Digital Commons Network^™

Investigation Of Pfas Exposure Risks In Kentucky Using Mapping Tools, Sweta Ojha

Theses and Dissertations--Civil Engineering

Per- and polyfluoroalkyl substances (PFAS), a group of environmentally-persistent compounds, are environmentally ubiquitous and challenging to remediate. Several studies show that PFAS are detected in drinking water systems when sampling is conducted, making human exposure via drinking water an important health consideration. This research: 1) develops a mapping tool for prioritizing sampling locations; 2) establishes a method for making GIS data and meta(data) in the mapping tool accessible; 3) fosters decision making by integrating knowledge brokering and the alignment interest and influence matrix (AIIM). The tool developed is this research is a geospatial and statistical PFAS hot-spot screening model that …

Energy And Economic Modeling Of Stillage Dewatering Processes In Kentucky Bourbon Distilleries, William Brennan

Theses and Dissertations--Mechanical and Aerospace Engineering

Stillage is a byproduct of alcohol distillation and must be managed in all distilleries to sustain operations. In the United States, fuel ethanol plants typically convert all stillage into Dried Distillers’ Grains with Solubles (DDGS). This process and its variations are well known. Typical stillage management approaches are not well known, however, for the Kentucky bourbon industry. A survey of stillage management approaches in operational bourbon distilleries was conducted. Process modeling was performed to evaluate the energy and economic considerations of the available stillage dewatering methods for a 7 Million Original Proof Gallon (MMOPG) distillery. Monte Carlo simulations were performed …

Formation Control With Bounded Controls And Collision Avoidance: Theory And Application To Quadrotor Unmanned Air Vehicles, Zachary S. Lippay

Theses and Dissertations--Mechanical and Aerospace Engineering

This dissertation presents new results on multi-agent formation control and applies the new control algorithms to quadrotor unmanned air vehicles. First, this dissertation presents a formation control algorithm for double-integrator agents, where the formation is time varying and the agents’ controls satisfy a priori bounds (e.g., the controls accommodate actuator saturation). The main analytic results provide sufficient conditions such that all agents converge to the desired time-varying relative positions with one another and the leader, and have a priori bounded controls (if applicable). We also present results from rotorcraft experiments that demonstrate the algorithm with time-varying formations and bounded controls. …

Numerical And Scaling Study On Application Of Inkjet Technology To Automotive Coating, Masoud Arabghahestani Dr.

Theses and Dissertations--Mechanical and Aerospace Engineering

A thorough literature review identified lack of precision control over quality of droplets generated by the currently available industrial sprayers and a growing need for higher quality droplets in the coating industry. Particularly, lack of knowledge and understanding in continuous inkjets (CIJ) and drop-on-demand (DOD) technologies is identified as significant. Motivated by these needs, this dissertation is dedicated to computational fluid dynamics (CFD) and scaling studies to improve existing inkjet technologies and develop new designs of efficient coating with single and/or multiple piezoelectric sensors to produce on-demand droplets. This dissertation study aims at developing a new DOD type coating technology, …

The Response Of Beef Cattle To Disturbances From Unmanned Aerial Vehicles (Uavs), Gabriel Abdulai

Theses and Dissertations--Biosystems and Agricultural Engineering

Unmanned aerial vehicles (UAVs) are increasingly becoming common in animal agriculture. However, research regarding the impact of UAV disturbance on animal wellbeing is lacking or limited. The goal of this study was to investigate the effect of UAV flights on beef cattle by measuring cattle heart and movement rate when introduced to single or multiple UAV flights. A total of 16 -18 crossbred beef heifers were introduced to different flights patterns at between 5 and 9 m above ground level (AGL) at approximately 1 to 2 m/s horizontal velocity for 4 weeks with flights repeated 3 days per week. Results …

Lignin Valorization Via Reductive Depolymerization Using Promoted Nickel Catalysts And Sub- And Supercritical Methanol, Julia Parker

Theses and Dissertations--Biosystems and Agricultural Engineering

While lignin has been regarded as the most promising renewable feedstock for the sustainable manufacture of aromatic compounds, lignin valorization is necessary to improve the economic viability of biorefineries. Reductive catalytic fractionation (RCF), which combines delignification and lignin depolymerization into a single stage while maintaining the structure and integrity of the cellulose component, has evolved as an effective method for processing biomass. The ability of Cu and Fe to promote the performance of a 20% Ni/alumina catalyst when converting native lignin to alkylphenols by RCF in sub- and supercritical methanol was tested. The effectiveness of lignin extraction as measured by …

