Digital Commons Network^™

Validation Experiments On Finite Element Models Of An Ostrich (Struthio Camelus) Cranium, Andrew R. Cuff, Jen A. Bright, Emily J. Rayfield

School of Geosciences Faculty and Staff Publications

The first finite element (FE) validation of a complete avian cranium was performed on an extant palaeognath, the ostrich (Struthio camelus). Ex-vivo strains were collected from the cranial bone and rhamphotheca. These experimental strains were then compared to convergence tested, specimen-specific finite element (FE) models. The FE models contained segmented cortical and trabecular bone, sutures and the keratinous rhamphotheca as identified from micro-CT scan data. Each of these individual materials was assigned isotropic material properties either from the literature or from nanoindentation, and the FE models compared to the ex-vivo results. The FE models generally replicate the location …

Source-Specific Molecular Signatures For Light-Absorbing Organic Aerosols, Amanda Susan Willoughby

Chemistry & Biochemistry Theses & Dissertations

Organic aerosols (OA) are universally regarded as an important component of the atmosphere based on quantitative significance as well as the far-reaching impact they have on global climate forcing and human health. Despite the acknowledged importance, OA amounts and impacts remain the largest uncertainties regarding radiative forcing estimates. Incomplete chemical characterization of aerosol organic matter (OM) and a lack of concrete source apportionment is a major source of this uncertainty. The primary focus of this study is to provide much needed molecular details regarding ambient OA from key emission sources, and establish links between molecular and optical properties.

Complete chemical …

Synthesis Panel Presentation & Discussion, Ernie Estevez, Susan Bell, Shawn M. Landry, Aaron Brown, Lindsay Cross, Holly Greening

School of Geosciences Faculty and Staff Publications

No abstract provided.

Effects Of Aerial Exposure On Preservation Of Low-Temperature Calothrix Biosignatures In Silica Sinter From Queen's Laundry, Yellowstone National Park, Usa, Shana Kendall

Dissertations and Theses

Mineral-depositing hydrothermal ecosystems, such as the hot springs in Yellowstone National Park, provide an unparalleled opportunity to document how microbial biosignatures form and contribute to the body of evidence indicative of the microbial inhabitants of active hot springs. Mineralization of microbial communities in silica-depositing hot springs can result in the preservation of microbial biofacies in the geologic record. To determine the effects of prolonged aerial exposure on the preservation potential of mid-to-low temperature cyanobacteria dominated microbial communities that are typically permineralized in the siliceous sinter, modern biofacies samples of such communities were collected from the active and inactive parts of …

Using Fish Population Metrics To Compare The Effects Of Artificial Reef Density, Catheline Y. M. Froehlich, Richard Kline

School of Earth, Environmental, & Marine Sciences Faculty Publications

Artificial reefs continue to be added as habitat throughout the world, yet questions remain about how reef design affects fish diversity and abundance. In the present study, the effects of reef density were assessed for fish communities and sizes of economically valuable Lutjanus campechanus 13 km off Port Mansfield, Texas, at a reef composed of more than 4000 concrete culverts. The study spanned from May to June in 2013 and 2014, and sites sampled included natural reefs, bare areas, and varying culvert patch density categories, ranging from 1–190 culverts. Abundances of adults and species evenness of juvenile populations differed between …

Coastal Ice-Core Record Of Recent Northwest Greenland Temperature And Sea-Ice Concentration, Erich C. Osterberg, Robert L. Hawley, Gifford Wong, Ben Kopec, David Ferris, Jennifer Howley

Dartmouth Scholarship

Coastal ice cores provide an opportunity to investigate regional climate and sea-ice variability in the past to complement hemispheric-scale climate reconstructions from ice-sheet-interior ice cores. Here we describe robust proxies of Baffin Bay temperature and sea-ice concentration from the coastal 2Barrel ice core collected in the Thule region of northwest Greenland. Over the 1990–2010 record, 2Barrel annually averaged methanesulfonic acid (MSA) concentrations are significantly correlated with May–June Baffin Bay sea-ice concentrations and summer temperatures. Higher MSA is observed during warmer years with less sea ice, indicative of enhanced primary productivity in Baffin Bay. Similarly, 2Barrel annually averaged deuterium excess (d-excess) …

