Digital Commons Network^™

A Histological Survey Of A Large, Sub-Adult Tylosaurus Nepaeolicus With Implications On The Validity Of Tylosaurus Kansasensis, Carson Cope

Master's Theses or Doctor of Nursing Practice

Tylosaurus nepaeolicus is a basal, medium-sized tylosaurine mosasaur that lived during the late Coniacian and early Santonian in the Western Interior Seaway. Despite being a well-studied species, there is debate over whether Tylosaurus kansasensis represents the juvenile form of T. nepaeolicus, or if the two species are distinct. Osteohistology can determine organism age at time of death and can be used to help resolve this debate and provide a better understanding of the growth of T. nepaeolicus. Thin-sections were taken from a humerus, rib, and vertebra of a single individual (FHSM VP-2209). All thin-sections show primarily parallel-fibered cortical …

Biochar For Soil Amendment: Applications, Benefits, And Environmental Impacts, Ujjwal Pokharel, Gururaj Neelgund, Ram L. Ray, Venkatesh Balan, Sandeep Kumar

Civil & Environmental Engineering Faculty Publications

The excessive use of chemical fertilizers results in environmental issues, including loss of soil fertility, eutrophication, increased soil acidity, alterations in soil characteristics, and disrupted plant–microbe symbiosis. Here, we synthesize recent studies available from up to 2025, focusing on engineered biochar and its application in addressing issues of soil nutrient imbalance, soil pollution from inorganic and organic pollutants, soil acidification, salinity, and greenhouse gas emissions from fields. Application of engineered biochar enhanced the removal of Cr (VI), Cd²⁺, Ni²⁺, Zn²⁺, Hg²⁺, and Eu³⁺ by 85%, 73%, 57.2%, 12.7%, 99.3%, and 99.2%, …

Moderate Heating Renders 7.8-Million-Year-Old Sedimentary Organic Matter Bioavailable, Shuchai Gan, Verena B. Heuer, Frauke Schmidt, Lars Wormer, Faming Wang, Rishi R. Adhikari, Patrick Hatcher, Ann Pearson, Kai-Uwe Hinrichs

Chemistry & Biochemistry Faculty Publications

Marine sediments are a large reservoir of recalcitrant organic matter and host microbes at subsurface depths exceeding 2.4 kilometers and temperatures up to 120°C, yet the mechanisms supplying bioavailable substrates remain unclear. Here, we investigated 7.8-million-year-old sediment from IODP Site C0012 off the Nankai Trough, Japan, through incubations at 20°, 35°, 55°, and 85°C to simulate burial temperatures. Using 3D fluorescence spectroscopy and ultrahigh-resolution mass spectrometry, we tracked changes in dissolved organic matter (DOM). At 35°C, humic-like DOM was released alongside metal ions, exhibiting low bioavailability. At 55°C, abiotic decomposition of humic compounds generated smaller, more bioavailable DOM, promoting fermentation. …

Molecular Characterization Of Humic And Fulvic Acids On Watterlogged And Well-Drained Amazonian Podzols, Amanda M. Tadini, Aleksandar I. Goranov, Stéphane Mounier, Débora M.B.P. Milori, Célia R. Montes, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

The Amazon rainforest is the largest tropical rainforest in the world. Amazonian Podzol soils, characteristic of this region, are known to store substantial amounts of organic carbon in both their surface and deep horizons. Despite decades of research, the molecular-level composition of these soils remains uncharacterized. This study addresses this knowledge gap by employing ultrahigh resolution mass spectrometry, namely, Fourier transform–ion cyclotron resonance–mass spectrometry (FT-ICR-MS), to determine the molecular composition of humic acid (HA) and fulvic acid (FA) fractions from two Amazonian Podzol profiles of varying levels of groundwater exposure (waterlogged vs well-drained). In the waterlogged soil compounds containing nitrogen, …

Deciphering The Chemistry Of Condensed Aromatic "Black" Carbon And Nitrogen In Amazonian Anthrosols, João Vitor Dos Santos, Aleksandar I. Goranov, Laís G. Fregolente, Marcia C. Bisinoti, Zhenhuan Sun, Klaus Schmidt-Rohr, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

