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Method Development For The Quantification Of Critically Valuable Elements In Permian Basin Produced Waters, Carley Oliver

Open Access Theses & Dissertations

Produced waters (PW) are a major byproduct of the oil and gas industrial hydraulic fracturing processes that create a major waste disposal issue with a need for disposal, treatment, and reuse method developments. The current primary disposal method is subsurface injection, which can lead to high pressures in the subsurface. PWs are often highly saline from mineral leaching due to long residence in subsurface reservoirs. According to the USGS National Minerals Information Center, bromine, calcium chloride, iodine, lithium, magnesium, and sodium chloride have been found in and extracted from these domestic subsurface brines, suggesting that there may be other economically …

Investigating Styles Of Contraction And Overprinting By Rio Grande Rift Extension In The Southern Indio Mountains, Western Texas, David W. West

Open Access Theses & Dissertations

Laramide-style intracontinental deformation occurred throughout a large area in the western United States from the late Cretaceous through the Eocene. This event is largely investigated and viewed from classic exposures in Colorado and Wyoming, extending south to southern New Mexico. In this region the Laramide orogen merges with the Mexican fold and thrust belt (MFTB) and the northern limits of the Mexican orogen along a blurry boundary. In the Indio Mountain range in western Texas, Cretaceous sediments were deposited in the Jurassic-Cretaceous Chihuahua trough. They were inverted due to contraction and emplaced adjacent to the Diablo Plateau. This region lies …

Upscaling Sapflow Measurements To Footprint Transpiration Estimations In The Jornada Experimental Range, New Mexico, Usa, Habibur R. Howlider

Open Access Theses & Dissertations

This study proposes a new method for computing transpiration across an eddy covariance footprint using field observations of plant sap flow, phytomorphology sampling, uncrewed aerial system (UAS) digital image processing, and eddy covariance micrometeorological measurements. The method is applied to the Jornada Experimental Range, New Mexico where we address three key questions: (1) How do daily summer transpiration rates of Mesquite (Prosopis glandulosa) and Creosote (Larrea tridentate) individuals of different ages compare? (2) How can the contributions of plants of varying sizes and ages be integrated for terrain-wide transpiration estimates? (3) What is the contribution of transpiration to total evapotranspiration …

Radiogenic Isotope And Ionic Concentration Ratios Reveal Hydrologic Mixing, Subsurface Residence Time, And Cross-Basin Transfer In A Snow-Fed Mountain Karst Watershed, Nathaniel Ashmead

Boise State University Theses and Dissertations

Snow-fed karst aquifers support various complex ecosystems and provide a vital water source to communities worldwide. Due to their nature and distribution, these watersheds may be particularly vulnerable to the effects of climate change. Water resource managers can mitigate uncertainty from climate impacts with accurate predictions of future water availability provided by hydrologic models. While many such models exist, their effectiveness at predicting streamflow in snow-fed karst watersheds is limited by a lack of insight into the significance of cross-basin groundwater transfers. This study used radiogenic isotope and ionic concentration ratios as natural tracers to detect cross-basin transfer between two …

Using Raman Spectroscopy To Validate Metamorphic P-T Paths From Western New Hampshire, Alexis Thomas

Boise State University Theses and Dissertations

Constructing and interpreting pressure-temperature (P-T) paths in metamorphic rocks is crucial to understanding tectonic processes occurring at mid- to deep-crustal levels. Conventional methods for obtaining P-T paths rely on mineral chemistry, such as chemical zoning in garnets, which assumes growth at chemical equilibrium. However, studies show that garnet growth can occur with disequilibrium nucleation, which can result in a biased or potentially incorrect P-T path. An alternative, physics-based approach using Raman spectroscopy can also be used to determine P-T paths. This method involves using elastic thermobarometry of quartz inclusions within garnet. In this study, I tested the hypothesis that P-T …

Image Processing Techniques For Water Droplet Penetration Time And Contact Angle Estimation, Sai Balaji Jai Kumar

UNLV Theses, Dissertations, Professional Papers, and Capstones

Water droplet behavior on soil surfaces plays a critical role in numerous environmental processes, including soil erosion, hydrological dynamics, and ecosystem health. Accurate characterization of soil water repellency, quantified by parameters such as water droplet penetration time (WDPT) and contact angles (WDCA), is essential for informed decision-making in agricultural management, forestry practices, and land-use planning. Despite the significance of these parameters, challenges exist in reliably estimating them due to the complex and dynamic nature of soil-water interactions. This thesis address challenges in estimating WDPT and WDCA, by leveraging state-of-the-art image processing techniques and machine learning algorithms. The research focuses on …

Soil Additives And Alternative Crops For Drought Defense In The Intermountain West, Tina M. Sullivan

All Graduate Theses and Dissertations, Fall 2023 to Present

The Western U.S. looks for water optimization and conservation as agriculture is the largest water diverter, and resources are pressured by urban growth, winter snowpack instability, and drought persistence. Agricultural producers have several potential options to optimize water use with different investments associated with them. Options with varying levels of risks and known management practices include alternative crops, soil wetting agents, and crop biologicals.

