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Hafnium Oxide-Based Nanoheterostructures For Catalytic Radiosensitization And Enhanced X-Ray Radiotherapy, Marlen Dariela Calix Quezada Jan 2025

Hafnium Oxide-Based Nanoheterostructures For Catalytic Radiosensitization And Enhanced X-Ray Radiotherapy, Marlen Dariela Calix Quezada

Theses and Dissertations

Orthovoltage X-ray beams are attractive for surface and intra-operative radiotherapy. Yet, their clinical utility is constrained by rapid attenuation and the limited dose that can be delivered without harming healthy tissue. High-Z hafnium oxide (HfO2) nanoparticles can boost local energy deposition through the photoelectric effect, while catalytic surface defects accelerate water radiolysis. Harnessing both mechanisms in a single nano-heterostructure could enable potent radiosensitization at diagnostic-range energies.

This thesis develops and evaluates HfO2-based nanoheterostructures, both bare and Au-decorated, as catalytic radiosensitizers.

Two types of HfO2 were evaluated, one was synthesized following a specific route and the …


Visible Modulation Of Epsilon Near Zero Materials, Jonathan M. Weber Jan 2025

Visible Modulation Of Epsilon Near Zero Materials, Jonathan M. Weber

Theses and Dissertations

While Epsilon-Near-Zero materials have offered many benefits from their introduction to the field of nonlinear optics, those materials have also narrowed the range of wavelengths often studied. With reliable and proven enhancements to light-matter interaction in the ENZ region, many researchers have had little reason to extend the spectrum measured in experiments. The purpose of this work is to measure the intensity dependent refractive index of Indium Tin Oxide across a broad spectral range, from ultraviolet to near infrared, to improve the understanding of semiconductor nonlinearities far from Lorentz and Drude resonances. Furthermore, the visible region is naturally low-loss in …


Plasmon-Assisted On-Chip Integration Of Quantum Emitter For Scalable Quantum Networking, Samprity Saha Jan 2025

Plasmon-Assisted On-Chip Integration Of Quantum Emitter For Scalable Quantum Networking, Samprity Saha

Theses and Dissertations

In recent decades, quantum theory has sparked a revolutionary outlook on our long-standing perception of information processing and communication technologies. Photon-based quantum systems, relying on single photons governed by quantum mechanics, hold immense promise for quantum networks due to their resilience against decoherence and fast propagation speeds. However, challenges persist in realizing practical quantum networks, including the need for scalable, robust, and cost-effective quantum light. To address these challenges with classical photonic concepts, this thesis focuses on a plasmon-assisted approach for on-chip integration of single-photon sources. The study aims to develop a scalable solution for integrating quantum emitters on-chip, leveraging …


Reverse Geometric Dispersion In The Beaufort Sea: Dissecting Sound Propagation At Long Ranges In Ducted Profiles, Jessica Desrochers Jan 2025

Reverse Geometric Dispersion In The Beaufort Sea: Dissecting Sound Propagation At Long Ranges In Ducted Profiles, Jessica Desrochers

Open Access Dissertations

Acoustic propagation in the Arctic is evolving as surface temperatures increase and ice melts, resulting in a changing sound propagation environment. This study investigates the acoustic arrival structure in the Canada Basin and its connection to the underlying sound speed profiles. Two Seagliders were deployed in the summer of 2016 and 2017, diving in a sawtooth pattern collecting conductivity, temperature, and depth (CTD) data as part of the Canada Basin Acoustic Glider Experiment (CABAGE). These data are used to calculate sound speed profiles used to predict and understand acoustic arrival structures.

