Digital Commons Network^™

Formation Of Lyotropic Liquid Crystals Through The Self-Assembly Of Bile Acid Building Blocks, Karan Tamhane

Electronic Theses and Dissertations

Liquid crystalline materials (LCMs) have gained much popularity over the past century. The thermotropic forms of these materials have been extensively studied and employed in a range of innovative applications. The lyotropic liquid crystal systems that have been studied in the past have often been formed by the organization of natural and synthetic small molecules in solutions. In this study, we use self-assembled supramolecular structures as building blocks to fabricate lyotropic liquid crystals. We investigate the self-assembly of a naturally occurring bile acid called lithocholic acid (LCA), to form supramolecular fibrous and tubular structures in basic aqueous solutions. We control …

Determining Emissions From Landfills And Creating Odor Buffer Distances, Nicholas Guarrieloo

Electronic Theses and Dissertations

With population growing every year, more and more people are looking for places to live. This can lead to construction of houses near and around landfills. As homes get closer to landfills, the odors these landfills produce become more of a problem, and lead to an increase in odor complaints. Modeling these odors and recommending odor buffer distances will help determine limits on how close to landfills new homes should be allowed. This should help reduce future odor complaints. To solve this problem one must accurately estimate odorous gas emissions from the landfill. Often odors can be indicated by methane …

Analyses Of Crash Occurence And Injury Severities On Multi Lane Highways Using Machine Learning Algorithms, Abhishek Das

Electronic Theses and Dissertations

Reduction of crash occurrence on the various roadway locations (mid-block segments; signalized intersections; un-signalized intersections) and the mitigation of injury severity in the event of a crash are the major concerns of transportation safety engineers. Multi lane arterial roadways (excluding freeways and expressways) account for forty-three percent of fatal crashes in the state of Florida. Significant contributing causes fall under the broad categories of aggressive driver behavior; adverse weather and environmental conditions; and roadway geometric and traffic factors. The objective of this research was the implementation of innovative, state-of-the-art analytical methods to identify the contributing factors for crashes and injury …

Sintering Additives For Nanocrystalline Titania And Processing Of Porous Bone Tissue Engineering Scaffolds, Arun Menon

Electronic Theses and Dissertations

Titania (Titanium dioxide, TiO2) has been researched as a promising biomaterial due to its excellent biocompatibility. However, the main limitation of titania is its poor mechanical properties which limit its use in many load-bearing applications. In this thesis report, the properties of titania were improved by doping with small quantities of MgO, ZnO and SiO2 as sintering additives. Nanocrystalline powder was selected, as it possesses outstanding properties over conventional coarse-grained powders due to reduced grain size. Nanocrystalline anatase powder of size 5-15 nm was synthesized via a simple sol-gel technique. Small quantities of dopants were introduced into pure titania powder, …

Characterizing Spontaneous Fires In Landfills, Shadi Moqbel

Electronic Theses and Dissertations

Landfill fires are relatively common incidents that landfill operators encounter which have great impact on landfill structure and the environment. According to a U.S. Fire Administration report in 2001, an average of 8,300 landfill fires occurs each year in the United States, most of them in the spring and summer months. Subsurface spontaneous fires are considered the most dangerous and difficult to detect and extinguish among landfill fires. Few studies have been conducted on spontaneous fires in landfills. Information regarding the thermal behavior of solid waste is not available nor have measurements been made to evaluate spontaneous ignition of solid …

An Integrated Hydrology/Hydraulic And Water Quality Model For Watershed-Scale Simulations, Cheng Wang

Electronic Theses and Dissertations

This dissertation presents the design of an integrated watershed model, WASH123D version 3.0, a first principle, physics-based watershed-scale model of integrated hydrology/hydraulics and water quality transport. This numerical model is comprised of three modules: (1) a one-dimensional (1-D) simulation module that is capable of simulating separated and coupled fluid flow, sediment transport and reaction-based water quality transport in river/stream/canal networks and through control structures; (2) a two-dimensional (2-D) simulation module, capable of simulating separated and coupled fluid flow, sediment transport, and reactive biogeochemical transport and transformation in two-dimensional overland flow systems; and (3) a three-dimensional (3-D) simulation module, capable of …

