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Electrical Resilience In Water Treatment Plants: An Extreme Weather And Lightning Protection Study, Genesis Martinez May 2026

Electrical Resilience In Water Treatment Plants: An Extreme Weather And Lightning Protection Study, Genesis Martinez

Theses and Dissertations

Water treatment plants (WTPs) are vital infrastructure systems that depend on sensitive electrical, electronic, and control equipment to ensure the continuous supply of safe drinking water and effective wastewater treatment. As global temperatures rise and climate change accelerates, the frequency and intensity of extreme weather events—such as hurricanes, flooding, and increased lightning activity—are becoming more pronounced. These events pose significant risks to the electrical resilience of water treatment facilities, often leading to power outages, equipment failures, grid instability, and prolonged service disruptions. This report explores the impacts of extreme weather, with a particular focus on lightning and electrical surges, on …


From Reactive To Predictive: A Hybrid Trust-Mediated Adoption Framework For Data-Driven Maintenance In Distributed-Authority Aviation Environments, Dustin J. Foote May 2026

From Reactive To Predictive: A Hybrid Trust-Mediated Adoption Framework For Data-Driven Maintenance In Distributed-Authority Aviation Environments, Dustin J. Foote

International Journal of Aviation, Aeronautics, and Aerospace

Modern aviation maintenance operates within increasingly data-intensive technological environments, yet the operational integration of predictive maintenance into routine decision-making remains inconsistent across sectors. Contemporary aircraft incorporate centralized maintenance computers and condition monitoring architectures capable of fault aggregation, exceedance capture, and trend-based data collection. Although prognostics and health management research continues to advance detection and prediction methods, implementation outcomes often depend on factors beyond analytical performance alone.

This paper examines predictive maintenance adoption in distributed-authority aviation environments and argues that constraints emerge less from sensing capability than from organizational structure, decision authority dispersion, and institutional trust dynamics. For purposes of analysis, …


Digital Twin–Oriented Certification Architecture For Advanced Air Mobility, Daniel Pleffken May 2026

Digital Twin–Oriented Certification Architecture For Advanced Air Mobility, Daniel Pleffken

International Journal of Aviation, Aeronautics, and Aerospace

Advanced Air Mobility (AAM) systems introduce certification challenges associated with distributed propulsion, increasing software reliance, and tightly coupled architectures. These characteristics evolve within regulatory environments that are still adapting to emerging vehicle concepts. While digital engineering practices are increasingly adopted during system development, certification workflows remain largely document-centric, limiting lifecycle traceability and consistent reasoning about change impacts as designs and regulatory interpretations evolve. This paper proposes a Digital Twin–oriented certification architecture that integrates regulatory knowledge, system representations, Means of Compliance (MoCs), and verification artifacts within a unified model-based environment. The architecture is organized around four elements: regulatory structuring, Model-Based Systems …


Design And Development Of A Passive Dust Protection System For Lunar Docking Operations, Simon Thengvall May 2026

Design And Development Of A Passive Dust Protection System For Lunar Docking Operations, Simon Thengvall

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Lunar docking systems face a unique set of environmental conditions that can create significant challenges for mechanical design. Among these, the abrasive nature of lunar regolith can impair the kinematic function of traditional terrestrial mechanisms as well as contaminate critical spacecraft components such as environmental seals, causing them to fail. For crew-rated docking systems, failure of these systems not only threatens mission success, but also crew safety, so dust protection is crucial for docking components. To address the concerns of regolith intrusion, the Simple External Attachment for Lunar Openings (SEALO) is developed as a key architecture for mechanism evaluation when …


Investigation Of Low-Pressure Mercury Lamp System Configurations And Xenon Excimer Lamp System Development As Vacuum Ultraviolet Sources For Optimal Photolytic Degradation Of Poly-/Perfluoroalkyl Substances, Eman Zuhair Alhamdan May 2026

Investigation Of Low-Pressure Mercury Lamp System Configurations And Xenon Excimer Lamp System Development As Vacuum Ultraviolet Sources For Optimal Photolytic Degradation Of Poly-/Perfluoroalkyl Substances, Eman Zuhair Alhamdan

All Dissertations

PFAS are persistent synthetic chemicals, with unique properties that enable them to easily enter and accumulate in water sources. Their public health impacts have raised concern and highlighted the need for effective treatment. Numerous techniques for PFAS removal from water have been studied, few have proven the ability of breaking down PFAS rather than separating and concentrating it. Many of these methods are chain-length dependent, showing slower degradation rate of short-chain PFAS and requiring substantial amounts of energy, and chemical agents that may produce byproducts.

