Digital Commons Network^™

Evaluation Of Rice Hulls As A Lignocellulosic Substitute In Wood Plastic Composites, P. Jack Bourne

Inquiry: The University of Arkansas Undergraduate Research Journal

Rising raw material costs and shortage of woody materials necessitate alternative sources for lignocellulosic material in wood plastic composites (WPC). This study was conducted to evaluate rice hull (RH), an agricultural residue, as a cellulosic substitute in WPC. Samples were fabricated with approximately 4% zinc stearate, 48% high-density polyethylene obtained from recycled plastics and 48% lignocellulosic material by mass. The composition of the lignocellulosic material was changed from 0 to 100% RH at 20% increments while the remainder was wood flour. The extruded sampled were tested for mechanical properties such as specific gravity, water absorption, linear coefficients of thermal expansion, …

Swarm Intelligence: Theoretical Proof That Empirical Techniques Are Optimal, Dmitry Iourinskiy, Scott A. Starks, Vladik Kreinovich, Stephen F. Smith

Departmental Technical Reports (CS)

A natural way to distribute tasks between autonomous agents is to use swarm intelligence techniques, which simulate the way social insects (such as wasps) distribute tasks between themselves. In this paper, we theoretically prove that the corresponding successful biologically inspired formulas are indeed statistically optimal (in some reasonable sense).

Proposed Evaluation Of Switchgrass Selections For Caddo House Construction, Charles Allen, Sara Thames, Jim Grafton, Bill Welton, Lorene Williams, Katina Mcclure, Darryl Monteau, Phil Cross, Andrew Hamblin, William Meyer

United States Army: Publications

The Caddo Indian tribe’s range was northwest Louisiana, northeast Texas, eastern Oklahoma, western Arkansas, and southwest Missouri. Historical records indicate the use of native switchgrass (Panicum virgatum) in the construction of houses. The frame and stringers for the houses were wood but the entire covering was bundles of switchgrass. In 2005, Fort Polk personnel and faculty and students at Haskell Indian Nations University in Lawrence, Kansas initiated a joint monitoring effort of biological (density, height, seed production), cultural, and other characteristics of switchgrass. Both groups have ongoing field and greenhouse plots with selections of switchgrass from throughout the …

Perchlorate Toxicity And Risk Assessment, David R. Mattie, Joan Strawson, Jay Zhao

United States Air Force: Publications

Ammonium perchlorate is the oxidizer ingredient in solid propellant mixtures for rockets, missiles and munitions such as Titan, Minuteman, Peacekeeper, Hawk, Polaris and the Space Shuttle. Perchlorate salts may also be used in medicine, matches, munitions and pyrotechnics (illuminating and signaling flares, colored and white smoke generators, tracers, incendiary delays, fuses, photo-flash compounds and fireworks). Perchlorate is also found in lubricating oils, finished leather, fabric fixer, dyes, electroplating, aluminum refining, manufacture of rubber, paint and enamel production, as an additive in cattle feed, in magnesium batteries and as a component of automobile air bag inflators.'

Atomic Force Microscopy Of Bacillus Spore Surface Morphology, Ruth A. Zolock, Guangming Li, Charles Bleckmann, Larry Burggraf, Douglas C. Fuller

United States Air Force: Publications

Bacillus spore surface morphology was imaged with atomic force microscopy (AFM) to determine if characteristic surface features could be used to distinguish between four closely related species; Bacillus anthracis Sterne strain, Bacillus thuringiensis var. kurstaki, Bacillus cereus strain 569, and Bacillus globigii var. niger. AFM surface height images showed an irregular topography across the curved upper surface of the spores. Phase images showed a superficial grain structure with different levels of phase contrast and significant differences in average surface morphologies among the four species. Although spores of the same species showed similarities, there was significant variability within each …

Nanoparticle-Induced Negative Differential Resistance And Memory Effect In Polymer Bistable Light-Emitting Device, Ricky J. Tseng, Jianyong Ouyang, Chih-Wei Chu, Jinsong Huang, Yang Yang

