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Adsorptive–Photocatalytic Performance For Antibiotic And Personal Care Product Using Cu0.5Mn0.5Fe2O4, Chanat Chokejaroenrat, Chainarong Sakulthaew, Athaphon Angkaew, Apiladda Pattanateeradetch, Wuttinun Raksajit, Kanokwan Teingtham, Piyaporn Phansak, Pawee Klongvessa, Daniel D. Snow, Clifford E. Harris, Steven Comfort

Nebraska Water Center: Faculty Publications

The amount of antibiotics and personal care products entering local sewage systems and ultimately natural waters is increasing and raising concerns about long-term human health effects. We developed an adsorptive photocatalyst, Cu_0.5Mn_0.5Fe₂O₄ nanoparticles, utilizing co-precipitation and calcination with melamine, and quantified its efficacy in removing paraben and oxytetracycline (OTC). During melamine calcination, Cu_0.5Mn_0.5Fe₂O₄ recrystallized, improving material crystallinity and purity for the adsorptive–photocatalytic reaction. Kinetic experiments showed that all four parabens and OTC were removed within 120 and 45 min. We found that contaminant adsorption and reaction …

Short-Term Responses Of Soil Carbon, Nitrogen, And Microbial Biomass To Cover Crop Mixtures And Monocultures, Igor Alexandre De Souza, Amanda B. Daly, Jorg Schnecker, Nicholas D. Warren, Adalfredo Rocha Lobo Jr., Richard G. Smith, Andre Fonseca Brito, A. Stuart Grandy

Faculty Publications

Increasingly, cover crops are being adopted for the purpose of improving soil health, yet the timescale and magnitude by which living annual cover crops might modify soil chemical and biological aspects of soil health is not well understood. At the same time, there is growing interest among farmers in cover crop mixtures due to perceptions that species-rich cover crop communities will enhance soil health relative to monocultures. In a field experiment in southeast New Hampshire, we investigated how groups of cover crops grown as monocultures and mixtures for specific seasonal niches (winter/spring, summer, and fall) influenced levels of soil nitrogen …

Polygonal Faults In The Austin Chalk: Invariance Of Scale From Mud Cracks To Polygons With Implications Of Structural, Geomorphic And Isotopic Data On Polygonal Fault Geometry And Origin., Kun Shang

Earth Sciences Theses and Dissertations

The Cretaceous Austin Chalk contains large numbers of fractures and normal faults whose orientations have been attributed to either regional stresses (e.g., the Balcones fault trend) or, by analogy with the mudrocks, to polygonal faulting resulting from compaction. In this study, we present geomorphic data, field study, and stable isotope data to support that the majority of these faults in North Texas are polygonal. Field-measured fault orientations suggest randomly distributed fault strikes, indicating a polygonal fault structure. Using geomorphologic data (topographic and DEM data) on stream orientations suggests that the polygonal fault patterns are best reflected in the headwater (1st …

Droughtscape, Summer 2023, National Drought Mitigation Center

DroughtScape: Quarterly Newsletter of the National Drought Mitigation Center (2007–2023)

DroughtScape, Summer 2023

Mentoring Experiences Of Undergraduate Students And Faculty Members In Science, Technology, Engineering, And Mathematics, Pamela Martínez Oquendo

School of Natural Resources: Dissertations, Theses, and Student Research

I present a comprehensive view of mentoring experiences of undergraduate students and faculty members in science, technology, engineering, and mathematics (STEM). In Chapter 1, I describe a brief outline of this dissertation. In Chapter 2, I present an interpretative phenomenological analysis of the lived experiences of former STEM undergraduate mentors of the Nebraska STEM For You (NE STEM 4U) afterschool mentoring program. In Chapter 3, I describe how the ramifications of faculty mentorship influence the science pipeline using a qualitative synthesis. In Chapter 4, I describe how the STEM faculty-student mentoring engagement involves a strong psychological support component using a …

Effects Of Landslides On Terrestrial Carbon Stocks With A Coupled Geomorphic-Biologic Model: Southeast Alaska, United States, Adam M. Booth, Brian Buma, S. Nagorski

Geology Faculty Publications and Presentations

Landslides influence the global carbon (C) cycle by facilitating transfer of terrestrial C in biomass and soils to offshore depocenters and redistributing C within the landscape, affecting the terrestrial C reservoir itself. How landslides affect terrestrial C stocks is rarely quantified, so we derive a model that couples stochastic landslides with terrestrial C dynamics, calibrated to temperate rainforests in southeast Alaska, United States. Modeled landslides episodically transfer C from scars to deposits and destroy living biomass. After a landslide, total C stocks on the scar recover, while those on the deposit either increase (in the case of living biomass) or …

