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Synthesis Of Bimetallic Nickel And Cobalt Phosphide Nanostructures For Electrocatalysis, Sarah Meixin York

Graduate Theses and Dissertations

Transition metal phosphides have become a new class of materials to be considered as promising catalysts for a number of applications including electrochemical hydrogen evolution (HER). Electrocatalysis in hydrogen evolution is a heavily studied field due to the increasing desire to develop more efficient and more cost-effective catalysts for clean hydrogen production. This project develops a chemical approach to synthesizing bimetallic cobalt-nickel phosphide nanostructures for their use in HER. The synthesis is accomplished by thermal decomposition of the metal precursors in the presence of carbon monoxide (CO) and trioctyl phosphine (TOP). The resulting nanostructures were characterized using transition electron microscopy …

Vr Circuit Simulation With Advanced Visualization For Enhancing Comprehension In Electrical Engineering, Elliott Wolbach

Department of Electrical and Computer Engineering: Dissertations, Theses, and Student Research

As technology advances, the field of electrical and computer engineering continuously demands innovative tools and methodologies to facilitate effective learning and comprehension of fundamental concepts. Through a comprehensive literature review, it was discovered that there was a gap in the current research on using VR technology to effectively visualize and comprehend non-observable electrical characteristics of electronic circuits. This thesis explores the integration of Virtual Reality (VR) technology and real-time electronic circuit simulation with enhanced visualization of non-observable concepts such as voltage distribution and current flow within these circuits. The primary objective is to develop an immersive educational platform that makes …

Additive Manufacturing Of Porous Tungsten Carbide Structural Electrode Components Using Robocasting, James Bevis

All Theses

Thanks to ideal mechanical and electrochemical properties, Tungsten Carbide (WC) shows excellent potential as a structural electrode material for multifunctional devices. These devices have applications in electric vehicles, for example, structural fuel cells and massless batteries. In such a context, structural WC electrodes will also benefit from porosity to decrease their weight and increase their surface area and chemical reactivity. Porous WC is a useful material for this field because of its high strength-to-weight ratio and electrical properties. However, current manufacturing methods can be expensive, complex, and limited, so the intent is to provide a more simplistic and sustainable method …

Dynamics Of Link Importance Across Flood Disaster Phases And Flood Impacts On Operation Of An Industry, Navin Bhatta

All Theses

Transportation damage and disruptions will become increasingly common as the frequency of floods increases due to climate change. Given the size and cost of the transportation network construction, communities' mitigation measures should be supported by evaluations that cover both normal and disaster management phases. This thesis examines the criticality of road segments in the normal, flood response, and recovery phases, considering the effects on emergency services, healthcare, industry, education, recreation, and transit and analyses that whether a flood disrupts the operational trips of a company in Anderson County, South Carolina. A 100-year event and a 500-year flood event provides context …

Advancements Of A Breast Tissue Marker And Localization System, Azrin Jamison

All Theses

Breast cancer has become the most prominent cancer worldwide in women. Annual mammograms are encouraged for women of high risk to increase early detection allowing for lumpectomies rather than mastectomies to occur. Prior to a lumpectomy, a biopsy must be taken to determine if the tissue is cancerous, and a breast cancer biopsy marker (BBM) is left in the region of possible cancerous tissue. Wire localization has been the gold standard for localizing these BBMs. However, due to the reported patient discomfort and logistical inefficiencies faced by healthcare providers (HCP), non-wire localization solutions have been recently developed. This study aims …

A Transdisicplinary, Survivor-Centered Approach For Creating A System Dynamics Model Of Closed-Buyer Sex Trafficking Networks, Kemonte Yow

All Theses

One of the largest drivers of sex trafficking operations is the demand for commercial sex. To date, research from a quantitative side typically focuses on understanding how to best identify and remove victims from their trafficking situation and then support their healing and recovery. This may be because this is where data exists (in limited forms) to support quantitative modeling. This thesis broadens that scope to understand how demand for commercial sex impacts trafficking operations. In particular, this research implemented a transdisciplinary, survivor-centered approach to build a system dynamics model of a closed-buyer sex trafficking network, which is a network …

Amazon Fba Vs Fbm; A Strategic Approach To Determine Which Method Can Effectively Utilize Project Management Principles To Enhance Your Success As A New Amazon Seller., Tiffany Renee White

