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Water Soluble Cationic Porphyrin Sensor For Detection Of Hg2+, Pb2+, Cd2+, And Cu2+, Matibur Zamadar, Christopher Orr, Miranda Uherek

Faculty Publications

Here we report the sensing properties of the aqueous solution of meso-tetra(N-methyl-4-pyridyl)porphine tetrachloride (1) for simultaneous detection of toxic metal ions by using UV-vis spectroscopy. Cationic porphyrin 1 displayed different electronic absorptions in UV-vis region upon interacting with Hg2+, Pb2+, Cd2+, and Cu2+ ions in neutral water solution at room temperature. Quite interestingly, the porphyrin 1 showed that it can function as a single optical chemical sensor and/or metal ion receptor capable of detecting two or more toxic metal ions, particularly Hg2+, Pb2+, and Cd2+ ions coexisting in a water sample. Porphyrin 1 in an aqueous solution provides a unique …

Bioavailability And Transformation Of Silver Nanoparticles In The Freshwater Environment, Seth W. Brittle

Browse all Theses and Dissertations

The proliferation of silver nanoparticles (AgNPs) in consumer products and industrial applications has generated many environmental concerns since the chemistry of silver changes at the nanoscale and the very properties that make them desirable – their unique reactivity – may pose environmental risks. This dissertation addresses these concerns from three different angles. First, freshwater crayfish is demonstrated as a potential benthic indicator of Ag pollution since Ag accumulation depends on the form of Ag. The uptake and distribution of Ag (from AgNPs or Ag+) in tissue samples were measured by inductively coupled plasma optical emission spectroscopy (ICP-OES). The hepatopancreas (1.5-17.4 …

Impacts Of Man-Made Structures On Avian Community Metrics In 4 State Parks In Northwestern Arkansas, R. D. Keith, B. Grooms, R. E. Urbanek

Journal of the Arkansas Academy of Science

Avian community metrics often differ between areas with no human disturbance and areas with high levels of human disturbance. However, the relationships between avian community metrics and smaller-scale disturbances are not as clear. Our goal was to investigate if avian abundance, richness, evenness, and diversity differed in areas with and without small-scale human developments. We used fixed-radius 50-m avian point counts to compare points which contained a man-made structure (n = 47), such as a picnic area, road, or campsite to those that did not contain a man-made structure (n = 181) at 4 state parks in Arkansas during 18 …

Our Gmo Labeling Debate: Human Health, The Environment, And The Precautionary Principle, Kate Porfilio 16

Honor Scholar Theses

No abstract provided.

Handbook Of Drought Indicators And Indices, Mark Svoboda, Brian Fuchs, Integrated Drought Management Programme (Idmp)

National Drought Mitigation Center: Faculty Publications

The purpose of this handbook is to cover some of the most commonly used drought indicators/indices that are being applied across drought-prone regions, with the goal of advancing monitoring, early warning and information delivery systems in support of risk-based drought management policies and preparedness plans. These concepts and indicators/indices are outlined below in what is considered to be a living document that will evolve and integrate new indicators and indices as they come to light and are applied in the future. The handbook is aimed at those who want to generate indicators and indices themselves, as well as for those …

Temporal Variability In Aboveground Plant Biomass Decreases As Spatial Variability Increases, Devan Allen Mcgranahan, Torre J. Hovick, R. Dwayne Elmore, David M. Engle, Samuel D. Fuhlendorf, Stephen L. Winter, James R. Miller, Diane M. Debinski

School of Natural Resources: Faculty Publications

Ecological theory predicts that diversity decreases variability in ecosystem function. We predict that, at the landscape scale, spatial variability created by a mosaic of contrasting patches that differ in time since disturbance will decrease temporal variability in aboveground plant biomass. Using data from a multi-year study of seven grazed tallgrass prairie landscapes, each experimentally managed for one to eight patches, we show that increased spatial variability driven by spatially patchy fire and herbivory reduces temporal variability in aboveground plant biomass. This pattern is associated with statistical evidence for the portfolio effect and a positive relationship between temporal variability and functional …

