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09.29.2025 Ored Connect, Liz Williamson

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Quantifying The Decay Timescale Of Volcanic Sulfur Dioxide In The Stratosphere, Paul A. Nicknish, Kane Stone, Susan Solomon, Simon Carn

Michigan Tech Publications

The injection of sulfur dioxide (SO2) into the stratosphere and its subsequent oxidation to form sulfate aerosols after large volcanic eruptions can have profound effects on Earth's climate. The removal of volcanic SO2 in the stratosphere is thought to be driven by its gas-phase oxidation by the hydroxyl radical (OH); once oxidized, it goes on to form sulfate aerosols. However, it has also been suggested that heterogeneous oxidation on ash could also be important or even dominant, which would imply the faster removal of SO2 and thus the faster formation of aerosols, at least in ash-rich plumes. Additionally, recent work …

Plasmonic Nanoparticle Integration On Fiber Optic: Role Of Organic Linker And Functionalization Length In Refractive Index Sensing, Shela Ilmiyah, Mohamad Syahadi, Muflikhah Muflikhah, Yuwana Pradana, Zainul Arifin Iman Supardi, Iwan Darmadi, Lia Aprilia

Makara Journal of Science

Nanoplasmonic fiber optic sensors leverage the optical fiber’s inherent compactness and surface sensitivity via evanescent-field interactions with the localized surface plasmon resonance of the metallic nanoparticles. One of the popular approaches is self-assembly owing to its relatively low cost. Despite its low cost, the self-assembly technique has low reproducibility and exhibits low sensitivity because of low nanoplasmonic coverage on the fiber optic surface. In this study, several fabrication techniques were explored to assess the refractive index sensitivity by comparing three common organosilanes, i.e., (3-Aminopropyl)triethoxysilane (APTES), (3-Aminopropyl)trimethoxysilane, and (3-Mercaptopropyl)trimethoxysilane. Comparative analyses assessed the anchoring efficiency of the three silanes, sensor reproducibility, …

Series Reports From Professor Wei’S Group Of Chongqing University: Advancements In Electrochemical Energy Conversions (2/4): Report 2: High-Performance Water Splitting Electrocatalysts, Ling Zhang, Wang-Yang Wu, Qiu-Yue Hu, Shi-Dan Yang, Li Li, Rui-Jin Liao, Zi-Dong Wei

Journal of Electrochemistry

The unavailability of high-performance and cost-effective electrocatalysts has impeded the large-scale deployment of alkaline water electrolyzers. Professor Zidong Wei’s group has focused on resolving critical challenges in industrial alkaline electrolysis, particularly elucidating hydrogen and oxygen evolution reaction (HER/OER) mechanisms while addressing the persistent activity-stability trade-off. This review summarizes their decade-long progress in developing advanced electrodes, analyzing the origins of sluggish alkaline HER kinetics and OER stability limitations. Professor Wei proposes a unifying “12345 Principle” as an optimization framework. For HER electrocatalysts, they have identified that metal/metal oxide interfaces create synergistic “chimney effect” and “local electric field enhancement effect”, enhancing selective …

Local Electric Fields Coupled With Cl− Fixation Strategy For Improving Seawater Oxygen Reduction Reaction Performance, Yu-Rong Liu, Miao Zhang, Yan-Hui Yu, Ya-Lin Liu, Jing Li, Xiao-Dong Shi, Zhen-Ye Kang, Dao-Xiong Wu, Peng Rao, Ying Liang, Xin-Long Tian

Journal of Electrochemistry

Development of robust electrocatalyst for oxygen reduction reaction (ORR) in a seawater electrolyte is the key to realize seawater electrolyte-based zinc-air batteries (SZABs). Herein, constructing a local electric field coupled with chloride ions (Cl⁻) fixation strategy in dual single-atom catalysts (DSACs) was proposed, and the resultant catalyst delivered considerable ORR performance in a seawater electrolyte, with a high half-wave potential (E_1/2) of 0.868 V and a good maximum power density (Pmax) of 182 mW·cm⁻² in the assembled SZABs, much higher than those of the Pt/C catalyst (E_1/2: 0.846 V; Pmax: 150 mW·cm^{−2 …}

Bridging Materials And Energy Storage Mechanisms In Zn-I2 Batteries, Rong-Qi Liu, Wen-Shuo Shang, Jin-Tao Zhang