Sediment Nitrogen Dynamics In Backwater Wetland Confluences Of A Regulated River, Gina Degraves

Theses and Dissertations--Biosystems and Agricultural Engineering

As harmful algal blooms in regulated river systems have increased in the past decade, the importance of understanding sediment nutrients has also increased. Research linking nutrient processes and fine sediment dynamics to harmful algal blooms in confluence wetlands along regulated rivers has recently become apparent. However, the relationship between sediment nutrient dynamics in confluence wetlands has been understudied. Utilization of sediment fingerprinting, high-frequency water quality monitoring, and tracer unmixing mass-balance modeling, was able to suggest sediment N mineralization in Appalachia confluence riparian wetland was not a dominate source of nitrate downstream. Further measures of supplementary tracers and additional sediment sources …

Classifying And Mapping Aquatic Vegetation In Heterogeneous Stream Ecosystems Using Visible And Multispectral Uav Imagery, Rozalia Agioutanti

Theses and Dissertations--Biosystems and Agricultural Engineering

The need for assessment and management of aquatic vegetation in stream ecosystems is recognized given the importance in impacting water quality, hydrodynamics, and aquatic biota. However, existing approaches to monitor are laborious and its currently not feasible to track spatial and temporal differences at broad scales. The objective of this study was therefore to map and classify aquatic vegetation of a shallow stream with heterogenous mixtures of emergent and submerged aquatic vegetation. Data was collected in the Camden Creek watershed within the Inner Bluegrass Region of central Kentucky. The use of unmanned aerial vehicles (UAVs) was employed and both visible …

Exploration Of Lignin-Based Superabsorbent Polymers (Hydrogels) For Soil Water Management And As A Carrier For Delivering Rhizobium Spp., Toby Adjuik

Theses and Dissertations--Biosystems and Agricultural Engineering

Superabsorbent polymers (hydrogels) as soil amendments may improve soil hydraulic properties and act as carrier materials beneficial to soil microorganisms. Researchers have mostly explored synthetic hydrogels which may not be environmentally sustainable. This dissertation focused on the development and application of lignin-based hydrogels as sustainable soil amendments. This dissertation also explores the development of pedotransfer transfer functions (PTFs) for predicting saturated hydraulic conductivity using statistical and machine learning methods with a publicly available large data set. A lignin-based hydrogel was synthesized, and its impact on soil water retention was determined in silt loam and loamy fine sand soils. Hydrogel treatment …

A Unified Health Information System Framework For Connecting Data, People, Devices, And Systems, Wu He, Justin Zuopeng Zhang, Huanmei Wu, Wenzhuo Li, Sachin Shetty

Information Technology & Decision Sciences Faculty Publications

The COVID-19 pandemic has heightened the necessity for pervasive data and system interoperability to manage healthcare information and knowledge. There is an urgent need to better understand the role of interoperability in improving the societal responses to the pandemic. This paper explores data and system interoperability, a very specific area that could contribute to fighting COVID-19. Specifically, the authors propose a unified health information system framework to connect data, systems, and devices to increase interoperability and manage healthcare information and knowledge. A blockchain-based solution is also provided as a recommendation for improving the data and system interoperability in healthcare.

Atmospheric Air Plasma Streamers Deliver Nanosecond Pulses For Focused Electroporation, Shu Xiao, Carol Zhou, Eric Appia, Shirshak Dhali

Bioelectrics Publications

Background: For electrotherapies that involve electrodes and high-intensity electric fields, such as in tissue ablation, we report a method of pulse delivery that can focus the electric field away from the electrodes, as demonstrated in vitro.

Materials and Methods: To electroporate cells in a monolayer seeded in a 35 mm culture dish, two atmospheric-pressure plasma channels generated by two thin, copper foil electrodes above the surface of the solution provided the current and established the electric field.