Temporal Variability In Aboveground Plant Biomass Decreases As Spatial Variability Increases, Devan Allen Mcgranahan, Torre J. Hovick, R. Dwayne Elmore, David M. Engle, Samuel D. Fuhlendorf, Stephen L. Winter, James R. Miller, Diane M. Debinski

School of Natural Resources: Faculty Publications

Ecological theory predicts that diversity decreases variability in ecosystem function. We predict that, at the landscape scale, spatial variability created by a mosaic of contrasting patches that differ in time since disturbance will decrease temporal variability in aboveground plant biomass. Using data from a multi-year study of seven grazed tallgrass prairie landscapes, each experimentally managed for one to eight patches, we show that increased spatial variability driven by spatially patchy fire and herbivory reduces temporal variability in aboveground plant biomass. This pattern is associated with statistical evidence for the portfolio effect and a positive relationship between temporal variability and functional …

Through My Great-Grandfather’S Eyes: The Environmental History Of Hilo, Carmen Garson-Shumway

Gateway Prize for Excellent Writing

No abstract provided.

Compliance Calendar/Logbook For Bulk Gasoline Plants: Less Than 19,999 Gallons/Day Throughput, Iowa Waste Reduction Center

Iowa Waste Reduction Center Book Gallery

EPA has new requirements for Gasoline Distribution Bulk Terminals, Bulk Gasoline Plants and Pipeline Facilities under 40 CFR Part 63 Subpart BBBBBB (NESHAP 6B) to reduce air pollution. This calendar has been developed to assist Bulk Gasoline Plants in complying with NESHAP 6B. Additional Iowa specific NESHAP 6B rules are discussed later.

Turning On The Lights: Transcending Energy Poverty Through The Power Of Women Entrepreneurs, Leslie C. Gray, Alaina Boyle, Victoria Yu

Miller Center Fellowship

Solar lanterns offer affordable, high-quality lighting in developing countries. A number of organizations, including social enterprises, make solar lanterns available to rural households as an alternative to candles or kerosene lamps. One of the most successful of these organizations is Solar Sister.

Solar Sister, a social enterprise operating in Tanzania, Uganda, and Nigeria, is dedicated to eradicating energy poverty through the economic empowerment of women. In addition to economically empowering its women entrepreneurs, the business model of Solar Sister also cultivates sales networks built on trust in last-mile distribution methods.

While Solar Sister has previously conducted research regarding its many …

Coastal Development And Precipitation Drive Pathogen Flow From Land To Sea: Evidence From A Toxoplasma Gondii And Felid Host System, Elizabeth Vanwormer, Tim E. Carpenter, Purnendu Singh, Karen Shapiro, Wesley W. Wallender, Patricia A. Conrad, John L. Largier, Marco P. Maneta, Jonna A. K. Mazet

School of Natural Resources: Faculty Publications

Rapidly developing coastal regions face consequences of land use and climate change including flooding and increased sediment, nutrient, and chemical runoff, but these forces may also enhance pathogen runoff, which threatens human, animal, and ecosystem health. Using the zoonotic parasite Toxoplasma gondii in California, USA as a model for coastal pathogen pollution, we examine the spatial distribution of parasite runoff and the impacts of precipitation and development on projected pathogen delivery to the ocean. Oocysts, the extremely hardy free-living environmental stage of T. gondii shed in faeces of domestic and wild felids, are carried to the ocean by freshwater runoff. …

Nebraska Water Center Annual Report 2016, Nebraska Water Center

Nebraska Water Center: Administrative Materials

Contents

Foreword

Director’s Letter

Since 1964: The Nebraska Water Center

Building the future

Nebraska’s Top 10 water challenges

Nebraska Water Center advisory board

Water Resources Advisory Panel: A key to success

Nebraska Water Sciences Laboratory

USGS 104b projects for 2016

Ogallala Aquifer focus of USDA research grant

Graduate research on amphetamines draws attention

NIC hosts water symposium and law conference

Water seminar lectures key on “Water and health”

