Digital Commons Network^™

A Seasonal Study Of Dissolved Cobalt In The Ross Sea, Antarctica: Micronutrient Behavior, Absence Of Scavenging, And Relationships With Zd, Cd, And P., M. A. Saito, T. J. Goepfert, A. E. Noble, E. M. Bertrand, Peter N. Sedwick, Giacomo R. Ditullio

OES Faculty Publications

We report the distribution of cobalt (Co) in the Ross Sea polynya during austral summer 2005-2006 and the following austral spring 2006. The vertical distribution of total dissolved Co (dCo) was similar to soluble reactive phosphate (PO(4)(3-)), with dCo and PO(4)(3-) showing a significant correlation throughout the water column (r(2) = 0.87, 164 samples). A strong seasonal signal for dCo was observed, with most spring samples having concentrations ranging from similar to ~ 45-85 pM, whereas summer dCo values were depleted below these levels by biological activity. Surface transect data from the summer cruise revealed concentrations at the low range …

On The Fractional Solubillity Of Copper In Marine Aerosols: Toxicity Of Aeolian Copper Revisited, Edward R. Sholkovitz, Peter N. Sedwick, Thomas M. Church

OES Faculty Publications

Paytan et al. (2009) argue that the atmospheric deposition of aerosols lead to copper concentrations that are potentially toxic to marine phytoplankton in a large area of tropical and subtropical North Atlantic Ocean. A key assumption in their model is that all marine aerosols (mineral dust and anthropogenic particles) have a high (40%) fractional solubility of copper. Our data show that the fractional solubility of copper for Saharan dust over the Sargasso Sea and Bermuda is significantly lower (1-7%). In contrast, anthropogenic aerosols with non-Saharan sources have significantly higher values (10-100%). Hence, the potential Cu toxicity in the tropical and …

Social-Ecological Resilience Of A Nuosu Community-Linked Watershed, Southwest Sichuan, China, Lauren S. Urgenson, R. Keala Hagmann, Amanda C. Henck Schmidt, Stevan Harrell, Thomas M. Hinckley, Sara Jo Shepler, Barbara L. Grub, Philip M. Chi

Faculty & Staff Scholarship

Farmers of the Nuosu Yi ethnic group in the Upper Baiwu watershed report reductions in the availability of local forest resources. A team of interdisciplinary scientists worked in partnership with this community to assess the type and extent of social-ecological change in the watershed and to identify key drivers of those changes. Here, we combine a framework for institutional analysis with resilience concepts to assess system dynamics and interactions among resource users, resources, and institutions over the past century. The current state of this system reflects a legacy of past responses to institutional disturbances initiated at the larger, national system …

Effects Of Livestock Antibiotics On Nitrification, Denitrification, And Microbial Community Compositon In Soils Along A Topographic Gradient, Sagarika Banerjee

University of Kentucky Master's Theses

Several types of antibiotics (roxarsone, virginiamycin, and bacitracin) are widely included in poultry feed to improve animal growth yields. Most of the antibiotics are excreted in manure which is subsequently applied to soils. One concern with this practice is that antibiotics may affect several microbially-mediated nutrient cycling reactions in soils that influence crop productivity and water quality. The main objectives of this study were to determine the effects of livestock antibiotics on nitrification, denitrification, and microbial community composition in soils along a topographic gradient. These objectives were addressed in a series of lab experiments by monitoring changes in inorganic N …

Post-Coring Entrapment Of Modern Air In Some Shallow Ice Cores Collected Near The Firn-Ice Transition: Evidence From Cfc-12 Measurements In Antarctic Firn Air And Ice Cores, Murat Aydin, S. A. Montzka, M. O. Battle, M. B. Williams, Warren J. De Bruyn, J. H. Butler, K. R. Verhulst, C. Tatum, B. K. Gun, D. A. Plotkin, B. D. Hall, Eric S. Saltzman

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

In this study, we report measurements of CFC-12 (CCl2F2) in firn air and in air extracted from shallow ice cores from three Antarctic sites. The firn air data are consistent with the known atmospheric history of CFC-12. In contrast, some of the ice core samples collected near the firn-ice transition exhibit anomalously high CFC-12 levels. Together, the ice core and firn air data provide evidence for the presence of modern air entrapped in the shallow ice core samples that likely contained open pores at the time of collection. We propose that this is due to closure of the open pores …

Complementary Nature Of Surface And Atmospheric Parameters Associated With Haiti Earthquake Of 12 January 2010, Ramesh P. Singh, Waseem Mehdi, Manish Sharma

