fry, R. Ryan Dupont, Joan Mclean

Spring Runoff Conference

Background

• >5.8 million dry metric tons of biosolids were produced in 2018.
• It is difficult & expensive to landfill all biosolids produced.
• Biosolids are increasingly used as an agricultural fertilizer and soil amendment.

Ground Water Assessment Of Cache Valley Using Modern Tracing Techniques, Eric Humphrey, Bethany Neilson

Spring Runoff Conference

Monitor, analyze, and predict current and evolving dynamics of complex human and natural Earth-system interactions and to deliver actionable information at scales and timeframes relevant to decision makers.

Is The Chesapeake Bay Browning?, Samantha Williamson, Jessie Turner

Knowledge and Creativity Expo

Brownification is when water bodies turn brown over time. It occurs due to high amounts of color-dissolved organic matter (CDOM). CDOM is organic material, such as decaying leaves and organisms, that leaches into the water column like tea. It absorbs ultraviolet and blue light more than red light, causing the water to appear brown. After comparing surveys from 1987 and 2018, scientists discovered the Adirondack lakes underwent brownification as they recovered from acid rain. However, while increased CDOM can signify an ecosystem’s recovery, it can also hinder seagrass growth. Although scientists have studied this phenomenon in lakes, estuaries have not …

Rethinking Harmful Algal Blooms In Utah Waters: A Paradigm Shift In Water Quality And Management, Kabilan Mani

Spring Runoff Conference

Droughts are intensifying in frequency and severity, straining already limited water supplies.

Hydrodynamics Of Bear Lake: Waves, Currents, Circulation, And Residence Times, Jeffrey Nielson

Spring Runoff Conference

Until we understand water movement, we’ll struggle to explain or manage what happens in Bear Lake.