Department of Mechanical and Materials Engineering: Faculty Publications

Recently, electrical bistability was demonstrated in polymer thin films incorporated with metal nanoparticles [J. Ouyang, C. W. Chu, C. R. Szmanda, L. P. Ma, and Y. Yang, Nat. Mater. 3, 918 (2004)]. In this letter, we show the evidence that electrons are the dominant charge carriers in these bistable devices. Direct integration of bistable polymer layer with a light-emitting polymer layer shows a unique light-emitting property modulated by the electrical bistability. A unique negative differential resistance induced by the charged gold nanoparticles is observed due to the charge trapping effect from the nanoparticles when interfaced with the light-emitting layer.

Reductive Biotransformation Of Fe In Shale–Limestone Saprolite Containing Fe(Iii) Oxides And Fe(Ii)/Fe(Iii) Phyllosilicates, Ravi K. Kukkadapu, John M. Zachara, James K. Fredrickson, James P. Mckinley, David W. Kennedy, Steven C. Smith, Hailiang Dong

United States Department of Energy: Publications

A <2.0-mm fraction of a mineralogically complex subsurface sediment containing goethite and Fe(II)/Fe(III) phyllosilicates was incubated with Shewanella putrefaciens (strain CN32) and lactate at circumneutral pH under anoxic conditions to investigate electron acceptor preference and the nature of the resulting biogenic Fe(II) fraction. Anthraquinone-2,6-disulfonate (AQDS), an electron shuttle, was included in select treatments to enhance bioreduction and subsequent biomineralization. The sediment was highly aggregated and contained two distinct clast populations: (i) a highly weathered one with ‘‘sponge-like’’ internal porosity, large mineral crystallites, and Fecontaining micas, and (ii) a dense, compact one with fine-textured Fe-containing illite and nano-sized goethite, as revealed by various forms of electron microscopic analyses. Approximately 10–15% of the Fe(III)_TOT was bioreduced by …

Kinetics Of Microbial Reduction Of Solid Phase U(Vi), Chongxuan Liu, Byong-Hun Jeon, John M. Zachara, Zheming Wang, Alice Dohnalkova, James K. Fredrickson

United States Department of Energy: Publications

Sodium boltwoodite (NaUO₂SiO₃OH•1.5 H₂O) was used to assess the kinetics of microbial reduction of solid-phase U(VI) by a dissimilatory metal-reducing bacterium (DMRB), Shewanella oneidensis strain MR-1. The bioreduction kinetics was studied with Na-boltwoodite in suspension or within alginate beads in a nongrowth medium with lactate as electron donor at pH 6.8 buffered with PIPES. Concentrations of U(VI)_tot and cell number were varied to evaluate the coupling of U(VI) dissolution, diffusion, and microbial activity. Microscopic and spectroscopic analyses with transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), and laser-induced fluorescence spectroscopy (LIFS) collectively indicated …

The Effect Of Calcium On Aqueous Uranium(Vi) Speciation And Adsorption To Ferrihydrite And Quartz, Patricia M. Fox, James A. Davis, John M. Zachara

United States Department of Energy: Publications

Recent studies of uranium (VI) geochemistry have focused on the potentially important role of the aqueous species, CaUO₂(CO₃)₃²⁻ and Ca₂UO₂(CO₃)₃⁰(aq), on inhibition of microbial reduction and uranium(VI) aqueous speciation in contaminated groundwater. However, to our knowledge, there have been no direct studies of the effects of these species on U(VI) adsorption by mineral phases. The sorption of U(VI) on quartz and ferrihydrite was investigated in NaNO₃ solutions equilibrated with either ambient air (430 ppm CO₂) or 2% CO₂ in the presence …

Isolation Of A High-Affinity Functional Protein Complex Between Omca And Mtrc: Two Outer Membrane Decaheme C-Type Cytochromes Of Shewanella Oneidensis Mr-1, Liang Shi, Baowei Chen, Zheming Wang, Dwayne A. Elias, M. Uljana Mayer, Yuri Gorby, Shuison Ni, Brian Lower, David Kennedy, David S. Wunschel, Heather M. Mottaz, Matthew Marshall, Eric Hill, Alexander Beliaev, John M. Zachara, James K. Fredrickson, Thomas Squier