Among available PFAS destruction methods, direct photolysis by high-energy UV with wavelength below 200 nm …


Learning Global Context For Sparse Activity Recognition In Lengthy Recordings With Limited Dataset Size, Zeyu Tang May 2026

Learning Global Context For Sparse Activity Recognition In Lengthy Recordings With Limited Dataset Size, Zeyu Tang

All Dissertations

This dissertation describes methods to analyze lengthy recordings of data in order to detect sparsely occurring activities. The narrative below describes the progression of research that led to the development of these methods and their generalization into a unified framework. My research started with designing models for dietary monitoring, including detecting meals from day-long recordings and detecting intake gestures from meal-length recordings. Both tasks share some common characteristics: (a) the target event takes only a small portion of data recordings, and (b) there is global context within full-length data recordings that can help a model make better decisions. After finishing …


Experimental And Computational Investigation Of The Effects Of Neck Musculature During Head Impacts In American Football, Anthony P. Marino May 2026

Experimental And Computational Investigation Of The Effects Of Neck Musculature During Head Impacts In American Football, Anthony P. Marino

All Dissertations

Anthropometric test devices (ATDs) are human surrogate models used to represent the human body response in the context of compliance and safety testing. These devices are used in multiple industries, including automotive and aerospace, and have recently been incorporated into impact testing for the evaluation of helmet performance in American football. The Hybrid III 50th percentile male ATD head and neck assembly is the most commonly used surrogate for these tests, although it was developed for automotive frontal crash scenarios that induce an inertial force on the body, leading to head and neck motion primarily in the sagittal plane. …


Versatile Exoskeleton Control Paradigms For Agile Human Locomotion: Task-Agnostic And Stability-Augmented Assistance, Miao Yu May 2026

Versatile Exoskeleton Control Paradigms For Agile Human Locomotion: Task-Agnostic And Stability-Augmented Assistance, Miao Yu

All Dissertations

Lower-limb exoskeletons have shown great potential for assisting human locomotion, but designing controllers that provide assistance across diverse locomotor tasks and under external perturbations remains a major challenge. Many existing controllers for steady-state walking rely on pre-defined reference trajectories, which constrain voluntary human motion and limit adaptability across tasks. Moreover, they usually assume stable walking, while their performance under unstable conditions remains largely unexplored. In addition, existing gait stability augmentation controllers are often reactive rather than proactive to unstable conditions. In this dissertation, we propose control frameworks that preserve voluntary human motion while addressing two major challenges: providing task-agnostic assistance …


Quantifying The Value Of Adaptability: Bridging Real Options Analysis And Adaptable Building Design, Miranda Grice May 2026

Quantifying The Value Of Adaptability: Bridging Real Options Analysis And Adaptable Building Design, Miranda Grice

All Dissertations

As the demands of the built environment continually evolve, buildings are expected to meet changing occupancy needs, or otherwise they become obsolete. Despite positive research on the benefits of adaptable building design, there is a knowledge gap regarding the long-term economic benefits of these designs. Practical methods are needed to determine if premium costs associated with adaptable designs are justified by the economic benefits inherent in adaptability. Therefore, this dissertation provides a discussion on the application of the financial theory of options analysis to the design of adaptable buildings. Additionally, a model and accompanying tool are presented as a solution …


Decision Making For Large-Scale Problems Under Uncertainty And Conflict, Benjamin J. Hamlin May 2026

Decision Making For Large-Scale Problems Under Uncertainty And Conflict, Benjamin J. Hamlin

All Dissertations

Large-scale decision-making problems appear in many areas including long-range forecasting such as energy generation forecasting. Many such problems are subject to conflicting objectives and uncertain data, and can be modeled as linear optimization problems. We study novel theoretical results and algorithms for large-scale linear decision problems under conflict and uncertainty. First, we propose a parametric Benders decomposition algorithm for solving large-scale linear optimization problems with multiple objectives or deterministically uncertain objectives. Second, we extend the parametric Benders decomposition to a multi-stage setting, developing a parametric stochastic dual dynamic programming algorithm, which enables decision-making when conflicts and uncertainty have planning impacts …