An alternative crop that grew incredibly fast in popularity was industrial hemp (Cannabis sativa) despite limited agronomic knowledge for best management practices. Field trials occurred (2020-2022) near Logan, UT to test a total of …

Dynamics Of Climate And Tectonics On Surface Processes And Their Sedimentary Archives In The Colorado Plateau And Basin And Range, Usa And The Calabrian Forearc, Sicily, Natalie M. Tanski

All Graduate Theses and Dissertations, Fall 2023 to Present

Landscapes change over time in response to movements of the Earth’s crust and the effects of climate. This dissertation examines how these factors shape different landscapes, focusing on erosion of river canyons in elevated plateaus, how the transport history in quartz sand may be encoded in its properties, and how a paleo-delta has formed in response to sea-level change and fault displacement. I use dating techniques, field methods, and topographic analyses to offer insight into erosional patterns and rates in different landscapes.

Rivers can take a long time to adjust to changes in boundary conditions, even after those changes have …

Hydrogen Stable Isotope Constraints On Hydration Of Colorado Plateau Lower Crust From Oligocene-Miocene Navajo Volcanic Field Xenoliths, Shelby Dianne Litton

All Graduate Theses and Dissertations, Fall 2023 to Present

Understanding flat-slab subduction is crucial as it involves the horizontal movement of an oceanic plate beneath a continental margin over a long distance. This tectonic process is widespread yet not fully understood, particularly regarding how it influences the chemical makeup of the continental plate and recycling in the hydrosphere. By analyzing isotopes, which are variations of certain elements found in minerals and water, we can gain insights into the sources of chemicals and geological processes at play. Our study area included six locations within the Navajo volcanic field (NVF), a region in the Colorado Plateau. We analyzed 23 lower crustal …

Silica Fault Mirror Development Along The Cordillera Blanca Detachment Fault, Peru, Kayla Michelle Chaudoir

All Graduate Theses and Dissertations, Fall 2023 to Present

Earthquakes occur along planes of geologic weakness called faults. Thin, light-reflective surfaces on faults are called fault mirrors and often considered signatures of previous earthquakes along these faults. The Cordillera Blanca mountain range in the Peruvian Andes provides a natural laboratory to explore meter scale exposures of fault mirrors. Three naturally formed fault mirror samples were collected from the Cordillera Blanca detachment fault which runs along the edge of the Cordillera Blanca mountain range. Prior work on this fault reveals that it is capable of destructive earthquakes every few thousand years and is a significant earthquake hazard to the surrounding …

Advancing Thermal Property Measurements And Water Management For Controlled Environment Agriculture On Earth And Beyond, Chihiro Dixon

All Graduate Theses and Dissertations, Fall 2023 to Present

Space exploration stands as one of humanity's most profound endeavors, and plant growth in space is essential for sustaining astronauts during long-duration missions. However, operating plant growth systems under reduced gravity conditions presents challenges, particularly in ensuring uniform water distribution in the root zone. Non-uniform water distribution such as excess water and/or insufficient water in the root zone can significantly impact plant yield, necessitating the need to accurately estimate water status in the root zone and understand the dynamics of water flow in plant growth media under reduced gravity conditions. The objectives of this research were to enhance the accuracy …

Interactions Between Nano/Micro-Sized Particles And Microbes For Agricultural And Environmental Applications, Li-Ting Yen

All Graduate Theses and Dissertations, Fall 2023 to Present

Among the challenges posed by a growing global population, diminishing arable land and water resources affected by climate change are critical for enhancing crop yields, ensuring food security, and maintaining water quality and environmental health.