Journal of Electrochemistry

Zinc-iodine (Zn-I₂) batteries have emerged as a compelling candidate for large-scale energy storage, driven by the growing demand for safe, cost-effective, and sustainable alternatives to conventional systems. Benefiting from the inherent advantages of aqueous electrolytes and zinc metal anodes, including high ionic conductivity, low flammability, natural abundance, and high volumetric capacity, Zn-I₂ batteries offer significant potential for grid-level deployment. This review provides a comprehensive overview of recent progress in three critical domains: positive-electrode engineering, zinc anode stabilization, and in situ characterization methods. On the cathode side, anchoring iodine to conductive matrices effectively mitigates polyiodide shuttling and enhances …

Significantly Enhanced Oxygen Reduction Reaction Activity In Co-N-C Catalysts Through Synergistic Boron Doping, Chang Lan, Jing-Sen Bai, Xin Guan, Shuo Wang, Nan-Shu Zhang, Yu-Qing Cheng, Jin-Jing Tao, Yu-Yi Chu, Mei-Ling Xiao, Chang-Peng Liu, Wei Xing

Journal of Electrochemistry

The weak adsorption energy of oxygen-containing intermediates on Co center leads to a considerable performance disparity between Co-N-C and costly Pt benchmark in catalyzing oxygen reduction reaction (ORR). In this work, we strategically engineer the active site structure of Co-N-C via B substitution, which is accomplished by the pyrolysis of ammonium borate. During this process, the in-situ generated NH₃ gas plays a critical role in creating surface defects and boron atoms substituting nitrogen atoms in the carbon structure. The well-designed CoB₁N₃ active site endows Co with higher charge density and stronger adsorption energy toward oxygen species, …

Carbonated High-Al Steel Slag As Supplementary Cementitious Material: Synergy Of Carbonation At Elevated Temperature And Addition Of Gypsum, Nannan Zhang, Gao Deng, Wenyu Liao, Chuanlin Hu, Lingyu Chi, Hongyan Ma

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

High-Al steel slags, such as ladle metallurgy furnace (LMF) slag, substantially retard the early hydration of cement when incorporated into cement pastes, primarily due to the high mayenite content. In this study, carbonation of slag at elevated temperatures of 60°C and 80°C, combined with gypsum addition, was proposed to synergistically mitigate the retardation effect and enhance the early-age strength of cement pastes. The physical and chemical properties of slags carbonated at various temperatures were analyzed to elucidate their impact on cement performance as a supplementary cementitious material. The results indicate that higher temperatures enhance carbonation reactivity, accelerating the carbonation of …

Feasibility Of Helium And Nitrogen As Surrogate Gases For Hydrogen Jet Using Planar Laser-Induced Fluorescence In A Constant Volume Chamber, Jungho Justin Kim, Seong Young Lee, Youngmin Ki, Joonsik Hwang, Choongsik Bae

Michigan Tech Publications

This study investigates the feasibility of using helium and nitrogen as surrogate gases for visualizing the non-reactive behavior of hydrogen jets in a constant volume chamber. Hydrogen, helium, and nitrogen were individually mixed with acetone vapor and injected using a hollow-cone injector. The fuel distribution was visualized using Planar Laser-Induced Fluorescence (PLIF), while simultaneous Schlieren imaging was employed to capture overall jet structures. Quantitative comparisons of jet areas extracted from both imaging techniques demonstrated that acetone effectively followed the gas-phase flow of each species, validating its use as a flow tracer. Furthermore, helium and nitrogen exhibited jet dispersion patterns comparable …

Wmu Maritime Affairs Conference 2025 : Transforming A Maritime Future : Digitalization And Decarbonization, World Maritime University

Books

No abstract provided.

Pendant Micro-Droplet Evaporation Fabricates Fiber-Optic Mof Gas Sensor In Seconds, Abhishek Prakash Hungund, Bohong Zhang, Narasimman Subramaniyam, Thomas Spudich, Ryan O'Malley, Farhan Mumtaz, Rex E. Gerald, Jie Huang

Electrical and Computer Engineering Faculty Research & Creative Works

The development of photonic-based gas sensors using metal–organic frameworks (MOFs) and other microporous solids is often a multistep, complex process, typically involving MOF synthesis, purification, and attachment of microcrystals to an optical fiber end face. This study introduces a one-step method that integrates MOF synthesis and sensor head fabrication directly onto the fiber end face, forming an extrinsic Fabry–Perot interferometer (EFPI) with a thin film of MOF microcrystals. The resulting film, only 3–10-μm-thick, enhances sensor response by enabling rapid gas detection within seconds. Utilizing a pendant micro-droplet evaporation technique, this method forms a microporous MOF layer in situ, allowing unreacted …

