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Integrative Physiology-Coupled Pilot-Centered Flight Simulation, Shawn C. Harrison Dec 2022

Integrative Physiology-Coupled Pilot-Centered Flight Simulation, Shawn C. Harrison

Electrical & Computer Engineering Theses & Dissertations

Maintaining the pilot’s physiological performance envelope within the limits of human capabilities may be crucial for avoiding hazardous physiological episodes in fighter aircraft that compromise safety. The main physiological episode of interest is impaired pilot respiration, better known as hypoxia caused by a high fraction of inspired oxygen (FiO2) at high altitudes and variation in accelerative gravitational forces (g-forces). Integrated into fighter aircraft is an Onboard Oxygen Generating System (OBOGS) developed to mitigate the necessity of gaseous and liquid oxygen cannisters [1]. OBOGS act as a life support in hypoxic environments by providing oxygen-rich air, thereby oxygenating the …


High-Performance Vlsi Architectures For Lattice-Based Cryptography, Weihang Tan Dec 2022

High-Performance Vlsi Architectures For Lattice-Based Cryptography, Weihang Tan

All Dissertations

Lattice-based cryptography is a cryptographic primitive built upon the hard problems on point lattices. Cryptosystems relying on lattice-based cryptography have attracted huge attention in the last decade since they have post-quantum-resistant security and the remarkable construction of the algorithm. In particular, homomorphic encryption (HE) and post-quantum cryptography (PQC) are the two main applications of lattice-based cryptography. Meanwhile, the efficient hardware implementations for these advanced cryptography schemes are demanding to achieve a high-performance implementation.

This dissertation aims to investigate the novel and high-performance very large-scale integration (VLSI) architectures for lattice-based cryptography, including the HE and PQC schemes. This dissertation first presents …


Enhancing The Performance Of Poly(3-Hexylthiophene) Based Organic Thin-Film Transistors Using An Interface Engineering Method, Eyob Negussie Tarekegn Dec 2022

Enhancing The Performance Of Poly(3-Hexylthiophene) Based Organic Thin-Film Transistors Using An Interface Engineering Method, Eyob Negussie Tarekegn

All Dissertations

An original design and photolithographic fabrication process for poly(3-hexylthiophene-2, 5-diyl) (P3HT) based organic thin-film transistors (OTFTs) is presented. The structure of the transistors was based on the bottom gate bottom contact OTFT. The fabrication process was efficient, cost-effective, and relatively straightforward to implement. Current–voltage (I-V) measurements were performed to characterize the primary electronic properties of the transistors. The measured mobility of these transistors was significantly higher than most results reported in the literature for other similar bottom gate bottom contact P3HT OTFTs. The higher mobility is explained primarily by the effectiveness of the fabrication process in keeping the interfacial layers …


Permanently-Installed Distributed Pressure Sensors For Downhole Applications, Xuran Zhu Dec 2022

Permanently-Installed Distributed Pressure Sensors For Downhole Applications, Xuran Zhu

All Dissertations

Technology advancements (e.g., hydraulic fracturing and horizontal drilling) to recover unconventional oil and gas (UOG) resources are critical in maintaining future U.S. oil and gas production levels. Permanently installed distributed downhole pressure sensors could monitor fracture propagation, assess the effectiveness of hydraulic fracturing, and optimize hydraulic fracturing placement so that overall UOG recovery efficiency can be increased. However, the harsh environment (high temperatures, high pressures, strong vibration, and presence of brine, mud, debris, hydrate, and various gases), the long data telemetry distance, and the requirements of reliability and service lifetime make the downhole monitoring a very challenging task. To combat …


Multi-Criteria Performance Evaluation And Control In Power And Energy Systems, Payam Ramezani Badr Dec 2022

Multi-Criteria Performance Evaluation And Control In Power And Energy Systems, Payam Ramezani Badr