Regulation Of Intracellular Calcium Concentration By Nanosecond Pulsed Electric Fields, Shaka S. Scarlett, Jody A. White, Peter F. Blackmore, Karl H. Schoenbach, Juergen Kolb

Bioelectrics Publications

Changes in [Ca²⁺]_i response of individual Jurkat cells to nanosecond pulsed electric fields (nsPEFs) of 60 ns and field strengths of 25, 50, and 100 kV/cm were investigated. The magnitude of the nsPEF-induced rise in [Ca²⁺]_i was dependent on the electric field strength. With 25 and 50 kV/cm, the [Ca²⁺]_i response was due to the release of Ca²⁺ from intracellular stores and occurred in less than 18 ms. With 100 kV/cm, the increase in [Ca²⁺]_i was due to both internal release and to influx across the plasma …

Synthesis Of Best Practices In Transportation Security, Volume Ii: Emergency Response, Rodrigo Vargas, Jon D. Fricker

JTRP Technical Reports

Part I of the research focused on developing a methodology to identify and evaluate the most critical and vulnerable INDOT assets. This method aims at obtaining an index that reflects the vulnerability and criticality of an asset on the basis of multiple performance criteria. This methodology was tested on the seven INDOT districts. Because not all the factors that influence the vulnerability do have same weight, the analytical hierarchical process is used to obtain the weights for the criteria. Countermeasures are suggested as a part of the research to reduce the vulnerability of a given asset based on its relevant …

Test 1945: John Deere 4520 S/N 65001 And Higher, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data. EXPLANATION OF THE TEST PROCEDURES Purpose The purpose of …

Pressure-Driven Transport Of Particles Through A Converging-Diverging Microchannel, Ye Ai, Sang W. Joo, Xiangchun Xuan, Shizhi Qian

Mechanical & Aerospace Engineering Faculty Publications

Pressure-driven transport of particles through a symmetric converging-diverging microchannel is studied by solving a coupled nonlinear system, which is composed of the Navier-Stokes and continuity equations using the arbitrary Lagrangian-Eulerian finite-element technique. The predicted particle translation is in good agreement with existing experimental observations. The effects of pressure gradient, particle size, channel geometry, and a particle's initial location on the particle transport are investigated. The pressure gradient has no effect on the ratio of the translational velocity of particles through a converging-diverging channel to that in the upstream straight channel. Particles are generally accelerated in the converging region and then …

Electron Microscopy And Optical Characterization Of Cadmium Sulphide Nanocrystals Deposited On The Patterned Surface Of Diatom Biosilica, Timothy Gutu, Debra K. Gale, Clayton Jeffryes, Wei Wang, Chih-Hung Chang, Gregory L. Rorrer, Jun Jiao

Physics Faculty Publications and Presentations

Intricately patterned biosilica obtained from the shell of unicellular algae called diatoms serve as novel templates for fabrication of optoelectronic nanostructures. In this study, the surface of diatom frustules that possessed hierarchical architecture ordered at the micro and nanoscale was coated with a nanostructured polycrystalline cadmium sulphide (CdS) thin film using a chemical bath deposition technique. The CdS thin film was composed of spherical nanoparticles with a diameter of about 75 nm. The CdS nanoparticle thin film imparted new photoluminescent properties to the intricately patterned diatom nanostructure. The imparted photoluminescent properties were dependent on the CdS coverage onto the frustules …

Update To Ansi/Ans-6.4.3-1991 For Low-Z And Compound Materials And Review Of Particle Transport Theory, Luis Durani

UNLV Theses, Dissertations, Professional Papers, and Capstones

The ANSI/ANS-6.4.3-1991 Gamma-Ray Attenuation Coefficients and Buildup Factors for Engineering Materials Standard (herein known as ANS Standard), contains derived gamma-ray attenuation coefficients and buildup factors for selected engineering materials and elements for use in shielding calculations (ANSI/ANS-6.1.1, 1991). The current status of the ANS Standard is withdrawn due to the lack of any updates since its last publication. Since the last update of the ANS standard, more accurate codes for particle transport and cross sectional data have become available. As a result, this study was carried out to update gamma-ray buildup factors for iron and water as a function of …

Quantity-Based Cost Forecasting System For Street Construction Projects, Nipesh Pradhananga

UNLV Theses, Dissertations, Professional Papers, and Capstones

Construction projects typically are not withdrawn after going into the competitive bidding process. The decision of contracting authorities regarding which projects will proceed to the bidding stage depends, in part, upon the early estimates of probable cost. Efforts are made to make this estimate as realistic as possible. Irrespective of the estimate of probable cost, the actual project cost is established by the amount of the winning bid.