Mathematics, Physics, and Computer Science Faculty Articles and Research

The present paper describes surface (surface air temperature) and atmospheric parameters (relative humidity, surface latent heat flux) over the epicenter (18A degrees 27A ' 25A ' A ' N 72A degrees 31A ' 59A ' A ' W) of Haiti earthquake of 12 January 2010. Our analysis shows pronounced changes in surface and atmospheric parameters few days prior to the main earthquake event. Changes in relative humidity are found from the surface up to an altitude of 500 hPa clearly show atmospheric perturbations associated with the earthquake event. The purpose of this paper is to show complementary nature of the …

Trace Metal Biogeochemistry In The Western North Pacific, Peter Lynn Morton

OES Theses and Dissertations

Dissolved and suspended particulate samples collected during the Intergovernmental Oceanographic Commission 2002 Contaminant Baseline Survey were analyzed to determine the surface and vertical distributions of Cd, Co, Cu, Mn, Ni Zn and Pb across the western and central North Pacific.

Dissolved trace metal concentrations were measured using a novel isotope dilution-ICP-MS method after extraction over an 8-hydroxyquinoline resin column and validated through the use of the SAFe consensus reference materials. Filtered suspended particulate matter was digested using an HCl/HNO3/HF mixture and analyzed by HR-ICP-MS to obtain total particulate concentrations for the trace metals and other tracer elements such as Al, …

Paleolimnological Reconstruction Of Hydrologic Change In The Slave River And Great Slave Lake During The Past Millennium, Matthew Ennis

Theses and Dissertations (Comprehensive)

The Slave River Delta (SRD), NWT, represents a pivotal node in the upper Mackenzie Basin watershed and is a productive northern wetland landscape with a rich natural and cultural heritage. Concerns over environmental consequences of natural and anthropogenic-driven decline in river discharge as well as climate variability have prompted hydroecological sstudies to improve understanding of how this ecosystem functions over time and space. However, long-term natural hydrological variability of the Slave River system is not well documented and needs to be further developed. In order to provide a temperal context for understanding and evaluating the impacts of climate variability and …

An Inventory And Condition Survey Of The Western Australian Part Of The Nullarbor Region, Peter-Jon A. Waddell, A K. Gardner, P Hennig

Technical Bulletins

The inventory and condition survey of the Western Australian part of the Nullarbor region, undertaken by the Department of Agriculture and Food, Western Australia (DAFWA) between 2005 and 2007, describes and maps the natural resources of the region. This survey report provides a baseline record of the existence and condition of the area's natural resources, to assist with the planning and implementation of land management practices. The report identified and described the condition of soils, landforms, vegetation, habitat, ecosystems, and declared plants and animals. It also assessed the impact of pastoralism and made land management recommendations. The Nullarbor region has …

A Methodology To Estimate The Future Extent Of Dryland Salinity In The Southwest Of Western Australia, Peter Caccetta, Robert Dunne, Richard J. George, Don J. Mcfarlane

Natural Resources Research Articles

In the southwestern agricultural region of Western Australia, the clearing of the original perennial vegetation for annual vegetation-based dryland agriculture has lead to rising saline groundwater levels. This has had effects such as reduced productivity of agricultural land, death of native vegetation, reduced stream water quality and infrastructure damage. These effects have been observed at many locations within the 18 million ha of cleared land. This has lead to efforts to quantify, in a spatially explicit way, the historical and likely future extent of the area affected, with the view to informing management decisions. This study was conducted to determine …

Results Of New Petrologic And Remote Sensing Studies In The Big Bend Region, Stevan Christian Benker

Open Access Theses & Dissertations

The initial section of this manuscript involves the South Rim Formation, a series of 32.2-32 Ma comenditic quartz trachytic-rhyolitic volcanics and associated intrusives, erupted and was emplaced in Big Bend National Park, Texas. Magmatic parameters have only been interpreted for one of the two diverse petrogenetic suites comprising this formation. Here, new mineralogic data for the South Rim Formation rocks are presented. Magmatic parameters interpreted from these data assist in deciphering lithospheric characteristics during the mid-Tertiary.

Results indicate low temperatures (< 750 °C), reduced conditions (generally below the FMQ buffer), and low pressures (≤ 100 MPa) associated with South Rim Formation magmatism with slight conditional differences between the two suites. Newly discovered fayalite microphenocrysts allowed determination of oxygen fugacity values (between -0.14 and -0.25 ΔFMQ over temperature ranges of 680-700 °C), via mineral equilibria based QUILF95 calculations, for Emory Peak Suite.

