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The Electrochemical Behavior Of Molybdenum In Acidic Chloride Solutions, Mun-Shan Lee

Masters Theses

"The anodic dissolution of Mo was studied in HC1-KC1 solutions at 25ºC. The apparent valences of Mo ions going into solution were approximately six. Lower values were obtained in HC1 solutions, with the most pronounced changes occurring with the higher concentrations. The resultant ions in solution were Mo-VI. The Mo surface in aqueous solutions appears to be covered with an oxide whose approximate composition is Mo₂O₅. The anodic dissolution is controlled by the oxidation of the surface oxide (Mo₂O₅) to MoO₃"--Abstract, page 1.

Shear Strength Characteristics Of Crushed Glass, Fred Ray Browning

Masters Theses

"Drained and undrained triaxial compression tests were performed on two gradations of crushed glass in order to determine the compressibility and shear strength characteristics. Consolidation pressures varied from 10 to 100 psi. Volume changes during consolidation were discussed because of the dependency of shear strength behavior on the density condition at the end of consolidation. Stress-strain-volume change characteristics were observed in order to discuss the load-deformation and dilatancy relationships and the effects of varying density, gradation and consolidation pressure. Stress-strain properties were also determined for the undrained tests. The undrained tests were constant volume tests, thus having no dilatancy effects. …

Shear Degradation Of Polystyrene In Toluene, Ali Asghar Sarmasti

Masters Theses

"The purpose of this study was to investigate the extent of flow degradation of narrow molecular weight distribution polystyrene samples under the conditions of laminar flow in capillary tubes. In all cases the solvent was toluene at 25ºC, the polymer concentration was 0.1 weight percentage, and the calculated shear rate at the wall was in the range of 10⁵ - 10⁶ sec⁻¹. The extent of degradation was obtained by measuring the intrinsic viscosity [eta] of the polystyrene samples before and after flow through capillary tubes having a wide range of length/diameter (L/D) ratios. The polystyrene samples here had molecular weight …

Comparison Of The Buckley-Leverett Technique With A Numerical Simulation Model Containing Heterogeneity And Capillary Pressure, Krishna Kumar Singh

Masters Theses

"A numerical model for a linear, two-phase fluid flow system has been developed with the capabilities of accounting for heterogeneity and capillarity. The model developed is general enough to analyze either water-oil or gas-oil systems. A hypothetical petroleum reservoir (containing only water and oil) under water flood was studied. The results for the homogeneous, no capillary pressure case were found to be similar to those obtained by the Buckley-Leverett technique. The study shows that the Buckley-Leverett is accurate even for a certain degree of heterogeneity. Also, capillarity does not substantially alter the results for the system studied. The results obtained …

Failure Of Lined And Unlined Small-Scale Cavities In Rock-Like Materials, Seung-Ki Yang

Masters Theses

"The strain conditions around statically loaded circular openings in rock-like materials and corresponding cavity-wall displacements were determined experimentally with resistance strain gages. The models were fabricated with lined and unlined openings simulating underground tunnels. Tests were performed with models of two different materials in plane stress and plane strain. Rock-like materials were designed and the strain gages were embedded at selected points within each model. The models often failed by tensile splitting through the opening early in the loading cycle causing the strains at certain points to deviate considerably from the theoretical values. Tangential strains on the vertical axis were …

The Anodic Dissolution Of Molybdenum In Acidic Nitrate Solutions, Kuan-Hsiung Hoh

Masters Theses

"The anodic dissolution of molybdenum in 1.0 N HNO₃ (pH = 0.3) , 0.1 N HNO₃-0.9 N KNO₃ (pH = 1.2), and 0.01 N HNO₃ -0.99 N KNO₃ (pH = 2.1) was investigated. The following conclusions were possible: 1. Mo is in general electrochemically oxidized to the Mo-VI state during anodic dissolution. 2. The resultant ions in solution are HMOO⁻₄. 3. The Mo surface in aqueous solutions is covered with an oxide whose approximate composition is Mo₂O₅. 4. The polarization curves have a linear Tafel region at potentials slightly above the rest potential. 5. There is no significant effect of …

Measurement Of Thermal Accommodation Coefficients Of Steel Surfaces, Wing On Ho

Masters Theses

"The thermal accommodation coefficient plays an important role in low density thermal energy transfer measurement. The object of this investigation was to measure the thermal energy transfer between a heated test surface and a water cooled reference surface (flat black lacquer) consisting of two infinite concentric cylinders separated by dry air. Two machined and sanded steel cylinders with mean surface roughnesses of 25 microinches and 7.5 microinches were used as the test surfaces . Measurements were made in the pressure range of 1.2 x 10⁻⁶ mm Hg. to 1.8 x 10⁻⁶ mm Hg. and temperature range for test cylinders of …