Iron (Fe), an essential micronutrient, is vital to plant growth. The partially oxidized form of vivianite, metavivianite (metaVT), is reported to be a promising alternative Fe fertilizer. Previous studies have shown the effectiveness of bulk metaVT on plants grown on calcareous soil for mitigating Fe efficiency and the extremely low solubility of bulk metaVT (Ksp=10^-36) in electrolyte solutions, such as CaCl₂. …

Tales In The Teeth: Using Isotopic Analysis To Understand The Paleoecology And Social Behavior Of Brontotheres Of The Intermountain Basins During The Middle Eocene, John Michael Michalski

All Graduate Reports and Creative Projects, Fall 2023 to Present

Isotopic analysis has been a common practice used in paleontology to study ancient ecosystems, and the lives of animals therein. Oxygen isotopic analysis is of particular importance not only because of its use in studying paleoecology, diet, and migration, but also its use in studying mountain elevation, and its impact on ancient ecosystems. I use stable oxygen isotopic analysis to study the habits and ecology of brontotheres from intermountain basins surrounding the Uinta Mountains of Utah and Wyoming, USA. I studied the oxygen isotopes from 16 fossil specimens of teeth, most of which belonged to brontotheres, including the genera Palaeosyops …

Accretion Of Warm Chondrules In Weakly Metamorphosed Ordinary Chondrites And Their Subsequent Reprocessing, Alex M. Ruzicka, Richard C. Hugo, Jon M. Friedrich, Michael T. Ream

Geology Faculty Publications and Presentations

To better understand chondrite accretion and subsequent processes, the textures, crystallography, deformation, and compositions of some chondrite constituents in ten lithologies of different cluster texture strength were studied in seven weakly metamorphosed (Type 3) and variably shocked ordinary chondrites (Ragland—LL3 S1, Tieschitz—H/L3 S1, NWA 5421—LL3 S2, NWA 5205—LL3 S2, NWA 11905—LL3-5 S3, NWA 5781—LL3 S3, NWA 11351—LL3-6 S4) using optical and electron microscopy and microtomography techniques.

Results support a four-stage model for chondrite formation. This includes 1) limited annealing following collisions during chondrule crystallization and rapid cooling in space prior to accretion, as evidenced by olivine microstructures consistent with dislocation …

Robust Hydropower Planning Balances Energy Generation, Carbon Emissions And Sediment Connectivity In The Mekong River Basin, M. Tangi, Rafael Schmitt, Rafael M. Almeida, S. Bossi, Alexander S. Flecker, F. Sala, A. Castelletti

School of Earth, Environmental, & Marine Sciences Faculty Publications

We present a framework for strategic dam planning under uncertainty, which includes GHG emissions mitigation as a novel objective. We focus on the Mekong River Basin, a fast‐developing region heavily relying on river‐derived ecosystem services. We employ a multi‐objective evolutionary algorithm to identify strategic dam portfolios for different hydropower expansion targets, using process‐related and statistical models to derive indicators of sediment supply disruption and GHG emissions. We introduce a robust optimization approach that explores variations in optimal portfolio compositions for more than 5,000 state‐of‐ the‐world configurations, regarding sediment origins and trapping and GHG emissions. Thus, we can rank dam projects' …

Seismic Imaging Of Mcmurdo Ice Shelf Near Williams Airfield, Yeshey Seldon

Open Access Theses & Dissertations

Seismic exploration has played a crucial role in understanding the Earth's interior and has been successfully employed in various regions, including Antarctica. This research focuses on analyzing a 1000-m seismic line on McMurdo Ice Shelf near Williams Airfield, as part of the Thwaites Interdisciplinary Margin Evolution (TIME) project. The McMurdo Ice Shelf, covering an expansive area within the Ross Ice Shelf, has undergone significant changes due to evolving oceanic and atmospheric conditions. The presence of Circumpolar Deep Water (CDW) has recently impacted the ice shelf, with warmer ocean waters causing basal melting and changes in wind patterns affecting ice flow …

Shedding Light On Past Ice-Free Intervals In Northwest Greenland: Luminescence Dating Of The Base Of The Camp Century Ice Core, Hawke Woznick

All Graduate Theses and Dissertations, Fall 2023 to Present

The goal of this thesis is to provide greater resolution on the age and character of the subglacial sediment recovered from the base of the Camp Century ice core, northwestern Greenland. Geochemical analysis indicated that the upper sub-ice sediments were geochemically different and experienced greater weathering than the basal unit underlying a one-meter silty ice lens. Analysis of feldspars within the very fine sand fraction indicates they are dominated by potassium feldspar. Sediment was dated using luminescence, which provides an age for the last time sediment was exposed to light. Luminescence analysis returned ages around 420 thousand years old, which …

Exploring Overbank Sediment Deposition Variation In Heavily Modified Floodplains Of The Lower Mississippi River: A Sedimentological And Geophysical Analysis, Seth Fradella