Modernizing Plastics And Composites Manufacturing Using Hybrid Modeling Techniques, Luke Shannon May 2026

Modernizing Plastics And Composites Manufacturing Using Hybrid Modeling Techniques, Luke Shannon

All Dissertations

Plastics and composites manufacturing encompasses a broad family of processes, including injection molding, resin transfer molding, compression molding, and extrusion, that together account for the vast majority of polymer and composite component production worldwide. These processes are inherently challenging due to the multi-physics nature of polymer processing, the vast possible combinations of resins, reinforcements, and additives, and the strong dependence of final part properties on process history. Among these processes, injection molding is one of the most widely deployed, producing high-volume components across automotive, medical, consumer electronics, and packaging industries. However, accurately monitoring and predicting process behavior in injection molding …


Optimal Allocation Of Flexible Servers In Healthcare Systems, Tong Zhang May 2026

Optimal Allocation Of Flexible Servers In Healthcare Systems, Tong Zhang

All Dissertations

This dissertation investigates the optimization of worker allocation in healthcare systems, focusing on flexible staffing models and the strategic prioritization of healthcare tasks. This research explores the dynamics among pre-operative, operative, and post-operative care units under various cost and service-rate constraints, using a series of models that represent realistic healthcare scenarios within a comprehensive framework for improving patient flow and reducing waiting costs.

In Chapter 2, we model and analyze cross-trained nurse allocation policies within an inpatient surgical system. We model the surgical system as a tandem clearing queueing system and formulate Markov decision processes under different business rules governing …


Development Of A Mixing-Controlled Combustion Model For 0d Engine Modeling: Using High-Order Models To Guide The Formulation Of Reduced-Order Models, James Gohn May 2026

Development Of A Mixing-Controlled Combustion Model For 0d Engine Modeling: Using High-Order Models To Guide The Formulation Of Reduced-Order Models, James Gohn

All Dissertations

Vehicles are becoming increasingly complex to comply with the increasingly stringent regulations placed on all market sectors while still maintaining performance requirements. This increased complexity leads to increases in the cost and time it takes to develop and produce these next generation vehicles. To meet demand therefore, it becomes necessary to evaluate numerous design iterations using computer models. There are multiple levels of models that may be necessary for different purposes or use cases. All levels of modeling for virtual prototyping, however, require a level of validation and predictive ability to be useful. To this end, the following thesis presents …


Multiscale Architecture Governs Stability In Suction-Actuated Variable Stiffness Catheters, Sheridan Lee May 2026

Multiscale Architecture Governs Stability In Suction-Actuated Variable Stiffness Catheters, Sheridan Lee

McKelvey School of Engineering Graduate Student Theses & Dissertations

Endovascular procedures require devices with widely varying mechanical properties: flexibility for navigating tortuous vessels and rigidity for stable therapeutic delivery. Suction-actuated variable stiffness sheaths address this challenge by incorporating axial wire string arrays that mechanically couple under suction to increase flexural rigidity. However, prototype devices achieve stiffening ratios below theoretical predictions, suggesting that interlayer mechanics and string positioning play a critical role. This study investigates whether interweaving polytetrafluoroethylene (PTFE) tape within the string array enhances flexural rigidity modulation and curvature stability. Prototype devices with varying wrap configurations were fabricated and evaluated using flexural testing, curvature stability testing, and mathematical modeling. …


Computational Fluid Dynamics (Cfd)-Based Performance Prediction Of Transcatheter Microvascular Plugs In Single-Ventricle Patients, Zhuhuan Zou May 2026

Computational Fluid Dynamics (Cfd)-Based Performance Prediction Of Transcatheter Microvascular Plugs In Single-Ventricle Patients, Zhuhuan Zou