Applications Of Environmental Dna (Edna) To Detect Subterranean And Aquatic Invasive Species: A Critical Review On The Challenges And Limitations Of Edna Metabarcoding, Sakib Tahmid Rishan, Richard Kline, Md Saydur Rahman

School of Earth, Environmental, & Marine Sciences Faculty Publications

The world is struggling to solve a devastating biodiversity loss that not only affects the extinction of treasured species and irreplaceable genetic variation, but also jeopardizes the food production, health, and safety of people. All initiatives aimed to conserve biodiversity rely heavily on the monitoring of both species and populations to get accurate spatial patterns and overall population assessments. Conventional monitoring techniques, such as visual surveys and counting individuals, are problematic due to challenges in identifying cryptic species or immature life stages. Environmental DNA (eDNA) is a relatively new technology that has the potential to be a faster, non-invasive, and …

Hurricane Impacts On Land In The Central And Eastern Caribbean Since 1494 Ce From Written Records, Michael Chenoweth, Ian Howard

Geosciences Faculty Publications and Presentations

Written accounts of hurricanes and their impacts in the Caribbean region date back to 1494 CE We report a new compilation of hurricanes in the longest settled regions of the central and eastern Caribbean region (CECR) that is the most complete yet produced and present basic statistics. We assess likely undercounts of hurricanes due to incomplete documentary records in the earliest part of the record by using the most complete reporting from Puerto Rico relative to the remainder of the CECR. We compare our results with other documentary and proxy data from the region and demonstrate using wavelet analysis significant …

Nitrous Oxide Cycling In The Eastern Tropical North Pacific Oxygen Deficient Zone From Concentrations, Stable Isotopes And Isotopomers, Margaret Ann Gaspar

Theses and Dissertations

Nitrous oxide (N₂O) is a potent greenhouse gas and ozone depleting substance. It is estimated that the ocean accounts for about one third of total atmospheric emissions, which mostly occur in Oxygen Deficient Zones (ODZs) connected to coastal upwelling regions. Modeling efforts and high-resolution datasets are starting to provide a clearer picture of global marine N₂O fluxes, spatiotemporal variability, and the impacts of submesoscale processes on N₂O distributions. We measured nitrous oxide concentrations, stable isotope ratios and isotopomers at 7 open ocean stations along a transect crossing the Eastern Tropical North Pacific ODZ as …

Groundwater Flow And Salt Marsh Migration: The Forest/Marsh Boundary, Camille Rossiello

Theses and Dissertations

Salt marshes migrate landward in response to sea level rise, but the rate of this migration is not constant and can be influenced by pulse disturbances. Long term observations at Sapelo Island, Georgia, show that salt marsh migration has occurred during droughts, but the mechanism for this migration is unclear. Drought is thought to influence salt marsh migration by reducing fresh groundwater discharge from the upland. Rising sea level also encroaches on the upland, which could cause movement of the freshwater lens inland. A two-dimensional numerical model was built to simulate groundwater flow and solute transport based on the Marsh …

Hf Radar: Shining A Light On Ocean Currents, Douglas Cahl

Theses and Dissertations

High Frequency (HF) radar systems are commonly used to estimate surface ocean currents over the coastal ocean. Their range depends on their operational frequency and low frequency systems (≤ 10 MHz) can reach distances up to 200 km from the coastline. These systems are used to estimate surface currents by measuring the phase speed of wind-driven waves and comparing the measured speed with that expected theoretically; deviations from the theoretical still-water phase speed are attributed to ocean surface currents. Although HF radar systems are considered a mature technology and the accuracy of the radar-derived surface current estimates is well studied, …

Forecasting Sea Level Rise-Driven Inundation In Diked And Tidally Restricted Coastal Lowlands, K. M. Befus, A. P.D. Kurnizki, K. D. Kroeger, M. J. Eagle, T. P. Smith

Geosciences Faculty Publications and Presentations

Diked and drained coastal lowlands rely on hydraulic and protective infrastructure that may not function as designed in areas with relative sea-level rise. The slow and incremental loss of the hydraulic conditions required for a well-drained system make it difficult to identify if and when the flow structures no longer discharge enough water, especially in tidal settings where two-way flows occur through the dike. We developed and applied a hydraulic mass-balance model to quantify how water levels in the diked and tidally restricted coastal wetlands and water bodies dynamically respond to sea-level rise, specifically applied to the Herring River Estuary …