All Dissertations

The role of intuition and human preferences are often overlooked in autonomous control of power and energy systems. However, the growing operational diversity of many systems such as microgrids, electric/hybrid-electric vehicles and maritime vessels has created a need for more flexible control and optimization methods. In order to develop such flexible control methods, the role of human decision makers and their desired performance metrics must be studied in power and energy systems. This dissertation investigates the concept of multi-criteria decision making as a gateway to integrate human decision makers and their opinions into complex mathematical control laws. There are two …


Processes & Toolchain For Automation Of Hybrid Direct-Write 3d Printing, Gilbert Thomas Carranza Dec 2022

Processes & Toolchain For Automation Of Hybrid Direct-Write 3d Printing, Gilbert Thomas Carranza

Open Access Theses & Dissertations

Hybrid 3D printing has evolved from a means to rapidly prototype devices to a fully viable means of manufacturing final products. In particular, electronic and electromagnetic devices have been a focus of hybrid 3D printing multi material structures. However, while the hardware capabilities have been around for years, the software capabilities have only begun to catch up. A process and toolchain for hybrid 3D printing is critically needed.This work details a process and toolchain for hybrid 3D printing metal dielectric structures. In it, a basic slicing algorithm is shown along with off-axis printing and conformal printing for arbitrary curvatures. These …


Optimized Learning Using Fuzzy-Inference-Assisted Algorithms For Deep Learning, Miroslava Barua Dec 2022

Optimized Learning Using Fuzzy-Inference-Assisted Algorithms For Deep Learning, Miroslava Barua

Open Access Theses & Dissertations

For years, researchers in Artificial Intelligence (AI) and Deep Learning (DL) observed that performance of a Deep Learning Network (DLN) could be improved by using larger and larger datasets coupled with complex network architectures. Although these strategies yield remarkable results, they have limits, dictated by data quantity and quality, rising costs by the increased computational power, or, more frequently, by long training times on networks that are very large. Training DLN requires laborious work involving multiple layers of densely connected neurons, updates to millions of network parameters, while potentially iterating thousands of times through millions of entries in a big …


Using Molecular Dynamics Simulations To Decipher Mechanistic Details Of Biomolecular Processes Of Biology And Biotechnology Oriented Applications, Adithya Polasa Dec 2022

Using Molecular Dynamics Simulations To Decipher Mechanistic Details Of Biomolecular Processes Of Biology And Biotechnology Oriented Applications, Adithya Polasa

Graduate Theses and Dissertations

Researchers in chemistry and biology often utilize computer simulations, in conjunction with experimental data, to model and predict the structures, energies, kinetics, processes, and functions of the systems that are their focus of study, ranging from single molecules to whole viruses. Here, we use molecular dynamics (MD) techniques to gain a deeper understanding of biomolecular processes in biology and biotechnology-oriented applications. Using a mixture of equilibrium and non-equilibrium MD simulations, this work describes the insertion process of YidC at the atomic level. In order to better comprehend the insertion process, several docking models of YidC-Pf3 in the lipid bilayer were …


A Voice And Facial Recognition System To Protect Students From Being Forgotten Inside School Buses In The Kingdom Of Saudi Arabia, Ibrahim Alferaih Dec 2022

A Voice And Facial Recognition System To Protect Students From Being Forgotten Inside School Buses In The Kingdom Of Saudi Arabia, Ibrahim Alferaih

Theses and Dissertations

In this research, we discuss the situation of students in the three to eight year old age group. Every day in the Kingdom of Saudi Arabia during school days, more than 1,000,000 students are transported throughout the country by more than 15,000 school buses. Everything is dependent on the human element. During school transportation around the world, many children are forgotten inside the school bus and with many of them eventually going missing or even dying. The bus driver is usually busy and tired due to the focus on the road, which may make him lose focus on those on …


Improved Compact Modeling Of High Voltage Gallium Nitride High Electron Mobility Transistors, Md Maksudul Hossain Dec 2022

Improved Compact Modeling Of High Voltage Gallium Nitride High Electron Mobility Transistors, Md Maksudul Hossain