Four picked for IRES program in Czech Republic

WARI program begins

2016 tour to Colorado’s South Platte basin

45th annual tour visits Platte River basin in Colorado

McCornick new Water for Food …

Alpha-Lipoic Acid Supplementation Protects Enzymes From Damage By Nitrosative And Oxidative Stress, Sylvia Hiller, Robert Dekroon, Eric D. Hamlett, Longquan Xu, Cristina Osorio, Jennifer Robinette, Witold Winnik, Stephen Simington, Nobuyo Maeda, Oscar Alzate, Xianwen Yi

United States Environmental Protection Agency: Publications

Background: S-nitrosylation of mitochondrial enzymes involved in energy transfer under nitrosative stress may result in ATP deficiency. We investigated whether α-lipoic acid, a powerful antioxidant, could alleviate nitrosative stress by regulating S-nitrosylation,which could result in retaining themitochondrial enzyme activity.

Methods: In this study, we have identified the S-nitrosylated forms of subunit 1 of dihydrolipoyllysine succinyltransferase (complex III), and subunit 2 of the α-ketoglutarate dehydrogenase complex by implementing a fluorescence-based differential quantitative proteomics method.

Results: We found that the activities of these two mitochondrial enzymes were partially but reversibly inhibited by S-nitrosylation in cultured endothelial cells, and that their activities …

Seasonality Of Coliform Bacteria Detection Rates In New Jersey Domestic Wells, Thomas B. Atherholt, Nicholas A. Procopio, Sandra M. Goodrow

United States Environmental Protection Agency: Publications

It is important that indicators of fecal pollution are reliable. Coliform bacteria are a commonly used indicator of fecal pollution. As other investigators have reported elsewhere, we observed a seasonal pattern of coliform bacteria detections in domestic wells in New Jersey. Examination of a statewide database of 10 years of water quality data from 93,447 samples, from 78,207 wells, generated during real estate transactions, revealed that coliform bacteria were detected in a higher proportion of wells during warm weather months. Further examination of the seasonal pattern of other data, including well water pH, precipitation, ground and surface water temperatures, surface …

Cyanotoxins In Inland Lakes Of The United States: Occurrence And Potential Recreational Health Risks In The Epa National Lakes Assessment 2007, Keith A. Loftin, Jennifer L. Graham, Elizabeth D. Hillborn, Sarah C. Lehmann, Michael T. Meyer, Julie E. Dietze, Christopher B. Griffith

United States Environmental Protection Agency: Publications

A large nation-wide survey of cyanotoxins (1161 lakes) in the United States (U.S.) was conducted during the EPA National Lakes Assessment 2007. Cyanotoxin data were compared with cyanobacteria abundance- and chlorophyll-based World Health Organization (WHO) thresholds and mouse toxicity data to evaluate potential recreational risks. Cylindrospermopsins, microcystins, and saxitoxins were detected (ELISA) in 4.0, 32, and 7.7% of samples with mean concentrations of 0.56, 3.0, and 0.061 mg/L, respectively (detections only). Co-occurrence of the three cyanotoxin classes was rare (0.32%) when at least one toxin was detected. Cyanobacteria were present and dominant in 98 and 76% of samples, respectively. Potential …

Carbon Storage In Us Wetlands, A. M. Nahlik, M. S. Fennessy

United States Environmental Protection Agency: Publications

Wetland soils contain some of the highest stores of soil carbon in the biosphere. However, there is little understanding of the quantity and distribution of carbon stored in our remaining wetlands or of the potential effects of human disturbance on these stocks. Here we use field data from the 2011 National Wetland Condition Assessment to provide unbiased estimates of soil carbon stocks for wetlands at regional and national scales. We find that wetlands in the conterminous United States store a total of 11.52 PgC, much of which is within soils deeper than 30 cm. Freshwater inland wetlands, in part due …

Polaris: A 30-Meter Probabilistic Soil Series Map Of The Contiguous United States, Nathaniel W. Chaney, Eric F. Wood, Alexander B. Mcbratney, Jonathan W. Hempel, Travis W. Nauman, Colby W. Brungard, Nathan P. Odgers