Crowdsourcing Global Wastewater Data, Don Mosteller, Sam Cohen, Cory Nestor, Angel Hsu, Omar Malik

Yale Day of Data

No time to waste: Crowdsourcing global wastewater treatment data

Worldwide, over 80 percent of wastewater is discharged into water bodies without undergoing treatment, severely impairing human well-being and ecosystem vitality along the way. National performance on wastewater treatment is difficult to quantify and is poorly understood due to a lack of common definitions, poor data collection standards, and limited historical data. To address this, the Yale Environmental Performance Index (EPI), a research group that produces a biennial ranking of country-level environmental performance, developed a first-of-its kind national wastewater treatment indicator.[1]

The indicator assesses wastewater treatment performance for 183 countries, …

A Multilevel Analysis Of Neighborhood Socioeconomic Effect On Preterm Births In Georgia, Usa, Wei Tu, Jun Tu, Stuart H. Tedders

Earth, Environment & Sustainability: Faculty Publications

This study estimates the neighborhood socioeconomic status (SES) effect on the risk of preterm birth (PTB) using multilevel regression (MLR) models. Birth data retrieved from year 2000 and 2010 Georgia Vital Records were linked to their respective census tracts. Principle component analysis (PCA) was performed on nine selected census variables and the first two principal components (Fac1 and Fac2) were used to represent the neighborhood-level SES in the MLR models. Two-level random intercept MLR models were specified using 122,744 and 112,578 live and singleton births at the individual level and 1613 and 1952 census tracts at the neighborhood level, for …

Development Of Enzymatic Biofuel Cell For Glucose Sensor Application, Ashar Turky Abd

Theses and Dissertations

For several decades, biological fuel cells have drawn significant attention as alternative power sources since they are environmentally friendly and less expensive, compared to the conventional noble metal-based fuel cells. Some enzymatic biocatalysts such as glucose dehydrogenase and glucose oxidase consume glucose as fuel, generating electric currents if paired with an oxygen reduction electrode. While microbial biofuel cells inevitably require a physical barrier or proton exchange membrane between anode and cathode, enzyme-based biofuel cells allow a membraneless or single compartment design, since enzymes are very selective on redox species. For example, glucose dehydrogenase oxidizes the glucose fuel only, while it …

A New Microenvironment For The Formation Of Clay Minerals: The Example Of Authigenic Halloysite-7Å And Gibbsite In A Stalactite From Agios Georgios Cave, Kilkis, North Greece, Elena Ifandi, Basilios Tsikouras, Dimitrios Papoulis, Konstantin Hatzipanagiotou, Aspasia Antonelou

International Journal of Speleology

An unusual authigenic origin for halloysite and gibbsite is reported in a stalactite from Agios Georgios Cave, Kilkis. This speleothem includes mostly pure calcite whereas minor areas of Mg-rich calcite and scarce dolomite are present in four growth phases. Abundant pores are created due to imperfect coalescence of the calcite crystals. Several of them contain detrital muscovite, which was presumably transferred from the dripping water, during the formation of speleothem and has been variably altered to halloysite. Several pores in the stalactite contain different mineral assemblages that we interpret as in situ: halloysite-7Å, halloysite + silica, gibbsite + silica and …

Homo Naledi, A New Species Of The Genus Homo From The Dinaledi Chamber, South Africa, Lee Berger, John Hawks, Darryl J. De Ruiter, Steve E. Churchill, Peter Schmid, Lucas Delezene, Tracy Kivell, Heather Garvin, Scott Williams, Jeremy Desilva

Dartmouth Scholarship

Homo naledi is a previously-unknown species of extinct hominin discovered within the Dinaledi Chamber of the Rising Star cave system, Cradle of Humankind, South Africa. This species is characterized by body mass and stature similar to small-bodied human populations but a small endocranial volume similar to australopiths. Cranial morphology of H. naledi is unique, but most similar to early Homo species including Homo erectus, Homo habilis or Homo rudolfensis. While primitive, the dentition is generally small and simple in occlusal morphology. H. naledi has humanlike manipulatory adaptations of the hand and wrist. It also exhibits a humanlike foot and lower …