Graduate Theses and Dissertations

Since power converters shape a wide range of power electronic applications, the 'heart' of these conversions, such as solid-state switches, is crucial for achieving higher power density, lower loss, and higher efficiency operations. Although the limitations imposed by silicon-based power devices have been reduced by introducing novel devices such as IGBTs and super junction MOSFETs to allow for broader applications, solutions beyond silicon have presented a continuous challenge to the device engineers. Driving these converters at a higher switching frequency allows for higher power density. However, to support a higher frequency and operating temperature, superior materials, e.g., wide bandgap materials, …


Modeling, Control And Estimation Of Reconfigurable Cable Driven Parallel Robots, Adhiti Raman Thothathri Dec 2022

Modeling, Control And Estimation Of Reconfigurable Cable Driven Parallel Robots, Adhiti Raman Thothathri

All Dissertations

The motivation for this thesis was to develop a cable-driven parallel robot (CDPR) as part of a two-part robotic device for concrete 3D printing. This research addresses specific research questions in this domain, chiefly, to present advantages offered by the addition of kinematic redundancies to CDPRs. Due to the natural actuation redundancy present in a fully constrained CDPR, the addition of internal mobility offers complex challenges in modeling and control that are not often encountered in literature.

This work presents a systematic analysis of modeling such kinematic redundancies through the application of reciprocal screw theory (RST) and Lie algebra while …


Deep Learning Approach To Speech Recognition: A Signal Extractor & Producer For Artificial General Intelligence, Ahmad Zuhair S. Hasanain Dec 2022

Deep Learning Approach To Speech Recognition: A Signal Extractor & Producer For Artificial General Intelligence, Ahmad Zuhair S. Hasanain

Theses and Dissertations

The efficient use of a communication bandwidth starts with the data source. The features of the speech signals can be extracted and reconstructed to lower the Internet traffic of the acoustic artificial agents and to increase the quality of the automatic speech recognition systems. The Speech Quefrency Transform (SQT) is hereby introduced in the work to enrich the communication space between the artificial agents and mankind. We describe the motivation, methodology, and deep learning approach in detail as we apply the SQT technology to several applications: sharp pitch track extraction, real-time speech communications, and emotion recognition. The results were excellent. …


Nonlinear Observers For Burning Zone Temperatures And Torque Estimation Of The Rotary Cement Kiln., Bhagyashri Aditya Bhagwat Dec 2022

Nonlinear Observers For Burning Zone Temperatures And Torque Estimation Of The Rotary Cement Kiln., Bhagyashri Aditya Bhagwat

Electronic Theses and Dissertations

Due to consistent expansion in the infrastructure and housing sectors worldwide have given a new way for the rapid growth of global cement market. Increased global demand for the cement production makes the attractive research topic which can lead to the quality and overall efficiency of the product. Measurement of the temperature in the burning zone is vital to maintain product quality and kiln efficiency in the cement industry. Often the BZT is un-measurable due to internal kiln conditions, dusty environment, extreme heat, harshness for example and this leads to kiln not being driven as efficient as possible. Multi-physics tools …


Gate-Controlled Quantum Dots In Two-Dimensional Tungsten Diselenide And One-Dimensional Tellurium Nanowires, Shiva Davari Dolatabadi Dec 2022

Gate-Controlled Quantum Dots In Two-Dimensional Tungsten Diselenide And One-Dimensional Tellurium Nanowires, Shiva Davari Dolatabadi

Graduate Theses and Dissertations

This work focuses on the investigation of gate-defined quantum dots in two-dimensional transition metal dichalcogenide tungsten diselenide (WSe2) as a means to unravel mesoscopic physical phenomena such as valley-contrasting physics in WSe2 flakes and its potential application as qubit, as well as realizing gate-controlled quantum dots based on elementaltellurium nanostructures which may unlock the topological nature of the host material carriers such as Weyl states in tellurium nanowires.The fabrication and characterization of gate-defined hole quantum dots in monolayer and bilayer WSe2 are reported. The gate electrodes in the device design are located above and below the WSe2 nanoflakes to accumulate …


