Digital Commons Network^™

Nitrite Oxidation During Ozonation Revisited: Mechanisms Of Nitration Reactions, Tarek Manasfi, Christoph Dieziger, Simon A. Rath, Daisuke Minakata, Urs Von Gunten

Michigan Tech Publications

The formation of toxicologically relevant nitro compounds has been observed during ozonation of nitrite-containing secondary wastewater effluents, but their formation mechanism remains unknown. To identify key nitrating species, three reaction systems were investigated: ozonation of nitrite (O3/NO2^–), peroxynitrite (ONOOH/ONOO^–), and hydroxyl radical oxidation of nitrite with γ-radiolysis (γ/NO2^–). Nitrite ozonation (O3/NO2^–) yielded significant amounts of the nitrating agent nitrogen dioxide ^•NO2 (9.4% at pH 7 to 22% at pH 12) besides the main product nitrate. No peroxynitrite formation was detected during ozonation of nitrite-containing waters, suggesting that ^•NO2 is the …

Past Present, & Future: Bushwick Inlet Redevelopment, Aaryan Nair

Publications and Research

This report examines how ecosystem structure, hydrology, and material flows in Williamsburg, Brooklyn have changed from pre-colonial conditions to the present and how they are expected to evolve under future climate change. Prior to European colonization, the landscape functioned as a forest–wetland mosaic with high infiltration capacity, slow water movement, and strong nutrient retention. These conditions supported stable aquatic ecosystems and minimized pollutant transport to the East River.

Modern urbanization has fundamentally altered this system. Impervious surfaces and engineered drainage systems have shifted hydrology from infiltration-dominated to runoff-dominated pathways, producing rapid “flashy” flows and reducing water residence time.

Storm events …

Processing Mechanism And Efficacy Maintenance Strategy Of Ginseng Active Ingredients Based On Spectroscopy Technology, Yang Hantong, Kong Linghui, Jiang Mengmeng, Wang Yingxiu, Li Xiangguo

Food and Machinery

Ginseng, as a medicinal and edible plant, has ginsenosides as its core active components, which are widely applied due to their physiological functions such as antioxidant and anti-inflammatory activities; however, their structures and activities are easily affected by food processing. During processing steps such as cleaning, steaming/boiling, and fermentation, temperature, pH, and microbial enzyme systems alter the types, contents, and stability of active components through reactions such as hydrolysis and oxidation. The intrinsic linkage mechanism of "component transformation-activity-bioavailability" constitutes a core focus and challenge in current research. This study, based on spectroscopic techniques including high-performance liquid chromatography (HPLC), nuclear magnetic …

Use Of Smart Safety Devices And Artificial Intelligence And Its Impact On Workplace Injury Reduction In High-Risk Industries In Cameroon: A Qualitative Exploration Of Worker And Management Perspectives, John Atabong Zifac

Doctoral Dissertations and Projects

Workplace injury has been a significant concern within high-risk industries in Sub-Saharan Africa, especially Cameroon, with weak worker safety standards, poor infrastructure, lack of compliance with regulatory requirements, and a limited level of digital infrastructure contributing to a high risk of worker injury. While artificial intelligence (AI) supported smart safety technologies have revolutionized the way companies conduct workplace safety management in developed nations, little research exists on the perception of these technologies and practicality among low-resource industrial operators in Sub-Saharan Africa. This qualitative phenomenological study investigated management and employee perceptions regarding the use of AI-based smart safety devices to reduce …

Adaptive Intervention Strategies In Co-Evolving Multiplex Networks: A Reinforcement Learning Approach To Real-Time Misinformation Containment, Anjali Ashokrao Bhadre Dr., Harshvardhan Prabhakar Ghongade Dr.