Amazonian anthrosols are renowned for their high fertility and dark color, properties primarily attributed to the abundance of condensed aromatic carbon (ConAC) in the soil organic matter. ConAC, commonly referred to as black carbon, play a key role in the stability and nutrient retention of these soils. However, the processes governing the formation of ConAC and its transformation into oxygenated derivatives remain poorly understood. In this study, we used multiple analytical platforms to investigate the chemistry of ConAC-rich humic acids (HA) extracted from Terra Mulata de Indio, a type of Amazonian anthrosol. The results reveal that ConAC are predominantly …

Oxidation Camouflages Terrestrial Organic Matter To Appear Marine-Like, Aleksandar I. Goranov, Susan J. Carter, Ann Pearson, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

The export of terrestrial organic matter (TOM) to the ocean has been traditionally viewed to be minimal or only of significance in near-coastal continental margins. The broadly accepted explanation for the widespread loss of terrestrial lignin biomarkers and apparent disappearance of the <-25‰ stable carbon isotopic signature (δ¹³C) of TOM is that TOM is almost fully degraded before reaching the open ocean. Oceanic carbon (δ¹³C value ≥ -22‰) is therefore thought to be derived primarily from algae. However, an alternative explanation for the different molecular and δ¹³C signatures in terrestrial and marine environments may be that oxidative processing transforms TOM to appear marine-like. To test this hypothesis, we subjected eight TOM samples to a strong oxidation gradient. At carbon losses typical of TOM degradation during transport and sedimentation (above 60%), the differentiators of provenance disappeared, leaving a residue that was marine-like both chemically (aliphatic- and nitrogen-rich) and isotopically (δ¹³C enrichment of 4 to 9‰). This challenges the validity of conventional two-endmember mixing models, suggesting that a much larger fraction than previously estimated of the organic matter found in the ocean may originate from terrestrial sources, impacting global models of carbon cycling and sequestration.

Advancing The Characterization Of Geophysical Signals Through Array Processing And Artificial Intelligence, Miro Ronac Giannone

Earth Sciences Theses and Dissertations

In geophysics, seismic and infrasound observations are routinely employed to constrain the nature and origin of events. Seismoacoustics, as a discipline, is built upon the simultaneous detection and integrated analysis of these data types. This joint approach is critical not only for advancing scientific understanding but also for supporting global monitoring efforts in hazard mitigation and nuclear explosion treaty verification. The data analyzed in this dissertation were recorded by array deployments, which consist of multiple sensors arranged in predetermined configurations to enhance signal detection, resolve directionality, and quantify waveform coherence. Leveraging these array recordings, I introduce novel approaches which combine …

The Signal Of Airplane Combustion In Soil At A Small Airport In Ohio, Rachel Engels

Williams Honors College, Honors Research Projects

Leaded gas has been banned for automobile use in the interest of public health since 1996. However, leaded gas is still used for small piston aircraft so the engine can run safely. To investigate potential environmental impacts of leaded gas, 90 soil samples were taken from around a small airport in Ohio. Soil elemental composition was measured by X-ray fluorescence (XRF), soil organic content determined by Loss-on-Ignition (LOI), and soil ferrimagnetic content measured by magnetic susceptibility. There is an unmistakable airplane fuel combustion signal in the soil at the ends of the runway, where aircraft wait to take off on …

Insights On The Cranial Anatomy And Osteohistology Of Cyonosaurus, Alexander Acker

Dissertations

This study investigates the cranial anatomy and life history of the small-bodied gorgonopsian Cyonosaurus. Previous research on gorgonopsians has disproportionately focused on larger members of the clade, leaving smaller forms relatively understudied. This gap has led to several unresolved questions, the most pressing of which concerns gorgonopsian ontogeny. Specifically, it remains unclear whether small-bodied gorgonopsians represent genuinely diminutive adult individuals or juveniles of larger species. The specimen NHCC LB1087 presents an ideal opportunity to address this issue and gain new insights into the biology of small-bodied gorgonopsians. The first chapter focuses on cranial anatomy. Due to the specimen’s preservation, many …

Investigation Of Dynamic Adsorption And Desorption Of Polymer Nanogel In Porous Media Through Microfluidics, Junchen Liu, Fuqiao Bai, Abdulaziz A. Almakimi, Mingzhen Wei, Xiaoming He, Ibnelwaleed A. Hussein, Baojun Bai