United States Geological Survey: Staff Publications

A newcomplete map of soil series probabilities has been produced for the contiguous United States at a 30mspatial resolution. This innovative database, named POLARIS, is constructed using available high-resolution geospatial environmental data and a state-of-the-art machine learning algorithm (DSMART-HPC) to remap the Soil Survey Geographic (SSURGO) database. This 9 billion grid cell database is possible using available high performance computing resources. POLARIS provides a spatially continuous, internally consistent, quantitative prediction of soil series. It offers potential solutions to the primary weaknesses in SSURGO: 1) unmapped areas are gap-filled using survey data from the surrounding regions, 2) the artificial discontinuities at …

Paying The Pipers: Mitigating The Impact Of Anticoagulant Rodenticides On Predators And Scavengers, John E. Elliott, Barnett A. Rattner, Richard F. Shore, Nico W. Van Den Brink

United States Geological Survey: Staff Publications

Anticoagulant rodenticides, mainly second-generation forms, or SGARs, dominate the global market for rodent control. Introduced in the 1970s to counter genetic resistance in rodent populations to first-generation compounds such as warfarin, SGARs are extremely toxic and highly effective killers. However, their tendency to persist and accumulate in the body has led to the widespread contamination of terrestrial predators and scavengers. Commercial chemicals that are classified by regulators as persistent, bio-accumulative, and toxic (PBT) chemicals and that are widely used with potential environmental release, such as dichloro-diphenyl-trichloroethane (DDT) or polychlorinated biphenyls (PCBs), have been removed from commerce. However, despite consistently failing …

Chesapeake Bay Fish–Osprey (Pandion Haliaetus) Food Chain: Evaluation Of Contaminant Exposure And Genetic Damage, Rebecca S. Lazarus, Barnett A. Rattner, Peter C. Mcgowan, Robert C. Hale, Natalie K. Karouna-Renier, Richard A. Erickson, Mary Ann Ottinger

United States Geological Survey: Staff Publications

From 2011 to 2013, a large-scale ecotoxicological study was conducted in several Chesapeake Bay (USA) tributaries (Susquehanna River and flats, the Back, Baltimore Harbor/Patapsco Rivers, Anacostia/ middle Potomac, Elizabeth and James Rivers) and Poplar Island as a mid-Bay reference site. Osprey (Pandion haliaetus) diet and the transfer of contaminants from fish to osprey eggs were evaluated. The most bioaccumulative compounds (biomagnification factor>5) included p,p’-dichlorodiphenyldichloroethylene (DDE), total polychlorinated biphenyls (PCBs), total polybrominated diphenyl ethers (PBDEs), and bromodiphenyl ether (BDE) congeners 47, 99, 100, and 154. This analysis suggested that alternative brominated flame retardants and other compounds (methoxytriclosan) are not appreciably …

Immunoglobulin Detection Inwild Birds: Effectiveness Of Three Secondary Anti-Avian Igy Antibodies In Direct Elisas In 41 Avian Species, Carol A. Fassbinder-Orth, Travis E. Wilcoxen, Tiffany Tran, Raoul K. Boughton, Jeanne M. Fair, Erik K. Hofmeister, Jennifer L. Grindstaff, Jen C. Owen

United States Geological Survey: Staff Publications

1.Immunological reagents for wild, non-model species are limited or often non-existent for many species.

2. In this study, we compare the reactivity of a newanti-passerine IgY secondary antibody with existing secondary antibodies developed for use with birds. Samples from 41 species from the following six avian orders were analysed: Anseriformes (1 family, 1 species), Columbiformes (1 family, 2 species), Galliformes (1 family, 1 species), Passeriformes (16 families, 34 species), Piciformes (1 family, 2 species) and Suliformes (1 family, 1 species). Direct ELISAs were performed to detect total IgY using goat anti-passerine IgY, goat anti-chicken IgY or goat anti-bird IgY secondary …

Endangered Species Research In The Caribbean, James W. Wiley

United States Geological Survey: Staff Publications

Although indigenous Amerindian populations adversely affected the biota of their island environments, it was not until the arrival of Europeans that populations of many plant and animal species in the Caribbean Islands declined dramatically (Snyder and others, 1987). Island species are particularly vulnerable to changes in the environment, which, in the extreme, can lead to their extinction. The small populations of many species that occupy islands have limited gene pools and typically show extremes of specialization, characteristics that place those species at high risk for decline and extinction with rapid environmental change. The most important factor in the decline of …