Master's Theses

Since the 1930s, the Lower Mississippi River (LMR) has experienced large-scale modifications to the channel profile and surrounding floodplains through dams, dikes, revetments, dredging, and channel cutoffs. Although these changes have improved navigation and reduced flood risk, unanticipated changes to the major flood return period, individual flood severity and duration, and sediment regime have become increasingly apparent and sometimes problematic, such as the 2011 and 2018-2020 floods. Flood control levees along the LMR have reduced the natural floodplain area by 70-90%, resulting in heavily restricted overbank storage capacity of water and sediment. For the same flood events in recent history, …

Shaking Off The Rust: Unraveling The Depositional And Diagenetic History Of Enigmatic Ferroan Dolostones In The Cambrian Bright Angel Formation, Tonto Group, Grand Canyon, Joseph J. Clevenger

All Graduate Theses and Dissertations, Fall 2023 to Present

Within the siliciclastic-sediment-dominated Bright Angel Formation (BAF) of the iconic Cambrian sedimentary strata (Tonto Group) in Grand Canyon National Park, Arizona, workers have identified and named prominent reddish-brown cliffs breaking up the generally slope-forming unit near, but separated from, its upper contact with the limestone-dominated Muav Formation, the "Rusty Brown Dolostones" (RBDs). Previous hypotheses suggest that the RBDs are chemically and physically altered tongues of the Muav Formation intercalated with the BAF at increasingly higher stratigraphic positions from west to east within the Canyon. A genetic association between the Muav Formation and the RBDs, as well as between the RBDs …

New Insights Into The Diverse Intraplate Volcanism Present Within The Howland And Baker Island United States Exclusive Economic Zone, Nicholas Foresta

UNLV Theses, Dissertations, Professional Papers, and Capstones

The origin of oceanic volcanism has been attributed to various mechanisms, such as upwelling mantle plumes, lithospheric extension driven decompression melting, and small-scale convective cells in the asthenosphere. Discovering the range of magmatic drivers present in the ocean basins aids in understanding mantle geodynamics and tectonic processes. A recent seafloor exploration campaign within the Howland and Baker Island (HBI) U.S. Exclusive Economic Zone (EEZ; approximately near the equator and the International Date Line) resulted in the collection of multiple lava flow samples, which offer valuable insights into the complex origins and dynamics of intraplate seamounts. According to current absolute plate …

Phylogenetic And Biogeographic Patterns Of Devonian Proetid Trilobites, Katherine Jane Jordan

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

Ecological disruption events such as mass extinctions can result in the permanent alteration in clades and ecosystems. A pivotal time of change during the history of life on Earth can be seen in the Devonian Period. During this time, major transitions in marine and terrestrial system resulted in a different world at the end of the period in comparison to the beginning. One such group most heavily impacted were trilobites. Trilobites were reduced to one order by the end of the Devonian: Proetida. My dissertation focuses on phylogenetic, biogeographic, and paleocommunity patterns of this group, known as the last of …

Experimental Investigations Of Elemental And Isotopic Partitioning With Applications To Geochronology, Lunar Crust, And Meteorite Erg Chech 002, Yuanyuan Liang

Arts & Sciences Graduate Student Theses and Dissertations

Elemental partitioning and crystallization processes on the Earth, Moon, and the meteorite Erg Chech 002 parent body are explored in this thesis, highlighting different mineral assemblage crystallization histories in three distinct geologic environments: the Earth's crust, the Moon's mantle, and the Erg Chech 002 (EC 002) parent body. Multiple series of one-atmosphere zircon synthesizing experiments, using basaltic andesite, andesite, and rhyolite starting materials, have been conducted (Chapter 2) to study the U/Th partitioning behavior between zircon and melt. The results reveal that sector zoning, fractional crystallization, typical igneous oxygen fugacities, and melt composition, particularly the whole rock silica content and …

Analyzing Fe/Mg-Silicate Chemical Gardens As Analogs To Silicate-Rich Hydrothermal Chimneys On Early Earth And Mars, Nancy Alejandra Carman

UNLV Theses, Dissertations, Professional Papers, and Capstones

Hydrothermal systems have been proposed as environments for prebiotic chemistry on early Earth. Ancient Mars was an ocean world and could also have had hydrothermal vents supporting biological or prebiotic processes. The Strytan Hydrothermal Field (SHF) in Iceland is a basalt-hosted alkaline vent that forms massive hydrothermal Mg-saponite chimneys and is a potential analog to basalt-hosted alkaline vents that may have existed at the Eridania basin on Mars, where saponite deposits are thought to have formed from ancient hydrothermal activity. Chemical garden experiments have previously been used to simulate aspects of hydrothermal chimney growth for other types of vent systems; …

Effects Of Climate Change On (Semi)-Arid Ecosystems In The Southwestern United States, Charlotte Van Der Nagel

UNLV Theses, Dissertations, Professional Papers, and Capstones

Climate change is considered amongst the most severe threats to terrestrial and aquatic ecosystems globally. Ecosystems in the southwestern United States have specifically been impacted by intense drought conditions since 2000. Higher temperatures combined with altered precipitation stresses many ecosystems; however, ecosystem specific responses to such stressors may vary. Here, the effects of climate change on semi-arid ecosystems are analyzed for some of the most vulnerable ecosystems in the southwestern United States: lacustrine, riparian, and dryland ecosystems.