Results: Depending on the pulse duration, the plasma channels were observed as corona (100 ns), streamer (300 ns), and mixture of streamer …

Valuable Biodiesel Catalyst From Solvay Wastewater, Mai Hassan Roushdy, Rana Adel Bayoumi

Chemical Engineering

Biodiesel is considered a renewable, green fuel as it is derived from renewable living resources like animal fats or vegetable oils. This research is utilized to investigate the possibility of using Solvay wastewater as a source of biodiesel catalyst, which is CaO. CaCl2 from Solvay wastewater reacts with CO2 to produce CaCO3. CaCO3 is then heated to produce pure CaO. Waste cooking oil, wastewater, and CO2, which are considered dangerous materials to the environment, are used to produce valuable products. This research has environmental and economic benefit benefits of using waste materials as a replacement for raw materials. The selected …

Castor Oil Conversion To Biodiesel: A Process Simulation Study, Yaser M. Asal Mr, Islam M. Al-Akraa, Ahmad M. Mohammad, Razan Aymen

Chemical Engineering

The aim of this study is to highlights the importance to shift from the use of traditional fossil fuels to biodiesel as a clean energy source. A simulation study has been conducted using ASPEN HYSIS software for the biodiesel production form castor oil. The simulation was run and the properties of the produced biodiesel were highlighted. The optimum conditions resulted in 88 % conversion.

Designing The Electrochemical Interface To Enable Lithium Metal Batteries, Supriya Koul

Electronic Theses and Dissertations, 2020-2023

Although Li-ion battery is one of the most widely used energy storage devices, there have been extensive efforts to push its limit to meet the ever-increasing demands to improve its energy density for applications such as electric vehicles, portable electronics, and grid storages. Here, Li metal anode plays a key role in the next generation energy storage devices, ultimately enabling the anode-free configuration. However, there are major challenges that need to be overcome for a successful deployment of anode-free batteries. These include designing a competitive SEI, low Coulombic efficiency, and the formation of dendrites. To realize an effective anode-free configuration …

A Study Of Microgravity On Fluid Transport Through Porous Structures In Microfluidic Devices, Sylvain Le Henaff

Electronic Theses and Dissertations, 2020-2023

The objective of this study is to refine the understanding of micro-fluidics subject to micro-gravity in an attempt to support future space exploration efforts. A combination of experimental and numerical approaches were utilized to build a validated assessment approach. A quasi-pore geometry, inspired by CT scans of rat bones, was used in lieu of human bone structures. A quasi-1D assessment of the conservation of momentum was used to identify the dominant forces acting on the fluid at the operating length-scales. The dominant forces were surface tension, gravity, and shear stress. Experiments were conducted to visualize the flow moving through the …

Collected Papers (On Various Scientific Topics), Volume Xiii, Florentin Smarandache

Branch Mathematics and Statistics Faculty and Staff Publications

This thirteenth volume of Collected Papers is an eclectic tome of 88 papers in various fields of sciences, such as astronomy, biology, calculus, economics, education and administration, game theory, geometry, graph theory, information fusion, decision making, instantaneous physics, quantum physics, neutrosophic logic and set, non-Euclidean geometry, number theory, paradoxes, philosophy of science, scientific research methods, statistics, and others, structured in 17 chapters (Neutrosophic Theory and Applications; Neutrosophic Algebra; Fuzzy Soft Sets; Neutrosophic Sets; Hypersoft Sets; Neutrosophic Semigroups; Neutrosophic Graphs; Superhypergraphs; Plithogeny; Information Fusion; Statistics; Decision Making; Extenics; Instantaneous Physics; Paradoxism; Mathematica; Miscellanea), comprising 965 pages, published between 2005-2022 in different …

Design Of Affordable Polyaniline - Based Wearable Sensor For Real Time Plant Growth Monitoring, Temitope Borode

Electronic Theses and Dissertations

The need for precision agriculture in today and future farming cannot be overstressed. Recent agriculture is characterized by numerous challenges such as environmental stressors and resource constraints resulting in low crop yield and unsustainable agriculture practices. Understanding plant growth mechanism and growth rate under the external influence is a bedrock towards precision agriculture practices ensuring optimum yield and sustainable utilization of resources. The current study addresses this need by developing and applying an affordable and stable sensor for monitoring plant growth. The sensor was fabricated by in-situ chemical polymerization of aniline on an elastic band substrate by dip coating. The …

Optimization Of Electrically Driven Fluid Flow Through Tissue Hydrogels, Joseph C. Walker

Electronic Theses and Dissertations

No abstract provided.