Decreased Moderate To Vigorous Physical Activity Levels In Children With Asthma Are Associated With Increased Traffic-Related Air Pollutants, Juan Aguilera, Soyoung Jeon, Amit U. Raysoni, Wen-Whai Li, Leah D. Whigham

School of Earth, Environmental, & Marine Sciences Faculty Publications

People with asthma, particularly young children, are more adversely aected by trac emissions-and regular exercise reduces asthma symptoms and improves lung function. We studied the relationship between air pollution and objectively measured physical activity in children with asthma who were attending a school near a freeway. We continuously monitored air pollutants-PM2.5, PM10, nitrogen dioxide (NO2), and ozone (O3)-at the school for 10 weeks and measured physical activity levels via accelerometry in children (n = 12, ages 6-12 years). Concentrations of PM2.5, PM10, and NO2 were negatively associated with moderate to vigorous physical activity (PM2.5 and PM10: p < .001; NO2: p = …

Oxygen And Hydrogen Isotopic Evidence That KamaʻEhuakanaloa (LōʻIhi) Seamount Hydrothermal Systems Are Recharged By Deep Pacific Seawater, Eric W. Chan, Brianna A. Alanis, Christopher R. German, Darlene S. S. Lim, John A. Breier

School of Earth, Environmental, & Marine Sciences Faculty Publications

We observed negative and positive δ18O and δ2H deviations from fluids collected at Kamaʻehuakanaloa (previously known as Lōʻihi) seamount relative to Pacific seawater from the same depth. Hydrothermal vents on the crater floor of Pele's Pit at Kamaʻehuakanaloa, at a depth of 1320 m, had δ18O and δ2H values as low as −0.19‰ and −0.3‰, respectively. Seawater collected within the caldera, within a zone 45 m above the crater floor, had δ18O and δ2H values as high as 1.15‰ and 6.5‰, respectively. In comparison, Pacific seawater at 1200 m and 1400 m at nearby station ALOHA exhibit intermediate δ18O and …

Life Cycle Assessment Of Calcium Oxide Pretreatment Of Corn Stover With Carbon Dioxide Neutralization For Ethanol Production, Jikai Zhao, Danyi Feng, Juhee Lee

School of Earth, Environmental, & Marine Sciences Faculty Publications

This work used life-cycle assessment (LCA) to determine the environmental and human health impacts of four ethanol production scenarios (S1: CaO pretreatment + H2SO4 neutralization + C6 yeast fermentation; S2: CaO pretreatment + CO2 neutralization + C6 yeast fermentation; S3: CaO pretreatment + H2SO4 neutralization + C6/C5 yeast fermentation; and S4: CaO pretreatment + CO2 neutralization + C6/C5 yeast fermentation), with the functional unit being 1 kg of 95 % ethanol. The LCA results showed that the total ozone depletion, global warming potential, smog, acidification, eutrophication, and ecotoxicity values were comparable when CO2 or H2SO4 were used to adjust the …

Maintaining Grassland Plant Diversity While Controlling Woody Plant Encroachment, James Stubbendieck, Kay L. Kottas, S. J. Tunnell, S. J. Palazzolo

IGC Proceedings (1977-2023)

The tallgrass prairie region of the United States is a fragmented grassland ecosystem. Much of the 1 to 2% of the remaining prairie is being degraded by invading woody plants, which frequently results in a shift from grassland to woodland. Smooth sumac (Rhus glabra L.), a shrub native to the region, can rapidly increase in density and become dominant in the plant community. Prescribed fire alone is not a constraint to this resprouting species (Stubbendieck et al., 2003). Herbicides are useful tools for managing woody plants in grasslands, but the negative response of desirable plants to herbicides is …

Do Species And Functional Diversity Indices Reflect Changes In Grazing Regimes And Climatic Conditions In Northeastern Spain?, F. De Bello, J. Leps, M. T. Sebastià

IGC Proceedings (1977-2023)

Understanding the mechanisms that maintain biodiversity in various ecosystems enables the development of management practices that prevent degradation (Canals & Sebastia, 2000). Each diversity index reflects some compositional properties and could be influenced differently by stress and disturbance factors (Magurran, 2004). In this study, we aim to reveal 1) which management practices and environmental factors affect biodiversity in rangelands of northeastern Spain and 2) the relationship between species diversity and functional diversity (SD and FD).