The warming of the Pacific Summer Water and surface …


Hypnosis And Mindfulness Audio Recordings For Reducing Fatigue In Individuals With Multiple Sclerosis: A Randomized Controlled Study, Mark P. Jensen, Susan Robles, Michael G. Nash, Susanne May, Dwan M. Ehde, Melissa A. Day, Owen Gottlieb, Laurence I. Sugarman, Kevin N. Alschuler Jan 2025

Hypnosis And Mindfulness Audio Recordings For Reducing Fatigue In Individuals With Multiple Sclerosis: A Randomized Controlled Study, Mark P. Jensen, Susan Robles, Michael G. Nash, Susanne May, Dwan M. Ehde, Melissa A. Day, Owen Gottlieb, Laurence I. Sugarman, Kevin N. Alschuler

Articles

Background

Fatigue is a common problem in individuals with multiple sclerosis (MS).

Objective

The objective was to evaluate the effects on fatigue of having 4 weeks of

access to audio recordings of therapeutic hypnosis (HYP) and mindfulness meditation

(MM) practices.

Methods

A total of 333 individuals with MS and fatigue were randomly assigned to

one of the three treatment conditions for 28 weeks: (1) access to therapeutic HYP audio

recordings, (2) access to MM audio recordings, or (3) no access to recordings

(treatment as usual or TAU). Fatigue impact (primary outcome) and other outcomes

were assessed at 4, 16, and …


Characterization Of A Large-Scale Electrohydrodynamic Vortex Confinement Flow For Particle Agglomeration, Sanjay Dangi Jan 2025

Characterization Of A Large-Scale Electrohydrodynamic Vortex Confinement Flow For Particle Agglomeration, Sanjay Dangi

Graduate Research Theses & Dissertations

With industrialization and the increasing use of microplastics and nanoparticle-based products, the concentration of fine particulate matter (PM2.5) in the biosphere has increased due to the disposal of manufacturing waste and expired parts. If inhaled, PM2.5 can have detrimental health effects, as these particles can travel deep into the lungs and even penetrate blood vessels. Conventional fabric filters used for indoor air quality control have drawbacks, including the need for periodic filter replacement and a high-pressure drop across the filter over time, which leads to increased power consumption. In power plants, electrostatic precipitators (ESPs) are primarily used to collect fly …


Piv Visualization Of A Sinusoidal Ehd Confinement Flow Induced By Variation In Ion Density For Electrostatic Particle Agglomeration, Md Eyasin Hossain Jan 2025

Piv Visualization Of A Sinusoidal Ehd Confinement Flow Induced By Variation In Ion Density For Electrostatic Particle Agglomeration, Md Eyasin Hossain

Graduate Research Theses & Dissertations

Long-term exposure to PM2.5, which is responsible for four million cardiovascular-related deaths worldwide, is a major concern as people spend 90% of their time indoors. Fabric filters have been commonly utilized for particle pollution control in indoor settings. However, the maintenance cost of fabric filters is relatively high, as particle accumulation on filters can lead to higher pressure drops (45 ∼ 300 Pa) and energy consumption, as well as the growth of biological organisms and the generation of airborne pathogens. An electrostatic precipitator (ESP) is filterless and widely used in the electric power industry for collecting coal fly ash. ESPs …


Md Simulation Of Femtosecond Laser-Controlled Melting Of Multiple Core-Shell Nanoparticle Systems, Shivansh Patel Jan 2025

Md Simulation Of Femtosecond Laser-Controlled Melting Of Multiple Core-Shell Nanoparticle Systems, Shivansh Patel

Graduate Research Theses & Dissertations

This thesis presents a molecular dynamics (MD) simulation study of femtosecond laser-induced melting and heat transfer in multiple Cu–Al core–shell nanoparticle systems. The research builds upon previous single-particle studies and extends the investigation to multiple interacting nanoparticles to better understand nanoscale thermal transport and melting behavior under ultrafast laser irradiation. Understanding this process is essential for improving laser-based additive manufacturing and sintering of metal matrix nanocomposites (MMNCs), where precise control of heat flow and particle bonding determines the final material quality. The simulations were performed using the Large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS) integrated with the Modified Two-Temperature Model (MTTM). …