Study Of Neutron Reflection From A Curved Surface Using The Monte Carlo Method, Marion Jay Rackley

Masters Theses

"The reflection patterns for neutrons impinging on both an infinite parabola and an infinite slab were studied using the Monte Carlo method. In the first case neutrons were sent into an infinite parabola (z =x²/2) moving on the XZ plane parallel to the z axis at 5 points, namely: y = 1.5, x = -1.5; y = 1.5, x = -.75; y = 1. 5, x = 0. 0; y = 15, x =.75; y = 1.5, x = 1.5. The results were that there appeared to be a "focusing" of the scattered neutrons. In the second case, neutrons were …

The Anodic Oxidation Of Oxalic Acid On Au, Steven C. Mueller

Masters Theses

"The anodic oxidation of oxalic acid on Au has been studied at 80°C in aqueous media. The reaction rate was measured as a function of potential, oxalic acid concentration, pH, and temperature in H₂SO₄-K₂SO₄-KOH solutions of unit ionic strength. The oxalic acid was oxidized only in acidic media. The oxidation to CO₂ was essentially complete. A first order dependence of the rate on both pH and undissociated oxalic acid was found. A mechanism is proposed in which the first decarboxylation is the rate determining step"--Abstract, page 1.

Radiative Heat Transfer Analysis From A Heated Airport Runway To Fog, Gordon L. Scofield, Tom J. Love

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Radiative heat transfer between a plane source and an aerosol is investigated through the Monte Carlo method. Thermal energy is transferred from a long rectangular source to monodisperse natural fog models. The analysis is only for radiative transport and does not include convection which would be coupled in a complete analysis. Direct energy transfer to the droplets of the aerosol is investigated for values of extinction coefficient of 10 km-1 and 80 km-1, absorption coefficient to extinction coefficient ratios of 0·4 and 0·5, and scattering functions of the strong forward and isotropic types. Monochromatic radiation at a wave length of …

Simulation Of A Gas Storage Reservoir With Leakage By A Two-Dimensional Layered Mathematical Model, Steven William Ohnimus

Doctoral Dissertations

"A generalized mathematical model was developed for two-dimensional compressible fluid flow accounting for the effects of relative permeability capillary pressure, and gravity drainage in addition to the reservoir properties of rock heterogenity and reservoir geometry. The generalized model developed was applied to an aquifer gas storage reservoir in which vertical leakage occurred from the main reservoir to two adjacent overlaying zones. The experimental results of Thomas, et al. were utilized in applying the model to gas storage injection/withdrawal periods yielding reasonable results for the three layers"--Abstract, page ii.

A Permeability Scaling Technique In The Numerical Simulation Of Water Coning, Virendra Kumar Dutta

Masters Theses

"A two-dimensional, two-phase, radial, horizontally layered water coning simulator was programmed for large memory digital computers. A permeability sealing technique is developed which allows the use of large size blocks as production blocks. As a result of this technique large time steps have been used without causing saturation instabilities around the well bore and the permeability scaling technique allows a more realistic simulation of a water cone. The IMPES method is used to calculate pressure and saturation in the system for each finite time step. The behaviour of the simulator is studied for various factors affecting the advance of a …

A Study Of The Effects Of Added Solid-Liquid Interfacial Area On The Stabilization Characteristics Of Simulated Wastewater Stabilization Lagoons, Gary Lee Gaines

Masters Theses

"Wastewater stabilization lagoons have recently become a popular and efficient method of sewage stabilization in many parts of the country. The purpose of this investigation was to determine the effect of added solid-liquid interfacial area on the treatment capabilities of simulated wastewater stabilization lagoons. The simulated lagoons consisted of six -15 gallon aquariums which were operated in the laboratory. The solid-liquid interfacial area was increased in four of these lagoons by suspending plastic panels in the aquariums. The lagoons were operated for a period of approximately two and a half months using dehydrated milk as a simulated waste substrate. During …

The Design, Construction And Experimental Verification Of A Split Hopkinson Bar, Woosoon Bai

Masters Theses

"This thesis presents the design considerations for a dynamic loading device utilizing a projectile fired from a tube. Also included is a preliminary investigation of the stress-strain relation, under dynamic loading with the device, for a plaster known as Hydrostone. Design of the unit is based on the split Hopkinson pressure bar originally developed by Kolsky and on a similar unit in use at the Lawrence Radiation Laboratory, Livermore, California. The strain pulses along the pressure bars are sensed by resistance wire strain gages and displayed on an oscilloscope. The oscilloscope traces are photographed and manually digitized for insertion into …

The Anodic Dissolution Of Tungsten, Ching-Lun Wu

Masters Theses

"The anodic dissolution of tungsten was studied in H₂SO₄-K₂SO₄ solutions (pH= -2 to 2.5) andK₂SO₄-K₂CO₃-KOH solutions (pH = 11.5 to 14.5) at 25ºC. Faradaic efficiency studies in basic solutions showed that the metal was oxidized to the +6 state. In acid solutions, a thick protective film of yellow WO₃ was formed. Polarization measurements showed linear Tafel behavior (slope ~ 2.3RT/F) in the potential region slightly more positive than the rest potentials. An anodic dissolution mechanism is proposed which involves a surface film of W₂O₅ that is further oxidized to WO₃ and dissolves by hydrolyzation"--Abstract, page 1.