Northeast Journal of Complex Systems (NEJCS)

The growing transmission of misinformation via social media creates serious challenges to public health, democracy and social cohesion. To date, methods used to contain misinformation rely upon static representations of networks and set rules for interventions. In contrast, this study presents the first Multiplex Adaptive Reinforcement Intervention Network (MARIN), a framework for real-time adaptive intervention in the context of dynamic misinformation transmission using co-evolving multiplex networks and deep reinforcement learning. Unlike past studies that have assumed static network structures, MARIN has the ability to allow for dynamic changes in network topology as a result of both misinformation transmission and intervention …

Skin Lesion Classification Using Cnn Model And Augmented Dataset, Mohammed Nawzad Mohammed-Ramzi, Aso M. Aladdin

Journal of Soft Computing and Computer Applications

Skin cancer is a deadly disease. Skin lesion classification is a critical challenge due to its prevalent and deadly nature. Skin lesions are difficult for dermatologists to detect using eye examination, which is time-consuming and variable. A deep learning model of skin lesions classification has been proposed using a Convolutional Neural Network (CNN) trained on the HAM10000 dataset of 10,015 dermatoscopies. To improve resilience and address the dataset's extreme class imbalance, data augmentation techniques such as geometric transformations, brightness/contrast adjustments, blurring, noise addition, histogram equalization, color space alterations, and elastic deformations are used. With a carefully balanced 10% test set, …

Enhanced Thermal Energy Storage In Buildings: Impregnation, Leakage, And Environmental Performance Of Organic And Inorganic Pcm Composites, Gökhan Genç, Esra Yılmaz, M. Yusuf Yazıcı

Journal of Sustainable Construction Materials and Technologies

This study experimentally investigates the impregnation and leakage performance of various organic (tobacco, sawdust, bay leaf, black cumin) and inorganic (vermiculite, perlite, bentonite, sepiolite) carrier materials used for phase change material (PCM) integration in building applications. The commercial paraffin-based PCM RT-31 was used as the thermal storage medium. Impregnation and leakage tests were conducted to evaluate the PCM absorption capacity, form stability, and energy storage potential of each carrier. The results revealed that perlite (C = 80%) and bay leaf (C = 78%) exhibited the highest impregnation capacities due to their porous and fibrous structures; however, they also demonstrated significant …

Techno-Economic And Environmental Analysis Of Wind-Powered Green Hydrogen Production In Nigeria, Ignatius Kema Okakwu, Ayodeji Akinsoji Okubanjo, Samson Oladayo Ayanlade, Akintunde Samson Alayande, Solomon Olanrewaju Giwa, Abraham Olatide Amole, Etinosa Noma-Osaghe, Ajibola Oluwafemi Oyedeji

Al-Bahir

Green hydrogen is becoming a viable option for clean energy, and the need to reduce greenhouse gas emissions has also become a popular sustainable energy source. In this paper, we evaluate the technoeconomic and environmental feasibility of green hydrogen production from wind energy in five Nigerian cities: Kano, Jos, Maiduguri, Ikeja, and Ikorodu. Energy potential from wind energy is estimated by using the Weibull distribution method, and six wind turbines are used to calculate electricity generation and hydrogen production. Economics of wind power are estimated through levelized cost of energy (LCOE), levelized cost of hydrogen (LCOH), payback period (PBP), and …

Optimization Of Bio-Briquettes Production From Cassava Stems Co-Blended With Sisal Bole Bagasse Using Response Surface Methodology, Agnes Nshoma Msobi, Neema O. Msuya, Kando Khalifa Janga

Tanzania Journal of Science

This research aimed at producing bio-briquettes from cassava stems and sisal bole bagasse as an alternative source of cooking energy. A Response Surface Methodology (RSM) with Face - Centered Central Composite Design (FCCCD) featured a multi-objective optimization of the effect of the production parameters, focusing on maximizing char yield and Higher Heating Value (HHV) of the produced briquette while minimizing carbonization temperature and residence time. The findings showed that bio-briquettes produced at the lowest temperature (250 ℃) and residence time (30 min) and the blending ratio of 75% by 25% had the highest char yield of 76.92% and HHV of …

The Dynamics Of Educational Change: A Complex Systems Perspective, Preethi Nanjundan, Lijo Thomas, Abith K. Sunil

Northeast Journal of Complex Systems (NEJCS)