McKelvey School of Engineering Graduate Student Theses & Dissertations

Transcatheter palliation using fenestrated Modified Micro Vascular Plugs (MVP) has emerged as a promising, minimally invasive alternative to surgical pulmonary artery banding (PAB) for high-risk neonates with single-ventricle physiology. However, clinical applications are currently limited by the difficulty in predicting the resulting pulmonary-to-systemic flow ratio () and the lack of a standardized approach for selecting the optimal fenestration size. This study utilizes patient-specific computational fluid dynamics (CFD) to quantitatively evaluate the impact of varying fenestration diameters on circulatory balance. Patient-specific 3D models of the pulmonary artery (PA) were reconstructed from imaging data for two clinical cases using SimVascular. Transient CFD …


Design Of An Extensible And Scalable Data Acquisition System For Pulse Shape Discrimination, Prince John May 2026

Design Of An Extensible And Scalable Data Acquisition System For Pulse Shape Discrimination, Prince John

McKelvey School of Engineering Graduate Student Theses & Dissertations

This thesis presents the design and development of a highly scalable, end-to-end data acquisition (DAQ) system for nuclear physics experiments that can be deployed in configurations ranging from a few to thousands of detector channels. The system is built as an extensible platform composed of modular 16-channel chipboards that support a wide range of scintillator and detector types and perform real-time, on-board data sparsification and pulse-shape processing. Three versions of the chipboard have been fabricated to date.

The DAQ architecture is based on a family of analog pulse-shape-processing application- specific integrated circuits (ASICs) developed by the IC Design Laboratory at …


Conditioning Hierarchical Diffusion Transformers On Rf Circuit Parameters, Ethan Morton May 2026

Conditioning Hierarchical Diffusion Transformers On Rf Circuit Parameters, Ethan Morton

McKelvey School of Engineering Graduate Student Theses & Dissertations

As modern ML techniques have become increasingly advanced, they have begun to be integrated into wireless RF systems for classification, identification, and spectrum management. Deep Neural Networks (DNNs) enable RF system operators and designers to design more flexible systems with greater robustness to errors and attacks. However, neural networks require significant amounts of properly annotated data to train. Current data labeling methods lack the ability to obtain reliable true labels for circuit properties such as carrier frequency offset (CFO), power amplifier (PA) non-linearity, and in-phase/quadrature (IQ) imbalance. This thesis investigates the efficacy of a novel architecture, RF-Diffusion, for generating high-quality …


Thermo-Hydro-Chemical Coupled Numerical Modeling Of Hydrogen-Thermal Co-Development In Hydraulically Fractured Peridotite, Jiacheng Dai, Zhonglin Ma, Yunzhi Yue, Yujie Yuan, Shouceng Tian May 2026

Thermo-Hydro-Chemical Coupled Numerical Modeling Of Hydrogen-Thermal Co-Development In Hydraulically Fractured Peridotite, Jiacheng Dai, Zhonglin Ma, Yunzhi Yue, Yujie Yuan, Shouceng Tian

Research outputs 2022 to 2026

Hydrogen generation through serpentinization reactions in peridotite formations under high temperature conditions represents a promising avenue for subsurface hydrogen production. However, the thermal energy in the formation environment have not been sufficiently considered. To integrate hydrogen production with thermal energy development, this study develops a thermo-hydro-chemical coupled numerical model, which is used to investigate hydrogen-thermal co-development in hydraulically fractured peridotite. Given that the hydrogen-thermal co-development process involves fluid flow, heat transfer and serpentinization reactions, the governing equations are formulated based on Darcy flow and energy conservation equations, with serpentinization kinetics incorporated through the reactive source terms. To evaluate hydrogen production …


Enameling Coating Of Pipes: Thermal Proprieties And Corrosion Tests, Signo Reis, Genda Chen, Mike Koenigstein, Liang Fan May 2026

Enameling Coating Of Pipes: Thermal Proprieties And Corrosion Tests, Signo Reis, Genda Chen, Mike Koenigstein, Liang Fan

Materials Science and Engineering Faculty Research & Creative Works

Enamel coating on pipelines can be done in several ways such as the wet process, plasma spray, and electrostatic process. Wet process requires little capital expenses and provides an acceptable finish for industrial applications particularly when the part to be coated is small. Electrostatic process of enamel powder is most promising to coating large pipelines in field conditions. The enamel coating applied by the electrostatic process is very consistent and smooth since each particle is glass only. However, the powder is very fragile until fired and the charge retention is lowered in high humidity conditions. Coupons cut from a full-size …