Design And Comparison Of Asynchronous Fft Implementations, Julie Bigot Dec 2022

Design And Comparison Of Asynchronous Fft Implementations, Julie Bigot

Graduate Theses and Dissertations

Fast Fourier Transform (FFT) is a widely used digital signal processing technology in a large variety of applications. For battery-powered embedded systems incorporating FFT, its physical implementation is constrained by strict power consumption, especially during idle periods. Compared to the prevailing clocked synchronous counterpart, quasi-delay insensitive asynchronous circuits offer a series of advantages including flexible timing requirement and lower leakage power, making them ideal choices for these systems. In this thesis work, various FFT configurations were implemented in the low-power Multi-Threshold NULL Convention Logic (MTNCL) paradigm. Analysis illustrates the area and power consumption trends along the changing of the number …


Data-Driven Deep Learning-Based Analysis On Thz Imaging, Haoyan Liu Dec 2022

Data-Driven Deep Learning-Based Analysis On Thz Imaging, Haoyan Liu

Graduate Theses and Dissertations

Breast cancer affects about 12.5% of women population in the United States. Surgical operations are often needed post diagnosis. Breast conserving surgery can help remove malignant tumors while maximizing the remaining healthy tissues. Due to lacking effective real-time tumor analysis tools and a unified operation standard, re-excision rate could be higher than 30% among breast conserving surgery patients. This results in significant physical, physiological, and financial burdens to those patients. This work designs deep learning-based segmentation algorithms that detect tissue type in excised tissues using pulsed THz technology. This work evaluates the algorithms for tissue type classification task among freshly …


Electrical Modeling For Dynamic Performance Prediction And Optimization Of Mcpms Layout, Quang Minh Le Dec 2022

Electrical Modeling For Dynamic Performance Prediction And Optimization Of Mcpms Layout, Quang Minh Le

Graduate Theses and Dissertations

In recent years, the fast development of Multichip Power Modules (MCPM) packaging and Wide Bandgap (WBG) technology has enabled higher voltage and current ratings, better thermal performance, lower parasitic parameters, and higher mechanical reliability. However, the design of the MCPM layout is a multidisciplinary problem leading to many time-consuming analyses and tedious design processes. Because of these challenges, the design automation tool for MCPM layout has become an emerging research area and gained much attention from the power electronics community. The two critical objectives of a design automation tool for MCPM layout are fast and accurate models for design insights …


Hybrid Model For Making Decision Methods In Wireless Sensor Networks Through Neuro-Fuzzy Inference System, Martha Lucia Torres Dec 2022

Hybrid Model For Making Decision Methods In Wireless Sensor Networks Through Neuro-Fuzzy Inference System, Martha Lucia Torres

Open Access Theses & Dissertations

Considering the complexity and multiple alternatives for technology decisions in Wireless Sensor Networks (WSNs), a multicriteria selection method (MCDM) is an appropriate approach for choosing the best option in technical projects. Purely quantitative decision-making procedures have currently been created based on client requirements and recommendations from industry professionals in many domains. In this context, implementation and operational costs could be increasing due to technical problems and additional processes. In order to prevent future difficulties and obtain a more accurate technology selection, a new method was being developed to involve qualitative and quantitative parameters taken from real scenarios and technical literature …


A Statistical Analysis Of Sporadic-E Characteristics Associated With Gnss Radio Occultation Phase And Amplitude Scintillations, Daniel J. Emmons, Dong L. Wu, Nimalan Swarnalingam Dec 2022

A Statistical Analysis Of Sporadic-E Characteristics Associated With Gnss Radio Occultation Phase And Amplitude Scintillations, Daniel J. Emmons, Dong L. Wu, Nimalan Swarnalingam