United States Department of Energy: Publications

Shewanella oneidensis MR-1 is a facultatively anaerobic bacterium capable of using soluble and insoluble forms of manganese [Mn(III/IV)] and iron [Fe(III)] as terminal electron acceptors during anaerobic respiration. To assess the structural association of two outer membrane-associated c-type decaheme cytochromes (i.e., OmcA [SO1779] and MtrC [SO1778]) and their ability to reduce soluble Fe(III)-nitrilotriacetic acid (NTA), we expressed these proteins with a C-terminal tag in wild-type S. oneidensis and a mutant deficient in these genes (i.e., ∆omcA mtrC). Endogenous MtrC copurified with tagged OmcA in wild-type Shewanella, suggesting a direct association. To further evaluate their possible interaction, …

Resonant Soft X-Ray Scattering From Structured Polymer Nanoparticles, Tohru Araki, Harald Ade, Jeffrey M. Stubbs, Donald C. Sundberg, Gary E. Mitchell, Jeffrey B. Kortright, A. L. D. Kilcoyne

United States Department of Energy: Publications

The application of resonant soft x-ray scattering to chemically heterogeneous soft condensed matter materials is presented. Two structured styrene-acrylic polymer composite latex particles ~230 nm in diameter were utilized to delineate the potential utility of this technique. Angular scans at photon energies corresponding to strong scattering contrast between specific chemical moieties made it possible to infer the effective radii that correspond to the two polymer phases in the nanoparticles. The results show that resonant soft x-ray scattering should be a powerful complementary tool to neutron and hard x-ray scattering for the characterization of structured soft condensed matter nanomaterials.

Changes In Manganese And Lead In The Environment And Young Children Associated With The Introduction Of Methylcyclopentadienyl Manganese Tricarbonyl In Gasoline—Preliminary Results, Brian Gulson, Karen Mizon, Alan Taylor, Michael Korsch, Jennifer Stauber, J. Michael Davis, Honway Louis, Michael Wu, Hilton Swan

United States Environmental Protection Agency: Publications

A 4-year longitudinal study is being conducted to evaluate potential changes to the environment and exposure of young children associated with the introduction of methylcyclopentadienyl manganese tricarbonyl (MMT) into Australia in 2001. The cohort consists of 57 females and 56 males, with an age range of 0.29–3.9 years. Samples are collected every 6 months from children in residences located at varying distances from major traffic thoroughfares in Sydney. Environmental samples include air, house, and daycare center dustfall, soil, dust sweepings, and gasoline; samples from the children include blood, urine, handwipes prior to and after playing outdoors, and a 6-day duplicate …

Inter-Habitat Variation In The Benthos Of The Upper Missouri River (North Dakota, Usa): Implications For Great River Bioassessment, Ted Angradi, E. William Schweiger, David Bolgrien

United States Environmental Protection Agency: Publications

We examined inter-habitat variation in benthic macroinvertebrate assemblages in the 180-km Garrison Reach of the Upper Missouri River, North Dakota (USA) in 2001–2003. The Garrison Reach is unchannelized with a mostly rural setting. Flows are regulated by Garrison Dam. We sampled benthos from three habitats defined a priori: channel, shoreline, and backwater. Benthic assemblages were different in each habitat. Average Bray-Curtis dissimilarity in assemblage composition ranged from 89% for backwater versus channel habitat to 70% for backwater versus shoreline habitat. There were distinct intra-habitat groups within a priori habitats: channel assemblages included moving-sand assemblages and other-substrate channel assemblages; backwater assemblages …

Mode Of Action In Relevance Of Rodent Liver Tumors To Human Cancer Risk, Michael P. Holsapple, Henri C. Pitot, Samuel H. Cohen, Alan R. Boobis, James E. Klaunig, Timothy Pastoor, Vicki L. Dellarco, Yvonne P. Dragan