Intercellular Mitochondrial Transfer Contributes To Microenvironmental Redirection Of Cancer Cell Fate, Julie Sofie Bjerring, Yara Khodour, Emilee Anne Peterson, Patrick Christian Sachs, Robert David Bruno Jan 2025

Intercellular Mitochondrial Transfer Contributes To Microenvironmental Redirection Of Cancer Cell Fate, Julie Sofie Bjerring, Yara Khodour, Emilee Anne Peterson, Patrick Christian Sachs, Robert David Bruno

School of Medical Diagnostics & Translational Sciences Publications

The mammary microenvironment has been shown to suppress tumor progression by redirecting cancer cells to adopt a normal mammary epithelial progenitor fate in vivo. However, the mechanism(s) by which this alteration occurs has yet to be defined. Here, we test the hypothesis that mitochondrial transfer from normal mammary epithelial cells to breast cancer cells plays a role in this redirection process. We evaluate mitochondrial transfer in 2D and 3D organoids using our unique 3D bioprinting system to produce chimeric organoids containing normal and cancer cells. We demonstrate that breast cancer tumoroid growth is hindered following interaction with mammary epithelial cells …


Systematic Co-Culture Of Ipsc-Cm And Ipsc-An Promote Co-Maturation In Vitro, William Gregory Terrell Jr. Jan 2025

Systematic Co-Culture Of Ipsc-Cm And Ipsc-An Promote Co-Maturation In Vitro, William Gregory Terrell Jr.

Graduate Dissertations and Theses

The cardiac microenvironment is a complex system of multicellular interactions that enables proper heart function. In native heart muscle, sympathetic neurons (SN) and parasympathetic neurons (PSN) modulate the beat rate of cardiomyocytes (CM) to maintain homeostasis. Pluripotent stem cells can differentiate into CM, but differentiated CMs are fetal-like, with a high beat rate, and lack organized sarcomeric structure. Recent reports of co-cultured pluripotent CM/SN pairs have reported electrophysiological changes in the SN (increased upstroke velocity). However, interpretation of these results are obscured by the differences in co-culture parameters between studies (stage of development, co-culture duration, etc.). The goal of this …


Zirconium-Based Amphoteric Metal–Organic Framework Membrane For Blue Energy Harvesting, Rockson Kwesi Tonnah, Milton Chai, Mohammad Khedri, Milad Razbin, Yasaman Boroumand, Reza Maleki, Huan Xiao, Amir Razmjou, Mohsen Asadnia Jan 2025

Zirconium-Based Amphoteric Metal–Organic Framework Membrane For Blue Energy Harvesting, Rockson Kwesi Tonnah, Milton Chai, Mohammad Khedri, Milad Razbin, Yasaman Boroumand, Reza Maleki, Huan Xiao, Amir Razmjou, Mohsen Asadnia

Research outputs 2022 to 2026

Salination of solutions of salinity gradient releases large-scale clean and renewable energy, which can be directly and efficiently transformed into electrical energy using ion-selective nanofluidic channel membranes. However, conventional ion-selective membranes are typically either cation- or anion-selective. A pH-switchable system capable of dual cation and anion transport along with salt gradient energy harvesting properties has not been demonstrated in ion-selective membranes. Here, we constructed an amphoteric heterolayer metal–organic framework (MOF) membrane with subnanochannels modified with carboxylic and amino functional groups. The amphoteric MOF-composite membrane, AAO/aUiO-66-(COOH)2/UiO-66-NH2, exhibits pH-tuneable ion conduction and achieves osmotic energy conversion of 7.4 and 5.7 W/m2 …


Navigating Big Data In Cyber Archaeology: An Updated Four-Field Approach Applied To San Miceli, Jared Wilson Jan 2025

Navigating Big Data In Cyber Archaeology: An Updated Four-Field Approach Applied To San Miceli, Jared Wilson

Dissertations

Problem

This dissertation examines the evolving role of digital technologies in archaeological research, focusing on the management and interpretation of extensive digital datasets generated by modern excavations. Drawing on six years of comprehensive fieldwork at San Miceli, Sicily, this study critically evaluates and updates the established four-field methodology proposed by Levy et al. (2012), encompassing acquisition, analysis, dissemination, and curation. While traditional archaeological documentation methods rely heavily on analog techniques, these approaches increasingly fall short due to the rapid expansion and complexity of digital data.