Faculty Publications

Statistical GNSS-RO measurements of phase and amplitude scintillation are analyzed at the mid-latitudes in the local summer for a 100 km altitude. These conditions are known to contain frequent sporadic-E, and the S4-σϕ trends provide insight into the statistical distributions of the sporadic-E parameters. Joint two-dimensional S4-σϕ histograms are presented, showing roughly linear trends until the S4 saturates near 0.8. To interpret the measurements and understand the sporadic-E contributions, 10,000 simulations of RO signals perturbed by sporadic-E layers are performed using length, intensity, and vertical thickness distributions from previous studies, with the assumption that the sporadic-E layer acts …


Modeling And Control Of Battery Management Systems With High-Frequency Ac Link Coupled Multiport Series Resonant Converters For 2nd Life Battery Applications, Brooks Jace Maughan Dec 2022

Modeling And Control Of Battery Management Systems With High-Frequency Ac Link Coupled Multiport Series Resonant Converters For 2nd Life Battery Applications, Brooks Jace Maughan

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

While the use and production of Electric Vehicles becomes more prevalent, it is also important to make this economical and ensure the reduction of a carbon footprint. Second-life batteries can satisfy both problems as batteries can be used in a second-life application for lower power purposes such as supplementing the grid so the infrastructure needed to charge the expanding fleet of Electric Vehicles can be easily supplied. This thesis goes through the process of Active Cell Balancing which will produce equal capacities, or similar batteries, that can be more efficiently used in these and other types of second-life applications. The …


Raman Scattering Measurements And Analyses Of Gan Thin Films Grown On Zno Substrates By Metalorganic Chemical Vapor Deposition, Zane Mcdaniel, Zhe Chuan Feng, Kevin Stokes Nov 2022

Raman Scattering Measurements And Analyses Of Gan Thin Films Grown On Zno Substrates By Metalorganic Chemical Vapor Deposition, Zane Mcdaniel, Zhe Chuan Feng, Kevin Stokes

Symposium of Student Scholars

Metalorganic chemical vapor deposition (MOCVD) is a popularly used method of growing thin films of GaN on ZnO (GZ) substrates, which pair well due to their structural and characteristic similarities. In this research, optical characterization of the surface quality of GZ sample films is measured by analyzing Raman scattering (RS) using a Renishaw inVia spectrometer fitted with a 532nm laser. Samples were grown in an improved double injection block rotating disc reactor. Multiple samples' spectra show broad peaks that correspond with the E2 (high) and A1 (LO) branches of GaN, and nicely fitted curves are observed for the characteristic E2 …


Parallel Distributed Compensation-Pid Controller Design For Maximum Power Point Tracking Of Dynamic Loaded Photovoltaic System, Anas Shomer, Helmy El Zoghby, Mohiy E. Bahgat, Soliman Sharaf Nov 2022

Parallel Distributed Compensation-Pid Controller Design For Maximum Power Point Tracking Of Dynamic Loaded Photovoltaic System, Anas Shomer, Helmy El Zoghby, Mohiy E. Bahgat, Soliman Sharaf

Future Engineering Journal

Control issues come from the output voltage of PV installations and systems operating in a range of irradiance and temperature. By using a DC converter, such systems are able to maintain a constant output voltage despite fluctuations in the generated voltage and load. The design of a maximum power point tracking (MPPT) on DC converter controller is presented in this article for a system. Fractional Order-Proportional Integral Derivative (FO-PID) and Parallel Distributed Compensation-Proportional Integral Derivative (PDC-PID) controllers have been implemented to the system converter as a proposed control approach. Particle Swarm Optimization (PSO) is used as optimization technique for determining …


Performance Comparison Of Several Control Algorithms For Tracking Control Of Pantograph Mechanism, Laylaa Mahmoud Eng, Mohamed Shamseldin Dr, Mohamed Sallam Dr, Abdelghany Mohamed Prof Nov 2022