United States Environmental Protection Agency: Publications

Hazard identification and risk assessment paradigms depend on the presumption of the similarity of rodents to humans, yet species specific responses, and the extrapolation of high-dose effects to lowdose exposures can affect the estimation of human risk from rodent data. As a consequence, a human relevance framework concept was developed by the International Programme on Chemical Safety (IPCS) and International Life Sciences Institute (ILSI) Risk Science Institute (RSI) with the central tenet being the identification of a mode of action (MOA). To perform a MOA analysis, the key biochemical, cellular, and molecular events need to first be established, and the …

The Fathead Minnow In Aquatic Toxicology: Past, Present And Future, Gerald T. Ankley, Daniel L. Villeneuve

United States Environmental Protection Agency: Publications

This paper reviews the roles of the fathead minnow (Pimephales promelas) as a small fish model in the field of aquatic toxicology. The species has been (and is) extensively used both for regulatory testing and research, especially in North America. For example, tests with the fathead minnow, ranging from 48-h lethality through partial and full life-cycle assays, are routinely used for regulatory programs aimed at assessing potential risks of new chemicals such as high-production volume materials and pesticides, as well as impacts of complex mixtures like effluents. The species also has been used for a wide variety of …

Isotope Sourcing Of Prehistoric Willow And Tule Textiles Recovered From Western Great Basin Rock Shelters And Caves: Proof Of Concept, Larry V. Benson, E. M. Hattori, H. E. Taylor, S. R. Poulson, E. A. Jolie

United States Geological Survey: Staff Publications

Isotope and trace-metal analyses were used to determine the origin of plants used to manufacture prehistoric textiles (basketry and matting) from archaeological sites in the western Great Basin. Research focused on strontium (⁸⁷Sr/⁸⁶Sr) and oxygen (¹⁸O/¹⁶O) isotope ratios of willow (Salix sp.) and tule (Schoenoplectus sp.), the dominant raw materials in Great Basin textiles. The oxygen-isotope data indicated that the willow and tule used to produce the textiles were harvested from the banks of rivers or in marshes characterized by flowing water and not from lakes or sinks. The strontium-isotope …

Spin-Polarized Electronic Structure, Arti Kashyap, Renat F. Sabirianov, Sitaram Jaswal

Materials Research Science and Engineering Center: Faculty Publications

This chapter is devoted to the electronic structure of nanoscale metallic magnets. After an introduction to methods of electronic structure calculations, we review how recent trends translate into the description of magnetic nanostructures. Among the considered structures are nanowires, small particles, surfaces and interfaces, and multilayers, and emphasis is on magnetic properties such as moment and magnetization, interatomic exchange, and anisotropy.

One of the goals of computational nanoscience is to calculate physical and chemical properties from first principles. This requires the knowledge of the electronic structures of the materials system in question. The density-functional theory (DFT) makes a huge step …

Human Transcriptome Corresponding To Human Oocytes And Use Of Said Genes Or The Corresponding Polypeptides To Trans-Differentiate Somatic Cells, Jose Bernardo Cibelli, Arif Murat Kocabas, Bing Lim, Hasan H. Otu

Department of Electrical and Computer Engineering: Faculty Publications

The identification of 101 genes upregulated or differentially expressed by mature human oocytes is provided herein. These genes and the corresponding gene products will facilitate a greater understanding of oogenesis, folliculogenesis, fertilization, and embryonic development. In addition these genes and the corresponding gene products can be used to effect dedifferentiation and/or transdifferentiation of desired somatic cells. The resultant dedifferentiated cells and somatic cells derived therefrom can be used in cell therapies such as in the treatment of cancer, autoimmunity, and other diseases wherein specific types of cells such as hematopoietic cells may be depleted because of the underlying disease or …

Development And Applications Of Inkjet Printed Conducting Polymer Micro-Rings, Rajneek K. Khillan

Doctoral Dissertations

A drying sessile drop moves the solute particles to the periphery where they get deposited in the form of a ring. This phenomenon is prevalent even with micro drops falling at high velocity from a piezo-actuator based inkjet printer. In polymer microelectronic field, this phenomenon is a major challenge for fabricating devices using inkjet printing. We exploited this problem and applied it for various novel applications in the field of polymer microelectronics.