A Federated Learning Framework For Data-Sovereign Predictive Maintenance In Distributed Smart Manufacturing, Md Sazol Ahmmed, Sriram Praneeth Isanaka, Frank Liou May 2026

A Federated Learning Framework For Data-Sovereign Predictive Maintenance In Distributed Smart Manufacturing, Md Sazol Ahmmed, Sriram Praneeth Isanaka, Frank Liou

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Featured Application: The proposed federated learning framework can be applied in distributed smart manufacturing environments where multiple factories or production facilities collaboratively develop predictive maintenance models without sharing sensitive operational data. This approach is particularly useful for industrial networks involving geographically distributed plants, contract manufacturing partners, and multi-site production systems where data sovereignty and avoidance of raw data sharing are critical. Predictive maintenance enables early detection of machine failures and reduces unexpected production downtime. However, conventional approaches typically rely on centralized data collection and model training which introduce challenges related to data sovereignty, communication overhead and data ownership. To address …


A Critical Review And Methodological Recommendations For Life Cycle Assessment Of Electrochemical Co₂ Mineralization, Dennis Dadzie, Kwame Awuah-Offei May 2026

A Critical Review And Methodological Recommendations For Life Cycle Assessment Of Electrochemical Co₂ Mineralization, Dennis Dadzie, Kwame Awuah-Offei

Mining Engineering Faculty Research & Creative Works

Purpose: While researchers have relied on life cycle assessments (LCAs) to make claims about the environmental benefits of electrochemical CO₂ mineralization, no systematic review literature exists that synthesizes what we know about the LCA of electrochemical mineralization. This review aims to synthesize established knowledge on the LCAs of electrochemical CO₂ mineralization studies, identify research gaps and discuss challenges, and suggest guidelines for applying the ISO 14040/14044 LCA methodology in this sector. Methods: This paper undertook a comprehensive review of LCA studies on CO₂ mineralization with emphasis on electrochemical mineralization. We utilized relevant keywords based on the theme to search in …


A Comparative Analysis Of Macro-Scale And Micro-Scale Pcswmm Models For Urban Flood Simulation In The Ormond Drainage System, Binit Gautam May 2026

A Comparative Analysis Of Macro-Scale And Micro-Scale Pcswmm Models For Urban Flood Simulation In The Ormond Drainage System, Binit Gautam

LSU New Orleans Theses and Dissertations

This research utilized an existing SWMM modeling framework of the Ormond area within St. Charles Parish, Louisiana. A micro scale PCSWMM model was updated using GIS Derived values for CN, percent imperviousness, and subcatchment slope and compared to an macro-scale model. Models were compared under several storm events, which included the recent May 14, 2020 storm as well as 2-, 10-, and 100-year design storms. Peak flow, total inflow volume, and hydrograph characteristics were analyzed to assess response of each model.

The results show that the macro-scale model generally produces higher peak flows and total volumes, while the micro-scale model …


Effect Of Environmental Conditions On Fracture Of Composite Materials And Thin Films, Victor Birman May 2026

Effect Of Environmental Conditions On Fracture Of Composite Materials And Thin Films, Victor Birman

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Environmental conditions, i.e., temperature and moisture, affect mechanical properties of materials, including composites. In this paper, we concentrate on one of the aspects of the effect of environment on fracture in a composite lamina. The paper demonstrates an analytical approach to account for the effect of the changes in environment on the strain energy release rate of composite materials and thin films. These analytically determined strain energy release rates should be compared to fracture toughness to predict the susceptibility of the material to fracture. Numerical examples are presented for several polymeric and metal matrix composites using available experimental data for …


Validity Of The Schrage Equation In Prediction Of Evaporation Rate Of Liquid N-Dodecane In High-Pressure Nitrogen Gas: A Molecular Dynamics Study, Wazih Tausif, Jordan Hartfield, Md Amin Haque, Zhi Liang May 2026

Validity Of The Schrage Equation In Prediction Of Evaporation Rate Of Liquid N-Dodecane In High-Pressure Nitrogen Gas: A Molecular Dynamics Study, Wazih Tausif, Jordan Hartfield, Md Amin Haque, Zhi Liang