Theses and Dissertations

Navigating the complexities of a platform such as Amazon demands a strategic approach guided by project management principles. A comparative analysis of Fulfillment by Amazon (FBA) and Fulfillment by Merchant (FBM) methods were completed by focusing on how project management principles optimize product acquisition, supply chain management, and shipping methods for Amazon sellers. The objectives of this study included the identification of top product acquisition tools, the evaluation of inventory management software, assessing shipping methods, and determining the most effective fulfillment process for Amazon seller success. A mixed-methods approach was applied, involving an Amazon seller survey, literature review, data analysis, …

Thermal Conductivity Of Thin Porous Ceramic Coatings: An Analytical And Experimental Study, Lei Zhao

Theses and Dissertations

An analytical model of the thermal conductivity of the porous yttrium-stabilized zirconia (YSZ) layer used in the thermal barrier coatings (TBCs) is presented. Such high-temperature resistant coatings are essential to protect the metallic components of gas turbine engines. The model calculates the conductivity based on the coating's porosity, pore size distribution, and pore morphology, including the individual pore cross-section area, aspect ratio, and orientation, which are extracted from the scanning electron microscopy images. The model was verified through comparisons with numerical simulation results from a multiphysics software tool. A laser temperature gradient test was performed to validate the analytical model …

4-Channel Spatially Multiplexed Communication System In Single-Core Optical Fibers, Ce Su

Theses and Dissertations

This dissertation delves into exploring and advancing spatial domain / space division multiplexing (SDM) technologies within single-core optical fibers, a frontier in optical fiber communications poised to meet the burgeoning global demand for data transmission. At the heart of this research is the pursuit to significantly enhance the capacity and efficiency of optical fiber communication systems without necessitating additional fiber infrastructure. This work unveils a new paradigm in optical fiber communications characterized by a pioneering 4-channel SDM system through a meticulous process encompassing theoretical modeling, computational simulations, design innovations, and rigorous experimental validations. Theoretical contributions include the development of refined …

Representation Learning For Generative Models With Applications To Healthcare, Astronautics, And Aviation, Van Minh Nguyen

Theses and Dissertations

This dissertation explores applications of representation learning and generative models to challenges in healthcare, astronautics, and aviation.

The first part investigates the use of Generative Adversarial Networks (GANs) to synthesize realistic electronic health record (EHR) data. An initial attempt at training a GAN on the MIMIC-IV dataset encountered stability and convergence issues, motivating a deeper study of 1-Lipschitz regularization techniques for Auxiliary Classifier GANs (AC-GANs). An extensive ablation study on the CIFAR-10 dataset found that Spectral Normalization is key for AC-GAN stability and performance, while Weight Clipping fails to converge without Spectral Normalization. Analysis of the training dynamics provided further …

Effect Of Patient Specific Blood Biomarkers On Nanoparticle - Cell Interactions, Veronica Gabriela Contreras

Open Access Theses & Dissertations

Nanoparticles are currently known to be a promising material class for bio-applications in drug delivery and vaccine development. Using gold nanoparticles of varied sizes, in this case 45 and 100 nanometers as a model nanomaterial system, we investigated how patients' blood physiology and chemistry (such as solute, protein, lipid levels) affect the biological response to bionanomaterials. When nanoparticles are injected into the body, biomolecules in the blood adsorb to the nanoparticle's surface to form a biomolecular corona that is specific to the patient's unique blood composition. This biomolecular corona is important because it affects the in vivo fate and biodistribution …

Earth Abundant Catalyst For Evironmental Sustainability Applications, Javier Hernandez

Open Access Theses & Dissertations

The development of experimental methodologies for synthesizing a diverse range of metallic and metal oxide nanoparticles tailored for sustainable water treatment applications was investigated. These nanoparticles are prepared using environmentally friendly and scalable synthesis methods, underscoring their potential for large-scale production. Synthesized nanoparticles are harnessed for various processes, including catalysis and electrocatalysis, with a primary objective of degrading and removing organic pollutants from water. Key to this research is the encapsulation of nanoparticles within solid supports. Multiple methodologies are explored to engineer supports that ensure nanoparticle stabilization, monodispersion, and prevent unintended release into the environment. Two alternative approaches were evaluated …

Microwave Emission Model Parameter Tuning For Surface Soil Moisture Retrieval Using Uav-Mounted Dual Polarization L-Band Radiometer, Santiago Hoyos Echeverri