Polymorphism Crystal Structure Prediction With Adaptive Space Group Diversity Control, Sadman Saadeed Omee, Lai Wei, Jianjun Hu

Faculty Publications

Crystalline materials can form different structural arrangements (i.e., polymorphs) with the same chemical composition, exhibiting distinct physical properties depending on how they are synthesized or the conditions under which they operate. For example, carbon can exist as graphite (soft, conductive) or diamond (hard, insulating). Computational methods that can predict these polymorphs are vital in materials science, which help understand stability relationships, guide synthesis efforts, and discover new materials with desired properties without extensive trial-and-error experimentation. However, effective crystal structure prediction (CSP) algorithms for inorganic polymorph structures remain limited. ParetoCSP2 is proposed, a multi-objective genetic algorithm for polymorphism CSP that incorporates …

Warpage-Resistant, Under-Extrusion-Free, High-Surface-Quality Additive Manufacturing Process For Polyethylene-Based Composite Radiation Shielding Material, Duo Xu, Volodymyr Korolovych, You Lyu, Jacqueline Aslarus, Domingo R. Flores-Hernandez, Simo Pajovic, William T. Heller, Lembit Sihver, Svetlana V. Boriskina

Informatics and Engineering Systems Faculty Publications

Polyethylene (PE) is one of the best shielding materials for primary space radiation due to its high hydrogen content. For effective secondary neutron shielding, boron-rich fillers are incorporated to enhance performance. The semicrystalline nature and high thermal expansion coefficient of PE impede its adoption for in situ additive manufacture in space via the fused deposition modeling (FDM) 3D printing. We developed an optimized PE blend to mitigate the effects of under-extrusion and warpage. Guided by studies on extrusion and warpage, we developed an optimal set of printing parameters for the proposed PE blend. The optimum PE blend─both in its pure …

Common Ground Newsletter Fall 2025, Missouri University Of Science And Technology

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Using Drone And Ai To Map Leaf Water Potential And Stem Water Potential For Water Stress Management In Commercial Vineyards, Alfonso F. Torres-Rua

Funded Research Records

No abstract provided.

Engineering, Innovation, And God’S Creation, Fred Haan

University Faculty Publications and Creative Works

Took place at YPPH Annual Retreat 2025 Coram Deo In the Presence of God Reflections on Biblical Christian Worldview at Pelita Harapan University on 9/26/2025 in Jakarta, Indonesia.

Microstructure Densification In Cement Pastes Enabled By Novel Graphene Types, Sahil Surehali, Taihao Han, Ranjith Divigalpitiya, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

The primary barriers hindering graphene's widespread adoption as a performance-enhancing additive in cement-based systems have traditionally been its prohibitive cost and the sustainability concerns associated with conventional manufacturing processes. However, these impediments have recently been mitigated by advancements in detonation synthesis techniques, enabling scalable, cost-effective, and environmentally favorable production of novel graphene types—specifically fractal graphene (FG) and reactive graphene (RG). This paper explores the influence of ultra-low dosages of FG and RG (≤ 0.04 % by mass of cement, which results in ∼20 % increase in compressive strengths) on the pore-structure features of cement pastes. Compared to the control paste, …

Magnesium Sulfate Attack Of Alite Paste And Mitigation By Surface Carbonation: Monitoring And Comparison Using Novel Portable Fiber-Optic Raman Probe, Bohong Zhang, Gao Deng, Hongyan Ma, Jie Huang

Electrical and Computer Engineering Faculty Research & Creative Works

Sulfate attack on cement matrix is still a "confused world" especially when magnesium sulfate (MgSO₄) is the sulfate source. Accurate assessment of sulfate attack is essential for evaluating the structural integrity and durability of concrete in relevant environments. This study presents a portable fiber-optic Raman probe approach with 125 μm spatial resolution, designed for depth-resolved sulfate ingress monitoring in tricalcium silicate (C₃S, Alite) pastes. The probe is also used to evaluate the effectiveness of surface carbonation in mitigating sulfate attack. The results demonstrate a strong correlation between sulfate penetration depth and Raman spectral intensity ratios of sulfate-related vibrational …

Improvement Of Lithium-Metal Electrode All-Solid-State Batteries Performance By Shot Peening And Magnetron Sputtering, Atsuro Okumura, Manabu Kodama