Mathematics and Statistics Faculty Research & Creative Works

Understanding the transport and retention of elastic nanogel and microgel particles in porous media has been a significant research subject for decades, essential to the application of enhanced oil recovery (EOR). However, a lack of dynamic adsorption and desorption studies, in which the kinetics in porous media are seldom investigated, hinders the design and application of polymer nanogel in underground porous media. In this work, we visualized and quantified the transport and dynamic adsorption of polymer nanogel in 3D glass micromodels that were manufactured by packing glass beads in capillaries. Calibrating the linearity of fluorescence intensity to concentration, we calculated …

A Unionid Mussel Biodiversity Hotspot Experiencing Unexplained Declines: Evaluating The Influence Of Chemical Stressors Using Caged Juveniles, W. Aaron Wilson, Christine Bergeron, Jennifer Archambault, Jason M. Unrine, Jess Jones, Braven Beaty, Damian Shea, Peter R. Lazaro, Jody L. Callihan, Jennifer J. Rogers

Plant and Soil Sciences Faculty Publications

Unionid mussel populations in a section of the Clinch River in Virginia, USA, has declined substantially, but the causes of the decline remain unknown. To investigate this zone of decline (ZOD), we deployed juvenile freshwater mussels (Villosa iris in 2012 and Lampsilis fasciola in 2013) in both cages and silos at sites within the Clinch River System. We analyzed mussel tissues for trace element and organic contaminant concentrations, shells for trace elements, and environmental media (total water, dissolved water, particulate sediment, and bedload sediment) for both inorganic and organic contaminants. We found a few differences between mussels deployed in cages …

Growth, Survival, And Herbivore Browsing Preferences Of Seedlings Planted In Black Ash Stands Of Northern Michigan And Wisconsin, Seth W. Davenport

Dissertations, Master's Theses and Master's Reports

To mitigate the cascading ecosystem impacts of widespread black ash (Fraxinus nigra) mortality due to the invasive emerald ash borer (Agrilus planipennis), forested wetlands can be underplanted with seedlings of alternative species that later repopulate the vacated canopy. This study examined the survival and growth, factors influencing performance, and herbivore browsing preferences of seven non-ash species planted in northern Michigan and Wisconsin. The best performing species were river birch (Betula nigra), silver maple (Acer saccharinum), and swamp white oak (Quercus bicolor). The worst performing species was black spruce (Picea …

The Serendipity Of Discovery: Life Of A Geochemist, Willard S. Moore

Faculty Publications

My strategy for writing this autobiography is to use examples of how working on seemingly different projects can often lead to outcomes more important than originally envisioned. Serendipity is a "happy accident"; specifically, the accident of discovering something useful without directly looking for it. This often occurs when two research projects converge unexpectedly. The main text contains examples of how serendipity has led me to important discoveries including: (a) finding surprisingly high ²²⁸Ra activities in the ocean, (b) developing a means of rapidly and quantitatively extracting radium from seawater, (c) devising a rapid, sensitive method of measuring ²²⁴Ra …

The Tyrant King Of The Auction House: The Disastrous “Fine Artification” Of The Dinosaur, Amelia C. Kolstad

Anthós

This article examines how fine art auctioneers market dinosaur fossils as art pieces to wealthy collectors, depriving the paleontological field of specimens for scientific research. Drawing from recent examples of fossils sold at fine art auctions, this article notes how rising auction prices for specimens as ‘art’ prevent museums and research institutions from acquiring specimens for research and restoration. Kolstad concludes that the art auction houses’ marketing of fossils as art is detrimental to paleontological research. To protect fossils and their scientific value, Kolstad proposes alternatives, such as selling replicas to collectors and highlighting the importance of original specimens for …

Cover Crops Can Reduce Greenhouse Gas Emissions From No-Till Maize In Southern Brazil: Insights From A Long-Term Field Experiment, Guilherme Rosa Da Silva, Adam J. Liska, Cimélio Bayer