Open Access Theses & Dissertations

Surface soil moisture retrieval from L-band brightness temperature has been developed for the past decades due to multiple beneficial characteristics of 1-2 GHz frequency bands for remote sensing of the environment. Numerous microwave emission models have been proposed for tower and satellite-based operations with successful retrieval of surface soil moisture and vegetation water content. As a result of the development of cost-effective and low-mass microwave L-band radiometers such as the Portable L-band Radiometer (PoLRa), surface soil moisture surveying traditionally developed by satellite missions SMOS and SMAP can now be developed at local scales, bringing these operations to commercial small unmanned …

Analysis Of Drying Behavior Of Robocasted Barium Titanate, Abigail Ortega

Open Access Theses & Dissertations

Finding an adequate ceramic formulation for material extrusion is a time-consuming process. The necessary equipment may be unavailable to perform the desired test. This study demonstrated an alternative to observe a material after extrusion to understand its drying process. This study focused on 55 solid loading volume percent and a 39 solid loading volume percent, each with two different binder treatments focusing on fresh same day made binder, a 30 day old, aged binder and lastly an artificial binder obtained by a fuming process. Firstly, a formulation was created and loaded onto a pressure-based syringe to be extruded with a …

Renewable Energy Misinformation: A Literature Based Approach To Rebutting False Claims, Matthew Ard

McNair Research Journal SJSU

No abstract provided.

Evaluation Of Cybersecurity In Remote Working Settings For Mobile Network Operators, Victoria Mahabi

Tanzania Journal of Engineering and Technology (TJET)

Cybersecurity has increasingly been a primary concern to people as technology advances and allows them to work remotely. This study thus evaluated the cybersecurity posture for organisations that have opted for remote working culture, whereas emerging cyber threats, practices to combat them, and appropriate guidelines for managing cyber threats were discussed. The study used a descriptive design with a quantitative approach from 118 information technology personnel working for Tanzania's three major mobile network operators (MNOs). SPSS analysed the collected data. The study revealed that predominant cyber-threats affecting MNOs in remote working include human errors, phishing attacks, malicious domains, denial of …

General Hydrogeochemical Characterization Of Groundwater In Coastal Aquifers Of Kilwa Kisiwani Oceanic Island, South East Tanzania, Simon R Melchioly

Tanzania Journal of Engineering and Technology (TJET)

The main objective of this study was to determine the hydrogeochemical processes controlling the groundwater chemistry on the Island and assess its suitability for human consumption and irrigation. The methodology used in the study include hydrogeological assessment of the study area and laboratory analysis for general physico-chemical parameters of groundwater. Other parameters such as Soluble sodium percentage (SSP) or % Na+, Sodium Adsorption Ratio (SAR), Magnesium adsorption ratio (MAR), Residual sodium carbonate (RSC), hydrochemical facies classification, and Water Quality Index (WQI) were calculated using empirical formulae. The effects of salinization of groundwater were classified using the chloride-Bicarbonate (Cl/HCO3) and the …

Characterizing Brain And Skull Mechanics In The Minipig Using Magnetic Resonance Elastography, Shuaihu Wang

McKelvey School of Engineering Graduate Student Theses & Dissertations

Computational models and simulation are important tools to investigate the mechanisms underlying traumatic brain injury (TBI); their accuracy depends strongly on accurate model parameters, including the mechanical properties of the brain and its interactions with the skull. However, most existing TBI modeling studies are performed using material properties derived from animal tissue obtained after death. Magnetic resonance elastography (MRE) provides a non-invasive method for estimating the mechanical properties of soft tissue. The overall objective of this thesis is to characterize the biomechanical properties of brain tissue and brain-skull interface in the minipig by using MRE. This was achieved through pursuit …

Dynamic Characteristics Of Magnetoelectric Linear Actuators Of Control Systems, Мakhmudjon Muxamedovich Аbdullayev, Rasul Ernazar Ogli Abdiev

Chemical Technology, Control and Management

This paper presents the results of studies carried out on magnetoelectric drives that carry out linear movement, models of drives are built and, on their basis, studies of the main indicators associated with the movement of a linear armature are carried out, such as: speed of movement, acceleration, current values, voltage and traction force of the armature. Also presented are the results of a study of magnetoelectric linear motion drives based on an analysis of graphs of their dynamic characteristics.