Removal Of Phosphate By Sorption On Activated Alumina, Checkman Michael Yue

Masters Theses

"The purpose of this investigation was to study the removal of phosphorus from waste water by sorption on activated alumina, and determine the capacity of the alumina to sorb phosphates in the presence of other ions, the effect of the influent flow rate and phosphorus concentration on the efficiency of the process, and the feasibility of regeneration of the used alumina. The studies were conducted using deionized and tap water to which inorganic phosphate had been added, and secondary effluent from bench-scale activated sludge units. They involved batch tests employing three types of activated alumina, ALCOA XM (minus 325 mesh), …

References [1969], Kentucky Transportation Center

Kentucky's Annual Forum on Transportation

No abstract provided.

Finite Element Analysis Of Nonlinear Soil Media, Y. H. Huang

Kentucky's Annual Forum on Transportation

No abstract provided.

Twenty-First Kentucky Highway Conference Committee, Kentucky Transportation Center

Kentucky's Annual Forum on Transportation

No abstract provided.

Experimental Investigation Of The Hydrodynamic Stability Of Flow In Rotating Pipes Using Thermistors, Hassan M. Nagib, Ludwig Wolf Jr.

Symposia on Turbulence in Liquids

The hydrodynamic stability of flow in a rotating pipe Is investigated experimentally using thermistors. The experimental apparatus consists of a rotating pipe made of lucite, 3-1/4 inch inside diameter, six feet long, equipped with porous plugs at the ends to minimize recirculation. The working fluid is water and a range of axial and tangential Reynolds numbers up to 7,000 and 20,000, respectively, is covered. Thermistors were chosen for this study since their high electrical resistivity yields strong signals which permit the use of inexpensive and convenient electronics. They also have a high temperature coefficient of electrical resistance which minimizes the …

Industrial Arts Research Methods, Clinton E. Langstraat

Graduate Research Papers

This report has been compiled as one of the culminating activities of 33:292 Industrial Arts Research Methods. This paper can be considered as a written record of the students' and instructor's efforts in establishing further guidelines for work in 33:270, and related activities. Consequently, the report is not highly technical in nature and the number of citations is considerably less than may be found in a typical report written for graduate credit.

However, it is the opinion of the writer that some valuable information has been recorded and it is his hope that some future graduate student may find it …

Chemistry Of The Oxidant, Ferrate, Its Interaction With Specific Organics Found In Waste Water, Donald H. Williams, J. T. Riley

KWRRI Research Reports

It became obvious during this investigation that while much work has been done with ferrate (VI) chemistry, discrepancies existed in the literature and very little attention had been given possible engineering uses. This work attempted to fulfill these two needs in an exploratory manner.

The preparative techniques were reviewed and mechanical improvements made in one which allowed improved yields. Essentially what was done was to enlarge and improve the filtering technique of the product and use cooler temperatures throughout the preparation. This greatly shortened the time required. Then it was learned that the addition of ethyl alcohol to the final …

Thin Layer Ionophoresis Of Sugars, Joseph Gilbert Vrindten

Theses

In 1952, Consden and Stanier published a report on paper ionophoresis of sugars in which they showed experimentally an increase in mobility of sugars with increasing pH in borate buffers. The object of the experiments in this thesis was to determine if this finding was also true of thin layer plates, there being no published literature on similar experiments using thin layer ionophoresis.

Glass plates 20 cm. x 20 cm. were coated with a 300 micron layer of cellulose powder and dried at 105° C. for one hour. They were then stored in an airtight tin box until ready for …

The Irish Plumbing And Heating Engineer, June 1969 (Complete Issue)

Building Services Engineering

No abstract provided.

Summary And Conclusions Of The Mining Environmental Conference, Thomas Ware

Mining Environmental Conference

No abstract provided.

Professional Engineer And Educator Viewpoint, J. D. Forrester

Mining Environmental Conference

No abstract provided.

Clean Air, Kenneth W. Nelson

Mining Environmental Conference

No abstract provided.

So₂ Problems, Erle K. Diehl

Mining Environmental Conference

No abstract provided.

Air Pollution Control In The Cement Industry, Russell E. Hailstone

Mining Environmental Conference

No abstract provided.

Procedures Following Mine Fires And Explosions, W. R. Park

Mining Environmental Conference

No abstract provided.