15th International Conference on Shot Peening

To enable fast charging in lithium-metal anode all-solid-state batteries, suppressing lithium dendrite formation at the solid electrolyte (SE) interface is critical. Increasing fracture toughness via shot peening (SP) and improving interfacial contact with Au sputtering can inhibit dendrite growth. However, conventional sputtering may reduce toughness due to localized thermal damage. This study investigated magnetron sputtering as a low-damage, plasma-based Au deposition method. SEs with and without SP were fabricated and coated via normal and magnetron sputtering. Critical current density (CCD) and fracture toughness were evaluated. Without SP, CCD improvement was limited regardless of sputtering method due to poor bonding. With …

Hydrogen Embrittlement In Shot-Peened Steel, Jia-Huei Tien, David R. Johnson, David Bahr

15th International Conference on Shot Peening

This work investigates the role of shot peening on hydrogen embrittlement resistance in quenched and tempered 1070 steel. Thermal desorption spectroscopy results revealed that shot-peened specimens contained nearly twice the hydrogen (H) content of unpeened samples when charged under the same electrochemical conditions, suggesting the introduction of additional trapping sites occur during peening. The mechanism underlying this behavior can be associated with increased dislocation density and is more consistent with the HELP mechanism. Residual stress measurements show a significant relaxation of compressive stresses in shot-peened specimen after H charging, indicating H enhanced dislocation rearrangement. Both unpeened and peened specimens exhibited …

Investigation Of Topography Changes Of Blasted Surfaces: An Experimental Perspective Using Fiducial Markers, Stefanie Stoeckel, Sophie Groeger

15th International Conference on Shot Peening

Abrasive blasting is a process that intentionally modifies surface topography to meet specific functional requirements. The blast media is accelerated and interacts directly with the surface through impact. It is evident that the number of impacts and the overlap increase with time. This study aims to investigate these alterations to surface topography through repeated examinations of the same location. A methodology has been developed that employs the use of fiducial markers, which are protected during blasting by a custom 3D-printed cover. This method was used to observe changes in the topography of smooth and rough initial surfaces that had been …

Anisotropic Residual Stress Measurements In Additively Manufactured 316 Stainless Steel Parts, Rajeshree Varma, Donovan Stumpf, Paul R. Mort

15th International Conference on Shot Peening

Additive manufacturing (AM) using laser powder bed fusion (L-PBF) is increasingly used to produce complex parts for industries like aerospace and medical devices. The intrinsic characteristics of AM – layer-wise deposition and rapid thermal cycling – generate significant, anisotropic, residual stresses that can compromise part quality and performance. Recent studies highlight how these stresses are strongly influenced by process parameters and build orientation. X-ray diffraction (XRD) techniques, including sin²ψ and advanced two-dimensional approaches, have become the preferred methods for non-destructive, directionally resolved measurement of residual stress in AM metals. This review surveys advancements in XRD residual stress methods with a …

From Strain To Stress: Stress Map Testing Of Almen Strips, Donovan Stumpf, Rajeshree Varma, Paul R. Mort

15th International Conference on Shot Peening

Almen strips have long been used to evaluate shot peening intensity, with arc height serving as a proxy for compressive residual stress. Stress mapping tests (SMT) in this work involve the controlled flattening of an Almen test strip onto a spatial pressure sensor, acting as an inferential measurement for the net bending moment caused by the relaxation of the peened strip. This work explores how stress mapping tests add insight into the stress state of Almen strips, potentially offering a fast and practical alternative to residual stress depth profiling. SMT data analysis provides a framework for relating Almen gauge height …

A Novel Scaffold-Based Model For Stage Ii Pressure Injury Simulation: Protocol Development And Future Directions In Tissue Engineering, Skyler B. Wrubleski

Undergraduate Research and Scholarship Symposium

This study developed a 3D tissue-engineered scaffold to mimic human sacral skin for modeling pressure injuries. The scaffold consisted of a composite hydrogel of sodium alginate, gelatin, and tannic acid, crosslinked with calcium chloride. Swelling tests showed moderate hydration capacity, while wound mimic formation using a custom 3D-printed apparatus produced consistent morphology and dimensions comparable to human dermal tissue. The scaffold maintained structural integrity under prolonged compressive forces, demonstrating viability for pressure injury studies. Future work will incorporate a bilayer model with keratinocytes and fibroblasts and introduce elastin to enhance elasticity and mechanical properties. This approach aims to improve in …

Fourier Analyses Of Optical Profilometry As An Inferential Measurement For Impact Coverage., Langdon Feltner, Paul Mort