Algorithms For Structural Synthesis Of Control Systems For Dynamic Objects Under Conditions Of Unmeasurable Disturbances, Husan Zakirovich Igamberdiev, Uktam Farkhodovich Mamirov, Bunyod Mamurjon Ugli Buronov

Chemical Technology, Control and Management

The paper talks about ways to use inverse dynamic models to structure a control system for moving objects when disturbances are not measured. To solve the main problems that arise when implementing the inverse dynamic model method, methods for synthesizing inverse systems with given dynamic characteristics are used. The solution to this problem is obtained based on the theory that dynamic observers are invariant to unmeasured input influences. We broke down the matrix operator on the right into elementary orthogonal rotation matrices and on the left into permutation matrices to get a stable answer to the equation of the current …

Farm Electricity System Simulator (Fess): A Platform For Simulating Electricity Utilisation On Dairy Farms, F. Buckley, J. Upton, R. Prendergast, L. Shalloo, Michael D. Murphy

Publications

The objective of this paper was to define, validate and demonstrate a model capable of accurately simulating dairy farm electricity consumption across varying herd and parlour sizes, to facilitate research investigating renewable energy systems (RES) and demand side management (DSM). The Farm Electricity System Simulator (FESS) was developed using grey-box modelling techniques utilizing empirical data for parameter tuning. Empirical data were gathered from nine spring calving, pasture based dairy farms located in the Republic of Ireland. A k-means clustering analysis was conducted, separating the farms into three, near homogenous groups, from which representative farms were selected. FESS was trained using …

Hardness Of Single Phase High Entropy Carbide Ceramics With Different Compositions, Paul M. Brune, Gregory E. Hilmas, William G. Fahrenholtz, Jeremy Lee Watts, Caillin J. Ryan, Chris M. Desalle, Douglas E. Wolfe, Stefano Curtarolo

Materials Science and Engineering Faculty Research & Creative Works

Five High Entropy Carbide Ceramics, (Hf0.2,Nb0.2,Ta0.2,Ti0.2,Zr0.2)C, (Cr0.2,Hf0.2,Ta0.2,Ti0.2,Zr0.2)C, (Hf0.2,Mo0.2,Ta0.2,Ti0.2,Zr0.2)C, (Hf0.2,Ta0.2,Ti0.2,W0.2,Zr0.2)C, and (Hf0.2,Mo0.2,Ti0.2,W0.2,Zr0.2)C, Were Synthesized by Carbothermal Reduction of Oxides and Direct Current Sintering. the Five High Entropy Carbide Ceramics Were Determined to Be Nominally Phase-Pure with Relative Densities of More Than 98.9% and Mean Grain Sizes of Less Than 5 Μm. Average Vickers Hardness Values Ranged from 19.2 ± 0.4 GPa for (Hf0.2,Nb0.2,Ta0.2,Ti0.2,Zr0.2)C at a Load of 2 Kgf to 43.5 ± 0.4 GPa for (Hf0.2,Mo0.2,Ti0.2,W0.2,Zr0.2)C at a Load of 0.05 Kgf. Hardness Generally Increased with Increasing the Valence Electron Concentration and Strain as Measured by the Williamson-Hall Analysis. However, Neither …

Optimal Environmental And Economic Performance Trade-Offs For Fifth Generation District Heating And Cooling Network Topologies With Waste Heat Recovery, Michael D. Murphy

Publications

Network topology greatly influences both the economic and environmental performance of fifth generation district heating and cooling (5GDHC) systems. In this study the optimal trade-offs between the environmental and economic performance of 5GDHC network topologies for a five-building district with waste heat recovery were explored. A life cycle assessment method was used to calculate the total life cycle CO2 emissions (LCCO2) associated with the installation and operation of various network topologies. Twelve months of empirical data from a data center cooling system were analyzed to assess its suitability for integration into a 5GDHC system. The most suitable method for utilizing …

The Santa Clara, 2024-04-26, Santa Clara University

The Santa Clara

No abstract provided.