Performance Comparison Of Several Control Algorithms For Tracking Control Of Pantograph Mechanism, Laylaa Mahmoud Eng, Mohamed Shamseldin Dr, Mohamed Sallam Dr, Abdelghany Mohamed Prof

Future Engineering Journal

A sort of parallel manipulator known as a pantograph robot mechanism was created primarily for industrial requests that required high precision and satisfied speed. While tracking a chosen trajectory profile requires a powerful controller. Because it has four active robot links and one robot passive link in place of just two links like the open chain does, it can carry more loads than the open chain robot mechanism while maintaining accuracy and stability. The calculated model for a closed chain pantograph robot mechanism presented in this paper takes into account the boundary conditions. For the purpose of simulating the dynamics …


Recognition Of Modern Modulated Waveforms With Applications To Abms And Vdats Test Program Set Development, Sylwester Sobolewski Nov 2022

Recognition Of Modern Modulated Waveforms With Applications To Abms And Vdats Test Program Set Development, Sylwester Sobolewski

USF Tampa Graduate Theses and Dissertations

A newly developed, near real-time, well-performing and potentially universally applicable Automatic Modulation Recognition (AMR) technique for discrimination of numerous modern modulated waveforms found in commercial as well as military communication systems applicable to the new Air Force’s Advanced Battle Management & Surveillance (ABMS) framework as well as Versatile Depot Automatic Test Station (VDATS) Test Program Set (TPS) development is presented. It involves generating complex feature vectors composed of High-Order Direct Cumulant, Cyclostationary and Fourier of Wavelet Transform features created with the help of Principal Component Analysis and Variance Data Compression.

Twelve modulated waveforms are used to evaluate the performance of …


Frequency Domain Diffuse Optics Spectroscopies For Quantitative Measurement Of Tissue Optical Properties, Sadhu Moka Nov 2022

Frequency Domain Diffuse Optics Spectroscopies For Quantitative Measurement Of Tissue Optical Properties, Sadhu Moka

USF Tampa Graduate Theses and Dissertations

Tissue oxygen saturation, blood flow and blood volume are physiological bio-markers of tissue health. Diffuse Optical Spectroscopy(DOS) and Diffuse Correlation Spectroscopy (DCS) are two complementary approaches to measure tissue oxygen saturation and blood flow respectively. Quantitative Diffuse Optical Spectroscopy (DOS) uses multi-spectral intensities of near-infrared light that have been modulated at RF frequencies to estimate static tissue optical properties and hence concentrations of oxygenated and de-oxygenated hemoglobin. Diffuse Correlation Spectroscopy estimates tissue dynamics - i.e., blood flow, by measuring temporal intensity auto-correlation function of backscattered light diffusing through the tissue. Conventionally, DCS instruments use coherent light sources with constant intensity. …


Reducing Instrumentation Barriers Of Diffuse Correlation Spectroscopy For Low-Cost Deep Tissue Blood Flow Monitoring, Arindam Biswas Nov 2022

Reducing Instrumentation Barriers Of Diffuse Correlation Spectroscopy For Low-Cost Deep Tissue Blood Flow Monitoring, Arindam Biswas

USF Tampa Graduate Theses and Dissertations

Cerebral blood flow (CBF) is a good indicator of brain health as blood carries necessary nutrients, oxygen, and metabolic byproducts. Quantitative blood flow information can be used in several clinical and therapeutic applications such as stroke detection, measuring autoregulation, evaluating brain injury, or determining neuronal activity. Over the past few decades, light-based deep tissue hemodynamic detection modalities have become popular for non-invasive CBF measurements. In particular, noninvasive Diffuse Correlation Spectroscopy (DCS), has become a tool of choice for research and clinical applications due to its depth sensitivity (>1 cm), portability, validity against other technologies such as Magnetic Resonance Imaging …