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Evaporation of liquid fuel in a high-pressure air is a process that critically influences fuel–air mixing in advanced propulsion systems. In this work, we use molecular dynamics (MD) simulations to study the validity and accuracy of the Schrage equation in quantifying the evaporation and condensation rates of n-dodecane (a diesel surrogate) in air (approximated as N2 gas) with gas pressure varying from 0 atm to above the critical pressure of n-dodecane. The MD simulation results show that the evaporation coefficient (αe) is higher than the condensation coefficient (αc) at the evaporating n-dodecane surface and is lower than αc at the …


Machine Vision For In Situ Measurement And Control Of Wire Stickout In Lwded Process, Braden Mclain, Remy Mathenia, Todd Sparks, Frank Liou May 2026

Machine Vision For In Situ Measurement And Control Of Wire Stickout In Lwded Process, Braden Mclain, Remy Mathenia, Todd Sparks, Frank Liou

Mechanical and Aerospace Engineering Faculty Research & Creative Works

This work presents a machine-vision–based measurement and control framework for laser wire directed energy deposition (LWDED) processes. A visible-light camera system is used to capture meltpool images, from which a novel vision algorithm extracts the wire–meltpool interface location. By utilizing a camera that is rigidly mounted to the deposition head, the vision algorithm provides a relative measurement of the distance between the nozzle tip and the workpiece, also referred to as wire stickout. A proportional-derivative (PD) control strategy is implemented using the measured stickout as feedback to adjust deposition feedrate. Results show that the control system successfully compensates for improper …


Using Machine-Learning-Based Process Map To Guide Evaluation Of Inconel 625 Mechanical Properties In Laser Foil Printing, Yu Hsiang Wang, Sung Heng Wu, Hung Chu Chiang, Pen Ning Yu, Chia Hung Hung, Ming C. Leu May 2026

Using Machine-Learning-Based Process Map To Guide Evaluation Of Inconel 625 Mechanical Properties In Laser Foil Printing, Yu Hsiang Wang, Sung Heng Wu, Hung Chu Chiang, Pen Ning Yu, Chia Hung Hung, Ming C. Leu

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Inconel 625 is widely studied in powder-based additive manufacturing, but its processing characteristics and mechanical performance in foil-feedstock laser foil printing (LFP) remain largely unexplored. In this study, a gradient boosting regression (GBR)-based process map was developed for LFP of Inconel 625 using 32 single-track experiments. The GBR model achieved R2 values of 0.859 and 0.793 and mean absolute errors of 22.25 μm and 19.83 μm for melt-pool depth and width, respectively, outperforming second- and third-order polynomial regressions in capturing nonlinear melt-pool responses and distinguishing lack-of-fusion, conduction, and keyhole regimes. Three conduction-mode conditions with target depth-to-foil thickness ratios (D/T) …


Evaluation Of Iron-Phosphate Glass–Ceramic Waste Form For Electrorefiner Salt Waste Simulant Dechlorinated With Phosphoric Acid, Harmony Werth, Paige Murray, Lucas Greiner, Jade Beland, Charmayne Lonergan, Brian Riley, Krista Carlson May 2026

Evaluation Of Iron-Phosphate Glass–Ceramic Waste Form For Electrorefiner Salt Waste Simulant Dechlorinated With Phosphoric Acid, Harmony Werth, Paige Murray, Lucas Greiner, Jade Beland, Charmayne Lonergan, Brian Riley, Krista Carlson

Materials Science and Engineering Faculty Research & Creative Works

The importance of glass and glass–ceramic nuclear waste forms has been reaffirmed in recent years by the growing interest in nuclear power as a reliable energy source. Determination of processing methods for the disposal of halide-containing wastes will be essential for the advancement of nuclear technologies such as non-aqueous fuel reprocessing. Phosphate-based dechlorination and subsequent vitrification of radioactive salt waste into an iron-phosphate waste form have been identified as a potential processing scheme for electrochemical processing waste. The impact of H3PO4-based dechlorination of complex salt mixtures on the vitrification process and structure of the final iron-phosphate …