Adam Liska Papers

Brazil is one of the countries that has the most agricultural area under no-till (NT) management. This research study aims to evaluate life-cycle greenhouse gas (GHG) emissions from maize (M) grain production in agroecosystems that used different cover crops under NT management in southern Brazil. The data for this study were from a long-term 41-year field experiment in southern Brazil. The long-term experiment evaluated the effects of fallow (F) and cover crops (oat (O), vetch (V), cowpea (B), pigeon pea (P), and lablab (L)) on nitrous oxide and methane emissions and soil carbon (C) sequestration in maize agroecosystems. Five cropping …

Advancing Root Trait Measurements For A Deeper Understanding Of Soil Biogeochemistry, Brian Rinehart

Theses and Dissertations--Plant and Soil Sciences

Climate change is disrupting (agro)ecosystems, with the potential for significant losses in crop productivity and ecosystem resilience due to changes in water and biogeochemical cycling. These disruptions can also release more carbon dioxide into the atmosphere through the degradation of soil organic matter. Plant roots have emerged as a potential tool for mitigating these effects, given their roles in plant function and in driving soil biogeochemistry. While this interest is growing, our ability to implement root trait selection is limited due to constraints on characterizing roots and limited clarity on the effects of traits on plant and ecosystem function. My …

Paleomagnetic Assessment Of The Appekunny And Greyson Fms., Lower Belt Supergroup, Montana, Usa., Olivia C. Moehl

Dartmouth College Master’s Theses

The Belt Supergroup of the northwestern United States is one of the most extensive Mesoproterozoic sedimentary successions in North America. Although certain stratigraphic units have been well studied, correlations across the entire outcrop region remain unresolved. This project uses magnetostratigraphy and lithostratigraphy to investigate a potential lateral equivalency between the 1.4 billion-year-old (Ga) Appekunny Formation (Fm.) in Glacier National Park, MT and the 1.4 Ga Greyson Fm. in the Helena Embayment, MT. Both formations consist predominantly of shallow-water mudstones and contain the only North American occurrences of Horodyskia moniliformis, one of the oldest known macrofossils. Paleomagnetic analyses were conducted on …

A Collaborative Assessment Of Coastal Ocean Acidification Monitoring In Maine & Standard Operating Procedures And Best Practices For The Collection Of Continuous Ph Data In Coastal Marine Environments, Christopher W. Hunt, Curtis Bohlen, Mike Doan, Jeremy Miller

Faculty Publications

The ‘Sensor Squad’ of the Maine Ocean Climate Collaborative is the product of a 2023 Maine Coastal and Marine Climate Action Fund grant to conduct “A two-year pilot project designed to address and overcome technological barriers to ocean acidification data collection, develop protocols to elevate quality assurance and ensure comparable data, and meet regularly to discuss project results and data compilation”. The Squad consists of representatives from Friends of Casco Bay (FOCB), Wells National Estuarine Research Reserve (WNERR), and the University of New Hampshire (UNH). This report is a summary of their efforts to assess affordable, repeatable means of continuously …

Geology, Paleoecology And Vertebrate Biostratigraphy Of The Hell Creek Formation, Carter County, Montana, Usa, Joshua Collin Mathews

Graduate Research Theses & Dissertations

The Hell Creek Formation of the Northern Great Plains records one of the greatest mass extinction events in Earth’s history, bringing to a close the reign of the dinosaurs at the end of the Cretaceous period. This rock unit comprises one of the most studied geological formations in the world and is one of the few locations on the planet that preserve terrestrial deposits containing ejecta from the bolide impact that slammed into the Yucatan Peninsula 66 million years ago. This profound event in the geologic record has led to numerous studies of paleobiotas, climate change, ecosystem recovery dynamics, and …

Evaluation Of Strip-Tillage And Banded Phosphorus And Potassium Fertilizer For Corn Production In Eastern South Dakota, Charles N. Tesch

Electronic Theses and Dissertations

In South Dakota, the adoption of no-till and other conservation tillage practices has grown in recent years. However, conventional tillage is still a common practice in the eastern third of the state, negatively affecting soil health and the environment. Strip-tillage has gained interest in this region as a way to transition to conservation tillage while retaining some benefits of conventional tillage. Strip-tillage also provides the ability to subsurface band nutrients, particularly phosphorus (P) and potassium (K) fertilizers within the tillage strip, potentially improving nutrient accessibility and recovery while reducing environmental risks. This study aimed to investigate (i) the effects of …