Various dispensing techniques and temperature variations for micro-drop printing were used for modifying the micro-drops in such a way that the periphery of the micro-ring holds most of …

Differences Between Tethered Polyelectrolyte Chains On Bare Mica And Hydrophobically Modified Mica, Marc Balastre, Phillip Schorr, J.-F. Argillier, Jinchuan Yang, Jimmy W. Mays, Matthew Tirrell

United States Department of Energy: Publications

This study investigates the structures of layers of amphiphilic diblock copolymers of poly(t-butyl styrene)-poly- (styrene sulfonate) (PtBS-PSS) adsorbed on both the bare mica surface (hydrophilic) and an octadecyltriethoxysilane (OTE)-modified mica surface (hydrophobic). When the surface is rendered hydrophobic, the nonsoluble block exhibits stronger interaction with the surface and higher adsorbed masses are achieved. Interaction forces between two such adsorbed layers on both substrates were measured using the surface forces apparatus. The effect of salt concentration (Cs) and molecular weight (N) on the height of the self-assembled layers (L₀) was examined in each case. The resulting scaling relationship is …

Changes In Uranium Speciation Through A Depth Sequence Of Contaminated Hanford Sediments, Jeffrey Catalano, James Mckinley, John M. Zachara, Steve Heald, Steven Smith, Gordon Brown Jr.

United States Department of Energy: Publications

The disposal of basic sodium aluminate and acidic U(VI)-Cu(II) wastes in the now-dry North and South 300 A Process Ponds at the Hanford site resulted in a groundwater plume of U(VI). To gain insight into the geochemical processes that occurred during waste disposal and those affecting the current and future fate and transport of this uranium plume, the solid-phase speciation of uranium in a depth sequence of sediments from the base of the North Process Pond through the vadose zone to groundwater was investigated using standard chemical and mineralogical analyses, electron and X-ray microprobe measurements, and X-ray absorption fine structure …

Towards Optimal Techniques For Solving Global Optimization Problems: Symmetry-Based Approach, Chirstodoulos A. Floudas, Vladik Kreinovich

Departmental Technical Reports (CS)

Most techniques for solving global optimization problems have parameters that need to be adjusted to the problem or to the class of problems: for example, in gradient methods, we can select different step sizes. When we have a single parameter (or few parameters) to choose, it is possible to empirically try many values and come up with an (almost) optimal value. Thus, in such situations, we can come up with optimal version of the corresponding technique.

In other approaches, e.g., in methods like convex underestimators, instead of selecting the value of single number-valued parameter, we have select the auxiliary function. …

Field-Scale Demonstration Of Induced Biogeochemical Reductive Dechlorination At Dover Air Force Base, Dover, Delaware, Lonnie G. Kennedy, Jess W. Everett, Erica Becvar, Donald Defeo

United States Air Force: Publications

Biogeochemical reductive dechlorination (BiRD) is a new remediation approach for chlorinated aliphatic hydrocarbons (CAHs). The approach stimulates common sulfate-reducing soil bacteria, facilitating the geochemical conversion of native iron minerals into iron sulfides. Iron sulfides have the ability to chemically reduce many common CAH compounds including PCE, TCE, DCE, similar to zero valent iron (Fe⁰). Results of a field test at Dover Air Force Base, Dover, Delaware, are given in this paper. BiRD was stimulated by direct injection of Epson salt (MgSO₄·7H₂O) and sodium (L) lactate (NaC₃H₅O₃) in five …

Disinfection Of Swine Wastewater Using Chlorine, Ultraviolet Light And Ozone, John J. Macauley, Zhimin Qiang, Rao Y. Surampalli, Melanie R. Mormile, Craig D. Adams

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Veterinary antibiotics are widely used at concentrated animal feeding operations (CAFOs) to prevent disease and promote growth of livestock. However, the majority of antibiotics are excreted from animals in urine, feces, and manure. Consequently, the lagoons used to store these wastes can act as reservoirs of antibiotics and antibiotic-resistant bacteria. There is currently no regulation or control of these systems to prevent the spread of these bacteria and their genes for antibiotic resistance into other environments. This study was conducted to determine the disinfection potential of chlorine, ultraviolet light and ozone against swine lagoon bacteria. Results indicate that a chlorine …