Method

To address this gap, the dissertation refines and expands the current methodological framework by …


Flame Boundary Effects Of Hydrogen-Air Premixing, Alecson L. De Lima Junior Jan 2025

Flame Boundary Effects Of Hydrogen-Air Premixing, Alecson L. De Lima Junior

Honors Undergraduate Theses

The objective of this research was to investigate the reaction of hydrogen and heated air premixing when injected into a combusting ethylene-air crossflow, and to study the flame stabilization location with varying premixing levels. The main parameter of this investigation was the flame stabilization diagnosed through chemiluminescence, based on recorded equivalence ratio, temperature, and flame boundaries, and maintaining a constant air temperature, hydrogen and air mass flow, and momentum flux ratios. Testing was conducted at different ratios of hydrogen and air premixing achieved through alternating the distance between the point where hydrogen and air are mixed and the combusting crossflow. …


Bibliometric Analysis With R Biblioshiny On Safety Behavior In Aviation, Büşra Yıldırım, İnan Eryılmaz, Ahmet Karacan, Nusret Erceylan Jan 2025

Bibliometric Analysis With R Biblioshiny On Safety Behavior In Aviation, Büşra Yıldırım, İnan Eryılmaz, Ahmet Karacan, Nusret Erceylan

International Journal of Aviation, Aeronautics, and Aerospace

Safety behaviors in aviation are not limited to technical knowledge and skills in ensuring the safety of flight operations, but also include the attitudes, decision-making processes and collaborations of individuals and teams. In this context, in this study, a bibliometric analysis of publication and citation trends, key concepts and interactions of studies in the field was conducted to identify current and potential trends in aviation and safety behavior-based research, and to explore the intersections between safety behavior and aviation studies and the areas waiting to be explored. The bibliometric analysis using the RStudio-based Biblioshiny program was conducted on 1065 articles …


Afit Generative Ai Teaching Guidebook, Afit Faculty Learning Community, Mark G. Bateman, Brett J. Borghetti, Allen W. Dukes, Nicholas C. Francis, Mike Frick, Bobbie Oh, Kevin Patterson, Hiren J. Patel, Mark G. Reith, Erick S. Tyndall, Teresa M. Walton, Torrey J. Wagner, Timothy S. Wolfe, Jonathan Zemmer Jan 2025

Afit Generative Ai Teaching Guidebook, Afit Faculty Learning Community, Mark G. Bateman, Brett J. Borghetti, Allen W. Dukes, Nicholas C. Francis, Mike Frick, Bobbie Oh, Kevin Patterson, Hiren J. Patel, Mark G. Reith, Erick S. Tyndall, Teresa M. Walton, Torrey J. Wagner, Timothy S. Wolfe, Jonathan Zemmer

AFIT Documents

AFIT is proud to highlight the Generative AI Teaching Guidebook, a resource designed to provide military educators with practical insights, strategies, and use cases for integrating Generative AI (Gen AI) into their teaching practices. Developed through a collaborative effort involving AFIT faculty across various departments within the Graduate School of Engineering and Management and the School of Systems and Logistics, this digital resource serves as a starting point for educators exploring how to leverage Gen AI in their classrooms. It offers accessible examples and best practices, ensuring utility for instructors of all technical backgrounds. The guidebook provides a comprehensive overview …


A Comprehensive Exploration Of 6g Wireless Communication Technologies, Md Nurul Absar Siddiky, Muhammad Enayetur Rahman, Md. Shahriar Uzzal, H. M. Dipu Kabir Jan 2025