Information Dissemination And Perpetual Network, Harshit Srivastava Nov 2022

Information Dissemination And Perpetual Network, Harshit Srivastava

USF Tampa Graduate Theses and Dissertations

Social networks have attracted increasing attention from both physical and social scientists. Social networks are essential elements in societies, serving as channels for exchanging various benefits, such as innovation, information, and social support. Moreover, research in social networks helps explain macro-level social phenomena, such as social polarization and social contagion. An understanding of social networks has significant implications, such as improving social welfare and political participation. Modeling social network formation has typically employed game theory or agent-based modeling. These studies typically propose simple and tractable micro-level rules for link formation mechanisms and show that these rules have implications for known …


Which Factor Dominates Battery Performance: Metal Ion Solvation Structure-Derived Interfacial Behavior Or Solid Electrolyte Interphase Layer?, Hao-Ran Cheng, Zheng Ma, Ying-Jun Guo, Chun-Sheng Sun, Qian Li, Jun Ming Nov 2022

Which Factor Dominates Battery Performance: Metal Ion Solvation Structure-Derived Interfacial Behavior Or Solid Electrolyte Interphase Layer?, Hao-Ran Cheng, Zheng Ma, Ying-Jun Guo, Chun-Sheng Sun, Qian Li, Jun Ming

Journal of Electrochemistry

Solid-electrolyte interphase (SEI) layer formed on the electrode by electrolyte decomposition has been considered to be one of the most important factors affecting the battery performance. We discover that the metal ion solvation structure can also influence the performance, particularly, it can elucidate many phenomena that the SEI cannot. In this review, we summarize the importance of the metal ion solvation structure and the derived metal ion de-solvation behaviors, by which we can build an interfacial model to show the relationship between the interfacial behavior and electrode performance, and then apply to different electrode and battery systems. We emphasize the …


Insight Into The Effects Of Cation Disorder And Surface Chemical Residues On The Initial Coulombic Efficiency Of Layered Oxide Cathode, Jin-Li Liu, Han-Feng Wu, Zhi-Bei Liu, Ying-Qiang Wu, Li Wang, Feng-Li Bei, Xiang-Ming He Nov 2022

Insight Into The Effects Of Cation Disorder And Surface Chemical Residues On The Initial Coulombic Efficiency Of Layered Oxide Cathode, Jin-Li Liu, Han-Feng Wu, Zhi-Bei Liu, Ying-Qiang Wu, Li Wang, Feng-Li Bei, Xiang-Ming He

Journal of Electrochemistry

Lithium layered oxide LiNi0.6Co0.2Mn0.2O2 (NCM622) is one of the most promising cathode materials in high-energy lithium-ion batteries for electric vehicles. However, one drawback for NCM622 is that its initial coulombic efficiency (ICE) is only about 87%, which is at least 6% lower than that of LiCoO2 or LiFePO4. In this work, we investigated the effects of surface chemical residues (e.g., LiOH and Li2CO3) and Li/Ni cation disorder resulted during the sintering on the ICE. We found that the ICE of the as-prepared samples could be boosted …


Review On Oxygen-Free Vanadium-Based Cathodes For Aqueous Zinc-Ion Batteries, Xiao-Ru Yun, Yu-Fang Chen, Pei-Tao Xiao, Chun-Man Zheng Nov 2022

Review On Oxygen-Free Vanadium-Based Cathodes For Aqueous Zinc-Ion Batteries, Xiao-Ru Yun, Yu-Fang Chen, Pei-Tao Xiao, Chun-Man Zheng

Journal of Electrochemistry

Aqueous zinc-ion batteries (AZIBs) are considered as one of the most promising next-generation electrochemical energy storage systems owing to their high-power density, environmental benign, intrinsic safety, and the low cost of the abundant zinc resources. However, their further development is still plagued by the inferior electrochemical performance of cathode materials. Though extensive research has been conducted to investigate various cathode materials (including manganese oxides, vanadium oxides, Prussian blues analogy, and organic materials), design of high-performance cathodes with satisfying capacity and long-term cycling stability still faces great challenges. Oxygen-free vanadium-based compounds, owing to their better conductivity, larger interlayer spacing, lower ion …