The perception of university teachers toward educational reforms plays an important role in determining the success of changes introduced in the education sector. This study focuses on teachers’ attitudes toward change, their emotional responses, and their overall views on educational reforms. Across the world, many educational reforms have failed to achieve their expected outcomes in improving teaching practices and student learning. As education systems are highly complex, the approach toward implementing reforms has also changed over time. Some reforms are introduced gradually, while others involve major innovations within the system. Complexity theory provides useful insights and tools that help educators …

Towards Sustainable Marine Education: Assessing High School Students’ Understanding Of Conservation Concepts, Cheng-Chieh Chang, Tsuyoshi Sasaki, Ya-Yin Liao, Ling-Ya Hung, Liang-Ting Tsai

Journal of Marine Science and Technology–Taiwan

This study assesses the concepts of marine resource conservation and sustainability among Taiwanese high school students by developing a Chinese version of the Marine Resources Conservation and Sustainability Scale. Grounded in the cognitive, socio-emotional, and behavioral learning objectives outlined in UNESCO’s Education for Sustainable Development Goals (ESDGs), the scale targets students aged 16 to 18 to examine gender differences in marine knowledge and conservation concepts. The scale comprises 31 items across four dimensions: the first section evaluates marine knowledge, while the remaining dimensions utilize a four-point Likert scale to assess cognitive, socio-emotional, and behavioral learning objectives, respectively. The results indicate …

From Aspiration To Obligation: A Contractual Sustainability Framework For The Egyptian Construction Industry, Salma Ali

Theses and Dissertations

The construction industry is responsible for approximately 40% of global energy consumption and 35% of total waste generation, making it one of the most significant contributors to the global sustainability challenge. In Egypt, that challenge takes a specific contractual form. Egypt’s construction sector contributes approximately 23% of national energy consumption, yet the survey findings reveal that 63.5% of construction professionals report that sustainability clauses rarely or never appear in contracts, and only 11.5% confirm the presence of enforceable provisions with measurable targets. This gap is structural rather than attitudinal. Competitive procurement penalises voluntary sustainability investment, and without contractual obligation, awareness …

Thrivetogether – A Community-Drivenwellness Platform Powered By Ai, Isaac Soto, James Hunter, Ethan Nguyen, Nathan Shimada

Computer Science and Engineering Senior Theses

ThriveTogether is a wellness platform powered by artificial intelligence that is designed to help users create personalized fitness and nutrition plans through a combination of community-shared content and intelligent personalization systems. The platform is developed to support people at all stages of their health journey, including beginners and users with physical limitations, by providing accessible and adaptable wellness guidance. Unlike many existing health applications that rely on generalized advice or costly personalized services, ThriveTogether emphasizes affordability, inclusivity, and practical usability through user-generated recipes, workout plans, and nutrition plans while also enhanced by trusted nutritional sources through a rule-based validation system. …

Engineering Nanoelectrocatalytic Systems For Co2 And Nitrate Conversion Into Value-Added Chemicals, Abdelrahman Mohamed Abdelmohsen

Theses and Dissertations

The thesis addresses two major related environmental crises: nitrate pollution of water systems and the ever-increasing levels of atmospheric carbon dioxide. Both challenges are closely linked to anthropogenic disturbance of nitrogen and carbon cycles and require sustainable, energy efficient mitigation techniques. In this study, we investigate electrochemical conversion routes as a unified approach to convert these pollutants into value-added compounds: ammonia (NH3) via nitrate reduction (NO3-RR) and ethylene (C2H4) via carbon dioxide reduction (CO2RR). The first half of this work deals with the design and engineering of Cu-Zn alloy electrocatalysts for efficient NO3-RR. Tuning the alloy composition and surface nanostructure …

Tuning Ion Mobility And Molecular Confinement In High-Performance Polymer Electrolytes For Energy Storage, Ezzeldien Yousef Muhammed Yousef

Theses and Dissertations

This research addresses the critical energy density limitations of aqueous supercapacitors, which are traditionally constrained by the narrow electrochemical stability window (ESW) of water 1.23 V. By employing two distinct molecular engineering strategies, this study developed high-performance electrolyte systems that significantly extend voltage stability and thermal resilience.