Impacts Of Fire-Driven Vegetation Changes On Evapotranspiration In North American Boreal Forests, Tyler Glen Albrethsen

Graduate Student Theses, Dissertations, & Professional Papers

A growing body of evidence suggests that land cover change could be impacting evapotranspiration (ET) trends more than the direct impacts of climate change (Dashti et al., 2022; Zhang et al., 2015). In boreal forests, one of the Earth’s most important carbon sinks (Kang et al., 2006), climate and disturbance-driven land cover change is progressing rapidly, threatening the resilience of conifer-dominated forests (Baltzer et al., 2021; Massey et al., 2023). The spread of deciduous trees and the changing structure of boreal forests likely have large implications for the magnitude and seasonality of ecosystem water fluxes (Young-Robertson et al., 2016). This …

Carbon Sequestration Through Conservation Tillage In Sandy Soils Of Arid And Semi-Arid Climates: A Meta-Analysis, Samantha Lynn Colunga, Leila Wahab, Alejandro Fierro-Cabo, Engil Isadora Pujol Pereira

School of Earth, Environmental, & Marine Sciences Faculty Publications

Highlights

• Under CST, SOC increased by 12.74 ± 1.46 % in sandy soils with 5 of the 6 practices contributing to this rise.
• SOC increased up to 15 years post-CST conversion, but more research is needed to assess long-term effects.
• SOC increased by 13% in soils with over 56% sand content under CST.
• SOC increased by 15% in the 0-20 cm depth under CST, with no significant increase at greater depths.
• SOC increased under CST when nitrogen was applied at rates up to 100 kg N ha⁻¹.

Abstract

This meta-analysis assessed soil organic carbon (SOC) percent changes in sandy soils, …

Assessing Inter-Organizational Collaboration Within The Transboundary Network Governing The Conservation Of Southern Resident Killer Whales, Dane Pedersen, Owen Temby, Antonia Sohns, Evelyn Roozee, Gordon M. Hickey

School of Earth, Environmental, & Marine Sciences Faculty Publications

The Southern Resident Killer Whale (SRKW) is an endangered and charismatic species whose home range spans the Salish Sea, an ecosystem that extends across the Canada-US border. Conserving and recovering the SRKW represents a high-profile transboundary governance challenge that depends heavily on collaboration between a wide range of organizations. To better understand the factors affecting transboundary SRKW governance in the Salish Sea, this study applies a multi-dimensional trust, control, perceived risk framework to assess the inter-organizational architecture supporting collaboration. The analysis is based on key informant interviews (n=32) and surveys (n=35) conducted with policy actors working for different organizations involved …

Isolation And Molecular Identification Of Pathogens Causing Sea Turtle Egg Fusariosis In Key Nesting Beaches In Costa Rica, Keilor E. Cordero-Umaña, Ruth Hernando-Martínez, María Martínez-Ríos, Jaime Restrepo, Roldán A. Valverde, Laura Martín-Torrijos, Pilar Santidrián Tomillo, Javier Diéguez-Uribeondo

School of Earth, Environmental, & Marine Sciences Faculty Publications

The global rise of fungal pathogens presents an emerging threat to biodiversity, with significant risks to species such as endangered sea turtles. The fungal disease known as sea turtle egg fusariosis (STEF) is associated with high embryo mortality rates and represents a substantial conservation challenge. This disease is caused by two fungal species, namely Fusarium falciforme (Ff) and Fusarium keratoplasticum (Fk), and their identification is essential for guiding future efforts to address potential fungal infections, particularly on important nesting beaches such as those in Costa Rica. In this study, we conducted fungal isolations from sea turtle eggshells …

Examining The Presence And Effects Of Coherence And Fragmentation In The Gulf Of Maine Fishery Management Network, Derek A. Katznelson, Antonia Sohns, Dongkyu Kim, Evelyn Roozee, William Donner, Andrew M. Song, Jasper R. De Vries, Owen Temby, Gordon M. Hickey