Petrologic information is correlated with structural evidence from Trans-Pecos Texas and adjacent regions to evaluate debated timing of tectonic …

Oxidation Of Dibenzothiophene To Dibenzothiophene Using Metal Nanoparticles Supported On Silica, Karina Castillo

Open Access Theses & Dissertations

Silica and nanoparticles of Pt, Au, and Ag supported on silica were tested for the ability to oxidize dibenzothiophene (DBT) to sulfone. High performance liquid chromatography was used to study the removal of DBT from solution. In addition, X- ray diffraction, infrared spectroscopy and Raman Spectroscopy were used to characterize the product of the oxidation reaction. Further studies involved the use X-ray absorption spectroscopy to characterize the nanoparticle catalysts before and after the oxidation reaction.

To better understand the reaction, silica was synthesized at different pHs using three different acids. The acids used to synthesize the silica were HCl, HNO3, …

Controlling Features And Processes For Radionuclide Release From Unsaturated Zone Geological Repositories, Lubna K. Hamdan

Open Access Theses & Dissertations

In the long run, nuclear waste packages will fail gradually due to localized and general corrosion and radionuclides will be transported to the accessible environment by ground water.

Two main failure scenarios are expected for the waste packages: Flow-through model and bathtub model; in the flow-through model water flows through the waste container, while in the bathtub model water pools inside the waste package. The Department of Energy, in their performance assessment of the proposed repository at Yucca Mountain, excluded the bathtub model from their analysis and assumed the diffusion and advection to be in the same direction in the …

Tectonic Geomorphology Of The Puna Tsang Chhu, Western Bhutan, Abby May Woody

Open Access Theses & Dissertations

There are two boundaries, or physiographic transitions, between three distinct topographic regions in Bhutan. The southern and northern regions have relatively steep hillslopes and high relief, while the central region has gentle hillslopes and low relief. The geomorphology of a 70-km stretch along the Puna Tsang Chhu valley between the towns of Uma and Amrimo was studied in March and April of 2009 to provide constraints on the active tectonics of western Bhutan and the nature of these physiographic transitions.

The Puna Tsang Chhu valley contains a set of alluvial cut-and-fill and bedrock (strath) river terraces with associated sediments - …

Urban Development Under Extreme Hydrologic And Weather Conditions For El Paso-Juárez: Recommendations Resulting From Hydrologic Modeling, Gis, And Remote Sensing Analyses, Alberto Barud-Zubillaga

Open Access Theses & Dissertations

During the 2006 El Paso-Juárez flood there were many concerns regarding the capability of the existing stormwater system to handle 50- and 100-year flood events in El Paso, Texas and Juárez, Mexico area. Moreover in 2008, a considerable wet year from the normal 223 mm of annual precipitation for El Paso demonstrated that the area could very well received large amounts of precipitation at localized areas in short periods of time, representing a great flood threat to residents living in areas prone to flood. Some climate change projections for the area are exactly what had occurred over the last two …

Application Of Copper And Zinc Isotopes To Fingerprint Metal Sources And Identify Attenuation Mechanisms In The Abandoned Waldorf Mine Area, Clear Creek County, Colorado, Suzan Aranda Luna

Open Access Theses & Dissertations

Acid rock drainage (ARD) is caused by the oxidative weathering of sulfide minerals. Sulfur is oxidized by dissolved oxygen or Fe(III) and sulfate ions, metals, and protons are released into the environment. Hence, the pH of nearby water and soils often decreases in response to ARD while metal concentrations increase. Because a large part of the Rocky Mountains of Colorado are highly mineralized (i.e., the Colorado Mineral Belt), ARD is a serious problem in this region. Moreover, the many abandoned mining areas in the Rocky Mountains that include waste rock piles, tailings impoundments, and surface disturbances add to the problem …

Granulometry And Geochemistry Of Dust Emission From Owens (Dry) Lake, California, Analila Rojo

Open Access Theses & Dissertations

Owens (dry) Lake, the terminus of Owens River, is located in the Basin and Range physiographic province in east–central California. The transformation of Owens Lake into a desiccated desert playa (approximately 280 km2) via diversion of the river into the Los Angeles Aqueduct (in 1913) led to extensive wind erosion, making the playa one of the most intense sources of airborne dust in the Western Hemisphere. The processes that direct the chemical and mineralogical composition of surface sediments at Owens (dry) Lake and the physical mechanisms of wind erosion, saltation and dust emission at Owens (dry) Lake are well–understood. However, …