This study analyzed historical bid data of street construction projects undertaken by the Public Works Department, Clark County, Nevada, from 1991 through 2006. The focus of this study was on utilizing statistical …

Sialic Acid Conjugated Chitosan For The Attenuation Of Amyloid-Beta Toxicity, Dhruva Dilip Dhavale

LSU Master's Theses

Amyloid-beta (Aβ), a 39 to 43 amino acid long peptide, is the primary species identified in senile plaques associated with Alzheimer’s disease (AD) and has been implicated in the neurotoxicity associated with AD. It is believed that Aβ toxicity is mediated through the interaction with neuronal membranes. A variety of evidence indicates that 1) Aβ may bind to the cell surface sialic acids, 2) the affinity of this interaction is higher if the gangliosides or sialic acids on the cell surface are clustered, 3) the removal of the surface sialic acids attenuate Aβ toxicity. Based on this data, we hypothesized …

Intracellular Ice Formation In Adult Stem Cells In The Presence Of Polyvinyl Pyrrolidone, Avishek Guha

LSU Master's Theses

The main objective of this work was to assess the effect of 10% (w/v) polyvinylpyrrolidone (PVP) on the pattern of intracellular ice formation (IIF) in human adipose tissue derived adult stem cells (ASCs) in the absence of serum and other cryoprotective agents (CPAs). Passage 1 (P1) ASCs were cultured, washed and suspended in either 1x PBS (Phosphate Buffered Saline) or 10% w/v solution of PVP in 1x PBS. The freezing experiments were carried out using a fluorescence microscope equipped with a Linkam™ cooling stage using two different temperature/time cooling protocols. Both the cooling protocols had a common cooling ramp: cells …

The Modification, System Software Development, Validation, And Clinical Trial Of A Novel Ankle Stiffness Testing Device, T. Tyler Clement

LSU Master's Theses

The purpose of this project is to modify, validate, and gather preliminary clinical data on a novel ankle stiffness device that measures stiffness (torque / degree) and range of motion (ROM) of the ankle joint complex (AJC). The initial device was designed by a mechanical engineering design group at Louisiana State University in 2006, but had not been tested on human participants. Clinical evaluation of the ankle joint is important in patients afflicted with diabetes mellitus, Hansen’s disease, or peripheral neuropathies. The combination of peripheral neuropathies, decreased ankle range of motion, and increased stiffness pose a threat to these patients, …

Thermomechanical Characterization Of A Shape Memory Polymer Based Syntactic Foam, Damon Nettles

LSU Master's Theses

Shape memory polymers (SMPs) are a type of smart material capable of “remembering” multiple shapes and transitioning between them in response to an external stimulus. They offer the potential to self-seal macro-length scale damage in a nearly autonomous fashion. Syntactic foams are lightweight structural materials currently used in the marine and aerospace industries. This study seeks to bring syntactic foams and SMPs together, retaining characteristics of both components, to create a low-density smart composite. The SMP based syntactic foam is used as the core of a grid stiffened sandwich structure capable of healing impact damage multiple times. In order to …

Enhancing Reductive Dechlorination Of Chlorinated Ethenes And Ethanes In A Natural Treatment System, Caroline Burda

LSU Master's Theses

Chlorinated solvent contamination continues to plague sites around the world. In many cases, lower chlorinated daughter products build up and remain in ground waters and soils. A Bio-Filter/Phytobed (BFP) system has been developed to replace a traditional pump and treat technology currently operating at the ReSolve Superfund site in North Dartmouth, MA. Pilot scale testing at the facility displayed a significant acclimation period prior to microbial dechlorination, as well as delayed degradation of chlorinated ethanes. Microcosm studies suggest that acidic conditions, possibly created by the peat mixture used to construct the bio-filter, inhibited bacterial growth. The neutralization of trench pH …

Advanced Microwave Technology For Biodiesel Feedstock Processing, Beatrice G. Terigar