Impact Of Grazing Regimes On Mean Sward Height: Implications For The Management Of Bird Habitats In Agricultural Landscapes, M. Tichit, D. Durant, E. Kernéïs

IGC Proceedings (1977-2023)

Grazing in wet grasslands is a key process to manage foraging and nesting habitats for waders. Grazing has positive and negative effects related to the importance of sward conditions for these species and to nest-trampling by cattle. For settlement and nesting, lapwings need a short sward ( ≤ 10cm; see Durant et al., this congress). However, when lapwings settle in early spring, grasslands seldom are grazed yet, due to low soil carrying capacity. We studied the effect of autumn and winter grazing regimes on sward structure in early spring, and the effect of grazing regime in early spring on …

Soil Carbon Sequestration Under Three Years Of No-Till Forage Cropping Systems, D. H. Min, J. D. Deyoung, Richard Leep

IGC Proceedings (1977-2023)

The effects of reduced tillage on soil organic carbon (SOC) are generally well established (Chan et al., 2002; Cabardella & Elliott, 1992). The effects of different crops are also somewhat understood (Drinkwater et al., 1998). However, many of these studies are done in the laboratory to study the effects of crop residues on SOC. Many forage-based systems have very little crop residue returned to the field. What residue does return is often in the form of manure or compost, which is usually broken down much more rapidly than most crop residues. The objective of this study is to …

Number And Viability Of Seeds Recovered From Faeces Of Ruminant Animals, Alaba O. Jolaosho, Olufemi S. Onifade, O. M. Arigbede, Jimoh A. Olanite, T. O. Akinola

IGC Proceedings (1977-2023)

Ruminants play a significant role in the dissemination of plant seeds as a result of ingested seeds during grazing on pasture escaping digestion that are voided with the faeces and returned to the seed bank (Russi et al., 1992).

Population Changes Of Invasive Annuals In California Annual And Perennial Grasslands, Richard King

IGC Proceedings (1977-2023)

Some non-native annual forbs and grasses can be invasive in California's annual grassland region. Taeniatherum caput-medusae (L.) Nevski and Centaurea solstitialis L. can spread quickly, become nearly monospecific stands, and reduce carrying capacity for livestock and wildlife. Centaurea also can be toxic to horses. Lathyrus hirsutus L. is less invasive, but the seed is toxic to various livestock. Since 1991, the author has raised beef cattle on 16 ha of predominantly annual grassland where these 3 species occur, and a family member has raised cattle on approximately 40 ha of adjacent property. Surface soils in this hilly land are …

The Effect Of Sheep Grazing At Two Stocking Rates On The Seedling Recruitment Of Grassland Forbs, Johannes Isselstein, Markus Kowarschik, S. Bonn, M. Hofmann

IGC Proceedings (1977-2023)

Limitations for seedling recruitment are major constraints to maintain and enhance plant species diversity in productive grasslands (Bakker & Berendse 1999). Grass sward condition plus species-specific requirements for germination and survival determine the recruitment success. Therefore, a field experiment investigated the establishment of oversown seeds from wildflower forbs in relation to grass sward management.

A Basis For Designing Policies To Optimize Soil Carbon Sequestration In Southeastern Us Grasslands, Joel R. Brown, D. L. Faulkner

IGC Proceedings (1977-2023)

Increasing the amount of carbon (C) stored in terrestrial ecosystems is an important part of most national greenhouse gas (GHG) management strategies. Among the policy and program options available to achieve increased C sequestration, improved management of grasslands offers an attractive option to both reduce atmospheric concentrations of C and enhance environmental co-benefits (soil quality, water quality, food and fibre production, and wildlife habitat). In the United States, incentives for applying improved land management practices come primarily via federal government conservation programs administered by the United States Department of Agriculture (USDA). While private sector markets offer opportunities to increase the …

The Nature Of Sequestered Carbon In Different Irish Mineral Soils, C. M. Byrne, D. Fay, J. A. Ferreira, M. H. B. Hayes

IGC Proceedings (1977-2023)

Humic substances (HS) provide the major sinks for carbon (C) in soils. Although HS have a degree of resistance to microbial degradation, they are degraded in time. Humin, the HS component in association with the soil mineral colloids, has greatest resistance to degradation. To understand the extent to which soil can be a sink for C it is important to know the soil mineralogy, and to be aware of aspects of the structures of the humic components. Enhanced biological oxidation occurs in soils in long term cultivation. Its effects can be observed by comparing the amounts and compositions of the …

Impact Of Soil Amelioration On Weed Ecology And Control, Catherine Borger, Arslan Peerzada Dr, Gaus Azam Dr

Experimental Summaries - Plant Research

The project focussed on three main findings from the literature review:

1. Weed ecology in response to changes in soil characteristics.
2. Soil movement and weed seed burial following use of varying strategic tillage implements; and
3. Management of weeds in the years directly after amelioration.