Is Atmospheric Phosphorus Pollution Altering Global Alpine Lake Stoichiometry?, Janice Brahney, Natalie Mahowald, Daniel S. Ward, Ashley P. Ballantyne, Jason C. Neff

Ecosystem and Conservation Sciences Faculty Publications

Anthropogenic activities have significantly altered atmospheric chemistry and changed the global mobility of key macro-nutrients. Here we show that contemporary global patterns in nitrogen (N) and phosphorus (P) emissions drive large hemispheric variation in precipitation chemistry. These global patterns of nutrient emission and deposition (N:P) are in turn closely reflected in the water chemistry of naturally oligotrophic lake (r² = 0.81, p < 0.0001). Observed increases in anthropogenic N deposition play a role in nutrient concentrations (r² = 0.02, p < 0.05); however, atmospheric deposition of P appears to be major contributor to this pattern (r² = 0.65, p < 0.0001). Atmospheric simulations indicate a global increase in P deposition by 1.4 times the pre-industrial rate largely due to increased dust and biomass burning emissions. Although changes in the mass flux of global P deposition are smaller than for N, the impacts on primary productivity may be greater because, on average, one unit of increased P deposition has 16 times the influence of one unit of N deposition. These stoichiometric considerations, combined with the evidence presented here, suggest that increases in P deposition may be a major driver of alpine Lake trophic status, particularly in the Southern Hemisphere. These results underscore the need for the broader scientific community to consider the impact of atmospheric phosphorus deposition on the water quality of naturally oligotrophic lakes.

The Impact Of Climate Change On Select Ecosystems, Mary Snow, Richard Snow

Publications

Terrestrial and marine environments are experiencing pronounced changes. As species and their ecosystems undergo rising temperatures, varying precipitation patterns and alterations in their chemistry and phenology, there is a great deal of added stress on many organisms. Many species attempting to adapt to a rapidly changing climate are forced to migrate or to become extinct. Forest communities are changing in composition as well as migrating northward. Often, roads, cities, and other forms of development physically impede migration. Some species are not able to migrate at the pace with which their ecosystems are warming. In some forest communities, southern boundaries are …

Hydrogeologic Investigation Of A Pumice Aquifer, Fremont/Winema National Forest, Oregon, Jonathan Michael Weatherford

Dissertations and Theses

The middle Holocene cataclysmic eruption of Mount Mazama blanketed Walker Rim, in south central Oregon, with 270 cm to 300 cm of pumice, causing capture of surface water systems by groundwater, stream relocation, and the formation of biologically diverse fens and seasonal wetlands. The pumice aquifer at Round Meadow, an 8.6 km² basin, hosts both a fen and seasonally ponded wetlands. The Round Meadow watershed lies within a closed basin between the upper Klamath and Deschutes river basins. As the highest meadow at Walker Rim, it is a relatively well-constrained system to study the effects of hydrological disruption.

A …

Ua24 Mcicsl Newsletter - September 2015, Shannon R. Trimboli Education Coordinator

MCICSL Newsletter

This issue includes the following:

Citizen Scientists Contribute Over $46,700 of Labor to Mammoth Cave National Park

Federal Agencies Directed to Advance Citizen Science

as well as education and research highlights,and MCICSL strategic planning.

Hydrological Partitioning In The Critical Zone: Recent Advances And Opportunities For Developing Transferable Understanding Of Water Cycle Dynamics, Paul D. Brooks, Jon Chorover, Ying Fan, Sarah E. Godsey, Reed M. Maxwell, James P. Mcnamara, Christina Tague

Geosciences Faculty Publications and Presentations

Hydrology is an integrative discipline linking the broad array of water-related research with physical, ecological, and social sciences. The increasing breadth of hydrological research, often where subdisciplines of hydrology partner with related sciences, reflects the central importance of water to environmental science, while highlighting the fractured nature of the discipline itself. This lack of coordination among hydrologic subdisciplines has hindered the development of hydrologic theory and integrated models capable of predicting hydrologic partitioning across time and space. The recent development of the concept of the critical zone (CZ), an open system extending from the top of the canopy to the …