Mineralization In The San Juan Mountains, Colorado, William M. Sheriff

Open Access Theses & Dissertations

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A Dynamic Physical Model For Soil Temperature And Water In Taylor Valley, Antarctica, H. W. Hunt, Andrew G. Fountain, Peter T. Doran, Hassan J. Basagic

Geography Faculty Publications and Presentations

We developed a simulation model for terrestrial sites including sensible heat exchange between the atmosphere and ground surface, inter- and intra-layer heat conduction by rock and soil, and shortwave and longwave radiation. Water fluxes included snowmelt, freezing/thawing of soil water, soil capillary flow, and vapour flows among atmosphere, soil, and snow. The model accounted for 96-99% of variation in soil temperature data. No long-term temporal trends in soil temperature were apparent. Soil water vapour concentration in thawed surface soil in summer often was higher than in frozen deeper soils, leading to downward vapour fluxes. Katabatic winds caused a reversal of …

Vitis Seeds (Vitaceae) From The Late Neogene Gray Fossil Site, Northeastern Tennessee, Usa., Fade Gong

Electronic Theses and Dissertations

This study focuses on the morphometric and systematic studies of fossil vitaceous seeds recently recovered from the Gray Fossil Site (7-4.5 Ma, latest Miocene-earliest Pliocene) northeastern Tennessee. Morphologically, all fossil seeds correspond to the extant subgenus Vitis (genus Vitis) of the Vitaceae based on the smooth dorsal surface with a centrally positioned chalaza connected with a conspicuous chalaza-apex groove and short linear ventral infolds that are slightly diverged apically. A multivariate analysis based on 11 measured characters from 76 complete seeds identified three types of seeds, each representing a distinct morphotaxon. Based on comparison with modern and fossil vitaceous …

Performance Of Dmt-Based Liquefaction Evaluation Methods On Case Histories Of Chi-Chi Earthquake, Gordon Tung-Chin Kung, Der-Her Lee, Pai-Hsiang Tsai

Journal of Marine Science and Technology–Taiwan

This study examines two recently-developed DMT-based methods, one CRR7.5-KD boundary curve and one CRR7.5-ED boundary curve, for evaluating the liquefaction resistance of soils using in-situ test data. The collected data consist of a number of liquefied and non-liquefied case histories, which were performed shortly after the disastrous Chi-Chi earthquake in 1999. The results of examining the CRR7.5-KD and CRR7.5-ED boundary curves showed that both curves are capable of accurately estimating the liquefaction resistance of soils and thus the liquefaction potential of soils. The developed DMT-based methods therefore have the potential to be an alternative to the existing procedure of liquefaction …

Fractal Location And Anomalous Diffusion Dynamics For Oil Wells From The Ky Geological Survey, Keith Andrew, Karla M. Andrew, Kevin A. Andrew

Physics & Astronomy Faculty Publications

Utilizing data available from the Kentucky Geonet (KYGeonet.ky.gov) the fossil fuel mining locations created by the Kentucky Geological Survey geo-locating oil and gas wells are mapped using ESRI ArcGIS in Kentucky single plain 1602 ft projection. This data was then exported into a spreadsheet showing latitude and longitude for each point to be used for modeling at different scales to determine the fractal dimension of the set. Following the porosity and diffusivity studies of Tarafdar and Roy[1] we extract fractal dimensions of the fossil fuel mining locations and search for evidence of scaling laws for the set of deposits. The …

Analysis Of Electromagnetic And Seismic Geophysical Methods For Investigating Shallow Sub-Surface Hydrogeology, Eric M. Parks

Theses and Dissertations

An integrated electromagnetic (EM) and seismic geophysical study was performed to evaluate non-invasive approaches to estimate depth to shallow groundwater in arid environments with elevated soil salinity where the installation of piezometers would be impractical or prohibited. Both methods were tested in two study areas (semi-arid and arid respectively), one in Palmyra, Utah, USA near the shore of Utah Lake where groundwater is shallow and unconfined in relatively homogeneous lacustrine sediments. The other area is Carson Slough, Nevada, USA near Ash Meadows National Wildlife Refuge in Amargosa Valley. The area is underlain by valley fill, with generally variable shallow depths …

A New Process For Organizing Assessments Of Social, Economic, And Environmental Outcomes: Case Study Of Wildland Fire Management In The Usa, Randall Jf Bruins, Wayne R. Munns Jr., Stephen J. Botti, Steve Brink, David Cleland, Larry Kapustka, Danny Lee, Valerie Luzadis, Laura Falk Mccarthy, Naureen Rana, Douglas B. Rideout, Matt Rollins, Peter Woodbury, Mike Zupko