The first system, CsBr@PAM/HA, utilizes a polyacrylamide and hyaluronic acid hydrogel matrix. This system exploits the chaotropic nature of Cs⁺ ions to disrupt the aqueous hydrogen-bonding network, enhancing ionic conductivity to 104 mS cm^-1. Through systematic salt screening, CsBr was identified as the optimal electrolyte, enabling a stable 2.0 V …

Adaptive Design Strategies For A Dual-Shaft Pvc Shredder, Gavin Balderas

University Honors Theses

This capstone project involved the design and development of a mid-size plastic shredder, created to process strong, ductile PVC sheets up to ½" thick. This application falls between the capabilities of consumer grade plastic shredders and heavy-duty industrial machines. Over 400 million tons of plastic produced annually and less than 10% of it is recycled; there is an ever-growing need for plastic recycling accessibility and infrastructure. This project aimed to create a compact dual-shaft shredder that can shred thick PVC sheets while being powered by a 120V outlet. Research into blade geometry and orientations aided an iterative design process driven …

A Computational Micropatterning Approach To Study Caveolae And Protein Localization In Vascular Biology, Andrew B. Grespin

Electronic Theses and Dissertations

Caveolae are specialized, flask-shaped membrane invaginations highly expressed in endothelium and dysregulated in atherosclerosis. Caveolae play a central role in buffering membrane tension, yet the principles governing their spatial organization remain elusive. Thus, we sought to generate the most comprehensive and systematic analysis of blood vessel caveolar spatial organization. However, cell culturing, the backbone of human-focused biological research, does not standardly do well to model physiologically relevant cell behaviors such as migration or polarity-based tissue formation, particularly for punctate proteins and structures like caveolae. Micropatterns are cell-adhesive shapes that biophysically confine cell(s) to a user defined geometry which stereotype organelle …

Metal Oxide Nanoparticle‑Integrated Phema Hydrogels: Morphology, Chemical Properties, And Biological Interaction, Venkateswar Rao, Collin Cox, Brandon Clark, Arushi Rai, Erick S. Vasquez-Guardado, Madhuri Kango-Singh, Soubantika Palchoudhury

Chemical and Materials Engineering Faculty Publications

Hydrogels offer attractive matrices for incorporating inorganic metal oxide nanoparticles (NPs) to generate multifunctional hybrid materials, but challenges remain in scalable synthesis and correlating their properties to bio-interaction. Therefore, we report the synthesis and characterization of poly(2-hydroxyethyl methacrylate) (pHEMA) hydrogels, and pHEMA hydrogels encapsulating iron oxide or zinc oxide NPs, using a modified free-radical polymerization. Dose-dependent survivorship studies on Drosophila melanogaster revealed that both NP-embedded hydrogels are tolerated over a wide dose range (e.g., 50–200 mg), although ZnO NP-gels exhibit lower survivorship at some concentrations due to their inherent composition and a wider size distribution of iron oxide NPs.

Bouillean - Ai Recipe Model, George Mouratoff, Hanol Yang, Helen Wang, Sebastian Verbinski

Computer Science and Engineering Senior Theses

AI generated food recipes are the second most desired AI innovation, however relatively few commercial systems exist to fill this niche. This is because while the solution is highly desired, cooking shouldn’t be approached with the same method by most LLMs and standard AIs. The leading models struggle to solve the issue of generating a semantically clear recipe while maintaining memory of the recipe status between steps. This is before we can even attempt to solve the flavor problem.

Cooking represents a unique challenge for AI, since it requires minimal loss in memory alongside already high quality text generation making …

An Integrated Sensor-Fusion Framework For Performance-Based Compensation In Construction, Aly Ayman El-Ashry

Theses and Dissertations

Construction productivity has historically stagnated due to a reliance on subjective labor monitoring and “lagging” performance indicators. This research proposes a novel compensation model with the use of Total Energy Management System (TEMS) to translate labor effort and efficiency into payment incentives with the integration of Internet of Things (IoT) wearables and Statistical Process Control (SPC) charts.