A Comprehensive Exploration Of 6g Wireless Communication Technologies, Md Nurul Absar Siddiky, Muhammad Enayetur Rahman, Md. Shahriar Uzzal, H. M. Dipu Kabir

Electrical & Computer Engineering Faculty Publications

As the telecommunications landscape braces for the post-5G era, this paper embarks on delineating the foundational pillars and pioneering visions that define the trajectory toward 6G wireless communication systems. Recognizing the insatiable demand for higher data rates, enhanced connectivity, and broader network coverage, we unravel the evolution from the existing 5G infrastructure to the nascent 6G framework, setting the stage for transformative advancements anticipated in the 2030s. Our discourse navigates through the intricate architecture of 6G, highlighting the paradigm shifts toward superconvergence, non-IP-based networking protocols, and information-centric networks, all underpinned by a robust 360-degree cybersecurity and privacy-by-engineering design. Delving into …


The Effect Of Need For Cognition & Need For Affect On Human Reliance And Artificial Intelligence Interactions, Aliyah Mcgowan Jan 2025

The Effect Of Need For Cognition & Need For Affect On Human Reliance And Artificial Intelligence Interactions, Aliyah Mcgowan

Doctoral Dissertations and Master's Theses

Abstract

With the increased use of Artificial Intelligence (AI) automations in fields like medical diagnoses and mental health queries, there are concerns regarding an individual’s trust and reliance on the technology. Reliance on AI output may lead an individual to accept inaccurate or incorrect information without further analysis. Trust may influence reliance and trust formation may be a product of affective processing. This study investigated the relationship between Need for Affect (NFA), Need for Cognition (NFC), and trust and reliance on AI interactions. Participants were assessed on the NFA scale for willingness to approach or avoid emotional stimuli, the NFC …


Dielectric Performance Of Fused Filament Fabricated Ultem 9085 For Naval Radome Application, Carson Rogers Jan 2025

Dielectric Performance Of Fused Filament Fabricated Ultem 9085 For Naval Radome Application, Carson Rogers

UNF Graduate Theses and Dissertations

ULTEM 9085 is a high-performance thermoplastic used in the fused filament fabrication (FFF) additive manufacturing process. It has found use in applications where mechanical strength, chemical integrity, and thermal stability are of paramount importance. In this thesis, the effects of process parameters, annealing, and weathering on the mechanical and dielectric properties of FFF ULTEM 9085 have been investigated.

The first part reviews existing research on how printing parameters such as nozzle temperature, chamber temperature, print speed, infill, and layer height affect the mechanical performance of FFF ULTEM 9085. Data from the manufacturer of commonly used ULTEM 9085 filament, Stratasys, has …


Enhanced Photocatalytic Reduction Of Cr(Vi) Under Visible Light A Magnetically Separable Tio2-Fe/Fe3o4 Photocatalyst Prepared From Iron Rusty Waste, Khoirunisa Khoirunisa, Novianti Dwi Lestari, Endang Tri Wahyuni, Taufik Abdillah Natsir Jan 2025

Enhanced Photocatalytic Reduction Of Cr(Vi) Under Visible Light A Magnetically Separable Tio2-Fe/Fe3o4 Photocatalyst Prepared From Iron Rusty Waste, Khoirunisa Khoirunisa, Novianti Dwi Lestari, Endang Tri Wahyuni, Taufik Abdillah Natsir

Journal of Metals, Materials and Minerals

This research deals with enhancing the visible activity and generating the magnetic property of TiO2 by Fe doping and Fe3O4 impregnation respectively, using rusty iron waste as Fe source. The prepared TiO2-Fe/Fe3O4 photocatalysts were characterized by SR-UV/Visible, FTIR, XRD, and SEM-EDX instruments. The resulting photocatalysts are responsive to visible light and can be separated magnetically and used for photoreduction of Cr (VI) ions. In the photoreduction of Cr(VI) over TiO2-Fe/Fe3O4 photo-catalysts with various amounts of Fe dopant and alteration of Fe3O4 fraction, the photocatalyst mass, irradiation time, and solution pH were optimized. The research results assign that doping Fe to …