Managing Water Quantity And Quality With Subsurface Drainage In Eastern South Dakota, Morghan Hurst

Electronic Theses and Dissertations

Moisture extremes (excess and deficit) impact crop loss and water quality. Due to excessively wet springs and dry summers, crop damage can occur within the same county or field within the same year. To determine the magnitude of this problem in eastern South Dakota, indemnified crop insurance data for drought and excessive moisture claims were assessed for the years 1991-2020 for the occurrence of both excess moisture and drought in four counties in eastern South Dakota. Results show that there is greater than a 70% chance of the moisture extremes happening in the same year, making subsurface drainage, controlled drainage, …

Gan-Based Super-Resolution And Segmentation Of Retinal Layers In Optical Coherence Tomography Scans, Paria Jeihouni

Graduate Theses, Dissertations, and Problem Reports (ETD)

Optical Coherence Tomography (OCT) has been identified as a noninvasive and cost-effective imaging modality for identifying potential biomarkers for Alzheimer's diagnosis and progress detection. Current hypotheses indicate that retinal layer thickness, which can be assessed via OCT scans, is an efficient biomarker for identifying Alzheimer's disease. Due to factors such as speckle noise, a small target region, and unfavorable imaging conditions manual segmentation of retina layers is a challenging task. Therefore, as a reasonable first step, this study focuses on automatically segmenting retinal layers to separate them for subsequent investigations. Another important challenge commonly faced is the lack of clarity …

Towards A Circular Economy: Liquid-Fed Fast Pyrolysis Of Waste Polyolefin Plastics, Daniel G. Kulas

Dissertations, Master's Theses and Master's Reports

Plastic usage has quickly grown in recent years as plastics have become an essential part of everyday life. Unfortunately, recycling rates have not matched the increased growth, with the majority of waste plastic landfilled. The strategy of circular economy has been proposed to reuse the waste plastic to create new polymers, thus avoiding both landfilling and the use of virgin raw materials. Achieving a circular economy for plastics requires the development of new technologies capable of recycling plastic waste under a circular economy perspective. In this dissertation, a novel liquid-fed fast pyrolysis process is introduced towards achieving a circular economy. …

Collective Hydrodynamics Of Robotic Fish, Rohit S. Pandhare

Dissertations, Master's Theses and Master's Reports

Many animals in nature travel in groups either for protection, survival, or endurance. Among these, fish do so under the burden of hydrodynamic loads, which incites questions as to the significance of the multi-body fluid-mediated interactions that facilitate collective swimming. We study such interactions in the idealized setting of a rotational array of robotic fish whose tails undergo a prescribed flapping motion, but whose swimming speed is determined as a natural result of the hydrodynamic effects. Specifically, we examine how the measured collective speed of the swimmers varies with the imposed frequency and amplitude of their tail flapping, and with …

An Analysis Of Compressive Convolutional Autoencoders For Image Archiving In Medical Informatics, Charles Warren

Dissertations, Master's Theses and Master's Reports

Within a given enterprise network, an array of data types needs to be communicated. These network transmissions consist of images, videos, text, and binaries that have unique requirements of bandwidth and computational overhead to transmit. With respect to medical informatics, these include a multitude of varying subjects, standards, and modalities which are communicated to and from imaging equipment, clinicians, and medical archives. To reduce the required bandwidth to transmit, or provide adequate storage capacity for archival purposes, the data may be compressed in such a way that reduces the size of the image when it is transferred or stored. The …

An Antimicrobial Polydopamine Surface Coating To Reduce Biofouling On Telemetry Tags Used In Marine Conservation Practices, Ariana Smies

Dissertations, Master's Theses and Master's Reports

Satellite telemetry tags are used to track the migration patterns of large cetaceans. These tags penetrate the dermis and remain embedded in the underlying blubber tissue. As the dermis of cetaceans is host to a diverse microbiome, and it is impossible to clean the skin before implanting the devices, the potential for infection is increased when the tags penetrate through the skin. H₂O₂ is a potential antimicrobial agent that, in addition to showing broad-spectrum efficacy against gram-negative and gram-positive bacteria, can promote wound healing outcomes by promoting proliferative factors and peptides that protect against oxidative stress. However, …

The Design Of Cmos Front-End Amplifiers For Electrical Impedance Applications, Yueh-Ching Teng