Finite Element Modelling Predicts Changes In Joint Shape And Cell Behaviour Due To Loss Of Muscle Strain In Jaw Development, Lucy H. Brunt, Joanna L. Norton, Jen A. Bright, Emily J. Rayfield, Chrissy L. Hammond

School of Geosciences Faculty and Staff Publications

Abnormal joint morphogenesis is linked to clinical conditions such as Developmental Dysplasia of the Hip (DDH) and to osteoarthritis (OA). Muscle activity is known to be important during the developmental process of joint morphogenesis. However, less is known about how this mechanical stimulus affects the behaviour of joint cells to generate altered morphology. Using zebrafish, in which we can image all joint musculoskeletal tissues at high resolution, we show that removal of muscle activity through anaesthetisation or genetic manipulation causes a change to the shape of the joint between the Meckel's cartilage and Palatoquadrate (the jaw joint), such that the …

Small Phytoplankton Drive High Summertime Carbonand Nutrient Export In The Gulf Of California And Eastern Tropical North Pacific, Viena Puigcorbé, Claudia R. Benitez-Nelson, Pere Masqué, Elisabet Verdeny, Angelicque E. White, Brian N. Popp, Fredrick G. Prahl, Phoebe J. Lam

Faculty Publications

Summertime carbon, nitrogen, and biogenic silica export was examined using 234Th:238U disequilibria combined with free floating sediment traps and fine scale water column sampling with in situ pumps (ISP) within the Eastern Tropical North Pacific and the Gulf of California. Fine scale ISP sampling provides evidence that in this system, particulate carbon (PC) and particulate nitrogen (PN) concentrations were more rapidly attenuated relative to 234Th activities in small particles compared to large particles, converging to 1–5 µmol dpm−1 by 100 m. Comparison of elemental particle composition, coupled with particle size distribution analysis, suggests that small particles are major contributors to …

The Science And Practice Of River Restoration, Ellen E. Wohl, Stuart N. Lane, Andrew C. Wilcox

Geosciences Faculty Publications

River restoration is one of the most prominent areas of applied water-resources science. From an initial focus on enhancing fish habitat or river appearance, primarily through structural modification of channel form, restoration has expanded to incorporate a wide variety of management activities designed to enhance river process and form. Restoration is conducted on headwater streams, large lowland rivers, and entire river networks in urban, agricultural, and less intensively human-altered environments. We critically examine how contemporary practitioners approach river restoration and challenges for implementing restoration, which include clearly identified objectives, holistic understanding of rivers as ecosystems, and the role of restoration …

Large-Scale And High-Resolution 3-D Cave Mapping By Terrestrial Laser Scanning: A Case Study Of The Domica Cave, Slovakia, Michal Gallay, Ján Kaňuk, Zdenko Hochmuth, John D. Meneely, Jaroslav Hofierka, Vladimír Sedlák

International Journal of Speleology

Mapping and modelling the complicated geometry of caves is a challenging task that has traditionally been undertaken by tacheometric surveying methods. These methods are excellent for capturing the general shape of a cave system but they are not suitable for high-speed, high-resolution mapping of complex surfaces found in this environment. Terrestrial laser scanning (TLS) technologies can acquire millions of points represented by 3-D coordinates, at very high spatial densities on complex multifaceted surfaces within minutes. In the last few years, advances in measurement speed, reduction in size / cost and increased portability of this technology has revolutionised the collection of …

Is Atmospheric Phosphorus Pollution Altering Global Alpine Lake Stoichiometry?, Janice Brahney, Natalie Mahowald, Daniel S. Ward, Ashley P. Ballantyne, Jason C. Neff