Impacts Of Calcination Temperature On The Crystallography, Granulometry And Impedance Of Licomno4, Chee Wayne Tan, Zul Hilmi Che Daud, Zainab Asus, Mohd Hasbullah Idris, Izhari Izmi Mazali, Mohd Kameil Abdul Hamid Jan 2025

Impacts Of Calcination Temperature On The Crystallography, Granulometry And Impedance Of Licomno4, Chee Wayne Tan, Zul Hilmi Che Daud, Zainab Asus, Mohd Hasbullah Idris, Izhari Izmi Mazali, Mohd Kameil Abdul Hamid

Journal of Metals, Materials and Minerals

Spinel structured lithium cobalt manganese oxide (LiCoMnO4) which exhibit reduction potential surpassing 5.0 V (vs. Li0 | Li+) was identified to be one of the prospective cathode candidates for next generation lithium-ion electrochemical systems. This article highlights the significance of calcination temperature on the crystallography of the resultant electroceramic compound as well as the corresponding response on the granulometry and impedance of LiCoMnO4. LiCoMnO4 compounds synthesised via sol-gel reaction in the first instance were converted into xerogel and subsequently subjected to facile one-step calcination protocol. Crystallography of the post-calcinated compounds were characterised via powder x-ray diffraction (XRD) technique. Temperature ranging …


Aluminium Oxide Particles-Containing Organogels For Cleaning Of Optical Glass Surfaces, Galina Vladimirovna Lyamina, Oksana Valerievna Dubinina, Alfa Edison I Lela Jan 2025

Aluminium Oxide Particles-Containing Organogels For Cleaning Of Optical Glass Surfaces, Galina Vladimirovna Lyamina, Oksana Valerievna Dubinina, Alfa Edison I Lela

Journal of Metals, Materials and Minerals

Hypothesis:  Some types of cleaning methods are not very effective and can actually increase damage to the optical parts being cleaned. As an alternative to these methods, we propose the use of gel-like substances to remove contaminants from optical surfaces. We have developed a method for cleaning optical glass surfaces that uses organogels, which are based on copolymers of methyl methacrylate and methacrylic acid. These organogels are loaded with polyethylene glycol, and aluminum oxide particles (Al2O3), which help to effectively remove contaminants without causing damage to the surface.   Experiments:  Al2O3 nanoparticles prepared by a Nano Spray Dryer were added to …


Simulating Positive Ion Distribution In The Protodune Single Phase Detector, Vishnu Pfeiffer Jan 2025

Simulating Positive Ion Distribution In The Protodune Single Phase Detector, Vishnu Pfeiffer

Electronic Theses and Dissertations

This work covers the validation and implementation of a model to solve for argon ion (Ar+) distribution in the ProtoDUNE-SP liquid argon time projection chamber (LArTPC). ProtoDUNE-SP undergoes a constant flux of cosmic ray muons due to surface operation. The performance of the ProtoDUNE-SP provided valuable insights into single-phase technology, membrane cryostat technology, and calibration of cryogenic instrumentation. Still, challenges in achieving precise measurements persist due to the space charge effect—the distortion of the electric field within the detector due to the accumulation of positive argon ions generated from constant cosmic muon flux. The overarching goal of this thesis is …


Safe Data-Enabled Control Of Human-In-The-Loop Robotic Manipulator Systems, Ritirupa Dey, Avimanyu Sahoo, Vignesh Narayanan Jan 2025

Safe Data-Enabled Control Of Human-In-The-Loop Robotic Manipulator Systems, Ritirupa Dey, Avimanyu Sahoo, Vignesh Narayanan