LSU Master's Theses

The goal of this work was to assist in overcoming the most important bottlenecks in the biodiesel production chain: to improve the biodiesel production process (oil extraction and esterification) using advanced microwave technologies from traditional and alternative feedstock; and identify the important characteristics of an alternative, high oil yield crop (TT). Dielectric properties of two feedstocks, soybean and rice bran were measured in presence of several solvents at different ratios, temperature and frequency. Results indicated that dielectric properties are ratio, temperature, frequency and solvent type dependent. Quasi-linear relationship using second order logarithmic transformation of the data provided a reliable estimator …

Poly (D, L-Lactide-Co-Glycolide) And Chitosan Particles For Oral Delivery Of Model Lipophilic Vitamin, Abitha Murugeshu

LSU Master's Theses

Improved oral delivery of vitamins and antioxidants via food, beverages or supplements can be achieved by encapsulation of the bioactive component in biodegradable and biocompatible colloidal and nanoparticle systems. Mucoadhesive chitosan/Poly (D, L-lactide-co-glycolide) particles were investigated as a means to control the release of bioactive compounds such as vitamin E in the gastrointestinal (GI) tract. Chitosan/PLGA particles with entrapped alpha-tocopherol at different initial loadings were synthesized by emulsion evaporation method, compared against PLGA particles in terms of their physical properties, stability, and gastrointestinal release profiles. Chi/PLGA particles of 250 ± 8.9 nm with a zeta potential of 61 ± 3.1 …

Phosphorus Dynamics In The Marshland Upwelling System, Dhaval Shirish Shah

LSU Master's Theses

The Marshland Upwelling System (MUS) is an alternative onsite wastewater treatment technology designed to utilize the natural ecology of saltwater marshes to remove human-borne contaminants. Previous research has assessed the ability of MUS to remove both total and orthophosphate. Studies have also indicated a clear zone of phosphorus (P) saturation occurring in MUS soils. Laboratory column study was performed to accomplish the objectives of this study which were to: 1) determine the fate and fractionation of phosphorus in the soil matrix, 2) understand sorption kinetics and determine phosphorus sorption potential of wetland soils in retaining phosphorus in the MUS, 3) …

Two-Dimensional Microscanners With T-Shaped Hinges And Piezoelectric Actuators, Wenyu Song

LSU Master's Theses

For a wide range of application areas such as medical instruments, defense, communication networks, industrial equipment, and consumer electronics, microscanners have been a vibrant research topic. Among various fabrication methodologies, MEMS (microelectromechanical system) stands out for its small size and fast response characteristics. In this thesis, piezoelectric actuation mechanism is selected because of its low voltage and low current properties compared with other mechanisms, which are especially important for the target application of biomedical imaging. Although 1- and 2-dimensional microscanners with piezoelectric actuators have been studied by several other groups, this thesis introduces innovative improvements in design of the piezoelectric …

Biocompatible/ Bioresorbable Polymer Based Silver Nanaomaterial Coatng For Chronic Indwelling Medical Devices And Bioscaffolds For Tissue Regrowth, Ammar T. Qureshi

LSU Master's Theses

The objective of this study is to synthesize and characterize antimicrobial, bio-polymer based silver nanomaterials composite coatings, for use in chronic indwelling medical devices, and bioscaffolds. The coatings and bioscaffolds are comprised of novel biomass mediated silver nano particles (SNP) that are biocompatible, highly concentrated, highly pure, cost-effective, polydispersed and compatible with a range of polymer systems applicable for use with existing chronic indwelling medical devices. This thesis is divided into three main chapters. In Chapter 1, detailed review on the need for antimicrobial nanocomposite coatings for chronic indwelling medical devices along with different SNP synthesis and characterization methods is …

Efficiency Of Cellulase Enzyme Immobilized On Magnetic Nanoparticles, Jason Jordan

LSU Master's Theses

Advances in enzymatic hydrolysis have developed new methods for conversion of lignocellulosic biomass into fermentable sugars for various applications, mainly ethanol production. The present study involves immobilization of a cellulase enzyme complex on a solid support which can be recovered for subsequent use in multiple reactions. The supports of interest include Fe3O4 nanoparticles (~13 nm) and polystyrene-coated particles containing a Fe3O4 core (1-2 µm). Each support contains amine functional groups based on the surface that allow covalent attachment of enzymes via carbodiimide activation. The nanoparticles were characterized using transmission electron microscopy (TEM) and immobilization was confirmed using Fourier transform infrared …