The work highlighted that weed growth was either less impacted by changes to soil properties than crop growth, or weed growth and competitive ability were favoured by the same amelioration techniques that favour crop growth. Following amelioration, improved growth of competitive weed species needs to be considered in weed management plans.

Research was conducted on weed seed …

Flow Generation And Propagation From Headwater Wetlands To Downstream Waters, Leanne Marie Stepchinski

USF Tampa Graduate Theses and Dissertations

Headwater wetlands are connected to one another and to downstream waters by dynamic hydrologic flowpaths, functioning as integrated hydrologic networks at the watershed scale. Headwater wetlands perform a variety of hydrologic lag, sink, and source functions, including flow generation and propagation, thereby contributing to the natural flow regimes of downgradient waters. The functions of individual wetlands and their contributions to hydrologic connectivity and subsequently to the natural flow regime have been widely studied and are well understood. Comparatively, the functions and hydrologic connectivity within wetland complexes as a whole and their collective subsequent contributions to the natural flow regime of …

Detection Of Subsidence In West-Central Florida Using Persistent Scatterer Interferometry And Near-Surface Geophysics, Tonian R. Robinson

USF Tampa Graduate Theses and Dissertations

This dissertation consists of three studies that employ Persistent Scatterer Interferometry (PSI, also known as PSInSAR) to better understand how subsidence in west-central Florida relates to underlying geological processes. In the first study, near-surface geophysical methods (Ground Penetrating Radar (GPR) and Electrical Resistivity (ERT)), terrestrial remote sensing applications (Light Detection and Ranging (LiDAR) and Structure from Motion (SfM)), and PSI were used to monitor the spatial and temporal behaviors of a suspected growing sinkhole in the Sandhill Boyscout Reservation, Hernando County, Florida. The survey area was located within and around a topographic low assumed to be the surface of the …

Dna Barcoding Reveals Occurrence Of Cardiocephaloides Sp. (Digenea: Strigeidae) Infecting The Great Cormorant Phalacrocorax Carbo (L. 1758) In Mwanza Gulf, Lake Victoria, Fred D Chibwana

Tanzania Journal of Science

Cormorants (Pelecaniformes) are widely distributed worldwide, occurring as coastal birds in inland waters and marine environments, and have been implicated in the transmission of some aquatic parasites. As such, the objective of the present work was to investigate the occurrence and morphological variations in Cardiocephaloides (Digenea: Strigeidae), parasites of the great cormorant Phalacrocorax carbo. The Cardiocephaloides specimens used for molecular analysis (DNA barcoding (cox1) region) were obtained from the intestines of the great cormorants collected from Mwanza Gulf in Lake Victoria. Morphological examination of Cardiocephaloides specimens showed the possible co-existence of four morphospecies belonging to the genus Cardiocephaloides. However, detailed …

The Effect Of Dairy Cow Genotype On Modelled Greenhouse Gas Emissions Derived From Pasture Based Milk Production Systems, Dan K. Lovett, L. Shalloo, P. Dillon, Frank O'Mara

IGC Proceedings (1977-2023)

A three-year systems comparison study was undertaken to see if progressively increasing the genetic potential for milk production of the dairy cow is desirable within pastoral based systems of spring milk production (Kennedy et al., 2002). The production data was inputted into the Moorepark Dairy System Model (MDSM) (Shalloo et al., 2004) to describe the economic, biological and production efficiency of each system. Output was then used to model whole farm greenhouse gas (GHG) emissions (Lovett et al., in press) from the nine systems studied (three concentrate levels by three genotype levels). Only the genotype effects are …

Methane Of Animal Origin In Cattle Fed High Or Low Tannin Sorghum Silage, T. T. Berchielli, S. G. Oliveira, M. P. Pedreira, O. Primavesi, M. A. Lima, R. Frighetto

IGC Proceedings (1977-2023)

The harmful or beneficial effects associated with the presence of tannin in plants depends on its concentration and form. One of these beneficial effects is the reduction of the production of methane in the rumen (Woodward et al., 2001). This study financed by FAPESP aimed to evaluat the effect of diets containing low or high tannin sorghum silage supplements on dry matter intake (DMI) and methane production in cattle.