Publications

Safe control of human-in-the-loop (HIL) robotic manipulators is critical for applications such as assistive robotics, teleoperation in hazardous environments, and collaborative manufacturing. However, this remains challenging due to the lack of a unified framework that simultaneously addresses safety constraints, external disturbances, unmodeled dynamics, and dynamic role switching in the HIL setting. In this paper, we propose a novel NN-driven HIL control framework in which human–robot dyadic interaction occurs through the haptic channel. Using Lyapunov stability analysis, we theoretically show that the proposed NN-based controller ensures accurate joint trajectory tracking, compensates for system uncertainties, and adapts to human inputs modeled as …


Neuroinflammatory Signaling And Immune Cell Infiltration Differ In Brains Of Rats Exposed To Space Radiation And Social Isolation, Austin M. Adkins, Zachary N. M. Luyo, Alea F. Boden, Riley S. Heerbrandt, Richard A. Britten, Laurie L. Wellman, Larry D. Sanford Jan 2025

Neuroinflammatory Signaling And Immune Cell Infiltration Differ In Brains Of Rats Exposed To Space Radiation And Social Isolation, Austin M. Adkins, Zachary N. M. Luyo, Alea F. Boden, Riley S. Heerbrandt, Richard A. Britten, Laurie L. Wellman, Larry D. Sanford

Center for Integrative Neuroscience and Inflammatory Diseases (CINID) Faculty Publications

Astronauts on the proposed Mars missions will be exposed to extended periods of social isolation (SI) and space radiation (SR). SI and SR-induced immune dysregulation can result in persistent neuroinflammation and neuronal damage which could negatively impact an astronaut’s health and ability to maintain adequate levels of performance. The synergistic effects of combined SI and SR on immune system functionality and the brain remain unknown. Determining how single and combined inflight stressors modulate the immune system is crucial for fully understanding pathways impacting astronaut health and performance. We used ground-based analogs of SI and SR in rodent models to investigate …


Green Chelation Strategy For Deashing Of Algal Biomass, Agyare Asante, George Daramola, Ryan W. Davis, Sandeep Kumar Jan 2025

Green Chelation Strategy For Deashing Of Algal Biomass, Agyare Asante, George Daramola, Ryan W. Davis, Sandeep Kumar

Civil & Environmental Engineering Faculty Publications

This study investigated a green chelation strategy for deashing algal biomass using nitrilotriacetic acid (NTA) and deionized water (DI) to enhance its suitability for biofuel and bioproduct applications. Solid-state algal turf scrubber (SS ATS), green algal turf scrubber (ATS), and Scenedesmus were analyzed, with Scenedesmus selected for detailed evaluation due to its high ash removal efficiency. The objective was to optimize a purification process that minimizes ash and heavy metal content while preserving biochemical integrity. Algal biomass underwent sequential washing with DI, NTA, and NTA+DI under varying temperatures (90-130 °C). Analytical techniques including Fourier Transform Infrared (FTIR) spectroscopy, Inductively Coupled …


Biochar For Soil Amendment: Applications, Benefits, And Environmental Impacts, Ujjwal Pokharel, Gururaj Neelgund, Ram L. Ray, Venkatesh Balan, Sandeep Kumar Jan 2025

Biochar For Soil Amendment: Applications, Benefits, And Environmental Impacts, Ujjwal Pokharel, Gururaj Neelgund, Ram L. Ray, Venkatesh Balan, Sandeep Kumar

Civil & Environmental Engineering Faculty Publications

The excessive use of chemical fertilizers results in environmental issues, including loss of soil fertility, eutrophication, increased soil acidity, alterations in soil characteristics, and disrupted plant–microbe symbiosis. Here, we synthesize recent studies available from up to 2025, focusing on engineered biochar and its application in addressing issues of soil nutrient imbalance, soil pollution from inorganic and organic pollutants, soil acidification, salinity, and greenhouse gas emissions from fields. Application of engineered biochar enhanced the removal of Cr (VI), Cd²+, Ni²+, Zn²+, Hg²+, and Eu³+ by 85%, 73%, 57.2%, 12.7%, 99.3%, and 99.2%, …