Dartmouth College Ph.D Dissertations

Electrical Impedance Tomography (EIT) is a medical imaging methodology that does not need any kind of ionizing radiation. It is significantly cheaper and smaller than Computerized Tomography (CT) or Magnetic Resonance Imaging (MRI). These advantages make EIT particularly suitable for emerging applications like the continuous medical imaging and telemonitoring of organ function. Current bench-top EIT systems are bulky and require shielded cables to interface with measurement electrodes. The cable introduces parasitic capacitances which shunt the desired signals and degrade the accuracy of the measurements. A EIT system based on application-specific integrated circuits (ASICs) can reduce the parasitic and stray capacitance …

Phase-Changing Nanodroplets As Nanotheranostic Platform For Combination Cancer Therapy, Catalina-Paula Spatarelu

Dartmouth College Ph.D Dissertations

Cancer is a cluster of diseases, and 1.8 million Americans are newly diagnosed each year. Treatment issues such as drug instability, the occurrence of severe side effects, as well as resistance make the need for solutions to improve conventional methods, like chemotherapy, apparent. Nano-sized drug-delivery platforms, particles loaded with therapeutic molecules that escape the immune system clearance and accumulate at the tumor site, were proposed as one of these solutions. Despite the expansion of the field, several aspects still need to be addressed: inconsistent delivery of the drugs, inability of measuring the effective dose being delivered to the tumor, lack …

Measuring The Physicochemical Properties Of Viral Vectors To Enhance Gene Therapy Production, Oluwatoyin Areo

Dissertations, Master's Theses and Master's Reports

Gene therapy is a therapeutic intervention designed to correct single gene disorders. AAV has been identified as a suitable vector for delivering therapeutic genes. However, the use of AAV has been hampered by manufacturing challenges inclusive of low virus recovery, and the presence of AAV without the gene of interest (empty capsids). To solve these problems, we characterized the charge and hydrophobicity of AAV, and surrogate viruses using chemical force microscopy (CFM). CFM uses a modified atomic force microscope (AFM) probe to measure the adhesion force between a virus particle and a functional chemistry.The virus particles to be measured are …

Framework For The Evaluation Of Perturbations In The Systems Biology Landscape And Inter-Sample Similarity From Transcriptomic Datasets — A Digital Twin Perspective, Mariah Marie Hoffman

Dissertations and Theses

One approach to interrogating the complexities of human systems in their well-regulated and dysregulated states is through the use of digital twins. Digital twins are virtual representations of physical systems that are descriptive of an individual's state of health, an object fundamentally related to precision medicine. A key element for building a functional digital twin type for a disease or predicting the therapeutic efficacy of a potential treatment is harmonized, machine-parsable domain knowledge. Hypothesis-driven investigations are the gold standard for representing subsystems, but their results encompass a limited knowledge of the full biosystem. Multi-omics data is one rich source of …

Nondestructive Multivariate Classification Of Codling Moth Infested Apples Using Machine Learning And Sensor Fusion, Nader Ekramirad

Theses and Dissertations--Biosystems and Agricultural Engineering

Apple is the number one on the list of the most consumed fruits in the United States. The increasing market demand for high quality apples and the need for fast, and effective quality evaluation techniques have prompted research into the development of nondestructive evaluation methods. Codling moth (CM), Cydia pomonella L. (Lepidoptera: Tortricidae), is the most devastating pest of apples. Therefore, this dissertation is focused on the development of nondestructive methods for the detection and classification of CM-infested apples. The objective one in this study was aimed to identify and characterize the source of detectable vibro-acoustic signals coming from CM-infested …

Using Stream Restoration To Mitigate Stormwater Runoff In An Urban Watershed: A Case Study, Jonathan M. Brantley

Theses and Dissertations--Biosystems and Agricultural Engineering

The goal of this case study was to evaluate the effectiveness a 275 m regenerative stream restoration design to mitigate stormwater runoff in a highly urbanized watershed. The restoration resulted in a wide, wetland-like floodplain, comprised of a rock base that was overtopped with a filtration media (approximately 30% woodchips and 70% topsoil). The creation of the floodplain-wetland complex in tandem with filtration media lead to increased storage capacity and an increase in hyporheic exchange within the system. Significant reductions were found for the storm hydrograph parameters volume, peak discharge, and time to peak. Reductions in baseflows were also noted …