15th International Conference on Shot Peening

A critical consideration in peening process design is achieving sufficient impact coverage. Conventional methods for assessing coverage rely on manual inspection, which is time-consuming and poorly suited for automated control. In this work, we investigate the use of frequency-domain analysis to quantify surface modification in peened samples using optical profilometry (OP) data. Three-dimensional surface maps of Almen strips were acquired using a high-resolution OP system and analyzed via fast Fourier transform (FFT) to compute spatial power spectral densities (PSDs). PSD maps and radially averaged profiles reveal consistent amplification of harmonic components similar to the nominal particle size, with increasing intensity …

Enhancing High Cycle Fatigue Perfomance Of Electron Beam Melted Ti6al4v: A Study On Shot Peening And Hot Isostatic Pressing, Naghmeh M. Mojib, Dwayne D. Arola, Ramulu Mamidala

15th International Conference on Shot Peening

The qualification of electron beam powder bed fusion (PBF-EB) for safety-critical applications is hindered by variability in high cycle fatigue performance, largely due to surface roughness and internal defects. While Hot Isostatic Pressing (HIP) effectively reduces internal porosity, it does not address surface-initiated fatigue failures. This study investigated the combined effects of HIP and shot peening on enhancing the fatigue performance of PBF-EB Ti6Al4V. Over 50 specimens, including both vertical and horizontal build orientations, underwent high cycle fatigue testing per ASTM E466. X-Ray computed tomography confirmed decrease in defect distribution following HIP, while shot peening resulted in a more uniform …

Comparison Of Peening Effect Between Additive Manufacutred And Drawing Titanium Alloy, Hitoshi Soyama

15th International Conference on Shot Peening

Although additively manufactured (AM) metals are attractive materials, their remarkable weak fatigue properties are an obstacle to their practical application. Thus, post-processing to improve their fatigue properties is required. In the present study, powder bed fusion using laser sintering titanium alloy, i.e., PBF-LS/Ti6Al4V was treated by shot peening (SP), submerged laser peening (SLP), cavitation peening (CP), and fine particle bombarding (FPB), then the fatigue properties were investigated by a torsional fatigue test, comparing with drawing Ti6Al4V. It was revealed that the fatigue strength at 10⁷ was 446 ± 5 MPa for PBF-LS/Ti6Al4V treated by FPB+CP, 359 ± 9 MPa …

Improvement Of The Fatigue Behaviour Of Additive Manufatured Scalmalloy By Using Surface Improvement Processes, Francisco José Boby Alcaide, Irene Eras, José Manuel De Los Santos, Alejandro Munoz Castro, Antonio Perinan Butrón, Jorge Sogorb

15th International Conference on Shot Peening

The use of light metals such as Aluminum alloys has experienced a remarkable increase for the additive manufacturing (AM) industry, especially in aerospace.

AM Scalmalloy®. (an Al-Mg-Sc alloy) shows outstanding behavior with much higher mechanical performance with respect to other alloys for powder bed fusion laser-based (PBF-LB) process like AlSi10Mg or AlSi7Mg. Recent studies have mainly focused on static loading, with minor attention to cyclic loading despite its vital importance in many applications.

In this work, the fatigue performance of PBF-LB Scalmalloy was investigated considering the effects of surface treatments to identify the set of optimal post-processes. Shot peening with …

Influence On Shot Peening And Blast Polishing For Rotating Bending Fatigue Strength Of Vacuum Carburized Steel With Circumferential Notch, Yuji Kobayashi, Hayato Taniguchi, Kiyotaka Masaki

15th International Conference on Shot Peening

In order to improve fuel efficiency in automobiles, weight reduction is necessary as well as improving engine efficiency. For transmission gears, thickness reduction is necessary for weight reduction. When the thickness is reduced, the cross-sectional area becomes smaller, and the load stress increases. Therefore, higher fatigue strength is required. Most gears carry out carburizing. Shot peening is often used to improve the fatigue strength of carburized heat-treated parts. After shot peening, compressive residual stress is introduced, but at the same time, surface roughness is increased. Therefore, the processing conditions of shot peening are very important. Blast polishing is a processing …

Reduced Order Approach For Peening Stress Field Variability, Langdon Feltner, Paul Mort

15th International Conference on Shot Peening

A common goal in shot peening research is to connect operational parameters to resultant residual stress fields, providing a means to control and optimize the effectiveness of surface treatment. In practice, experimental measurements of residual stresses are often averaged values over regions that are large in comparison to an impact dimple. In fact, the stochastic nature of impact locations leads to residual stress fields that are distributed. Finite element peening simulations confirm this observation. The goal of this report is to connect operational parameters to localized fluctuations in residual stress through probabilistic reasoning (Figure 1). In particular, the development of …