Watershed Sciences Faculty Publications

Anthropogenic activities have significantly altered atmospheric chemistry and changed the global mobility of key macronutrients. Here we show that contemporary global patterns in nitrogen (N) and phosphorus (P) emissions drive large hemispheric variation in precipitation chemistry. These global patterns of nutrient emission and deposition (N:P) are in turn closely reflected in the water chemistry of naturally oligotrophic lakes (r2 = 0.81, p < 0.0001). Observed increases in anthropogenic N deposition play a role in nutrient concentrations (r2 = 0.20, p < 0.05); however, atmospheric deposition of P appears to be major contributor to this pattern (r2 = 0.65, p < 0.0001). Atmospheric simulations indicate a global increase in P deposition by 1.4 times the preindustrial rate largely due to increased dust and biomass burning emissions. Although changes in the mass flux of global P deposition are smaller than for N, the impacts on primary productivity may be greater because, on average, one unit of increased P deposition has 16 times the influence of one unit of N deposition. These stoichiometric considerations, combined with the evidence presented here, suggest that increases in P deposition may be a major driver of alpine Lake trophic status, particularly in the Southern Hemisphere. These results underscore the need for the broader scientific community to consider the impact of atmospheric phosphorus deposition on the water quality of naturally oligotrophic lakes.

Comparative Sorption Of Methylene Blue Onto Hydrophobic Clays, Alvaro D. Sponza, Natalia J. Fernandez, David Yang, Karla A. Ortiz, Abel E. Navarro

Publications and Research

Chemical modifications of clay to remove methylene blue (MB) from aqueous solutions at room temperature were compared. Natural bentonite (NC) was modified by cation exchange with hexadecyltrimethylammonium chloride (HC), bencyltriethylammonium chloride (BC), and tetramethylammonium chloride (TC) to reverse the surface polarity of the hydrophilic bentonite. The adsorption of MB was studied and fitted by the adsorption theories of Langmuir, Freundlich, Dubinin-Radushkevich, and Temkin. Equilibrium parameters were calculated, indicating that chemical modification did not improve the adsorption, due to the electrostatic adsorption mechanism. Specific surface area was determined, reporting the following trend: NC > TC > BC > HC. Isotherms show that TC is …

Predicting Landscape-Scale Co 2 Flux At A Pasture And Rice Paddy With Long-Term Hyperspectral Canopy Reflectance Measurements, J. H. Matthes, S. H. Knox, C. Sturtevant, O. Sonnentag

Dartmouth Scholarship

Measurements of hyperspectral canopy reflectance provide a detailed snapshot of information regarding canopy biochemistry, structure and physiology. In this study, we collected 5 years of repeated canopy hyperspectral reflectance measurements for a total of over 100 site visits within the flux footprints of two eddy covariance towers at a pasture and rice paddy in northern California. The vegetation at both sites exhibited dynamic phenology, with significant interannual variability in the timing of seasonal patterns that propagated into interannual variability in measured hyperspectral reflectance. We used partial least-squares regression (PLSR) modeling to leverage the information contained within the entire canopy reflectance …

Biogeochemical Studies Of Metal Uptake And Transportation In Plants On An Urban Brownfield, Yu Qian

Theses, Dissertations and Culminating Projects

Soil metal contamination has been a concern due to the potential ecological and human health risks. In order to assist with the management and sustainable restoration of vegetated metal contaminated land, this dissertation targets at understanding the biogeochemical processes that control the assimilation of metals by plants on urban costal brownfield soils. The dissertation includes: i) micro-scale measurement of metal spatial distribution and speciation using synchrotron techniques to investigate the mechanism of metal uptake and translocation in roots based on the association between metal localizations in plant roots, ii) study on the biogeochemical factors that control plant metal assimilation efficiency …

Changes In Tall Shrub Abundance On The North Slope Of Alaska, 2000-2010, Rocio Raquel Duchesne-Onoro

Theses, Dissertations and Culminating Projects

The observed greening of Arctic vegetation and the expansion of shrubs in the last few decades has likely had profound implications for the tundra ecosystem, including feedbacks to climate. Uncertainty surrounding the magnitude, direction, and implications of this vegetation shift calls for monitoring of vegetation structural parameters, such as fractional cover of shrubs. Due to the extent of the North Slope of Alaska and its extreme environments, remote sensing may be the most suitable tool to produce wall-to-wall fractional shrub cover maps for the entire region, however, most regional maps have relied on vegetation indices or needed many years worth …