User-Centered Virtual Environment Assessment And Design For Cognitive Rehabilitation Applications, Cali Fidopiastis

Electronic Theses and Dissertations

Virtual environment (VE) design for cognitive rehabilitation necessitates a new methodology to ensure the validity of the resulting rehabilitation assessment. We propose that benchmarking the VE system technology utilizing a user-centered approach should precede the VE construction. Further, user performance baselines should be measured throughout testing as a control for adaptive effects that may confound the metrics chosen to evaluate the rehabilitation treatment. To support these claims we present data obtained from two modules of a user-centered head-mounted display (HMD) assessment battery, specifically resolution visual acuity and stereoacuity. Resolution visual acuity and stereoacuity assessments provide information about the image quality …

Multiobjective Simulation Optimization Using Enhanced Evolutionary Algorithm Approaches, Hamidreza Eskandari

Electronic Theses and Dissertations

In today's competitive business environment, a firm's ability to make the correct, critical decisions can be translated into a great competitive advantage. Most of these critical real-world decisions involve the optimization not only of multiple objectives simultaneously, but also conflicting objectives, where improving one objective may degrade the performance of one or more of the other objectives. Traditional approaches for solving multiobjective optimization problems typically try to scalarize the multiple objectives into a single objective. This transforms the original multiple optimization problem formulation into a single objective optimization problem with a single solution. However, the drawbacks to these traditional approaches …

Using The Software Adapter To Connect Legacy Simulation Models To The Rti, Deepak Kumar Rachapalli

Electronic Theses and Dissertations

The establishment of a network of persistent shared simulations depends on the presence of a robust standard for communicating state information between those simulations. The High Level Architecture (HLA) can serve as the basis for such a standard. While the HLA is architecture, not software, use of Run Time Infrastructure (RTI) software is required to support operations of a federation execution. The integration of RTI with existing simulation models is complex and requires a lot of expertise. This thesis implements a less complex and effective interaction between a legacy simulation model and RTI using a middleware tool known as Distributed …

Development Of Thermally Processed Nanocomposites With Controlled Surfaces, Petya Georgieva

Electronic Theses and Dissertations

The ever increasing need for technology development requires the integration of inexpensive, light weight and high strength materials which are able to meet the high standards and specifications for various engineering applications. The intention of this work is to show that the suitable material selection and the utilization of plasma spray processing can be of potential interest to a large number of industrial, biomedical and everyday life applications. This research demonstrates also that plasma processing is a promising engineering tool for multifunctional coatings and near-net-shape manufacturing. Further, the theoretical and experimental results are combined in order to explain the mechanisms …

Sensor-Based Computing Techniques For Real-Time Traffic Evacuation Management, Georgiana Hamza-Lup

Electronic Theses and Dissertations

The threat of terrorist incidents is higher than ever before and devastating acts, such as the terrorist attacks on the World Trade Center and the Pentagon, have left many concerns about the possibility of future incidents and their potential impact. Unlike some natural disasters that can be anticipated, terrorist attacks are sudden and unexpected. Even if sometimes we do have partial information about a possible attack, it is generally not known exactly where, when, or how an attack will occur. This lack of information posses great challenges on those responsible for security, specifically, on their ability to respond fast, whenever …

An Authentic Ecg Simulator, Paul Michalek

Electronic Theses and Dissertations

An ECG (electrocardiogram) simulator is an electronic tool that plays an essential role in the testing, design, and development of ECG monitors and other ECG equipment. Principally an ECG simulator provides ECG monitors with an electrical signal that emulates the human heart's electrical signal so that the monitor can be tested for reliability and important diagnostic capabilities. However, the current portable commercially available ECG simulators are lacking in their ability to fully test ECG monitors. Specifically, the portable simulators presently on the market do not produce authentic ECG signals but rather they endeavor to create the ECG signals mathematically. They …