This research addresses the systemic problem of declining construction productivity caused by industry’s inability to objectively quantify human effort. While traditional models rely on post-facto production tallies, a significant research gap exists in real-time physiological labor monitoring. To bridge this, the proposed TEMS …

Developing Custom High Resolution 3d Printers For Microfluidic Device Fabrication, Dallin Scott Miner

Theses and Dissertations

The advancement of microfluidics in biomedical diagnostics and lab-on-a-chip systems is increasingly dependent on the ability to fabricate complex, three-dimensional architectures with high-resolution negative features. While Digital Light Processing Stereolithography (DLP-SLA) has emerged as a leading fabrication method, it remains constrained by a fundamental trade-off between feature resolution and build volume, as well as challenges regarding fabrication consistency and design accessibility. This dissertation presents an integrated ecosystem of hardware, materials, and software designed to overcome these barriers and enable scalable, high-resolution microfluidic fabrication. We first introduce a novel multi-resolution 3D printing technique utilizing a dual-optical engine architecture, comprising a Very …

Evaluating C-Band Scatterometer Images For Estimating Deforestation In The Amazon Rainforest, Alex Mcbride

Theses and Dissertations

Satellite-based active microwave sensors have been successfully employed for a wide range of vegetation and soil studies. Spaceborne microwave instruments have proven particularly useful for wide-scale monitoring of the vegetation, especially under conditions that limit the effectiveness of high-resolution optical sensors. Satellite scatterometry can be used to detect and model deforestation in the Amazon rainforest by correlating changes in the C-band backscatter data to observed changes in vegetation coverage. The exploratory methodology developed in this paper applies the longest continuous microwave satellite record to the problem of deforestation. The backscatter measurements taken by the ERS and ASCAT missions provide more …

Ai In Precision Medicine: Redefining Blindness Treatment Via Retinal Stem Cell Differentiation, Calissa Leong, Tiffany Nguyen

Interdisciplinary Design Senior Theses

Age Macular Degeneration (AMD) is currently the leading cause of blindness, driven by the degradation of Retinal Pigment Epithelial (RPE) cells. Stem-cell based therapies, particularly those involving induced pluripotent stem cells (iPSCs), typically consists of differentiating stem cells into RPE cells in vitro and transplanting them into the subretinal space. Our goal is to improve the accuracy of differentiation into RPE cells to better promote retinal regeneration. Traditional methods to alleviate symptoms of AMD is through therapeutic medications to slow disease progression, though stem cell therapy has emerged as a promising alternative. However, despite its potential, stem cell therapy presents …

Investigation Of Electrochemical Transport, Gate Leakage, And Transconductance Behavior In Pedot:Pss Organic Electrochemical Transistors, Vinay Bhudhraja, Bilal Khan, Abijeet Mehta

Health & Biomedical Sciences Faculty Publications

Organic Electrochemical Transistors (OECTs) are promising candidates for low-voltage bioelectronic systems due to their high transconductance, mixed ionic–electronic transport, and compatibility with flexible substrates. In this work, we investigate the electrochemical transport, gate leakage, and transconductance behavior of screen-printed PEDOT:PSS OECTs, with emphasis on the relationship between ionic coupling and output characteristics. Key electrical and electrochemical parameters—including drain current modulation, transconductance evolution, gate current behavior, and capacitance–voltage response—were systematically analyzed to elucidate the mechanisms governing device operation. The results reveal clear trade-offs between parasitic resistance, volumetric electrochemical capacitance, and effective gate control, which in turn influence signal integrity and amplification …

Methylglyoxal And Glyoxal In High-Puff Disposable Electronic Cigarette Liquids: Unexpected Accumulation And Enhanced Cytotoxicity, Esther E. Omaiye, Wentai Luo, Kevin J. Mcwhirter, Man Wong, Prue Talbot

Civil and Environmental Engineering Faculty Publications and Presentations

Despite concerns regarding the potential health risks associated with EC use, their design, puff count, and e-liquid formulations have continued to evolve. Aldehydes are a key class of thermal degradation byproducts generated during the vaporization of EC fluids. This study tested the hypothesis that aldehyde concentrations would be elevated in used ECs with high puff numbers. Devices from multiple brands were analyzed to assess the impact of extended use on aldehyde formation. E-fluids were extracted from field-collected and user-donated devices and analyzed using gas chromatography/mass spectrometry to quantify 178 flavor chemicals, two synthetic coolants, nicotine, solvents, and aldehydes (methylglyoxal (MGO), …