The Bird Banding Laboratory: Support For And Collaboration With Research At Patuxent, John Tautin

United States Geological Survey: Staff Publications

Located at Patuxent Research Refuge (PRR) and functionally part of the Patuxent Wildlife Research Center (Patuxent), Laurel, MD, the Bird Banding Laboratory (BBL) is the service and administrative center for bird banding in the United States. Over the years, the BBL has been associated with both the PRR and Patuxent, which collectively are commonly referred to by the public (and in this chapter) as “Patuxent.” The BBL issues permits and bands; supplies banding software, instructional materials, and technical advice; coordinates the use of auxiliary markers such as neck collars and radio transmitters; serves as the repository for banding records and …

Endangered Species Research In Hawaii: The Early Years (1965–87), Michael J. Scott, Cameron B. Kepler

United States Geological Survey: Staff Publications

Hawaii is an ecologically isolated archipelago 2,500 miles from the nearest continent. Its isolation resulted in a taxonomically unbalanced flora and fauna with remarkable examples of adaptive radiation among those groups of organisms that won the dispersal sweepstakes. It was one of the last oceanic island groups to be populated by humans, about 900 A.D. by Polynesian travelers and in 1778 by Europeans. Relatively recent colonization by humans did not save it, however, from the biodiversity losses suffered by other isolated archipelagos—it only delayed them (Scott and others, 1988; Pratt and others, 2009a).

Energy And Economy: Recognizing High-Energy Modernity As A Historical Period, Thomas Love, Cindy Isenhour

Faculty Publications

This introduction to Economic Anthropology’s special issue on “Energy and Economy” argues that we might find inspiration for a much more engaged and public anthropology in an unlikely place—19th century evolutionist thought. In addition to studying the particularities of energy transitions, which anthropology does so well, a more engaged anthropology might also broaden its temporal horizons to consider the nature of the future “stage” into which humanity is hurtling in an era of resource depletion and climate change. Net energy (EROEI), or the energy “surplus” on which we build and maintain our complex societal arrangements, is a key tool …

The Influence Of A Severe Reservoir Drawdown On Springtime Zooplankton And Larval Fish Assemblages In Red Willow Reservoir, Nebraska, Jason A. Deboer, Christa M. Webber, Taylor A. Dixon, Kevin L. Pope

Nebraska Cooperative Fish and Wildlife Research Unit: Staff Publications

Reservoirs can be dynamic systems, often prone to unpredictable and extreme waterlevel fluctuations, and can be environments where survival is difficult for zooplankton and larval fish. Although numerous studies have examined the effects of extreme reservoir drawdown on water quality, few have examined extreme drawdown on both abiotic and biotic characteristics. A fissure in the dam at Red Willow Reservoir in southwest Nebraska necessitated an extreme drawdown; the water level was lowered more than 6 m during a two-month period, reducing reservoir volume by 76%. During the subsequent low-water period (i.e., post-drawdown), spring sampling (April-June) showed dissolved oxygen concentration was …

Potential Population And Assemblage Influences Of Non-Native Trout On Native Nongame Fish In Nebraska Headwater Streams, Kelly C. Turek, Mark A. Pegg, Kevin L. Pope, Steve Schainost

Nebraska Cooperative Fish and Wildlife Research Unit: Staff Publications

Non-native trout are currently stocked to support recreational fisheries in headwater streams throughout Nebraska. The influence of non-native trout introductions on native fish populations and their role in structuring fish assemblages in these systems is unknown. The objectives of this study were to determine (i) if the size structure or relative abundance of native fish differs in the presence and absence of non-native trout, (ii) if native fish-assemblage structure differs in the presence and absence of non-native trout and (iii) if native fish-assemblage structure differs across a gradient in abundances of non-native trout. Longnose dace Rhinichthys cataractae were larger in …

Letter Resisting Resilience Theory: Aresponse To Connelland Ghedini, Shana M. Sundstrom, Craig R. Allen, Lance H. Gunderson