School of Earth, Environmental, & Marine Sciences Faculty Publications

Natural resource management networks cohere due to mutual dependencies and fragment, in part, due to the perceived risks of interaction. However, research on these networks has tended to accept coherence a priori rather than problematizing dependence, and few studies exist on interorganizational risk perception. This article presents the results of a study operationalizing these concepts and measuring the distribution of three types of dependence (capital, legitimacy, and regulatory) and two types of perceived risk (performance and sanction) among nearly fifty stakeholder groups and organizations participating in the management of fisheries in the binational Gulf of Maine. The analysis reveals an …

Sulfate Sources In Groundwater From An Agricultural Area Central Illinois, Christabel I. Obi

Theses and Dissertations

Increasing sulfate (SO₄^2-) concentrations in the water environment, corresponding with increases in urbanization and industrialization, are a rising global concern. Over 250 mg/L, sulfate threatens human health and ecosystems. Elevated concentrations influence carbonate rock weathering, contributing to the evolution of the global carbon cycle. Knowledge of sulfate sources, whether natural or anthropogenic, is essential for understanding sulfate transport and fate in groundwater. This study investigates SO₄^2- origin and transport in groundwater in an area dominated by agricultural land use in Mclean County, Illinois. Specifically, we explored these questions: 1) Do sulfate concentrations change with groundwater …

Efficacy Of Stress Acclimation Techniques In Coastal Wetland Plants (Spartina Alterniflora And S. Patens): Implications For Restoration And Nursery Production, Taylor M. Sloey, Kylie D. Gieser, Kaitlyn Pounders, Sofía E. Báez, Jennifer L. Whytlaw

Biological Sciences Faculty Publications

The implementation of coastal nature-based features, created wetlands, and wetland restoration has increased globally over recent years. Many of these projects have been successful in meeting their goals, however, when projects fail, it is often attributed to mortality of transplanted vegetation. Transplant mortality may be due to inappropriate timing, poor site selection, or abiotic stressors associated with transplant shock. Science-backed guidelines have been well established in many coastal regions regarding site specifications and species selection, but nursery practices for reducing transplant shock remain inconsistent. In this study, we tested a combination of four salinity acclimation treatments and two inundation acclimation …

The Role Of Floodplain Complexity In Wood Turtle Habitat Use, Laura S. Deming

Antioch University Dissertations & Theses

Wood turtles occupy cold, low-gradient riverine habitat throughout the northeastern United State and southeastern Canada. Stream alterations, such as dams, channel straightening, and floodplain development have diminished the natural hydrologic and sedimentation regimes that result in complex channel and floodplain geomorphology. Studies throughout the species’ range have quantified many aspects of their habitat, but none have quantified components of geomorphology of wood turtle sites. The goal of this study was to explore the role of stream channel and floodplain geomorphology in wood turtle habitat use, with specific objectives to (1) quantify components of stream channel and floodplain geomorphic complexity, (2) …

Fluvial Geomorphic Resilience In Alluvial Mountain Rivers To Large Floods, Riley T. Henson

Graduate Student Theses, Dissertations, & Professional Papers

As hydroclimatic extremes intensify, large floods increasingly reshape river systems and threaten infrastructure. Fluvial geomorphic resilience, defined as a river’s resistance to, and recovery from, flood disturbance, offers a useful framework for understanding river response and guiding management. We assessed resilience at two scales: (1) a detailed geomorphic and hydraulic analysis of the June 2022 flood on East Rosebud Creek, Montana, which was part of broader flooding in the Greater Yellowstone Ecosystem, and (2) a broad-scale comparison of 12 flood-impacted alluvial mountain rivers across North America and Europe. We quantified resistance using active channel width ratios (W_R) and …

Investigating The Thermal Stratification Patterns Of A Shallow Polymictic Boreal Shield Lake And The Effectiveness Of Models In Predicting Shallow Lake Thermal Profiles, Matthew Roberts

Theses and Dissertations (Comprehensive)

Thermal stratification is a core process of lakes which plays a critical role in shaping the ecological dynamics of lakes, influencing major processes like nutrient cycling and oxygen availability. For shallow polymictic lakes, thermal stratification patterns present some unique differences due to the complex and variable nature of these lakes. In this thesis, I examined thermal stratification in a shallow polymictic lake in northwestern Ontario during the ice-free season of 2019 to investigate the frequency, duration, and driving factors of thermal stratification. The lake underwent 146 separate stratification events, with a median duration of 2 hours per event, with a …