Practical Engineering Design: Hands-On Learning In An Undergraduate Embedded Systems Design Course, Nadieh Moghadam

School of Engineering: Faculty Scholarship

Hands-on engineering design can help bridge the gap between theoretical coursework and real-world engineering practice, particularly during the middle years of undergraduate programs. This paper presents the implementation and outcomes of an open-ended final project in ELEC 310: Embedded Systems Design at the University of San Diego. Student teams designed and prototyped smart environmental monitoring systems using STM32 microcontrollers, selecting sensors and defining system objectives under realistic constraints. Project outcomes were evaluated using prototype demonstrations, team technical reports, and post-project student reflections analyzed through inductive thematic analysis. Reflections and project artifacts suggest that debugging and hardware–software integration functioned as key …

Comparative Analysis Of Leaflet Materials, Stent Materials, And Stent Cell Density For Bileaflet Transcatheter Mitral Valve Design, Joseph Chibuike Nwokeafor, Joshua D. Hofmeister, Breandan B. Yeats, Lakshmi Prasad Dasi, Charanjit S. Rihal, Juan A. Crestanello, Leigh Griffiths, Mohamad A. Alkhouli, Hoda Hatoum

Michigan Tech Publications

Background: The biomechanical performance of bileaflet transcatheter mitral valves (TMVs) depends on complex interactions between leaflet material behavior and stent design. However, the contributions of leaflet materials and constitutive models, stent materials, and stent geometry to valve function and durability remain poorly understood. Methods: A parametric finite element study was conducted using a CAD model of a bileaflet TMV subjected to physiological pressure loading. Five leaflet material models were evaluated: 3 glutaraldehyde-fixed tissues—bovine pericardium (BP; FBP1, FBP2) and porcine pericardium (PP; FPP)—and 2 unfixed tissues—bovine (UBP) and porcine pericardium (UPP). BP was modeled as a linear elastic (FBP1) and Ogden …

Ora (Oneball Robotic Arm), Isabella Murillo, Juan Pablo Fernandez Garza, Gabriel Kotab, Catherine Epstein

Electrical and Computer Engineering Senior Theses

Confined spaces are dangerous and awkward to navigate environments, often putting those who work in them at risk. To reduce effort and human exposure to these hazards, robotic systems can be used to navigate and inspect these areas to limit, or even eliminate the need for human presence in confined spaces. This project proposes an autonomous robot that can navigate confined spaces while sending data back to the user. The robot features a spherical body that is capable of a zero rotational axis, with an external, magnetically attached head. This head contains scanners or tools that the user can remotely …

Integrating Production And Repair Operations Through Data Driven Defect Flow Analytics For Yield And Resource Optimization In Pcba Manufacturing, Ali Tahmasebi, Yingge Zhou, Daryl Santos, Sai Srikanth Reddy Kolli, Edward Wong

Systems Science and Industrial Engineering Student Scholarship

In Printed Circuit Board Assembly (PCBA) manufacturing, maintaining a closed loop connection between production and repair operations is critical to improving product quality and operational efficiency. However, in the manufacturing environment that motivated this work, production and repair data are often managed separately, and repair findings are not systematically fed back to production teams, limiting visibility into defect routing patterns and repair workload drivers. This study developed a data-driven framework that integrates production and repair data streams to analyze defect flow and support repair resource planning. The framework applies descriptive statistics, cross tabulations of repair inflow by product/project and repair …

Adopting Critical Power Grid Infrastructure Technologies: An Organizational Cybersecurity Assessment Against Ransomware, Fayez Alsoubaie

Dissertations and Theses

For many years, researchers and practitioners have studied emerging technologies in field of energy production and distribution. Power grid systems carry major weights in the energy branch of the economy. Researchers and scientists have been interested in finding ways to connect the power grid gap and improve protection for its technologies.

The research supports organizational adoption and prioritization of critical cybersecurity technologies for ransomware protection in power grid infrastructure. As utilities increasingly integrate digital technologies, they become more vulnerable to sophisticated cyberattacks that can disrupt services and put public safety at risk. The main focus of the study is to …