Effect Of Composition On Grain-Boundary Chemistry And Fracture Behavior In High-Entropy Carbides, Caleb Schenck, Marium Mostafiz Mou, Elizabeth Pritchett, Fu Yun Tsai, Josephine Hartmann, Michael Lastovich, Sam Daigle, Kayla Yano, Matthew J. Olszta, Sanjit Bhowick, Elizabeth Kautz, Gregory E. Hilmas, William G. Fahrenholtz, Donald W. Brenner May 2026

Effect Of Composition On Grain-Boundary Chemistry And Fracture Behavior In High-Entropy Carbides, Caleb Schenck, Marium Mostafiz Mou, Elizabeth Pritchett, Fu Yun Tsai, Josephine Hartmann, Michael Lastovich, Sam Daigle, Kayla Yano, Matthew J. Olszta, Sanjit Bhowick, Elizabeth Kautz, Gregory E. Hilmas, William G. Fahrenholtz, Donald W. Brenner

Materials Science and Engineering Faculty Research & Creative Works

High-entropy carbides (HECs) are often treated as a single material class defined by configurational entropy; however, their properties are governed by composition-specific defects and grain-boundary chemistry. This study demonstrates that substituting a single element can qualitatively change grain-boundary structure and fracture behavior in HEC ceramics. Two HECs, (Cr,Hf,Ta,Ti,Zr)C (HEC-Cr) and (Hf,Ta,Ti,W,Zr)C (HEC-W), were examined via electron microscopy, atom probe tomography, and molecular dynamics simulations. Simulations predict preferential segregation of Cr, W, and Zr to grain boundaries. Experiments confirmed Cr enrichment at grain boundaries and the formation of W-rich nanograins along boundary networks. Mechanical testing revealed that these compositional differences translated …


Evaluating The Integration Of Bio-Based Waste Into Cement Production: A Pathway To Sustainable Building, Anja Terzić, Suzana Filipović, Adriana Peleš Tadić, Jelena Živojinović, Ivana N. Jelić, Nina Obradović, William G. Fahrenholtz May 2026

Evaluating The Integration Of Bio-Based Waste Into Cement Production: A Pathway To Sustainable Building, Anja Terzić, Suzana Filipović, Adriana Peleš Tadić, Jelena Živojinović, Ivana N. Jelić, Nina Obradović, William G. Fahrenholtz

Materials Science and Engineering Faculty Research & Creative Works

Rapid urbanization has increased the demand for building materials, depleting natural resources used in cement production and prompting the use of alternative and waste materials. This research verifies that eggshell powder waste can fully replace limestone in clinker synthesis. Five clinkers were produced using eggshell powder, aluminum sources (bentonite, zeolite, fly ash, and kaolinitic–illitic clay), Fe-slag, and quartz sand, with mechanical preprocessing (10–30 min) before sintering at 1300 °C. Experimental tests assessed the effects of mix design and mechanical activation on clinkerization, phase formation, temperature, and mechanical properties. XRD, FTIR, and SEM/EDS confirmed consistent phase compositions and primary cement minerals. …


Selective Extraction Of Nickel And Cobalt From Limonitic Laterite Via Optimized Sulfation Roasting–Water Leaching And Solvent Extraction, Maryam Osali, Farid Ahani, Mohammad Reza Aboutalebi, Mandana Adeli, Javad Moghaddam, Saeid Karimi, Janaka Jayamini Wijenayake, Lana Alagha May 2026

Selective Extraction Of Nickel And Cobalt From Limonitic Laterite Via Optimized Sulfation Roasting–Water Leaching And Solvent Extraction, Maryam Osali, Farid Ahani, Mohammad Reza Aboutalebi, Mandana Adeli, Javad Moghaddam, Saeid Karimi, Janaka Jayamini Wijenayake, Lana Alagha

Mining Engineering Faculty Research & Creative Works

Limonitic laterites typically contain low Ni and Co contents and significant impurities, making the development of technical and economically feasible processes challenging. To address this challenge, this study investigates and evaluates an integrated hydrometallurgical process comprising sulfation roasting, water leaching, and solvent extraction (SX) for the selective recovery of Ni and Co from limonite-type laterite. Response Surface Methodology coupled with a Central Composite Design (RSM-CCD) was employed as a statistical experimental design tool to efficiently optimize the sulfation roasting conditions. Under the optimal sulfation roasting conditions (temperature 703 °C), selective leaching efficiencies of 87.2% for Ni and 96.6% for Co …