Geological Controls On Stratigraphy And Sedimentation Of The Mississippian Marshall Formation, Michigan Basin, U.S.A., Joseph G. Adducci

Masters Theses

An understanding of regional orogenic, climatic, and eustatic processes is critical to the interbasinal correlation of Paleozoic strata in eastern North America. Tectonic activity associated with the culmination of Appalachian Orogenic events has been shown to have regional influence on paleostructure and sediment dispersal in the Appalachian foreland basin and adjacent intracratonic Illinois and Michigan basins. The culmination of the Acadian Orogeny at the end of the Devonian represents the beginning of a period of general tectonic quiescence extending throughout the early and middle Mississippian in eastern North America. Early Mississippian strata in the Michigan basin is distinctive and marks …

Biogeochemical Processes In Hydrosoil Of Pilot-Scale Constructed Wetland Treatment Systems Designed For Treatment Of Selenium, Christina Blaszkiewicz

All Theses

Two pilot-scale wetland treatment system cells (nutrient amended and unamended) were designed and constructed to reduce aqueous Se concentrations in simulated energy-derived water. Specific objectives of this study were: (i) measure and correlate hydrosoil conditions with Se concentrations vertically through the hydrosoil; (ii) investigate Se-accumulating biogeochemical processes (dissimilatory Se reduction and sorption) operating in the hydrosoil; and (iii) evaluate the effect of a nutrient amendment on hydrosoil conditions, Se accumulation, and Se-sequestering biogeochemical processes in the hydrosoil. Se accumulation (i.e. total Se concentration) and hydrosoil conditions were measured with depth in the hydrosoil. Se-sequestering biogeochemical processes were investigated by counting …

Ecology And Morphology Of The Late Miocene Musk Deer, Longirostromeryx Wellsi (Artiodactyla: Moschidae: Blastomerycinae), Katheryn Y. C. Chen

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

Longirostromeryx wellsi, one of the latest surviving members of the extinct clade Blastomerycinae (Artiodactyla: Moschidae), possesses highly derived craniodental morphology that deviates from typical musk deer form. Previous work suggests that the unique anatomy of L. wellsi represents adaptations for occupying open savannas. To test this hypothesis I conduct principal components analysis on five postcranial bones of L. wellsi, comparing them to that of several extant ruminant artiodactyls, which are divided among seven habitat categories. These elements are also compared with the postcrania of other blastomerycines. These analyses indicate that L. wellsi anatomy is most similar to that of other …

Stable Isotopes Reveal A Disconnect Between Biotic And Abiotic Hydrological Processes In A Seasonally-Dry, Semi-Arid Watershed, Ryan James Mccutcheon

Boise State University Theses and Dissertations

Until recently, it had been thought that humid catchment woody plants transpired primarily mobile soil water that would otherwise flow to streams or recharge groundwater. However, several recent studies have suggested that trees in seasonally-dry humid catchments use primarily tightly-bound, immobile soil water that does not fully mix with new precipitation or participate in translatory flow. McDonnell (2014) called this existence of two, hydrologically-distinct, water pools “the two water worlds hypothesis.” This ecohydrological behavior has important implications for understanding a wide range of catchment processes, including the spatial and temporal variability of evapotranspiration and nutrient cycling, and our abilities to …

Stable Isotope Analysis Of Bison Latifrons And Paleoecological Inferences, Fabian Ceron Hardy

UNLV Theses, Dissertations, Professional Papers, and Capstones

Bison latifrons was a large Pleistocene herbivore that is traditionally hypothesized to have been adapted to living in forest openings and woodlands. According to this view, the species was primarily a browser of high-growing, woody plants. Very little isotopic work has been conducted on this species, and there have been no prior studies of high altitude localities containing this species. This study aims to address both of these issues.

B. latifrons is known from sites in several states, including California, Idaho, Colorado, Nevada, and Florida, among others. These sites provide diverse examples of this species’ habitat and the opportunity to …