Self-Healing Of Fiber Reinforced Polymer Compoistes [Sic], Nebiyu Fikru

LSU Master's Theses

The study of self-healing materials is inspired by biological systems in which damage triggers an autonomous healing response. In recent years, this concept of autonomic healing material, where initiation of repair is integral to the material, is being considered for engineering applications. The concept offers the designer an ability to incorporate secondary functional ability of counteracting service degradation in addition to achieving the primary, usually structural integrity, requirement. Self-healing materials also have the benefit of offering lighter and optimized structures as well as reduced maintenance cost. Previous works on polymer matrix composites have shown that significant fractions of mechanical properties …

Nano-Mechanics Of Cartilage Glycosaminoglycans Using Molecular Dynamics Methods, Kevin Neil Hendrickson

Master's Theses

Articular Cartilage (AC) is the main load carrying material in synovial joints {Hamerman, 1962} and degeneration of AC can cause pain in the form of arthritis. Current work is centered on the method of replacing damaged cartilage inside the body (in vivo) with tissue engineered outside the body (ex vivo) {Temenoff, 2000}. In order to engineer tissue ex vivo similar to the native tissue in structure and function there must be a comprehensive understanding of the mechanical properties of AC. This work focuses on the study of glycosaminoglycans (GAGs), a molecule known to be primarily responsible for the compressive stiffness …

Electrical Apparoaches For Selective Detection Of Cancer Biomarker Proteins With Aptamers, Priyanka Pachampettai Ramachandran

Bioengineering Theses - Archive

Cancer is a disease that is the central focus of many a researcher's attention. As it is a disease that can spread very rapidly and can be fatal in many cases, its early detection and early treatment can dramatically change mortality. Towards the early detection of the disease, antibodies are most commonly used for the detection of cancer biomarkers. The use of antibodies in diagnostics has proven fruitful in the past. But advancements in molecular biology have introduced aptamers for diagnostic and therapeutic purposes. Aptamers are oligonucleotides or peptides that are usually synthesized by a selective process called SELEX. Aptamers …

Agents And Service-Oriented Computing For Autonomic Computing: A Research Agenda, Frances M.T. Brazier, Jeffrey O. Kephart, H. Van Dyke Parunak, Michael N. Huhns

Faculty Publications

Autonomic computing is the solution proposed to cope with the complexity of today's computing environments. Self-management, an important element of autonomic computing, is also characteristic of single and multiagent systems, as well as systems based on service-oriented architectures. Combining these technologies can be profitable for all - in particular, for the development of autonomic computing systems.

Temperature Impact On Nitrification And Bacterial Growth Kinetics In Acclimating Recirculating Aquaculture Systems Biofilters, Milton Maada-Gomoh Saidu

LSU Doctoral Dissertations

This project assessed short-term temperature effects on total ammonia nitrogen (TAN) utilization rates in a batch laboratory-scale recirculating system. The tank system was designed for experiments on short term steady state and diurnal temperatures. A set of numerical models was developed to simulate observed results. The performance of the biofilters was determined with three tank replicates at fixed temperatures of 13, 20 and 300C; and at diurnal transient (sinusoidal) temperature regimes of (20 ± 30C; 30 ± 30C). Ammonia utilization rates and biofilter performance for beads acclimated at different temperatures regimes separated and mixed were also determined. Total ammonia utilization …

A Modular Approach To High Throughput Microsystems, Pin-Chuan Chen

LSU Doctoral Dissertations

A modular high throughput microsystem was developed using microfabrication technology and nucleic acid analysis. The purpose of developing this microsystem is to identify acute infectious disease and prevent contagious outbreak in a matter of time. This microsystem included three major components, a reagent distribution device, a 96 CFPCR array, and a multi-zone thermal system, to efficiently amplify specific DNA fragments to determine the disease status or precisely pinpoint a disease from multiple patients. Polymerase chain reaction (PCR) is the key component in the nucleic acid analysis for disease because it can be used to amplify interested DNA fragments by repeatedly …