Nebraska Cooperative Fish and Wildlife Research Unit: Staff Publications

ConnellandGhedini [1] arguethatecolo- gistsareprimarily [1TD$DIF]concernedwithcommu- nitychangeandtendtoignoreprocesses liketrophiccompensationthatcontribute to communityorsystem-levelstability. Resilience,theyclaim,isthestudyof change,andresearchersshouldspend moretimestudyingstabilizingprocesses to betterpredictthetypesofchanges documentedbyecologistswhostudyresil- ience [2,3]. Thebulkoftheirpaper addressesresilienceandrelatedconcepts to contextualizeresistancetochange,but theirargumentsarediminishedbecause theauthorsfailtoexplicitlyplacetheirwork withintherangeofresilienceconceptsthat haveproliferatedacrossacademicdisci- plines.Moreimportantly,thepaperfurthers confusionregardingcoreecologicalresil- ienceconcepts.Withinthedisciplineof ecology,resilienceconceptshavebeen developedinafundamentallycohesive way [4]. Understandingtheresilienceof complexsystemsofhumansandnature duringthistimeofrapidglobalchangeis importantandthemisuseorcasualuseof conceptswithspecific meaningismore thansimplyatrivialpointofcontention;it potentiallyobscuresprocessesandprop- ertiesthathavedirectrelevancetohuman- ity'sinteractionwiththeenvironment.

Influence Of Anglers’ Specializations On Catch, Harvest, And Bycatch Of Targeted Taxa, Kevin L. Pope, Christopher J. Chizinski, Christopher L. Wiley, Dustin R. Martin

Nebraska Cooperative Fish and Wildlife Research Unit: Staff Publications

Fishery managers often use catch per unit effort (CPUE) of a given taxon derived from a group of anglers,those that sought said taxon, to evaluate fishery objectives because managers assume CPUE for this group of anglers is most sensitive to changes in fish taxon density. Further, likelihood of harvest may differ for sought and non-sought taxa if taxon sought is a defining characteristic of anglers’ attitude toward harvest.We predicted that taxon-specific catch across parties and reservoirs would be influenced by targeted taxon after controlling for number of anglers in a party and time spent fishing (combine to quantify fishing effort …

Morphological Variation Of Mesobuthus Eupeus Mongolicus (Birula, 1911) (Scorpiones: Buthidae) In Mongolia, Mike Heddergott, D. Pohl, Michael Stubbe, Annegret Stubbe, P. Steinbach

Erforschung biologischer Ressourcen der Mongolei / Exploration into the Biological Resources of Mongolia, ISSN 0440-1298

In the present study, we investigated morphological variation of Mesobuthus eupeus mongolicus (Birula, 1911) in Mongolia. Samples were collected in 16 sites located in the provinces Bayankhongor, Khovd, Dundgovi, Dornogovi, Govisümber and Ömnögovi. Statistical analyses (Kruska-Wallis one-way ANOVA, PCA and hierarchical cluster analysis) showed that (a) morphologically the M. e. mongolicus males sampled in Dundgovi, Dornogovi, Govisümber and Ömnögovi were similar to each other, while the populations of Bayankhongor and Khovd were differentiated, and (b) the females from Bayankhongor, Dundgovi, Dornogovi, Govisümber and Ömnögovi had a similar morphology, while the population from Khovd was differentiated.

Geographical Distribution Of The Genus Mesobuthus (Scorpiones: Buthidae) In Mongolia, Mike Heddergott, Michael Stubbe, W. Stubbe, P. Steinbach, Annegret Stubbe

Erforschung biologischer Ressourcen der Mongolei / Exploration into the Biological Resources of Mongolia, ISSN 0440-1298

In the present study, we surveyed the diversity of scorpions in six provinces of Mongolia (Bayankhongor, Khovd, Dundgovi, Dornogovi, Govisümber and Ömnögovi) between 2001 and 2012. A total of 385 individuals were collected at 17 different sites. In addition to opportunistic sampling, animals were collected after detection with ultraviolet light. Only species from the genus Mesobuthus have been reported from Mongolia thus far. It was possible to confirm the occurrence of the species Mesobuthus eupeus mongolicus and report the presence of M. martensii martensii for the first time. We could not confirm the presence of M. caucasicus przewalskii and suggest …