The Bioremediation Of Nutrients And Heavy Metals In Watersheds: The Role Of Floating Treatment Wetlands, Nirmal Kumar, Bhupinder Singh, Yuanze Chen, Abishek Kafle, Ram L. Ray, Sandeep Kumar, Xiaonan Shan, Venkatesh Balan Jan 2025

The Bioremediation Of Nutrients And Heavy Metals In Watersheds: The Role Of Floating Treatment Wetlands, Nirmal Kumar, Bhupinder Singh, Yuanze Chen, Abishek Kafle, Ram L. Ray, Sandeep Kumar, Xiaonan Shan, Venkatesh Balan

Civil & Environmental Engineering Faculty Publications

Floating treatment wetlands (FTWs) are engineered systems that utilize floating platforms planted with aquatic vegetation to treat polluted water such as stormwater, agricultural runoff, and wastewater. FTWs have emerged as promising and environmentally sustainable solutions for water purification. This review synthesizes the current knowledge on FTW design, plant selection, and performance evaluation. It highlights key factors influencing nutrient and heavy metal removal, including the hydraulic retention time, mat thickness, and types of plant species. Recent findings on the roles of root architecture, microbial interactions, and seasonal variability in treatment efficiency are also discussed. Additionally, the review explores advanced analytical methods …


Contextual Augmentation In Artificial Intelligence, Emmanuel Joshua Balogun Jan 2025

Contextual Augmentation In Artificial Intelligence, Emmanuel Joshua Balogun

College of Graduate Studies: Theses & Dissertations

Contextual understanding is a significant challenge of Large Language Models (LLMs), which are typically trained on general-purpose datasets. Due to this, LLMs fail to capture nuanced or domain-specific information and may struggle to interpret user queries accurately. Consequently, prompt engineering can become complex in automating, and LLMs are prone to “hallucinating”—generating random or irrelevant texts—when they lack sufficient context. This undermines their ability to provide focused, accurate responses. Accordingly, this thesis seeks to enhance the contextual understanding capabilities of Artificial Intelligence systems to facilitate more precise and relevant answer generation. Study A looks into a new approach to combating misinformation …


Evaluation Of The Dnazyme Gr5 For The Determination Of Lead Speciation In Natural Waters, Gaganprit Gill Jan 2025

Evaluation Of The Dnazyme Gr5 For The Determination Of Lead Speciation In Natural Waters, Gaganprit Gill

Theses and Dissertations (Comprehensive)

This thesis explores the development and application of a DNAzyme-based biosensor designed to detect labile metal species in environmental samples. Real time and on-site monitoring of labile metal fractions would make a valuable contribution to environmental management, as these fractions are the most bioavailable and pose significant toxicity risks to aquatic organisms. Conventional methods for detecting labile metals, while effective, are often burdened by high costs, complexity, and lengthy processing times, making them less ideal for rapid and widespread environmental assessments.

The first manuscript of this thesis (chapter 2) establishes the fundamental capabilities of the Pb2+-specific DNAzyme GR5 …


Transport And Plugging Behavior Of Co2-Resistant Preformed Particle Gels In High Conductive Channels For Conformance Control, Adel Alotibi Jan 2025

Transport And Plugging Behavior Of Co2-Resistant Preformed Particle Gels In High Conductive Channels For Conformance Control, Adel Alotibi

Doctoral Dissertations

"Improving oil recovery is essential with rising global oil demand and declining production in mature fields. CO2 flooding has been widely applied as a major Enhanced Oil Recovery (EOR) method due to its effectiveness in boosting oil recovery while enabling safe carbon storage in the subsurface. However, in fractured and highly heterogeneous reservoirs, CO2 often flows through paths of least resistance, leading to early breakthrough or quick excessive CO2 production and leaving substantial oil in unswept zones or areas. Traditional in-situ polymer gels have been applied to control CO2 flooding conformance, their performance has been varied, …