Lakes and reservoirs in arid environments often serve as drinking water sources and recreational areas where high water quality is essential. Climate change …

Case Study: Abandoned Mines Reclamation And Extrapolation Technique In Gis, Yuri Gorokhovich

Open Educational Resources

The goal of this exercise is to integrate vector/raster data for the input in the model that will predict locations of possible mine reclamation projects in USA. The original publication is: Gorokhovich Y., A. Voros, M. Reid, E. Mignone. 2003. Prioritizing Abandoned Coal Mine Reclamation Projects Within Contiguous United States Using Geographic Information System Extrapolation. Environmental Management, October 2, vol. 32, issue 4. 527-534.

Economics - The Neglected Dimension Of Pasture Disease R&D, N D. Macleod

IGC Proceedings (1977-2023)

Pasture utilisation underpins a significant contribution of livestock industries to Australia’s economic well-being. Pasture disease represents a direct threat to these enterprises but the economic magnitude of this threat remains largely unknown as the contribution of agricultural economics to pasture disease R&D, management and policy making has been minimal to date. Some insights to explain this apparent neglect are highlighted and a suggestion is made for a multiple disciplinary approach to R&D.

The 'Pendulum Paradigm' - Trends In Nitrogen Fertilizer Use On Temperate Grass/ Clover Pastures, R J. Eckard, F R. Mckenzie, P A. Lane

IGC Proceedings (1977-2023)

Nitrogen fertiliser responses, on perennial ryegrass (Lolium perenne) / white clover (Trifolium repens) dominant pastures, are compared between sub-tropical South Africa and temperate Australia. The data highlight the similarity in inflection point of the response curve, while emphasising the influence of high residual soil N at lower N application rates. The propensity of communities to oscillate between extremes in terms of N fertiliser use on intensive pasture, or the ‘Pendulum Paradigm’ is discussed. Particular reference is made to the dramatic increase in N fertiliser use in dairy pasture of temperate Australia and New Zealand. Emphasis is …

Linking Grassland And Range National Goals With The Grazing Lands Conservation Initiative For National Benefit, David B. Hannaway, Walter F. Wedin, Gerald W. Evers

IGC Proceedings (1977-2023)

Grassland and Range National Goals (GRNGs) were developed to identify national research and education needs for these resources, both public and private. The Grazing Lands Conservation Initiative (GLCI) developed within the NRCS to address the need for technical assistance for the management of privately held grazing lands. These activities are complimentary and, when combined, will address the national need for research, education, and technical assistance leading to better management of grassland and range resources.

The Effect Of Grazing On Etiolated Regrowth In Eight Grass Species, H A. Lardner, S.B M. Wright, R.D H. Cohen

IGC Proceedings (1977-2023)

Grazing by herbivores affects grass species both morphologically and physiologically. A grazing study was conducted on an irrigated pasture near Outlook, Saskatchewan, Canada during the summers of 1991 and 1992 to determine etiolated regrowth after grazing of reed canarygrass (Phalaris arundinacea L.), slender wheatgrass (Elymus trachycaulus (Link) Gould ex Shinners subsp. trachycaulus), intermediate wheatgrass (Thinopyrum intermedium (Host) Barkw. & D.R. Dewey subsp. intermedium), orchardgrass (Dactylis glomerata L.), meadow bromegrass (Bromus beibersteinii Roem. & Schult.), smooth bromegrass (Bromus inermis Leyss.), tall fescue (Festuca arundinacea (Schreb.) Wimm.) and timothy (Phleum pratense L.) in …

A Vison Of The Future World Food Production And Implications For The Environment And Grasslands, Per Pinstrup Andersen, Rajul Pandya Lorch

IGC Proceedings (1977-2023)

Increases in world population, projected to rise to 8 billion by 2020, and the resultant demand for food places great pressure on our agricultural and aquacultural resources. Anxiety about the future is exacerbated by decreasing grain stocks. Production increases of many commodities are projected to be between 1 and 2% per annum and will generally be higher in developing than in developed countries. Cultivatable land area will increase in some areas of the world but not in others. To cope with these challenges, yield increases will be essential and the application of existing knowledge and technologies will not suffice. Accelerated …