United States Environmental Protection Agency: Publications

Ecological risk assessments typically are organized using the processes of planning (a discussion among managers, stakeholders, and analysts to clarify ecosystem management goals and assessment scope) and problem formulation (evaluation of existing information to generate hypotheses about adverse ecological effects, select assessment endpoints, and develop an analysis plan). These processes require modification to be applicable for integrated assessments that evaluate ecosystem management alternatives in terms of their ecological, economic, and social consequences.We present 8 questions that define the steps of a new process we term integrated problem formulation (IPF), and we illustrate the use of IPF through a retrospective case …

Creation Of Soil Liquefaction Susceptibility Maps For San Luis Obispo & Marin Counties Using Geographic Information Systems., Amelia M. Lowman

Earth and Soil Sciences

Liquefaction of soils in response to earthquake shaking is a pressing issue in the state of California. Using Geographic Information Systems, Geological and lithology layers, along with criteria in order to separate out the data into four risk categories, a liquefaction risk assessment map was created for San Luis Obispo and Marin Counties. The accuracy of these maps was then assessed using liquefaction occurrences for San Luis Obispo County, and it was determined that while the map is somewhat accurate, in order to obtain a greater amount of accuracy and increase the usefulness of these maps, more data would need …

Using Conservative And Biological Tracers To Better Understand The Transport Of Agricultural Contaminants From Soil Water Through The Epikarstic Zone, Brian Ham

Masters Theses & Specialist Projects

Agriculture contamination is very common in karst systems due to the vulnerability of these aquifers. Animal waste is often spread across crop land to enrich the soil with nitrates and phosphates. Herbicides and pesticides are also applied to the crops. The transport of these pollutants through the soil and epikarst is a difficult process to monitor due to the complex, heterogeneous behavior of the groundwater as it makes its way down to the aquifer below.

An experimental site at Crumps Cave lended a unique opportunity to monitor the vadose zone at a waterfall in the cave below. A previous dye …

Heirloom And Hybrid Tomato Yield And Quality In Organic And Conventional Production Systems, Diana J. Edlin

Masters Theses & Specialist Projects

Due to the recent changes in the economy of Kentucky tobacco production, some producers are seeking an alternative crop that will provide similar economic gains to tobacco without needing more acreage. Tomatoes are an existing crop in Kentucky that have been declining in acreage over the last five years. There is evidence to suggest that, through niche and local marketing, tomatoes may be able to fill the void left by tobacco. However, there is concern among producers that they will lose yield and/or quality if they switch to one of these niche production systems or cultivars.

A two year study …

Reconciling Holocene Alluvial Records In Buckskin Wash, Southern Utah, Jonathan E. Harvey

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Most approaches to interpreting alluvial records in drylands fall into one of two categories: (1) The "arroyo problem," wherein workers study cycles of streambed aggradation and degradation in broad, unconstricted alluvial valleys; and (2) paleoflood hydrology, where alluvial sequences in constricted bedrock canyons are interpreted as paleoflood deposits from streams with stable channel grade and geometry. Both approaches can be valid in their end-member settings, but there is confusion about how the two record types relate in a single drainage. We address this disconnect in Buckskin Wash, an ephemeral stream that consists of a broad alluvial reach draining into a …

A Comparison Of Soil Moisture And Hillslope-Stream Connectivity Between Aspen And Conifer-Dominated Hillslopes Of A First Order Catchment In Northern Utah, Amy R. Burke

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Mountain headwater catchments in the semi-arid Intermountain West are important sources of surface water because these high elevations receive more precipitation than neighboring lowlands. The hydrology of these mountain catchments is especially important as the region faces water shortages and conflicts. Conifer encroachment on aspen stands has been observed across the western US and can result in a decline in water yield. The overall objective of this study was to further our understanding of hillslope-stream connectivity in a headwater catchment of Northern Utah and any observable differences in this connection between aspen and conifer hillslopes. Hillslopes are the fundamental unit …

Empirical Mode Decomposition Operator For Dewowing Gpr Data, Bradley M. Battista, Adrian Addison, Camelia C. Knapp

Faculty Publications

Signal processing tools available to ground penetrating radar data used for shallow subsurface imaging and hydrogeophysical parameter estimation are significantly handled using the same tools available to seismic reflection data. Overall, the same tools produce interpretable images from both data types, but particular noise (wow noise) in electromagnetic data must be removed before stable and accurate quantitative results can be produced. Wow noise is an inherent, nonlinear electromagnetic interference and a significant component of GPR data. Further, the nonlinear and non-stationary nature of wow noise provides a strong argument for preprocessing radar traces with time-domain operators. Time-domain operators designed for …