The Advancement Of Experimental And Computation Tools For The Study Of Molten Salt Chemistry To Facilitate The Extraction Of Strategic Elements In Nuclear Applications, Michael Stoddard

Theses and Dissertations

Nuclear energy presents environmental benefits, yet the challenge of radioactive waste management persists. Advanced solutions, such as Molten Salt Reactors (MSRs), require a more profound understanding of molten salt chemistry. This research aims to develop tools, including a depletion simulator, molten salt electrochemical simulator, and a fluoride-based thermodynamic reference electrode for electrochemical purification. The computationally inexpensive depletion simulator allows for exploration into extraction and processing strategies for molten salt reactors. An illustrative case study on Mo-99 production from MSRs demonstrates the practical application of the theoretical framework, emphasizing the need for optimization in extraction effectiveness and separation difficulty. The electrochemical …

Development Of Deployable Arrays For Satellites Through Origami-Pattern Design, Modeling, And Optimization, Nathan Mckellar Coleman

Theses and Dissertations

This research presents methods for modeling and optimizing an origami design using compliant mechanisms, improving origami design processes, modeling and analyzing rolling behavior of compliant designs, and an antenna design for SmallSats. A framework for the optimization of the origami Flasher pattern to mitigate issues with rigid-foldability is shown, and several optimization solutions are presented to overcome these issues. An alternative design method is presented which allows designers to more accurately predict the characteristics of a design in the deployed state, and configurations are shown for an example use case. A model for rolled gossamer structures is presented which predicts …

Laws Of Changes In The Energy Of Gas Hydrate-Bearing Coals Under Different Confining Pressures And Saturations, Zhu Wei, Gao Xia, Zhang Baoyong, Wu Qiang

Coal Geology & Exploration

Gas hydration for the solidification of coal seams susceptible to outbursts is a novel technology used to prevent coal and gas outbursts by reducing gas pressure and enhancing coal strength. However, an unclear understanding of the failure characteristics and the energy dissipation law of gas hydrate-bearing coals under different confining pressures and saturations leads to the lack of a theoretical basis for the prevention of dynamic disasters such as field coal and gas outbursts in deep mines. Based on the deviatoric stress-strain curves obtained using triaxial compression tests, this study calculated and analyzed the laws of changes in energy of …

Sulphate Contamination In An Abandoned Coal Mine In Light Of Mining Effects, Qi Yueming, Zhou Pei, Zhou Lai, Jiang Dan, Yang Yuqing, Liu Yanzhuo

Coal Geology & Exploration

Abandoned high-sulfur coal mines will become deeply buried acid-producing contamination sites, posing hazards to adjacent aquifers and surrounding environments. Furthermore, mining effects and the complex spatial distribution of abandoned mines complicate the assessment of the contamination processes and degrees in adjacent aquifers. Focusing on a certain abandoned coal mine, this study examined the migration characteristics of SO₄ ²⁻ pollution in acid mine drainage using numerical simulations by taking sulfate (SO₄ ²⁻) as the characteristic contaminant and considering the effects of the fractures formed by the mining of multiple coal seams on the aquifer structure. Furthermore, it analyzed …

Three-Dimensional Forward Modeling Using The Transient Electromagnetic Method Under Complex Terrains And The Analysis Of Terrain Effects, Qu Shaobo, Zhu Jiao, Jiang Zhihai, Li Maofei, He Zhilong

Coal Geology & Exploration

The ground-based transient electromagnetic method (TEM), with unique advantages, has been extensively applied for hydrogeological exploration in coal mines. However, in field exploration, complex terrains tend to cause variations in geometric shapes of transmitting sources and deviations in signals received, reducing exploration accuracy. Hence, by integrating theoretical analysis and numerical simulations with the analysis of actual terrain data, this study systematically investigated the response characteristics of electrical- and magnetic-source TEM fields under complex terrains. Using the vector finite-element electromagnetic forward modeling technique based on second-order backward Euler discretization, this study delved into the laws of influence of peak and valley …

Exploring The Detection Performance Of Different Array Configurations For Multi-Electrode Resistivity Method Tomography Using A 2.5d Finite Element Method, Zhao Rongchun, Lyu Yuzeng, Zhang Zhi, Wei Liuye, Pan Hongxu

Coal Geology & Exploration

Multi-electrode resistivity method is equipped with various electrode array configurations. Due to their different electrode arrangements, various electrode array configurations tend to exhibit significantly varying detection effects under different survey environments. Hence, to achieve satisfactory detection effects using high-resolution electrical resistivity tomography, it is necessary to explore the strategy for choosing appropriate array configurations targeting different objects in practical work. Given the high applicability of the method, its forward and inversion calculations remain a critical task. Based on the differential equations to be satisfied by the point source potential in a three-dimensional structure, this study derived the variational problem to …